Obscuring time of smokescreen is an important parameter, and diffusion coefficient is a crucial parameter to the obscuring time of smokescreen. The relational equation that effective obscuring area of smoke changes wi...Obscuring time of smokescreen is an important parameter, and diffusion coefficient is a crucial parameter to the obscuring time of smokescreen. The relational equation that effective obscuring area of smoke changes with diffusion co- efficient and diffusing time was derived. And based on experimental data, the parabolas that the area changes with time are drawn, and the relation between diffusion coefficient and obscuring time of smoke-screen is analyzed. Diffusion coefficients of smoke cloud in the infrared (IR) and in the visible light are compared with, the two-phase flow character of aerosol particle is found while diffusing in the two wavebands. And their differences are analyzed in detail.展开更多
Activated carbon/nanosized CdS/chitosan(AC/n-CdS/CS) composites as adsorbent and photoactive catalyst were prepared under low temperature(≤60 ℃) and ambient pressure.Methyl orange(MO) was chosen as a model pollutant...Activated carbon/nanosized CdS/chitosan(AC/n-CdS/CS) composites as adsorbent and photoactive catalyst were prepared under low temperature(≤60 ℃) and ambient pressure.Methyl orange(MO) was chosen as a model pollutant to evaluate synergistic effect of adsorption and photocatalytic decolorization by this innovative photocatalyst under visible light irradiation.Effects of various parameters such as catalyst amount,initial MO concentration,solution pH and reuse of catalyst on the decolorization of MO were investigated to optimize operational conditions.The decolorization of MO catalyzed by AC/n-CdS/CS fits the Langmuir-Hinshelwood kinetics model,and a surface reaction,where the dyes are absorbed,is the controlling step of the process.Decolorization efficiency of MO is improved with the increase in catalyst amount within a certain range.The photodecolorization of MO is more efficient in acidic media than alkaline media.The decolorization efficiency of MO is still higher than 84% after five cycles and 60 min under visible light irradiation,which confirms the reusability of AC/n-CdS/CS composite catalyst.展开更多
The role of oxygen and the generation of active radicals in the photocatalitic degradation of phenol were investigated using the eosin sensitized TiO2 as photocatalyst under visible light irradiation. Diffuse reflecta...The role of oxygen and the generation of active radicals in the photocatalitic degradation of phenol were investigated using the eosin sensitized TiO2 as photocatalyst under visible light irradiation. Diffuse reflectance spectra show that the absorbancy range of eosin/TiO2 is expanded from 378 nm (TiO2 ) to about 600 nm. The photocatalitic degradation of phenol is almost stopped when the eosin/TiO2 system is saturated with N2 , which indicates the significance of O2 . The addition of NaN 3 (a quencher of single oxygen) causes about a 62% decrease in the phenol degradation. The phenol degradation ratio is dropped from 92% to 75% when the isopropanol (a quencher of hydroxyl radical) is present in the system. The experimental results show that there are singlet oxygen and hydroxyl radical generated in the eosin/TiO2 system under visible light irradiation. The changes of absorbancy indicate that the hydrogen peroxide might be produced. Through the analysis and comparison, it is found that the singlet oxygen is the predominant active radical for the degradation of phenol.展开更多
The ultraviolet-visible light spectrophotometer method was adopted to determine thioglucoside in cabbage with the seeds.Individual plant of cabbage was used as test materials,palladium chloride as complexing agent and...The ultraviolet-visible light spectrophotometer method was adopted to determine thioglucoside in cabbage with the seeds.Individual plant of cabbage was used as test materials,palladium chloride as complexing agent and sodium cellulose glycolate as dispersing agent.The results showed that palladiumd thioglucoside method could be taken as a quick,easy and precise quantitative analysis method to determine thioglucoside in cabbage.展开更多
在室内可见光通信中符号间干扰和噪声会严重影响系统性能,K均值(K-means)均衡方法可以抑制光无线信道的影响,但其复杂度较高,且在聚类边界处易出现误判。提出了改进聚类中心点的K-means(Improved Center K-means,IC-Kmeans)算法,通过随...在室内可见光通信中符号间干扰和噪声会严重影响系统性能,K均值(K-means)均衡方法可以抑制光无线信道的影响,但其复杂度较高,且在聚类边界处易出现误判。提出了改进聚类中心点的K-means(Improved Center K-means,IC-Kmeans)算法,通过随机生成足够长的训练序列,然后将训练序列每一簇的均值作为K-means聚类中心,避免了传统K-means反复迭代寻找聚类中心。进一步,提出了基于神经网络的IC-Kmeans(Neural Network Based IC-Kmeans,NNIC-Kmeans)算法,使用反向传播神经网络将接收端二维数据映射至三维空间,以增加不同簇之间混合数据的距离,提高了分类准确性。蒙特卡罗误码率仿真表明,IC-Kmeans均衡和传统K-means算法的误码率性能相当,但可以显著降低复杂度,特别是在信噪比较小时。同时,在室内多径信道模型下,与IC-Kmeans和传统Kmeans均衡相比,NNIC-Kmeans均衡的光正交频分复用系统误码率性能最好。展开更多
建立了一种在温和条件下,通过可见光催化合成一系列N-芳基吲哚类化合物的方法。该方法在室温条件下,以邻烯基苯胺和重氨萘酮为模板底物,以曙红Y作为光催化剂,在40 W 460 nm的蓝色LED灯照射下,合成一系列N-芳基吲哚衍生物,最高产率可达到...建立了一种在温和条件下,通过可见光催化合成一系列N-芳基吲哚类化合物的方法。该方法在室温条件下,以邻烯基苯胺和重氨萘酮为模板底物,以曙红Y作为光催化剂,在40 W 460 nm的蓝色LED灯照射下,合成一系列N-芳基吲哚衍生物,最高产率可达到74%。该合成路径具有底物适用范围广、经济实用等特点,为N-芳基吲哚衍生物合成提供了一种经济简便的方法。展开更多
【目的】针对极限学习机(ELM)神经网络在室内可见光定位(VLP)中收敛不稳定,易陷入局部最优状态,导致定位精度降低的问题,文章引入了麻雀搜索算法(SSA)确定ELM神经网络的初始权值和阈值,提出了SSA-ELM神经网络算法。【方法】首先,采集定...【目的】针对极限学习机(ELM)神经网络在室内可见光定位(VLP)中收敛不稳定,易陷入局部最优状态,导致定位精度降低的问题,文章引入了麻雀搜索算法(SSA)确定ELM神经网络的初始权值和阈值,提出了SSA-ELM神经网络算法。【方法】首先,采集定位区域内接收信号强度(RSS)与位置信息作为指纹数据;然后,训练SSA-ELM神经网络并得到预测模型,将测试集数据输入预测模型得到待测位置的定位结果;最后,设计了仿真实验和测试平台。【结果】仿真表明,在立体空间模型中0、0.3、0.6和0.9 m 4个接收高度,平均误差分别为1.73、1.86、2.18和3.47 cm,与反向传播(BP)、SSA-BP和ELM定位算法相比,SSA-ELM神经网络算法定位精度分别提高了83.55%、45.71%和26.26%,定位时间分别降低了36.48%、17.69%和6.61%。实验测试表明,文章所提SSA-ELM神经网络算法的平均定位误差为3.75 cm,比未优化的ELM神经网络定位精度提高了16.38%。【结论】SSA对ELM神经网络具有明显的优化作用,能够显著降低定位误差,减少定位时间。展开更多
建立了一种在温和条件下,用可见光催化合成一系列3,4-二氢异喹啉-1(2H)-酮及其衍生物的方法。该方法在室温条件下,以2-烯丙基-N-甲氧基苯甲酰胺为模板底物,以碘化钾作为光催化剂,25 W 460 nm的蓝色LED灯照射下,合成一系列3,4-二氢异喹啉...建立了一种在温和条件下,用可见光催化合成一系列3,4-二氢异喹啉-1(2H)-酮及其衍生物的方法。该方法在室温条件下,以2-烯丙基-N-甲氧基苯甲酰胺为模板底物,以碘化钾作为光催化剂,25 W 460 nm的蓝色LED灯照射下,合成一系列3,4-二氢异喹啉-1(2H)-酮衍生物,最高产率可达到83%。该合成路径具有底物适用范围广、经济实用等特点,为3,4-二氢异喹啉-1(2H)-酮衍生物合成提供了一种经济简便的方法。展开更多
文摘Obscuring time of smokescreen is an important parameter, and diffusion coefficient is a crucial parameter to the obscuring time of smokescreen. The relational equation that effective obscuring area of smoke changes with diffusion co- efficient and diffusing time was derived. And based on experimental data, the parabolas that the area changes with time are drawn, and the relation between diffusion coefficient and obscuring time of smoke-screen is analyzed. Diffusion coefficients of smoke cloud in the infrared (IR) and in the visible light are compared with, the two-phase flow character of aerosol particle is found while diffusing in the two wavebands. And their differences are analyzed in detail.
基金Project(21007044) supported by the National Natural Science Foundation of ChinaProject(20050532009) supported by the Doctoral Foundation of Ministry of Education of China
文摘Activated carbon/nanosized CdS/chitosan(AC/n-CdS/CS) composites as adsorbent and photoactive catalyst were prepared under low temperature(≤60 ℃) and ambient pressure.Methyl orange(MO) was chosen as a model pollutant to evaluate synergistic effect of adsorption and photocatalytic decolorization by this innovative photocatalyst under visible light irradiation.Effects of various parameters such as catalyst amount,initial MO concentration,solution pH and reuse of catalyst on the decolorization of MO were investigated to optimize operational conditions.The decolorization of MO catalyzed by AC/n-CdS/CS fits the Langmuir-Hinshelwood kinetics model,and a surface reaction,where the dyes are absorbed,is the controlling step of the process.Decolorization efficiency of MO is improved with the increase in catalyst amount within a certain range.The photodecolorization of MO is more efficient in acidic media than alkaline media.The decolorization efficiency of MO is still higher than 84% after five cycles and 60 min under visible light irradiation,which confirms the reusability of AC/n-CdS/CS composite catalyst.
基金Project(8451063201001261) supported by the Guangdong Natural Science Fund Committee,ChinaProject(LYM08022) supported by the Foundation for Distinguished Young Talents in Higher Education of Guangdong,China+1 种基金Project (2007A032400001, 2008A030202010) supported by the Scientific and Technological Planning of Guangdong Province,ChinaProject(216113132) supported by the Scientific Research Cultivation and Innovation Fund, Jinan University,China
文摘The role of oxygen and the generation of active radicals in the photocatalitic degradation of phenol were investigated using the eosin sensitized TiO2 as photocatalyst under visible light irradiation. Diffuse reflectance spectra show that the absorbancy range of eosin/TiO2 is expanded from 378 nm (TiO2 ) to about 600 nm. The photocatalitic degradation of phenol is almost stopped when the eosin/TiO2 system is saturated with N2 , which indicates the significance of O2 . The addition of NaN 3 (a quencher of single oxygen) causes about a 62% decrease in the phenol degradation. The phenol degradation ratio is dropped from 92% to 75% when the isopropanol (a quencher of hydroxyl radical) is present in the system. The experimental results show that there are singlet oxygen and hydroxyl radical generated in the eosin/TiO2 system under visible light irradiation. The changes of absorbancy indicate that the hydrogen peroxide might be produced. Through the analysis and comparison, it is found that the singlet oxygen is the predominant active radical for the degradation of phenol.
文摘The ultraviolet-visible light spectrophotometer method was adopted to determine thioglucoside in cabbage with the seeds.Individual plant of cabbage was used as test materials,palladium chloride as complexing agent and sodium cellulose glycolate as dispersing agent.The results showed that palladiumd thioglucoside method could be taken as a quick,easy and precise quantitative analysis method to determine thioglucoside in cabbage.
文摘在室内可见光通信中符号间干扰和噪声会严重影响系统性能,K均值(K-means)均衡方法可以抑制光无线信道的影响,但其复杂度较高,且在聚类边界处易出现误判。提出了改进聚类中心点的K-means(Improved Center K-means,IC-Kmeans)算法,通过随机生成足够长的训练序列,然后将训练序列每一簇的均值作为K-means聚类中心,避免了传统K-means反复迭代寻找聚类中心。进一步,提出了基于神经网络的IC-Kmeans(Neural Network Based IC-Kmeans,NNIC-Kmeans)算法,使用反向传播神经网络将接收端二维数据映射至三维空间,以增加不同簇之间混合数据的距离,提高了分类准确性。蒙特卡罗误码率仿真表明,IC-Kmeans均衡和传统K-means算法的误码率性能相当,但可以显著降低复杂度,特别是在信噪比较小时。同时,在室内多径信道模型下,与IC-Kmeans和传统Kmeans均衡相比,NNIC-Kmeans均衡的光正交频分复用系统误码率性能最好。
文摘建立了一种在温和条件下,通过可见光催化合成一系列N-芳基吲哚类化合物的方法。该方法在室温条件下,以邻烯基苯胺和重氨萘酮为模板底物,以曙红Y作为光催化剂,在40 W 460 nm的蓝色LED灯照射下,合成一系列N-芳基吲哚衍生物,最高产率可达到74%。该合成路径具有底物适用范围广、经济实用等特点,为N-芳基吲哚衍生物合成提供了一种经济简便的方法。
文摘【目的】针对极限学习机(ELM)神经网络在室内可见光定位(VLP)中收敛不稳定,易陷入局部最优状态,导致定位精度降低的问题,文章引入了麻雀搜索算法(SSA)确定ELM神经网络的初始权值和阈值,提出了SSA-ELM神经网络算法。【方法】首先,采集定位区域内接收信号强度(RSS)与位置信息作为指纹数据;然后,训练SSA-ELM神经网络并得到预测模型,将测试集数据输入预测模型得到待测位置的定位结果;最后,设计了仿真实验和测试平台。【结果】仿真表明,在立体空间模型中0、0.3、0.6和0.9 m 4个接收高度,平均误差分别为1.73、1.86、2.18和3.47 cm,与反向传播(BP)、SSA-BP和ELM定位算法相比,SSA-ELM神经网络算法定位精度分别提高了83.55%、45.71%和26.26%,定位时间分别降低了36.48%、17.69%和6.61%。实验测试表明,文章所提SSA-ELM神经网络算法的平均定位误差为3.75 cm,比未优化的ELM神经网络定位精度提高了16.38%。【结论】SSA对ELM神经网络具有明显的优化作用,能够显著降低定位误差,减少定位时间。
文摘建立了一种在温和条件下,用可见光催化合成一系列3,4-二氢异喹啉-1(2H)-酮及其衍生物的方法。该方法在室温条件下,以2-烯丙基-N-甲氧基苯甲酰胺为模板底物,以碘化钾作为光催化剂,25 W 460 nm的蓝色LED灯照射下,合成一系列3,4-二氢异喹啉-1(2H)-酮衍生物,最高产率可达到83%。该合成路径具有底物适用范围广、经济实用等特点,为3,4-二氢异喹啉-1(2H)-酮衍生物合成提供了一种经济简便的方法。
