Soil cadmium(Cd)contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils...Soil cadmium(Cd)contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils,vegetables and paddy rice were investigated,and potential non-carcinogenic and carcinogenic health risks exposure to Cd were estimated at six villages around the Dabaoshan Mine,South China.A total of 87 soil samples were found to exceed the China's maximum permission level(MPL)for Cd,while the highest value of 4.42 mg/kg was found near irrigation ditch associated with Hengshi River in Xinyi(XY)Village.Cd contents in vegetables and rice exceeded the maximum permissible concentration by more than five times in every village.Cadmium accumulation in plants is in the order of celery>lactuca sativa L>Chinese cabbage>Romaine lettuce>asparagus lettuce>mustard>cabbage mustard>cabbage.The mean hazard quotient(HQ)of all villages is in the range of [5.29,25.75],and the mean values of cancer risk for investigated areas are more than 10 times greater than the USEPA(2009)threshold limit value of 10-4.Moreover,human non-carcinogenic and carcinogenic risks are mainly attributable to paddy rice intake,followed by vegetables intake,soil ingestion,inhalation,and dermal contact.The results indicate that Cd has a huge potential risk on human health for the local residents.展开更多
The cold chain in the production area of fruits and vegetables is the primary link to reduce product loss and improve product quality,but it is also a weak link.With the application of big data technology in cold chai...The cold chain in the production area of fruits and vegetables is the primary link to reduce product loss and improve product quality,but it is also a weak link.With the application of big data technology in cold chain logistics,intelligent devices,and technologies have become important carriers for improving the efficiency of cold chain logistics in fruit and vegetable production areas,extending the shelf life of fruits and vegetables,and reducing fruit and vegetable losses.They have many advantages in fruit and vegetable pre-cooling,sorting and packaging,testing,warehousing,transportation,and other aspects.This article summarizes the rapidly developing and widely used intelligent technologies at home and abroad in recent years,including automated guided vehicle intelligent handling based on electromagnetic or optical technology,intelligent sorting based on sensors,electronic optics,and other technologies,intelligent detection based on computer vision technology,intelligent transportation based on perspective imaging technology,etc.It analyses and studies the innovative research and achievements of various scholars in applying intelligent technology in fruit and vegetable cold chain storage,sorting,detection,transportation,and other links,and improves the efficiency of fruit and vegetable cold chain logistics.However,applying intelligent technology in fruit and vegetable cold chain logistics also faces many problems.The challenges of high cost,difficulty in technological integration,and talent shortages have limited the development of intelligent technology in the field of fruit and vegetable cold chains.To solve the current problems,it is proposed that costs be controlled through independent research and development,technological innovation,and other means to lower the entry threshold for small enterprises.Strengthen integrating intelligent technology and cold chain logistics systems to improve data security and system compatibility.At the same time,the government should introduce relevant policies,provide necessary financial support,and establish talent training mechanisms.Accelerate the development and improvement of intelligent technology standards in the field of cold chain logistics.Through technological innovation,cost control,talent cultivation,and policy guidance,we aim to promote the upgrading of the agricultural industry and provide ideas for improving the quality and efficiency of fruit and vegetable cold chain logistics.展开更多
The list of underutilized green leafy vegetables is enormous: ranging from commonly consumed and underutilized vegetables. There are data on commonly consumed vegetables, but information is sparse on nutritional, chem...The list of underutilized green leafy vegetables is enormous: ranging from commonly consumed and underutilized vegetables. There are data on commonly consumed vegetables, but information is sparse on nutritional, chemical and anti-nutritional properties of less explored vegetables. This work aimed to evaluate some attributes of less explored or underutilized leafy vegetables. Some nutritional and anti-nutritional contents of 10 under-utilized leafy vegetables(Amaranthus spinosus Linnaeus, Basella alba Linnaeus, Corchorous tridens L., Cyrtosperma senegalense(Schott), Erigeron floribundus Sch, Hoslundia opposita Vahl, Lagenaria siceraria(Molina) Standl, Ocimum basilicum L., Solanum aethiopicum L. and Talinum portulacifolium(Forssk.) Asch. ex Schweinf) were investigated. Cyrtosperma senegalense had the highest protein value(5.93%). Hoslundia opposita had the highest fat content(0.54%). Amaranthus spinosus was high in β-carotene content(346.3 mg · 100 g-1); Cyrtosperma senegalense had the highest moisture content. A. spinosus had the highest ascorbic acid content(108.1 mg · 100 g-1). The highest tannin level(0.0057%) was found in C. senegalense and the lowest(0.0003%) was found in Solanum aethiopicum. Saponin was the highest in C. tridens(0.0052%) and the lowest in T. portulacifolium(0.00014%). C. senegalense and S. aethiopicum had their highest and the lowest phytate values, respectively. Although anti-nutrients could interfere with nutrient utilization, their values in these vegetables were not at toxic levels.展开更多
The paper is to study the main co-extractions existing in multiresidue analysis of pesticides in vegetables.For this,extracted 10 vegetable and analyzed the extractions with GC-MS.Compared the spectra of those co-extr...The paper is to study the main co-extractions existing in multiresidue analysis of pesticides in vegetables.For this,extracted 10 vegetable and analyzed the extractions with GC-MS.Compared the spectra of those co-extractions in different vegetables,confirm the main co-extractions of vegetables.The result shows the co-extractions are same including pigment,phenols,fat acids,lipin and steroid.But the mass of those co-extractions in different vegetable is different.The study result is help for the development of pesticide residue method.展开更多
To establish a new GC-MS/MS method for quantitative detection of 22 kinds of pesticide in fruit and vegetable including organic phosphorus,carbamate & pyrethrin etc.Working was performed by Xcalibur software with ...To establish a new GC-MS/MS method for quantitative detection of 22 kinds of pesticide in fruit and vegetable including organic phosphorus,carbamate & pyrethrin etc.Working was performed by Xcalibur software with multitask mode.We Carried on qualitative and quantitative analysis to mass spectrum of MS/MS in order to obtained a credible experiment result.This method is sensitive and accurate,it is suitable for determination of multifarious pesticide residues.展开更多
A direct determination method for the atrazine residue on the vegetable was developed by using desorption electrospray ionization mass spectrometry (DESI MS) without any sample pretreatment.Acetonitrile-water (1:1,v/v...A direct determination method for the atrazine residue on the vegetable was developed by using desorption electrospray ionization mass spectrometry (DESI MS) without any sample pretreatment.Acetonitrile-water (1:1,v/v),which contained 0.1% formic acid,was used as the spray solvent.The working conditions,such as ESI gas inlet pressure,ESI flow rate,ESI spray voltage,spray-to-sample distance,spray-to-cone-hole distance and the collision induced dissociation (CID) voltage for MS/MS,were optimized for both DESI and esquires 6 000 mass spectrometer.The linear range of atrazine on cabbage leaves was 25.25-2 525 pg/mm2,the R2 was 0.991 6,and the relative standard deviations were between 3.37% and 26.17%.The LOD of atrazine calculated by S/N=3 was 2.50 pg/mm2.展开更多
A new method was developed for the simultaneous analysis of 12 pesticide residues in onion and fennel by gas chromatography(GC)-triple quadrupole mass spectrometry(MS/MS)-electron impact ion source(EI)-select reaction...A new method was developed for the simultaneous analysis of 12 pesticide residues in onion and fennel by gas chromatography(GC)-triple quadrupole mass spectrometry(MS/MS)-electron impact ion source(EI)-select reaction monitoring mode(SRM).The 12 pesticide includes fungicide,acaricide,carbamate and plant growth regulator pesticide.The complicated matrix samples of onion and fennel were extracted by acetonitrile,cleaned up by solid phase extraction of Carb/PSA.By optimizing the GC-MS/MS-SRM parameters,the interference from clean-up procedure was further removed and 12 pesticide residues were determined accurately.The average recoveries for most pesticides(at the spiked level of 0.05-0.20 mg/kg) were between 114%-156%,the relative standard deviation(RSD) of the method was less than 20%,and the limit of detection were 0.5-5 μg/kg.展开更多
基金Project(51204074)supported by the National Natural Science Foundation of ChinaProjects(2010009017,201209048,ZX021-201106-031)supported by the National Environmental Protection Public Welfare Industry Targeted Research Fund,China
文摘Soil cadmium(Cd)contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils,vegetables and paddy rice were investigated,and potential non-carcinogenic and carcinogenic health risks exposure to Cd were estimated at six villages around the Dabaoshan Mine,South China.A total of 87 soil samples were found to exceed the China's maximum permission level(MPL)for Cd,while the highest value of 4.42 mg/kg was found near irrigation ditch associated with Hengshi River in Xinyi(XY)Village.Cd contents in vegetables and rice exceeded the maximum permissible concentration by more than five times in every village.Cadmium accumulation in plants is in the order of celery>lactuca sativa L>Chinese cabbage>Romaine lettuce>asparagus lettuce>mustard>cabbage mustard>cabbage.The mean hazard quotient(HQ)of all villages is in the range of [5.29,25.75],and the mean values of cancer risk for investigated areas are more than 10 times greater than the USEPA(2009)threshold limit value of 10-4.Moreover,human non-carcinogenic and carcinogenic risks are mainly attributable to paddy rice intake,followed by vegetables intake,soil ingestion,inhalation,and dermal contact.The results indicate that Cd has a huge potential risk on human health for the local residents.
基金National Natural Science Foundation of China(32301718)Chinese Academy of Agricultural Sciences under the Special Institute-level Coordination Project for Basic Research Operating Costs(S202328)。
文摘The cold chain in the production area of fruits and vegetables is the primary link to reduce product loss and improve product quality,but it is also a weak link.With the application of big data technology in cold chain logistics,intelligent devices,and technologies have become important carriers for improving the efficiency of cold chain logistics in fruit and vegetable production areas,extending the shelf life of fruits and vegetables,and reducing fruit and vegetable losses.They have many advantages in fruit and vegetable pre-cooling,sorting and packaging,testing,warehousing,transportation,and other aspects.This article summarizes the rapidly developing and widely used intelligent technologies at home and abroad in recent years,including automated guided vehicle intelligent handling based on electromagnetic or optical technology,intelligent sorting based on sensors,electronic optics,and other technologies,intelligent detection based on computer vision technology,intelligent transportation based on perspective imaging technology,etc.It analyses and studies the innovative research and achievements of various scholars in applying intelligent technology in fruit and vegetable cold chain storage,sorting,detection,transportation,and other links,and improves the efficiency of fruit and vegetable cold chain logistics.However,applying intelligent technology in fruit and vegetable cold chain logistics also faces many problems.The challenges of high cost,difficulty in technological integration,and talent shortages have limited the development of intelligent technology in the field of fruit and vegetable cold chains.To solve the current problems,it is proposed that costs be controlled through independent research and development,technological innovation,and other means to lower the entry threshold for small enterprises.Strengthen integrating intelligent technology and cold chain logistics systems to improve data security and system compatibility.At the same time,the government should introduce relevant policies,provide necessary financial support,and establish talent training mechanisms.Accelerate the development and improvement of intelligent technology standards in the field of cold chain logistics.Through technological innovation,cost control,talent cultivation,and policy guidance,we aim to promote the upgrading of the agricultural industry and provide ideas for improving the quality and efficiency of fruit and vegetable cold chain logistics.
文摘The list of underutilized green leafy vegetables is enormous: ranging from commonly consumed and underutilized vegetables. There are data on commonly consumed vegetables, but information is sparse on nutritional, chemical and anti-nutritional properties of less explored vegetables. This work aimed to evaluate some attributes of less explored or underutilized leafy vegetables. Some nutritional and anti-nutritional contents of 10 under-utilized leafy vegetables(Amaranthus spinosus Linnaeus, Basella alba Linnaeus, Corchorous tridens L., Cyrtosperma senegalense(Schott), Erigeron floribundus Sch, Hoslundia opposita Vahl, Lagenaria siceraria(Molina) Standl, Ocimum basilicum L., Solanum aethiopicum L. and Talinum portulacifolium(Forssk.) Asch. ex Schweinf) were investigated. Cyrtosperma senegalense had the highest protein value(5.93%). Hoslundia opposita had the highest fat content(0.54%). Amaranthus spinosus was high in β-carotene content(346.3 mg · 100 g-1); Cyrtosperma senegalense had the highest moisture content. A. spinosus had the highest ascorbic acid content(108.1 mg · 100 g-1). The highest tannin level(0.0057%) was found in C. senegalense and the lowest(0.0003%) was found in Solanum aethiopicum. Saponin was the highest in C. tridens(0.0052%) and the lowest in T. portulacifolium(0.00014%). C. senegalense and S. aethiopicum had their highest and the lowest phytate values, respectively. Although anti-nutrients could interfere with nutrient utilization, their values in these vegetables were not at toxic levels.
文摘The paper is to study the main co-extractions existing in multiresidue analysis of pesticides in vegetables.For this,extracted 10 vegetable and analyzed the extractions with GC-MS.Compared the spectra of those co-extractions in different vegetables,confirm the main co-extractions of vegetables.The result shows the co-extractions are same including pigment,phenols,fat acids,lipin and steroid.But the mass of those co-extractions in different vegetable is different.The study result is help for the development of pesticide residue method.
文摘To establish a new GC-MS/MS method for quantitative detection of 22 kinds of pesticide in fruit and vegetable including organic phosphorus,carbamate & pyrethrin etc.Working was performed by Xcalibur software with multitask mode.We Carried on qualitative and quantitative analysis to mass spectrum of MS/MS in order to obtained a credible experiment result.This method is sensitive and accurate,it is suitable for determination of multifarious pesticide residues.
文摘A direct determination method for the atrazine residue on the vegetable was developed by using desorption electrospray ionization mass spectrometry (DESI MS) without any sample pretreatment.Acetonitrile-water (1:1,v/v),which contained 0.1% formic acid,was used as the spray solvent.The working conditions,such as ESI gas inlet pressure,ESI flow rate,ESI spray voltage,spray-to-sample distance,spray-to-cone-hole distance and the collision induced dissociation (CID) voltage for MS/MS,were optimized for both DESI and esquires 6 000 mass spectrometer.The linear range of atrazine on cabbage leaves was 25.25-2 525 pg/mm2,the R2 was 0.991 6,and the relative standard deviations were between 3.37% and 26.17%.The LOD of atrazine calculated by S/N=3 was 2.50 pg/mm2.
文摘A new method was developed for the simultaneous analysis of 12 pesticide residues in onion and fennel by gas chromatography(GC)-triple quadrupole mass spectrometry(MS/MS)-electron impact ion source(EI)-select reaction monitoring mode(SRM).The 12 pesticide includes fungicide,acaricide,carbamate and plant growth regulator pesticide.The complicated matrix samples of onion and fennel were extracted by acetonitrile,cleaned up by solid phase extraction of Carb/PSA.By optimizing the GC-MS/MS-SRM parameters,the interference from clean-up procedure was further removed and 12 pesticide residues were determined accurately.The average recoveries for most pesticides(at the spiked level of 0.05-0.20 mg/kg) were between 114%-156%,the relative standard deviation(RSD) of the method was less than 20%,and the limit of detection were 0.5-5 μg/kg.
