The pore structures and electrochemical performances of mesoporous carbons prepared by silica sol template method as electrode material for supercapacitor were investigated. The mean pore size and mass specific capaci...The pore structures and electrochemical performances of mesoporous carbons prepared by silica sol template method as electrode material for supercapacitor were investigated. The mean pore size and mass specific capacitance of the mesoporous carbons increase with the increase of mass ratio of silica sol to carbon source （glucose）. A modified template method, combining silica sol template method and ZnCl2 chemical activation method, was proposed to improve the mass specific capacitance of the mesoporous carbon with an improved BET surface area. The correlation of rate capability and pore structure was studied by constant current discharge and electrochemical impedance spectroscopy. A commercially available microporous carbon was used for comparison. The result shows that mesoporous carbon with a larger pore size displays a higher rate capability. Mesoporous carbon synthesized by modified template method has both high mass specific capacitance and good rate capability.展开更多
To improve the adsorption properties of chemically modified chitosan, the chelating resin of salicylal chitosan Schiff bases was prepared by the template cross-linking method using Cu（Ⅱ） as template ion and ethylen...To improve the adsorption properties of chemically modified chitosan, the chelating resin of salicylal chitosan Schiff bases was prepared by the template cross-linking method using Cu（Ⅱ） as template ion and ethylene glycol bisglycidyl ether as cross-linking agent in microwave, and was characterized by IR. The adsorption capacity and selectivity coefficient of the chemically modified chitosan for Cu（Ⅱ）, Fe（Ⅲ） and Zn（Ⅱ） were investigated, respectively. The results show that the adsorption capacity of the resin 2.73 mmol/g for Cu（Ⅱ） is bigger than that for other two metal ions, 0.22 mmol/g for Fe（Ⅲ）, and 0.42 mmol/g for Zn（Ⅱ）, and the selectivity coefficients are as follows: KCu（Ⅱ）/Fe（Ⅲ）=12.4, KCu（Ⅱ）/Zn（Ⅱ）=6.5.展开更多
An adaptive dwell scheduling algorithm for phased array radar(PAR)is proposed in this paper.The concept of online dynamic template is introduced,based on which a general pulse interleaving technique for PAR is put for...An adaptive dwell scheduling algorithm for phased array radar(PAR)is proposed in this paper.The concept of online dynamic template is introduced,based on which a general pulse interleaving technique for PAR is put forward.The pulse interleaving condition of the novel pulse interleaving is more intuitive and general.The traditional adaptive dwell scheduling algorithm combined with the general novel pulse interleaving technique results in the online adaptive dwell scheduling based on dynamic template for PAR is given.The proposed algorithm is suitable for radar tasks with multiple pulse repetition intervals(PRIs),which can be utilized in the actual radar system.For the purpose of further improving the scheduling efficiency,an efficient version is proposed.Simulation results demonstrate the effectiveness of the proposed algorithm and the efficient one.The proposed efficient algorithm can improve the time utilization ratio(TUR)by 9%,the hit value ratio(HVR)by 3.5%,and reduce the task drop ratio(TDR)by 6%in comparison with existing dwell scheduling algorithms considering pulse interleaving in PAR and the proposed efficient one.展开更多
To preserve the original signal as much as possible and filter random noises as many as possible in image processing,a threshold optimization-based adaptive template filtering algorithm was proposed.Unlike conventiona...To preserve the original signal as much as possible and filter random noises as many as possible in image processing,a threshold optimization-based adaptive template filtering algorithm was proposed.Unlike conventional filters whose template shapes and coefficients were fixed,multi-templates were defined and the right template for each pixel could be matched adaptively based on local image characteristics in the proposed method.The superiority of this method was verified by former results concerning the matching experiment of actual image with the comparison of conventional filtering methods.The adaptive search ability of immune genetic algorithm with the elitist selection and elitist crossover(IGAE) was used to optimize threshold t of the transformation function,and then combined with wavelet transformation to estimate noise variance.Multi-experiments were performed to test the validity of IGAE.The results show that the filtered result of t obtained by IGAE is superior to that of t obtained by other methods,IGAE has a faster convergence speed and a higher computational efficiency compared with the canonical genetic algorithm with the elitism and the immune algorithm with the information entropy and elitism by multi-experiments.展开更多
Highly ordered and porous anodic aluminum oxide templates were prepared. The ordered copper nanowires arrays were assembled in nano-holes of the template by alternating current electrodeposition at lover voltage. The ...Highly ordered and porous anodic aluminum oxide templates were prepared. The ordered copper nanowires arrays were assembled in nano-holes of the template by alternating current electrodeposition at lover voltage. The morphologies of template and copper nano-wires arrays were characterized by means of field emission scanning electron microscope (FESEM) and the crystal structure of copper nano-wires was determined by means of X-ray diffraction. The results indicate that copper nano-wires hold the preferred crystalline orientation along (111), (200), (220) and (331) crystal faces during growth, and the growth of copper nano-wires in the nano-holes of the template is homogenous and continuous.展开更多
A low computational cost cancelable fingerprint template, namely the multi-line codes was proposed. The formulation of a single-line code involves the inspection of minutiae distribution along a straight line construc...A low computational cost cancelable fingerprint template, namely the multi-line codes was proposed. The formulation of a single-line code involves the inspection of minutiae distribution along a straight line constructed based on the reference minutia. Multi-line code is introduced to elevate the performance by combining several single-line codes. Experiments were carried out on a few FVC databases. It has been proven that the proposed method yields relatively low computational complexity as compared to existing minutiae distribution-based methods, while preserving the performance. The equal error rate obtained for FVC2002 DB1 is 4.69% in stolen-key case, and the total arithmetic operations utilized are 14 520 additions and zero multiplication.展开更多
Copper azide(CA), as a primary explosive with high energy density, has not been practically used so far because of its high electrostatic sensitivity. The Cu2O@HKUST-1 core-shell structure hybrid material was synthesi...Copper azide(CA), as a primary explosive with high energy density, has not been practically used so far because of its high electrostatic sensitivity. The Cu2O@HKUST-1 core-shell structure hybrid material was synthesized by the “bottle around ship” methodology in this research by regulating the dissolution rate of Cu2O and the generation rate of metal-organic framework(MOF) materials. Cu2O@HKUST-1 was carbonized to form a Cu O@porous carbon(CuO@PC) composite material. CuO@PC was synthesized into a copper azide(CA) @PC composite energetic material through a gas-solid phase in-situ azidation reaction.CA is encapsulated in PC framework, which acts as a nanoscale Faraday cage, and its excellent electrical conductivity prevents electrostatic charges from accumulating on the energetic material’s surface. The CA@PC composite energetic material has a CA content of 89.6%, and its electrostatic safety is nearly 30times that of pure CA(1.47 mJ compared to 0.05 mJ). CA@PC delivers an outstanding balance of safety and energy density compared to similar materials.展开更多
The template carbonization method was utilized for the production of mesoporous carbons using attapulgite as a template and sucrose as carbon precursor. Sucrose was polymerized and carbonized in the tubes of natural a...The template carbonization method was utilized for the production of mesoporous carbons using attapulgite as a template and sucrose as carbon precursor. Sucrose was polymerized and carbonized in the tubes of natural attapulgite using a sulfuric acid catalyst. The structure of the template and carbons were investigated by powder X-ray diffraction, transmission electron microscopy, and Nitrogen adsorption analysis techniques. At the micrometer level, the carbon material templated with the natural attapulgite had the similar morphology. Nitrogen adsorption analysis showed that the obtained porous carbons possess a wide pore size distribution and a large pore volume, especially in the range of mesopores.展开更多
Porous carbons are extensively applied in gas separation, water purification, catalytic reaction, and electrochemical processing, attributing to their high specific surface area, large pore volume, chemical inertness,...Porous carbons are extensively applied in gas separation, water purification, catalytic reaction, and electrochemical processing, attributing to their high specific surface area, large pore volume, chemical inertness, and good mechanical and thermal stability. The templating method is widely used to synthesize porous carbons with the controlled pore structure. Among them, preparation of diatomite-templated carbons attracts increasing attention because the obtained carbon has unique developed macropores and exhibits the promising application in adsorption and support of large-sized molecules. Macroporous diatomite-templated carbons are prepared by using additive or inherent solid acid sites of diatomite as the catalyst. The obtained carbons showed tubular and pillared macroporous structures, and had a few mesopores and micropores. However, the carbons possessed the small specific surface area and micropore volume, and thus showed the low adsorption capacity of small-sized molecules, such as methylene blue (MB). In this case, enhancement of porosity, especially microporosity, is necessary.展开更多
基金The authors are grateful for the financial support of this work from National Natural Science Foundation of China(No.20021002,29925310,29833090)Ministry of Science and Technology(2001CB610506).
文摘The pore structures and electrochemical performances of mesoporous carbons prepared by silica sol template method as electrode material for supercapacitor were investigated. The mean pore size and mass specific capacitance of the mesoporous carbons increase with the increase of mass ratio of silica sol to carbon source （glucose）. A modified template method, combining silica sol template method and ZnCl2 chemical activation method, was proposed to improve the mass specific capacitance of the mesoporous carbon with an improved BET surface area. The correlation of rate capability and pore structure was studied by constant current discharge and electrochemical impedance spectroscopy. A commercially available microporous carbon was used for comparison. The result shows that mesoporous carbon with a larger pore size displays a higher rate capability. Mesoporous carbon synthesized by modified template method has both high mass specific capacitance and good rate capability.
文摘To improve the adsorption properties of chemically modified chitosan, the chelating resin of salicylal chitosan Schiff bases was prepared by the template cross-linking method using Cu（Ⅱ） as template ion and ethylene glycol bisglycidyl ether as cross-linking agent in microwave, and was characterized by IR. The adsorption capacity and selectivity coefficient of the chemically modified chitosan for Cu（Ⅱ）, Fe（Ⅲ） and Zn（Ⅱ） were investigated, respectively. The results show that the adsorption capacity of the resin 2.73 mmol/g for Cu（Ⅱ） is bigger than that for other two metal ions, 0.22 mmol/g for Fe（Ⅲ）, and 0.42 mmol/g for Zn（Ⅱ）, and the selectivity coefficients are as follows: KCu（Ⅱ）/Fe（Ⅲ）=12.4, KCu（Ⅱ）/Zn（Ⅱ）=6.5.
基金This work was supported by the National Natural Science Froundation of China(61032010).
文摘An adaptive dwell scheduling algorithm for phased array radar(PAR)is proposed in this paper.The concept of online dynamic template is introduced,based on which a general pulse interleaving technique for PAR is put forward.The pulse interleaving condition of the novel pulse interleaving is more intuitive and general.The traditional adaptive dwell scheduling algorithm combined with the general novel pulse interleaving technique results in the online adaptive dwell scheduling based on dynamic template for PAR is given.The proposed algorithm is suitable for radar tasks with multiple pulse repetition intervals(PRIs),which can be utilized in the actual radar system.For the purpose of further improving the scheduling efficiency,an efficient version is proposed.Simulation results demonstrate the effectiveness of the proposed algorithm and the efficient one.The proposed efficient algorithm can improve the time utilization ratio(TUR)by 9%,the hit value ratio(HVR)by 3.5%,and reduce the task drop ratio(TDR)by 6%in comparison with existing dwell scheduling algorithms considering pulse interleaving in PAR and the proposed efficient one.
基金Project(20040533035) supported by the National Research Foundation for the Doctoral Program of Higher Education of ChinaProject (60874070) supported by the National Natural Science Foundation of China
文摘To preserve the original signal as much as possible and filter random noises as many as possible in image processing,a threshold optimization-based adaptive template filtering algorithm was proposed.Unlike conventional filters whose template shapes and coefficients were fixed,multi-templates were defined and the right template for each pixel could be matched adaptively based on local image characteristics in the proposed method.The superiority of this method was verified by former results concerning the matching experiment of actual image with the comparison of conventional filtering methods.The adaptive search ability of immune genetic algorithm with the elitist selection and elitist crossover(IGAE) was used to optimize threshold t of the transformation function,and then combined with wavelet transformation to estimate noise variance.Multi-experiments were performed to test the validity of IGAE.The results show that the filtered result of t obtained by IGAE is superior to that of t obtained by other methods,IGAE has a faster convergence speed and a higher computational efficiency compared with the canonical genetic algorithm with the elitism and the immune algorithm with the information entropy and elitism by multi-experiments.
文摘Highly ordered and porous anodic aluminum oxide templates were prepared. The ordered copper nanowires arrays were assembled in nano-holes of the template by alternating current electrodeposition at lover voltage. The morphologies of template and copper nano-wires arrays were characterized by means of field emission scanning electron microscope (FESEM) and the crystal structure of copper nano-wires was determined by means of X-ray diffraction. The results indicate that copper nano-wires hold the preferred crystalline orientation along (111), (200), (220) and (331) crystal faces during growth, and the growth of copper nano-wires in the nano-holes of the template is homogenous and continuous.
文摘A low computational cost cancelable fingerprint template, namely the multi-line codes was proposed. The formulation of a single-line code involves the inspection of minutiae distribution along a straight line constructed based on the reference minutia. Multi-line code is introduced to elevate the performance by combining several single-line codes. Experiments were carried out on a few FVC databases. It has been proven that the proposed method yields relatively low computational complexity as compared to existing minutiae distribution-based methods, while preserving the performance. The equal error rate obtained for FVC2002 DB1 is 4.69% in stolen-key case, and the total arithmetic operations utilized are 14 520 additions and zero multiplication.
基金the financial support by Postgraduate Research & Practice Innovation Program from Jiangsu Science and Technology Department under Grant number KYCX19_0320。
文摘Copper azide(CA), as a primary explosive with high energy density, has not been practically used so far because of its high electrostatic sensitivity. The Cu2O@HKUST-1 core-shell structure hybrid material was synthesized by the “bottle around ship” methodology in this research by regulating the dissolution rate of Cu2O and the generation rate of metal-organic framework(MOF) materials. Cu2O@HKUST-1 was carbonized to form a Cu O@porous carbon(CuO@PC) composite material. CuO@PC was synthesized into a copper azide(CA) @PC composite energetic material through a gas-solid phase in-situ azidation reaction.CA is encapsulated in PC framework, which acts as a nanoscale Faraday cage, and its excellent electrical conductivity prevents electrostatic charges from accumulating on the energetic material’s surface. The CA@PC composite energetic material has a CA content of 89.6%, and its electrostatic safety is nearly 30times that of pure CA(1.47 mJ compared to 0.05 mJ). CA@PC delivers an outstanding balance of safety and energy density compared to similar materials.
文摘The template carbonization method was utilized for the production of mesoporous carbons using attapulgite as a template and sucrose as carbon precursor. Sucrose was polymerized and carbonized in the tubes of natural attapulgite using a sulfuric acid catalyst. The structure of the template and carbons were investigated by powder X-ray diffraction, transmission electron microscopy, and Nitrogen adsorption analysis techniques. At the micrometer level, the carbon material templated with the natural attapulgite had the similar morphology. Nitrogen adsorption analysis showed that the obtained porous carbons possess a wide pore size distribution and a large pore volume, especially in the range of mesopores.
文摘Porous carbons are extensively applied in gas separation, water purification, catalytic reaction, and electrochemical processing, attributing to their high specific surface area, large pore volume, chemical inertness, and good mechanical and thermal stability. The templating method is widely used to synthesize porous carbons with the controlled pore structure. Among them, preparation of diatomite-templated carbons attracts increasing attention because the obtained carbon has unique developed macropores and exhibits the promising application in adsorption and support of large-sized molecules. Macroporous diatomite-templated carbons are prepared by using additive or inherent solid acid sites of diatomite as the catalyst. The obtained carbons showed tubular and pillared macroporous structures, and had a few mesopores and micropores. However, the carbons possessed the small specific surface area and micropore volume, and thus showed the low adsorption capacity of small-sized molecules, such as methylene blue (MB). In this case, enhancement of porosity, especially microporosity, is necessary.
