The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricat...The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above issues.The coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer shell.The resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer shell.The phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene composites.Meanwhile,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell structure.In general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.展开更多
Structure-based protein classification can be based on the similarities in primary, second or tertiary structures of proteins. A method using virtual-bond-angles series that transformed the protein space configuration...Structure-based protein classification can be based on the similarities in primary, second or tertiary structures of proteins. A method using virtual-bond-angles series that transformed the protein space configuration into a sequence was used for the classification of three-dimensional structures oi proteins. By transforming the main chains formed by C^a atoms of proteins into sequences, the series of virtual-bond-angles corresponding to the tertiary structure of the proteins were constructed. Then a distance-based hierarchical clustering method similar to Ward method was introduced to classify these virtual-bond-angles series of proteins. 200 files of protein structures were selected from Brookheaven protein data bank, and 11 clusters were classified.展开更多
The Qaidam Basin is a petroleum province in Northeastern Qinghai—Tibetan plateau, China. The Basin is bounded by the Aljin Mountains to the Northwest, the Qilian Mountains to the Northeast, the Qimantager Mountains t...The Qaidam Basin is a petroleum province in Northeastern Qinghai—Tibetan plateau, China. The Basin is bounded by the Aljin Mountains to the Northwest, the Qilian Mountains to the Northeast, the Qimantager Mountains to the Southeast and East Kunlun Mountains to the Southwest. The average elevation of the basin and these mountains are 2700m and 3000～ 5000 m respect to the sea level, respectively. The basin was developed on the pre\|Mesozoic basement. Thickness of Tertiary system is more than 10000m in the basin,but Quaternary is mainly in the eastern basin with thickness more than 3000m. The lithology in Mesozoic and Cenozoic of the basin are mainly sandstone, shale, calcic rocks and the interlayers of sandstone and shale.展开更多
Improving the thermal decomposition performance of hexanitrohexaazaisowurtzitane(CL-20)by appropriate methods is helpful to promote the combustion performance of CL-20-based solid propellants.In this study,we synthesi...Improving the thermal decomposition performance of hexanitrohexaazaisowurtzitane(CL-20)by appropriate methods is helpful to promote the combustion performance of CL-20-based solid propellants.In this study,we synthesized a sandwich structure of CL-20 and nanoporous carbon scaffolds film(NCS)and emphatically studied the thermal decomposition performance of the composite structure.Thermogravimetric analysis and differential scanning calorimetry were used to measure the thermal decomposition process of the composite structure.The kinetic parameters of thermal decomposition were calculated by the thermal dynamic analysis software AKTS.These results showed that the thermal decomposition performance of the sandwich structure of CL-20 and NCS was better than CL-20.Among the tested samples,NCS with a pore size of 15 nm had the best catalytic activity for the thermal decomposition of CL-20.Moreover,the thermal decomposition curve of the composite structure at the heating rate of 1 K/min was deconvoluted by mathematical method to study the thermal decomposition process.And a possible catalytic mechanism was proposed.The excellent thermal decomposition performance is due to the sandwich structure enhances the interface reaction of CL-20 and NCS.This work may promote the extensive use of CL-20 in the field of solid rocket propellant.展开更多
Nitrocellulose,or cellulose nitrate,has received considerable interest due to its various applications,such as propellants,coating agents and gas generators.However,its high mechanical sensitivity caused many accident...Nitrocellulose,or cellulose nitrate,has received considerable interest due to its various applications,such as propellants,coating agents and gas generators.However,its high mechanical sensitivity caused many accidents during its storage and usage in ammunition.In this work,two kinds of insensitive step ladderstructured nitrocellulose(LNC)with different nitrogen contents were synthesized.The products were characterized by FT-IR,Raman,XRD,SEM,elemental analysis,TGA,DSC,accelerating rate calorimeter analysis(ARC),and drop weight test to study their molecular structure,thermal characteristics and desensitization performance.Compared with raw nitrocellulose,LNC has a sharper exothermic peak in the DSC and ARC curves.The H50values of the two kinds of LNC increased from 25.76 to 30.01 cm for low nitrogen content and from 18.02 to 21.84 cm for high nitrogen content,respectively.The results show that the ladder-structure of LNC which provides regular molecular arrangement and a soft buffer made with polyethylene glycol could affect the energy releasing process of LNC and reduce the sensitivity of LNC.Insensitive LNC provides an alternative to be used as a binder in insensitive propellants formulation.展开更多
A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of...A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30 ℃and 15 ℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 ram, respectively. The surface temperature without nickel layers is depressed by 10 ℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5 ℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.展开更多
The powerful alternate magnetic field treatment is an effective not-heat treatment, which improves the coriaceous performance of the material. In order to reveal the effect rule of the powerful alternate magnetic fiel...The powerful alternate magnetic field treatment is an effective not-heat treatment, which improves the coriaceous performance of the material. In order to reveal the effect rule of the powerful alternate magnetic field on the structure capability after thermal plastic forming, the experimental methods were adopted to compare the microcosmic structure of the LY12 aluminium alloy test pieces before and after the powerful alternate magnetic field treatment. The mechanism of the structure refining was analyzed theoretically. According to the effect rule of the alternate magnetic field on critical grain growth work and the magnetic vibration-constriction mechanism, the structure dynamics factors were analyzed. The results show that, after a certain powerful alternate magnetic field treatment, the mechanical capability of the LY12 aluminium alloy after thermal plastic forming can be reinforced, the structure intertwist deriving from the thermal plastic forming becomes even and the branch crystal is also smashed, consequently refines the structure. The powerful alternate magnetic field treatment can be regarded as an effective method to improve metal structure performance after heat plastic forming.展开更多
Thermal and moisture characteristics of the bamboo structure wall were tested in natural climate and three representative variation processes of heat and moisture： heating from solar radiation in summer at normal tem...Thermal and moisture characteristics of the bamboo structure wall were tested in natural climate and three representative variation processes of heat and moisture： heating from solar radiation in summer at normal temperature and humidity, heating from solar radiation in summer at normal temperature and high humidity after rain, humidifying from brash in summer at high temperature and normal humidity. The results show that, in summer, the largest temperature difference between external and internal surface of the 28 mm-thick bamboo plywood wall is 11.73℃ （at 15：40） and the largest strain difference is 136 μm/m （at 18：50）, both in ambient and indoor conditioned environment. In heating process, lengthways of the wall surface are in contracting strain while transverse ways are in expanding strain at initial stage and in contracting strain during later period. When the high temperature wall is humidified by rain, the surface temperature drops, moisture content increases and the expanding strain is presented on the surface during the whole process. Temperature and moisture content are two important factors which affect thermal and moisture stress （TMS） of the bamboo structure wall. The TMS is not only related to temperature and moisture content, but also greatly affected by temperature gradient, moisture content gradient and rates of changing.展开更多
Ammonium perchlorate(AP)is the component with the highest content in composite propellants,and it plays a crucial role in propellant performance.In view of the effects of low-temperature AP thermal decomposition on th...Ammonium perchlorate(AP)is the component with the highest content in composite propellants,and it plays a crucial role in propellant performance.In view of the effects of low-temperature AP thermal decomposition on thermal safety and combustion characteristics,porous ammonium perchlorate(PAP)samples with different mass losses were first prepared by thermal convection heating,and the structures were characterized and analysed.Second,the effects of decomposition degree on the thermal decomposition characteristics of PAP were studied by DSC-TG.Finally,the combustion characteristics of AP/Al binary mixtures were tested with high-speed photography and in a sealed bomb.The results showed that low-temperature decomposition of AP resulted in formation of porous structures for AP particles.The pores first appeared near the surfaces of the particles and began from multiple points at the same time.The pores increased in size to approximately 5 mm and then expanded,and finally,the AP particles were full of pores.After partial decomposition,the crystal structure of AP remained unchanged,but the low and high decomposition temperatures decreased obviously.The decomposition rate accelerated.Due to the porous structure of PAP,the combustion rate of the AP/Al system increased obviously with increasing decomposition of AP.The relationship between the combustion rate and the mass loss was approximately linear under open conditions,and it was exponential for a high-pressure environment.A computational model of the combustion process for the AP/Al binary system was established to explain the effects of pore structure and pressure on the combustion process.展开更多
This study proposes a general imperfect thermal contact model to predict the thermal contact resistance at the interface among multi-layered composite structures.Based on the Green-Lindsay(GL)thermoelastic theory,semi...This study proposes a general imperfect thermal contact model to predict the thermal contact resistance at the interface among multi-layered composite structures.Based on the Green-Lindsay(GL)thermoelastic theory,semi analytical solutions of temperature increment and displacement of multi-layered composite structures are obtained by using the Laplace transform method,upon which the effects of thermal resistance coefficient,partition coefficient,thermal conductivity ratio and heat capacity ratio on the responses are studied.The results show that the generalized imperfect thermal contact model can realistically describe the imperfect thermal contact problem.Accordingly,it may degenerate into other thermal contact models by adjusting the thermal resistance coefficient and partition coefficient.展开更多
Prior to the collision and accretion of the Kohistan arc terrane during the late Cretaceous and the Indian plate after the early Eocene, the southern margin of Asia along the Hindu Kush, Karakoram and Lhasa block terr...Prior to the collision and accretion of the Kohistan arc terrane during the late Cretaceous and the Indian plate after the early Eocene, the southern margin of Asia along the Hindu Kush, Karakoram and Lhasa block terranes was an active Andean\|type continental margin. In south Tibet this margin was dominated by the calc\|alkaline Ladakh—Gangdese granite batholith, associated andesitic volcanic rocks and continental red\|beds. In contrast, the southern Karakoram exposes deep crustal metamorphic rocks and crustal melt leucogranites. New U\|Pb age dating from the Hunza valley and Baltoro glacier region has revealed four spatially and temporally distinct metamorphic episodes. M1 sillimanite grade metamorphism in Hunza was a late Cretaceous event, probably caused by the accretion of the Kohistan arc to Asia. M2 was the major kyanite and sillimanite grade event during late Eocene—Oligocene crustal thickening and shortening, following India\|Asia collision. Numerous melting events resulted in the formation of crustal melt granites throughout the last 50Ma with multiple generations of dykes and very large scale crustal melting along the Baltoro monzogranite\|leucogranite ba tholith during the late Oligocene—early Miocene. M3 metamorphism was a high\| T , low\| p contact thermal metamorphism around the Baltoro granite. In Hunza, younger staurolite grade metamorphism has been dated by U\|Pb monazites at 16Ma, with the Sumayar leucogranite intruded at 9 5Ma cross\|cutting the metamorphic isograds. In the Baltoro region the youngest metamorphism, M4, is the sillimanite grade Dassu gneiss core complex dated by U\|Pb on monazites as late Miocene—Pliocene (5 4±0 25)Ma with Precambrian protolith zircon cores (1855±11)Ma. Numerous gem\|bearing pegmatite dykes cross\|cut these rocks and are thought to have been intruded within the last 2～3Ma. Structural mapping, combined with U\|Pb geochronology shows that major metamorphic events can be both long\|lasting (up to 20Ma) and very restrictive, both in time and space.展开更多
The electronic structures of pure V, Nb and Ta metals with bcc structure were determined by one atom (OA) theory. According to the electronic structures of these metals, their potential curves, cohesive energies, latt...The electronic structures of pure V, Nb and Ta metals with bcc structure were determined by one atom (OA) theory. According to the electronic structures of these metals, their potential curves, cohesive energies, lattice parameters, elasticity and the dependence of linear thermal expansion coefficients on temperature were calculated. The electronic structures and characteristic properties of these metals with fcc and hcp structures and liquid states were studied.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant No. 22275173)the Open Project of State Key Laboratory of Environment-friendly Energy Materials (Grant No. 22kfhg10)。
文摘The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above issues.The coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer shell.The resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer shell.The phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene composites.Meanwhile,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell structure.In general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.
文摘Structure-based protein classification can be based on the similarities in primary, second or tertiary structures of proteins. A method using virtual-bond-angles series that transformed the protein space configuration into a sequence was used for the classification of three-dimensional structures oi proteins. By transforming the main chains formed by C^a atoms of proteins into sequences, the series of virtual-bond-angles corresponding to the tertiary structure of the proteins were constructed. Then a distance-based hierarchical clustering method similar to Ward method was introduced to classify these virtual-bond-angles series of proteins. 200 files of protein structures were selected from Brookheaven protein data bank, and 11 clusters were classified.
文摘The Qaidam Basin is a petroleum province in Northeastern Qinghai—Tibetan plateau, China. The Basin is bounded by the Aljin Mountains to the Northwest, the Qilian Mountains to the Northeast, the Qimantager Mountains to the Southeast and East Kunlun Mountains to the Southwest. The average elevation of the basin and these mountains are 2700m and 3000～ 5000 m respect to the sea level, respectively. The basin was developed on the pre\|Mesozoic basement. Thickness of Tertiary system is more than 10000m in the basin,but Quaternary is mainly in the eastern basin with thickness more than 3000m. The lithology in Mesozoic and Cenozoic of the basin are mainly sandstone, shale, calcic rocks and the interlayers of sandstone and shale.
基金supported by the National Natural Science Foundation of China(No:21975227)the Shanxi Province Graduate Student Innovation Project(No:2020SY403)。
文摘Improving the thermal decomposition performance of hexanitrohexaazaisowurtzitane(CL-20)by appropriate methods is helpful to promote the combustion performance of CL-20-based solid propellants.In this study,we synthesized a sandwich structure of CL-20 and nanoporous carbon scaffolds film(NCS)and emphatically studied the thermal decomposition performance of the composite structure.Thermogravimetric analysis and differential scanning calorimetry were used to measure the thermal decomposition process of the composite structure.The kinetic parameters of thermal decomposition were calculated by the thermal dynamic analysis software AKTS.These results showed that the thermal decomposition performance of the sandwich structure of CL-20 and NCS was better than CL-20.Among the tested samples,NCS with a pore size of 15 nm had the best catalytic activity for the thermal decomposition of CL-20.Moreover,the thermal decomposition curve of the composite structure at the heating rate of 1 K/min was deconvoluted by mathematical method to study the thermal decomposition process.And a possible catalytic mechanism was proposed.The excellent thermal decomposition performance is due to the sandwich structure enhances the interface reaction of CL-20 and NCS.This work may promote the extensive use of CL-20 in the field of solid rocket propellant.
基金supported in part by the National Natural Science Foundation of China(No.22075146)。
文摘Nitrocellulose,or cellulose nitrate,has received considerable interest due to its various applications,such as propellants,coating agents and gas generators.However,its high mechanical sensitivity caused many accidents during its storage and usage in ammunition.In this work,two kinds of insensitive step ladderstructured nitrocellulose(LNC)with different nitrogen contents were synthesized.The products were characterized by FT-IR,Raman,XRD,SEM,elemental analysis,TGA,DSC,accelerating rate calorimeter analysis(ARC),and drop weight test to study their molecular structure,thermal characteristics and desensitization performance.Compared with raw nitrocellulose,LNC has a sharper exothermic peak in the DSC and ARC curves.The H50values of the two kinds of LNC increased from 25.76 to 30.01 cm for low nitrogen content and from 18.02 to 21.84 cm for high nitrogen content,respectively.The results show that the ladder-structure of LNC which provides regular molecular arrangement and a soft buffer made with polyethylene glycol could affect the energy releasing process of LNC and reduce the sensitivity of LNC.Insensitive LNC provides an alternative to be used as a binder in insensitive propellants formulation.
基金Project(51004031) supported by the National Natural Science Foundation of ChinaProject(50925415) supported by the National Outstanding Young Scientist Foundation of China+1 种基金Project(20100042120012) supported by the Special Research Fund for Doctoral Programs of Ministry of Education of ChinaProject(N090402022) supported by the Fundamental Research Funds for the Central Universities of China
文摘A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30 ℃and 15 ℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 ram, respectively. The surface temperature without nickel layers is depressed by 10 ℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5 ℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.
基金Project(50675190) supported by the National Natural Science Foundation of China
文摘The powerful alternate magnetic field treatment is an effective not-heat treatment, which improves the coriaceous performance of the material. In order to reveal the effect rule of the powerful alternate magnetic field on the structure capability after thermal plastic forming, the experimental methods were adopted to compare the microcosmic structure of the LY12 aluminium alloy test pieces before and after the powerful alternate magnetic field treatment. The mechanism of the structure refining was analyzed theoretically. According to the effect rule of the alternate magnetic field on critical grain growth work and the magnetic vibration-constriction mechanism, the structure dynamics factors were analyzed. The results show that, after a certain powerful alternate magnetic field treatment, the mechanical capability of the LY12 aluminium alloy after thermal plastic forming can be reinforced, the structure intertwist deriving from the thermal plastic forming becomes even and the branch crystal is also smashed, consequently refines the structure. The powerful alternate magnetic field treatment can be regarded as an effective method to improve metal structure performance after heat plastic forming.
基金Project(50878078) supported by the National Natural Science Foundation of China
文摘Thermal and moisture characteristics of the bamboo structure wall were tested in natural climate and three representative variation processes of heat and moisture： heating from solar radiation in summer at normal temperature and humidity, heating from solar radiation in summer at normal temperature and high humidity after rain, humidifying from brash in summer at high temperature and normal humidity. The results show that, in summer, the largest temperature difference between external and internal surface of the 28 mm-thick bamboo plywood wall is 11.73℃ （at 15：40） and the largest strain difference is 136 μm/m （at 18：50）, both in ambient and indoor conditioned environment. In heating process, lengthways of the wall surface are in contracting strain while transverse ways are in expanding strain at initial stage and in contracting strain during later period. When the high temperature wall is humidified by rain, the surface temperature drops, moisture content increases and the expanding strain is presented on the surface during the whole process. Temperature and moisture content are two important factors which affect thermal and moisture stress （TMS） of the bamboo structure wall. The TMS is not only related to temperature and moisture content, but also greatly affected by temperature gradient, moisture content gradient and rates of changing.
基金the National Natural Science Foundation of China(Grant No.11772058).
文摘Ammonium perchlorate(AP)is the component with the highest content in composite propellants,and it plays a crucial role in propellant performance.In view of the effects of low-temperature AP thermal decomposition on thermal safety and combustion characteristics,porous ammonium perchlorate(PAP)samples with different mass losses were first prepared by thermal convection heating,and the structures were characterized and analysed.Second,the effects of decomposition degree on the thermal decomposition characteristics of PAP were studied by DSC-TG.Finally,the combustion characteristics of AP/Al binary mixtures were tested with high-speed photography and in a sealed bomb.The results showed that low-temperature decomposition of AP resulted in formation of porous structures for AP particles.The pores first appeared near the surfaces of the particles and began from multiple points at the same time.The pores increased in size to approximately 5 mm and then expanded,and finally,the AP particles were full of pores.After partial decomposition,the crystal structure of AP remained unchanged,but the low and high decomposition temperatures decreased obviously.The decomposition rate accelerated.Due to the porous structure of PAP,the combustion rate of the AP/Al system increased obviously with increasing decomposition of AP.The relationship between the combustion rate and the mass loss was approximately linear under open conditions,and it was exponential for a high-pressure environment.A computational model of the combustion process for the AP/Al binary system was established to explain the effects of pore structure and pressure on the combustion process.
基金Projects(42477162,52108347,52178371,52168046,52178321,52308383)supported by the National Natural Science Foundation of ChinaProjects(2023C03143,2022C01099,2024C01219,2022C03151)supported by the Zhejiang Key Research and Development Plan,China+6 种基金Project(LQ22E080010)supported by the Exploring Youth Project of Zhejiang Natural Science Foundation,ChinaProject(LR21E080005)supported by the Outstanding Youth Project of Natural Science Foundation of Zhejiang Province,ChinaProject(2022M712964)supported by the Postdoctoral Science Foundation of ChinaProject(2023AFB008)supported by the Natural Science Foundation of Hubei Province for Youth,ChinaProject(202203)supported by Engineering Research Centre of Rock-Soil Drilling&Excavation and Protection,Ministry of Education,ChinaProject(202305-2)supported by the Science and Technology Project of Zhejiang Provincial Communication Department,ChinaProject(2021K256)supported by the Construction Research Founds of Department of Housing and Urban-Rural Development of Zhejiang Province,China。
文摘This study proposes a general imperfect thermal contact model to predict the thermal contact resistance at the interface among multi-layered composite structures.Based on the Green-Lindsay(GL)thermoelastic theory,semi analytical solutions of temperature increment and displacement of multi-layered composite structures are obtained by using the Laplace transform method,upon which the effects of thermal resistance coefficient,partition coefficient,thermal conductivity ratio and heat capacity ratio on the responses are studied.The results show that the generalized imperfect thermal contact model can realistically describe the imperfect thermal contact problem.Accordingly,it may degenerate into other thermal contact models by adjusting the thermal resistance coefficient and partition coefficient.
文摘Prior to the collision and accretion of the Kohistan arc terrane during the late Cretaceous and the Indian plate after the early Eocene, the southern margin of Asia along the Hindu Kush, Karakoram and Lhasa block terranes was an active Andean\|type continental margin. In south Tibet this margin was dominated by the calc\|alkaline Ladakh—Gangdese granite batholith, associated andesitic volcanic rocks and continental red\|beds. In contrast, the southern Karakoram exposes deep crustal metamorphic rocks and crustal melt leucogranites. New U\|Pb age dating from the Hunza valley and Baltoro glacier region has revealed four spatially and temporally distinct metamorphic episodes. M1 sillimanite grade metamorphism in Hunza was a late Cretaceous event, probably caused by the accretion of the Kohistan arc to Asia. M2 was the major kyanite and sillimanite grade event during late Eocene—Oligocene crustal thickening and shortening, following India\|Asia collision. Numerous melting events resulted in the formation of crustal melt granites throughout the last 50Ma with multiple generations of dykes and very large scale crustal melting along the Baltoro monzogranite\|leucogranite ba tholith during the late Oligocene—early Miocene. M3 metamorphism was a high\| T , low\| p contact thermal metamorphism around the Baltoro granite. In Hunza, younger staurolite grade metamorphism has been dated by U\|Pb monazites at 16Ma, with the Sumayar leucogranite intruded at 9 5Ma cross\|cutting the metamorphic isograds. In the Baltoro region the youngest metamorphism, M4, is the sillimanite grade Dassu gneiss core complex dated by U\|Pb on monazites as late Miocene—Pliocene (5 4±0 25)Ma with Precambrian protolith zircon cores (1855±11)Ma. Numerous gem\|bearing pegmatite dykes cross\|cut these rocks and are thought to have been intruded within the last 2～3Ma. Structural mapping, combined with U\|Pb geochronology shows that major metamorphic events can be both long\|lasting (up to 20Ma) and very restrictive, both in time and space.
文摘The electronic structures of pure V, Nb and Ta metals with bcc structure were determined by one atom (OA) theory. According to the electronic structures of these metals, their potential curves, cohesive energies, lattice parameters, elasticity and the dependence of linear thermal expansion coefficients on temperature were calculated. The electronic structures and characteristic properties of these metals with fcc and hcp structures and liquid states were studied.
