Application of thermal electrochemical equation to metal-hydride half-cell system was investigated, and the influence of state of charge on the thermal electrochemical performance of hydrogen storage materials was stu...Application of thermal electrochemical equation to metal-hydride half-cell system was investigated, and the influence of state of charge on the thermal electrochemical performance of hydrogen storage materials was studied. The results show that both the absolute value of the molar enthalpy change and the internal resistance of evolution hydrogen reaction are less than that of absorption hydrogen reaction at the same state of charge. The molar reaction enthalpy change of absorption and evolution of hydride electrode change contrarily with the enhancement of filling degree of hydrogen in hydride electrode. The relation curve of molar reaction enthslpy change to state of charge, both absorption and evolution hydrogen reaction, is close to a constant when the state of charge is 10%- 60%, and during state of charge below 10% or state of charge above 60%, the molar reaction enthalpy change varies sharply. Meanwhile, the internal resistance of electrode reaction has an ascending trend with the enhancement on filling degree of hydrogen in hydride electrode in both absorption and evolution hydrogen reaction.展开更多
The debris from exploded buildings can ricochet after colliding with the ground,thus increasing the debris travel distance and danger from any associated impacts or collisions.To reduce this danger,the travel distance...The debris from exploded buildings can ricochet after colliding with the ground,thus increasing the debris travel distance and danger from any associated impacts or collisions.To reduce this danger,the travel distance of ricocheted debris must be accurately predicted.This study analyzed the change in the travel distance of ricocheted concrete debris relative to changes in the properties of a sand medium.Direct shear tests were conducted to measure the change in internal friction angle as a function of temperature and water content of the sand.Finite element analysis(FEA)was then applied to these variables to predict the speed and angle of the debris after ricochet.The FEA results were compared with results of low-speed ricochet experiments,which employed variable temperature and water content.The travel distance of the debris was calculated using MATLAB,via trajectory equations considering the drag coefficient.As the internal friction angle decreased,the shear stress decreased,leading to deeper penetration of the debris into the sand.As the loss of kinetic energy increased,the velocity and travel distance of the ricocheted debris decreased.Changes in the ricochet velocity and travel distance of the debris,according to changes in the internal friction angle,indicated that the debris was affected by the environment.展开更多
基金Project(2001AA501433) supported by the National High Technology Research and Development Programof China
文摘Application of thermal electrochemical equation to metal-hydride half-cell system was investigated, and the influence of state of charge on the thermal electrochemical performance of hydrogen storage materials was studied. The results show that both the absolute value of the molar enthalpy change and the internal resistance of evolution hydrogen reaction are less than that of absorption hydrogen reaction at the same state of charge. The molar reaction enthalpy change of absorption and evolution of hydride electrode change contrarily with the enhancement of filling degree of hydrogen in hydride electrode. The relation curve of molar reaction enthslpy change to state of charge, both absorption and evolution hydrogen reaction, is close to a constant when the state of charge is 10%- 60%, and during state of charge below 10% or state of charge above 60%, the molar reaction enthalpy change varies sharply. Meanwhile, the internal resistance of electrode reaction has an ascending trend with the enhancement on filling degree of hydrogen in hydride electrode in both absorption and evolution hydrogen reaction.
基金This study was financially supported by the Foundation Research Program[grant number UD170027GD]of the Agency for Defense Development and the Defense Acquisition Program Administration of the Republic of Korea.
文摘The debris from exploded buildings can ricochet after colliding with the ground,thus increasing the debris travel distance and danger from any associated impacts or collisions.To reduce this danger,the travel distance of ricocheted debris must be accurately predicted.This study analyzed the change in the travel distance of ricocheted concrete debris relative to changes in the properties of a sand medium.Direct shear tests were conducted to measure the change in internal friction angle as a function of temperature and water content of the sand.Finite element analysis(FEA)was then applied to these variables to predict the speed and angle of the debris after ricochet.The FEA results were compared with results of low-speed ricochet experiments,which employed variable temperature and water content.The travel distance of the debris was calculated using MATLAB,via trajectory equations considering the drag coefficient.As the internal friction angle decreased,the shear stress decreased,leading to deeper penetration of the debris into the sand.As the loss of kinetic energy increased,the velocity and travel distance of the ricocheted debris decreased.Changes in the ricochet velocity and travel distance of the debris,according to changes in the internal friction angle,indicated that the debris was affected by the environment.
