Proton exchange membrane fuel cells(PEMFC)have attracted much attention because of their high energy conversion efficiency,high power density and zero emission of pollutants.However,the high cost of the cathode platin...Proton exchange membrane fuel cells(PEMFC)have attracted much attention because of their high energy conversion efficiency,high power density and zero emission of pollutants.However,the high cost of the cathode platinum group metal(PGM)catalysts creates a barrier for the large-scale application of PEMFC.Tremendous efforts have been devoted to the development of low-cost PGM-free catalysts,especially the Fe-N-C catalysts,to replace the expensive PGM catalysts.However,the characterization methods and evaluation standards of the catalysts varies,which is not conducive to the comparison of PGM-free catalysts.U.S.Department of energy(DOE)is the only authority that specifies the testing standards and activity targets for PGM-free catalysts.In this review,the major breakthroughs of Fe-N-C catalysts are outlined with the reference of DOE standards and targets.The preparation and characteristics of these highly active Fe-N-C catalysts are briefly introduced.Moreover,the efforts on improving the mass transfer and the durability issue of Fe-N-C fuel cell are discussed.Finally,the prospective directions concerning the comprehensive evaluation of the Fe-N-C catalysts are proposed.展开更多
A highway in the floodplain of the Abandoned Yellow River in the north of Jiangsu Province is recently remediated to reduce liquefaction potential using the dynamic compaction(DC)method of densification of in-place so...A highway in the floodplain of the Abandoned Yellow River in the north of Jiangsu Province is recently remediated to reduce liquefaction potential using the dynamic compaction(DC)method of densification of in-place soils.Firstly,the liquefaction potential of the soil at the project site is analysed according to the code of seismic design.Then the in-situ single point impact tests are performed on the liquefiable soil.Settlement of crater,excess pore pressure,ground heave and lateral deformation under DC impact are measured and analyzed.Subsequently, the standard penetration test(SPT)and cone penetration test(CPT)are used for investigating the compaction effectiveness.At last,the improvement effect of DC is discussed according to the technical specification of dynamic consolidation to ground treatment.The investigation results indicate that the DC technique is an effective way for remediating liquefiable soil in highway engineering practice.展开更多
基金supported by the National Thousand Talents Plan of Chinathe National Natural Science Foundation of China(Grant Nos.21673014 and U1766216)+1 种基金the 111 project(B17002)funded by the Ministry of Education of Chinathe Fundamental Research Funds for the Central Universities of China
文摘Proton exchange membrane fuel cells(PEMFC)have attracted much attention because of their high energy conversion efficiency,high power density and zero emission of pollutants.However,the high cost of the cathode platinum group metal(PGM)catalysts creates a barrier for the large-scale application of PEMFC.Tremendous efforts have been devoted to the development of low-cost PGM-free catalysts,especially the Fe-N-C catalysts,to replace the expensive PGM catalysts.However,the characterization methods and evaluation standards of the catalysts varies,which is not conducive to the comparison of PGM-free catalysts.U.S.Department of energy(DOE)is the only authority that specifies the testing standards and activity targets for PGM-free catalysts.In this review,the major breakthroughs of Fe-N-C catalysts are outlined with the reference of DOE standards and targets.The preparation and characteristics of these highly active Fe-N-C catalysts are briefly introduced.Moreover,the efforts on improving the mass transfer and the durability issue of Fe-N-C fuel cell are discussed.Finally,the prospective directions concerning the comprehensive evaluation of the Fe-N-C catalysts are proposed.
基金Supported by the National Youth Science Foundation of China(40802065)the Jiangsu Province Ed-ucation Science Foundation(08KJD580004)the Innovation Research Foundation of Nanjing Institute of Technology(CKJ2011010)
文摘A highway in the floodplain of the Abandoned Yellow River in the north of Jiangsu Province is recently remediated to reduce liquefaction potential using the dynamic compaction(DC)method of densification of in-place soils.Firstly,the liquefaction potential of the soil at the project site is analysed according to the code of seismic design.Then the in-situ single point impact tests are performed on the liquefiable soil.Settlement of crater,excess pore pressure,ground heave and lateral deformation under DC impact are measured and analyzed.Subsequently, the standard penetration test(SPT)and cone penetration test(CPT)are used for investigating the compaction effectiveness.At last,the improvement effect of DC is discussed according to the technical specification of dynamic consolidation to ground treatment.The investigation results indicate that the DC technique is an effective way for remediating liquefiable soil in highway engineering practice.
