In this study,Schwertmannite,Akaganéite and ammoniojarosite were biosynthesized by different bacteria and characterized.The results showed that bacteria are critical in mediating the mineral formation process:the...In this study,Schwertmannite,Akaganéite and ammoniojarosite were biosynthesized by different bacteria and characterized.The results showed that bacteria are critical in mediating the mineral formation process:the morphology,crystallinity,grain size and specific surface area of each mineral varied upon different bacteria and culturing conditions.In addition,the formed minerals’elemental composition and group disparity lead to different morphology,crystallinity and subsequent adsorption performance.In particular,adsorption difference existed in iron minerals biosynthesized by different bacteria.The maximal adsorption capacities of Akaganéite,Schwertmannite and ammoniojarosite were 26.6 mg/g,17.5 mg/g and 3.90 mg/g respectively.Cr(VI)adsorption on iron-minerals involves hydrogen bonding,electrostatic interaction,and ligand exchange.The adsorption only occurred on the surface of ammoniojarosite,while for Akaganéite and Schwertmannite,the tunnel structure greatly facilitated the adsorption process and improved adsorption capacity.Thus,the molecular structure is the primary determining factor for adsorption performance.Collectively,the results can provide useful information in selecting suitable bacteria for synthesizing heavy-metal scavenging minerals according to different environmental conditions.展开更多
The Kohistan Terrane in N. Pakistan straddles the suture zone between the collided Indian and Eurasian plates in the NW Himalayas of N. Pakistan. Initiated as an intra\|oceanic island\|arc crust in Neotethys, the terr...The Kohistan Terrane in N. Pakistan straddles the suture zone between the collided Indian and Eurasian plates in the NW Himalayas of N. Pakistan. Initiated as an intra\|oceanic island\|arc crust in Neotethys, the terrane accreted with the southern margin of the Karakoram Plate in the Late Cretaceous (about 90Ma). Continued subduction at its southern margin resulted in Andean\|type magmatism and tectonics, until collision with the Indian Plat in the Early Eocene.Whereas much of the central and eastern Kohistan expose Cretaceous volcanic and sedimentary rocks of intra\|oceanic island arc setting, the western Kohistan in Swat, Dir, Chitral and upper Ghizer valleys preserves remnants of the Late Paleocene—Early Eocene volcanism and sedimentation of Andean\|type setting. These volcano\|sedimentary lithologies in western Kohistan are geographically divisible into two, separated by the Lowari Pluton; (1) Dir\|Swat Belt, (2) Drosh\|Shamran Belt. Late Paleocene\|Early Eocene siliceous volcanics termed Utror Volcanics and Shamran Volcanics are common in the two belts and so are the plutons intrusive into these volcanics (Late Stage\|II of the Kohistan Batholith). The difference is in the sedimentary successions presented in the two belts. Whereas in the Dir\|Swat belt, the sedimentary succession comprises Baraul Banda Slate Formation, deposited in deep\|water fore\|arc setting and contemporaneous in age with that of the nearby Utror Volcanic Formation (about 55～60Ma), the sediments in the Drosh\|Shamran belt are distinctly red beds of fluvial origin (the Purit Formation) those overlie unconformably on top of the Shamran Volcanics and their equivalents.展开更多
The Kyzylalmasay gold-silver deposit is located within the Southwest spurs of the Chatkal ridge of the Beltau-Kurama volcanic-plutonic belt.The deposit is related to typical sub-aerial margin-continental structures of...The Kyzylalmasay gold-silver deposit is located within the Southwest spurs of the Chatkal ridge of the Beltau-Kurama volcanic-plutonic belt.The deposit is related to typical sub-aerial margin-continental structures of tectonic-magmatic activation,in which there is a wide development of volcanogenic Au-Ag deposits.The deposits are conjugate with a basalt-andesite-dacite volcanic fractionation sequence. Ore-forming processes are related to展开更多
The study area is part of the Urumieh–Dokhtar volcanic arc that a large part of its surface is covered by extrusive Igneous rocks(tuff,intermediate lavas and ignimbrites sheets),plutonic igneous(diorite and granodior...The study area is part of the Urumieh–Dokhtar volcanic arc that a large part of its surface is covered by extrusive Igneous rocks(tuff,intermediate lavas and ignimbrites sheets),plutonic igneous(diorite and granodiorite)and semi-deep stones(dyke and sill).Studied samples are situated in calc-alkaline domain of magmatic series diagrams.Harker diagrams show the fractional crystallization of Clinopyroxene,amphibole,plagioclase,alkali feldspars and opaque minerals(ilmenite Titano-magnetite,ilmenite and rutile).In spider diagrams,light rare earth elements(LREE)are enriched compared to heavy rare earth elements(HREE),and HFS elements(Ti,Nb)show negative anomaly and LFS elements(Cs,K,Pb)show positive anomaly,showing that it is a distinct characteristic of subduction zones.Skarns of the area mainly are of exoskarns and are rich in plagioclase,microcline,amphibole,biotite and epidote.Skarn is enriched of iron,copper,molybdenum,vanadium,lead,zinc and silver.Deposits of barite in the area show characteristics of volcanic-sedimentary barites and are associated to ore-bearing hydrothermal solutions.Using satellite images and processing information,four areas with high mineral potential are identified in the area.展开更多
Eastern Tianshan, a cardinal part of Northern Xinjiang compound continental crustoblock, is located in the east of Tianshan Diwa region. By analysis of regional geological and geophysical data, and by using crustobody...Eastern Tianshan, a cardinal part of Northern Xinjiang compound continental crustoblock, is located in the east of Tianshan Diwa region. By analysis of regional geological and geophysical data, and by using crustobody theory and researching methods, this region can be divided into three sectors of different crustal structure. During Proterozoic to Eopaleozoic, the spreading and closing of Northern Tianshan Sea, on the foundation of disparate continental basements of each sectors, the transversal heterogeneity of tectonic movement and evolution resulted in the diversity of crustal structure and material formations. The metallogenic evolution indicated that different geotectonic evolution periods had not only different characteristics of mineralization commodity and mineral deposit types, but also the progressive mineralization feature. In Neopaleozoic, the closing of Northern Tianshan Sea from north to south and the difference of transmeridional tectonic deformation and magmation formed in the movement constituted the different metallogenic environment in shallow crust. Furthermore, it brought on the diverse Cu-Au-polymetal mineral deposit types and metallogenetic epoch from north to south and from west to east.展开更多
Longtoushan Sn-polymetal deposit is a large-scale deposit of high-tenor. The ore-bodies occur in reef limestone of middle Devonian. There is much anthraxolite in reef limestone and ore-bodies. The anthraxolite is the ...Longtoushan Sn-polymetal deposit is a large-scale deposit of high-tenor. The ore-bodies occur in reef limestone of middle Devonian. There is much anthraxolite in reef limestone and ore-bodies. The anthraxolite is the postmature result of oil-gas' thermal metamorphism. The close relationship of anthraxolite and Sn-polymetal deposit reveals the space-time relation between oil-gas evolution and Sn-polymetal mineralization. Sulfur isotope of Longtoushan deposit is close to oil's sulfur in Devonian, which indicates obvious relationship between the sulfur's source of deposit and oil-gas' activity. The forming of Longtoushan deposit relates to exhalative-sedimentary mineralization in Devonian. Because of the favorable hydrocarbon-forming condition of Longtoushan reef and surrounding basin facies' black shale and peat, coupling of ore-formation and hydrocarbon-forming occurs in seabed's hydrothermal convection. The distributing of ore-forming elements indicates the presence of hydrothermal convection system. The thermal fluid containing organic matters conduces to Sn-polymetal elements' activation and transfer, and provides catalyzing condition to the transforming from SO42- to S2-. The erosion action of brine containing organic acid to reef limestone induces the growing of crannies and karst's caverns, which provides advantageous space to Sn-polymetal mineralization. The heat source of mineralization provides thermocatalysis condition to hydrocarbon-forming. When the circulatory fluid containing oil-gas enters the high-temperature region(＞150 ℃ ), the oil-gas is decomposed and anthraxolite comes into being.展开更多
Introduction Mechanotransduction has demonstrated potentials for tissue adaptation in vivo and in vitro. It is well documented that ultrasound,as a mechanical signal,can produce a wide variety of biological effects in...Introduction Mechanotransduction has demonstrated potentials for tissue adaptation in vivo and in vitro. It is well documented that ultrasound,as a mechanical signal,can produce a wide variety of biological effects in vitro and in vivo [1]. As an example,展开更多
基金Project(42277256)supported by the National Natural Science Foundation of ChinaProjects(HBKT-2021011,HBKT-2021014)supported by the Hunan Province Environmental Protection Research Program,ChinaProject(CDSKY-2023-05)supported by the Scientific Research of Project Hunan Provincial Urban Geological Survey and Monitoring Institute,China。
文摘In this study,Schwertmannite,Akaganéite and ammoniojarosite were biosynthesized by different bacteria and characterized.The results showed that bacteria are critical in mediating the mineral formation process:the morphology,crystallinity,grain size and specific surface area of each mineral varied upon different bacteria and culturing conditions.In addition,the formed minerals’elemental composition and group disparity lead to different morphology,crystallinity and subsequent adsorption performance.In particular,adsorption difference existed in iron minerals biosynthesized by different bacteria.The maximal adsorption capacities of Akaganéite,Schwertmannite and ammoniojarosite were 26.6 mg/g,17.5 mg/g and 3.90 mg/g respectively.Cr(VI)adsorption on iron-minerals involves hydrogen bonding,electrostatic interaction,and ligand exchange.The adsorption only occurred on the surface of ammoniojarosite,while for Akaganéite and Schwertmannite,the tunnel structure greatly facilitated the adsorption process and improved adsorption capacity.Thus,the molecular structure is the primary determining factor for adsorption performance.Collectively,the results can provide useful information in selecting suitable bacteria for synthesizing heavy-metal scavenging minerals according to different environmental conditions.
文摘The Kohistan Terrane in N. Pakistan straddles the suture zone between the collided Indian and Eurasian plates in the NW Himalayas of N. Pakistan. Initiated as an intra\|oceanic island\|arc crust in Neotethys, the terrane accreted with the southern margin of the Karakoram Plate in the Late Cretaceous (about 90Ma). Continued subduction at its southern margin resulted in Andean\|type magmatism and tectonics, until collision with the Indian Plat in the Early Eocene.Whereas much of the central and eastern Kohistan expose Cretaceous volcanic and sedimentary rocks of intra\|oceanic island arc setting, the western Kohistan in Swat, Dir, Chitral and upper Ghizer valleys preserves remnants of the Late Paleocene—Early Eocene volcanism and sedimentation of Andean\|type setting. These volcano\|sedimentary lithologies in western Kohistan are geographically divisible into two, separated by the Lowari Pluton; (1) Dir\|Swat Belt, (2) Drosh\|Shamran Belt. Late Paleocene\|Early Eocene siliceous volcanics termed Utror Volcanics and Shamran Volcanics are common in the two belts and so are the plutons intrusive into these volcanics (Late Stage\|II of the Kohistan Batholith). The difference is in the sedimentary successions presented in the two belts. Whereas in the Dir\|Swat belt, the sedimentary succession comprises Baraul Banda Slate Formation, deposited in deep\|water fore\|arc setting and contemporaneous in age with that of the nearby Utror Volcanic Formation (about 55～60Ma), the sediments in the Drosh\|Shamran belt are distinctly red beds of fluvial origin (the Purit Formation) those overlie unconformably on top of the Shamran Volcanics and their equivalents.
文摘The Kyzylalmasay gold-silver deposit is located within the Southwest spurs of the Chatkal ridge of the Beltau-Kurama volcanic-plutonic belt.The deposit is related to typical sub-aerial margin-continental structures of tectonic-magmatic activation,in which there is a wide development of volcanogenic Au-Ag deposits.The deposits are conjugate with a basalt-andesite-dacite volcanic fractionation sequence. Ore-forming processes are related to
文摘The study area is part of the Urumieh–Dokhtar volcanic arc that a large part of its surface is covered by extrusive Igneous rocks(tuff,intermediate lavas and ignimbrites sheets),plutonic igneous(diorite and granodiorite)and semi-deep stones(dyke and sill).Studied samples are situated in calc-alkaline domain of magmatic series diagrams.Harker diagrams show the fractional crystallization of Clinopyroxene,amphibole,plagioclase,alkali feldspars and opaque minerals(ilmenite Titano-magnetite,ilmenite and rutile).In spider diagrams,light rare earth elements(LREE)are enriched compared to heavy rare earth elements(HREE),and HFS elements(Ti,Nb)show negative anomaly and LFS elements(Cs,K,Pb)show positive anomaly,showing that it is a distinct characteristic of subduction zones.Skarns of the area mainly are of exoskarns and are rich in plagioclase,microcline,amphibole,biotite and epidote.Skarn is enriched of iron,copper,molybdenum,vanadium,lead,zinc and silver.Deposits of barite in the area show characteristics of volcanic-sedimentary barites and are associated to ore-bearing hydrothermal solutions.Using satellite images and processing information,four areas with high mineral potential are identified in the area.
文摘Eastern Tianshan, a cardinal part of Northern Xinjiang compound continental crustoblock, is located in the east of Tianshan Diwa region. By analysis of regional geological and geophysical data, and by using crustobody theory and researching methods, this region can be divided into three sectors of different crustal structure. During Proterozoic to Eopaleozoic, the spreading and closing of Northern Tianshan Sea, on the foundation of disparate continental basements of each sectors, the transversal heterogeneity of tectonic movement and evolution resulted in the diversity of crustal structure and material formations. The metallogenic evolution indicated that different geotectonic evolution periods had not only different characteristics of mineralization commodity and mineral deposit types, but also the progressive mineralization feature. In Neopaleozoic, the closing of Northern Tianshan Sea from north to south and the difference of transmeridional tectonic deformation and magmation formed in the movement constituted the different metallogenic environment in shallow crust. Furthermore, it brought on the diverse Cu-Au-polymetal mineral deposit types and metallogenetic epoch from north to south and from west to east.
文摘Longtoushan Sn-polymetal deposit is a large-scale deposit of high-tenor. The ore-bodies occur in reef limestone of middle Devonian. There is much anthraxolite in reef limestone and ore-bodies. The anthraxolite is the postmature result of oil-gas' thermal metamorphism. The close relationship of anthraxolite and Sn-polymetal deposit reveals the space-time relation between oil-gas evolution and Sn-polymetal mineralization. Sulfur isotope of Longtoushan deposit is close to oil's sulfur in Devonian, which indicates obvious relationship between the sulfur's source of deposit and oil-gas' activity. The forming of Longtoushan deposit relates to exhalative-sedimentary mineralization in Devonian. Because of the favorable hydrocarbon-forming condition of Longtoushan reef and surrounding basin facies' black shale and peat, coupling of ore-formation and hydrocarbon-forming occurs in seabed's hydrothermal convection. The distributing of ore-forming elements indicates the presence of hydrothermal convection system. The thermal fluid containing organic matters conduces to Sn-polymetal elements' activation and transfer, and provides catalyzing condition to the transforming from SO42- to S2-. The erosion action of brine containing organic acid to reef limestone induces the growing of crannies and karst's caverns, which provides advantageous space to Sn-polymetal mineralization. The heat source of mineralization provides thermocatalysis condition to hydrocarbon-forming. When the circulatory fluid containing oil-gas enters the high-temperature region(＞150 ℃ ), the oil-gas is decomposed and anthraxolite comes into being.
基金supported by the NIH (R01 AR52379 & R01 AR49286),U S Army Medical Research and NSBRI
文摘Introduction Mechanotransduction has demonstrated potentials for tissue adaptation in vivo and in vitro. It is well documented that ultrasound,as a mechanical signal,can produce a wide variety of biological effects in vitro and in vivo [1]. As an example,
