This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only b...This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only be obtained by some USVs.In order to achieve semi-encirclement tracking of noncooperative targets under maritime security conditions,a fixed-time tracking control method based on dynamic surface control(DSC)is proposed in this paper.Firstly,a novel TACC architecture with decoupled kinematic control law and decoupled kinetic control law was designed to reduce the complexity of control system design.Secondly,the proposed DSC-based target-guided kinematic control law including tracking points pre-allocation strategy and sigmoid artificial potential functions(SigAPFs)can avoid collisions during tracking process and optimize kinematic control output.Finally,a fixed-time TACC system was proposed to achieve fast convergence of kinematic and kinetics errors.The effectiveness of the proposed TACC approach in improving target tracking safety and reducing control output chattering was verified by simulation comparison results.展开更多
The work takes a new liquid-cooling plate in a power battery with pin fins inside the channel as the object.A mathematical model is established via the central composite design of the response surface to study the rel...The work takes a new liquid-cooling plate in a power battery with pin fins inside the channel as the object.A mathematical model is established via the central composite design of the response surface to study the relationships among the length,width,height,and spacing of pin fins;the maximum temperature and temperature difference of the battery module;and the pressure drop of the liquid-cooling plate.Model accuracy is verified via variance analysis.The new liquid-cooling plate enables the power battery to work within an optimal temperature range.Appropriately increasing the length,width,and height and reducing the spacing of pin fins could reduce the temperature of the power battery module and improve the temperature uniformity.However,the pressure drop of the liquid-cooling plate increases.The structural parameters of the pin fins are optimized to minimize the maximum temperature and the temperature difference of the battery module as well as the pressure drop of the liquid-cooling plate.The errors between the values predicted and actual by the simulation test are 0.58%,4%,and 0.48%,respectively,which further verifies the model accuracy.The results reveal the influence of the structural parameters of the pin fins inside the liquid-cooling plate on its heat dissipation performance and pressure drop characteristics.A theoretical basis is provided for the design of liquid-cooling plates in power batteries and the optimization of structural parameters.展开更多
Since the discovery of carbon dots(CDs)in 2004,the unique photoluminescence phenomenon of CDs has attracted widespread attention.However,the molecular weight of CDs has not been adequately quantified at present,due to...Since the discovery of carbon dots(CDs)in 2004,the unique photoluminescence phenomenon of CDs has attracted widespread attention.However,the molecular weight of CDs has not been adequately quantified at present,due to CDs are atomically imprecise and their molecular weight distribution is broad.In this paper,a series of Pluronic-modified CDs were prepared and the structure of the CDs was briefly analyzed.Subsequently,a molecular weight measurement method based on colligative properties was developed,and the correction coefficient in the algorithm was briefly analyzed.The calculated molecular weight was applied to the determination of surface adsorption capacity.This work provided a method for averaging the molecular weight of atomically imprecise particulate materials,which is expected to provide new opportunities in related fields.展开更多
Changes to the microstructure of a hard carbon(HC)and its solid electrolyte interface(SEI)can be effective in improving the electrode kinetics.However,achieving fast charging using a simple and inexpensive strategy wi...Changes to the microstructure of a hard carbon(HC)and its solid electrolyte interface(SEI)can be effective in improving the electrode kinetics.However,achieving fast charging using a simple and inexpensive strategy without sacrificing its initial Coulombic efficiency remains a challenge in sodium ion batteries.A simple liquid-phase coating approach has been used to generate a pitch-derived soft carbon layer on the HC surface,and its effect on the porosity of HC and SEI chemistry has been studied.A variety of structural characterizations show a soft carbon coating can increase the defect and ultra-micropore contents.The increase in ultra-micropore comes from both the soft carbon coatings and the larger pores within the HC that are partially filled by pitch,which provides more Na+storage sites.In-situ FTIR/EIS and ex-situ XPS showed that the soft carbon coating induced the formation of thinner SEI that is richer in NaF from the electrolyte,which stabilized the interface and promoted the charge transfer process.As a result,the anode produced fastcharging(329.8 mAh g^(−1)at 30 mA g^(−1)and 198.6 mAh g^(−1)at 300 mA g^(−1))and had a better cycling performance(a high capacity retention of 81.4%after 100 cycles at 150 mA g^(−1)).This work reveals the critical role of coating layer in changing the pore structure,SEI chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced fast charging capability.展开更多
Surface pretreatment can change the surface properties of minerals,placing them in either a favorable or an unfavorable state for flotation.To solve the separation problem associated with magnesite and dolomite,surfac...Surface pretreatment can change the surface properties of minerals,placing them in either a favorable or an unfavorable state for flotation.To solve the separation problem associated with magnesite and dolomite,surface pretreatment experiments with citric acid,tartaric acid,and tannic acid(TA)on magnesite and dolomite as well as flotation experiments on pretreated samples were performed in this study.Experimental results demonstrated that when citric acid and tartaric acid are used for surface pretreatment,the separation effect of magnesite and dolomite is poor.However,when TA is used,the separation effect of magnesite and dolomite improves.SEM and BET analysis indicated that surface pretreatment with TA changes the surface morphology of the two minerals,resulting in additional concave pores on the dolomite surface,and a significant increase in pore size and specific surface area.The adsorption quantity test and contact angle measurement demonstrated that after surface pretreatment with TA,the magnesite adsorption capacity on sodium oleate(NaOL)slightly decreases and the dolomite adsorption capacity on NaOL considerably decreases.XPS detection concluded that the surface pretreatment of TA on the magnesite surface mainly relies on physical adsorption with weak adsorption ability and poor ability to act on Mg sites.The TA surface pretreatment action on the dolomite surface is mainly through chemical adsorption,and it is strongly and selectively adsorbed on the Ca site of dolomite through O.Actual ore rough selection experiments reveal that TA pretreatment successfully removes dolomite from magnesite,resulting in a high-quality magnesite concentrate characterized by a MgO grade of 45.49%and a CaO grade of 0.75%.展开更多
On-machine measurement(OMM)stands out as a pivotal technology in complex curved surface adaptive machining.However,the complex structure inherent in workpieces poses a significant challenge as the stylus orientation f...On-machine measurement(OMM)stands out as a pivotal technology in complex curved surface adaptive machining.However,the complex structure inherent in workpieces poses a significant challenge as the stylus orientation frequently shifts during the measurement process.Consequently,a substantial amount of time is allocated to calibrating pre-travel error and probe movement.Furthermore,the frequent movement of machine tools also increases the influence of machine errors.To enhance both accuracy and efficiency,an optimization strategy for the OMM process is proposed.Based on the kinematic chain of the machine tools,the relationship between the angle combination of rotary axes,the stylus orientation,and the calibration position of pre-travel error is disclosed.Additionally,an OMM efficiency optimization model for complex curved surfaces is developed.This model is solved to produce the optimal efficiency angle combinations for each to-be-measured point.Within each angle combination,the effects of positioning errors on measurement results are addressed by coordinate system offset and measurement result compensation method.Finally,the experiments on an impeller are used to demonstrate the practical utility of the proposed method.展开更多
This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural fe...This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural features of cellular structures,which stems from the degree of porosity and the distri-bution of the pores.Unlike the phonon-driven surface effect at the nanoscale,the macro-scale surface mechanism in thermal cellular structures is found to be the microstructure-induced changes in the heat conduction path based on fully resolved 3D numerical simulations.The surface region is determined by the microstructure,characterized by the intrinsic length.With the coupling between extrinsic and intrinsic length scales under the surface mechanism,a surface-enriched multiscale method was devel-oped to accurately capture the complex size-dependent thermal conductivity.The principle of scale separation required by classical multiscale methods is not necessary to be satisfied by the proposed multiscale method.The significant potential of the surface-enriched multiscale method was demon-strated through simulations of the effective thermal conductivity of a thin-walled metamaterial struc-ture.The surface-enriched multiscale method offers higher accuracy compared with the classical multiscale method and superior efficiency over high-fidelity finite element methods.展开更多
The intricate grinding process exposes various cleavage surfaces of mineral particles.This paper systematically investigates the structural characteristics of exposed malachite crystal surfaces and the adsorption beha...The intricate grinding process exposes various cleavage surfaces of mineral particles.This paper systematically investigates the structural characteristics of exposed malachite crystal surfaces and the adsorption behavior and mechanism of hydroxamic acid and water molecules using first-principle density functional theory.The study reveals anisotropic surface energies among crystal surfaces,ranked as(201)>(100)>(110)>(001)>(010)>(201).The adsorption of hydroxamic acid and water molecules on malachite surfaces also exhibited anisotropy.The difference in adsorption strength between hydroxamic acid and water molecules on the six exposed surfaces followed the order of(110)>(100)>(010)>(001)>(201)>(201),and the resistance of water molecules to the adsorption of hydroxamic acid on the six exposed surfaces was(110)>(201)>(010)>(201)>(001)>(100).It indicates that the reagent exhibits a strong competitive advantage in adsorption on the(100)surface,and the hindrance of water molecules to reagent adsorption is relatively small,which is favorable for flotation.This study provides theoretical references and innovative insights for the precise design of flotation reagents,as well as for the meticulous optimization of mineral surface interfaces,with the objective of enhancing flotation separation.展开更多
This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor ...This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor series.This expansion enables the reasonable construction of a function describing the NS on the SS.Additionally,by directly incorporating the nonlinear Generalized Hoke-Brown(GHB)strength criterion and utilizing the slope factor of safety(FOS)definition,a function of the shear stress on the SS is derived.This function considers the mutual feedback mechanism between the NS and strength parameters of the SS.The stress constraints conditions are then introduced at both ends of the SS based on the spatial stress relation of one point.Determining the slope FOS and stress solution for the SS involves considering the mechanical equilibrium conditions and the stress constraint conditions satisfied by the sliding body.The proposed approach successfully simulates the tension-shear stress zone near the slope top and provides an intuitive description of the concentration effect of compression-shear stress of the SS near the slope toe.Furthermore,compared to other methods,the present method demonstrates superior processing capabilities for the embedded nonlinear GHB strength criterion.展开更多
The primary concern in stealth aircraft design is the very large electrical size objects.However,the computational and storage requirements of these objects present significant obstacles for current highfidelity desig...The primary concern in stealth aircraft design is the very large electrical size objects.However,the computational and storage requirements of these objects present significant obstacles for current highfidelity design methods,particularly when addressing high-dimensional complex engineering design problems.To address these challenges,we developed a surface sensitivity technique based on the multilevel fast multipole algorithm(MLFMA).An access and storage of sparse partial derivative tensor was improved to significantly enhanced the computation performance.The far-field interactions of the surface sensitivity equation were realized by differential the multipole expansion.In addition,we proposed a fast far-field multiplication method to accelerate the multiplication process.The surface mesh derivative with respect to the design variables was calculated by analytical and complex variable methods,substantially improving computational efficiency.These advancements enabled the MLFMAbased surface sensitivity method to millions meshes and large-scale gradients,extending gradientbased optimization for very large electrical size problems.Test cases have verified the effectiveness of this method in optimizing very large electrical objects in terms of both accuracy and efficiency.展开更多
In order to improve the quality of 3D printed raspberry preserves after post-processing,microwave ovens combining infrared and microwave methods were utilized.The effects of infrared heating temperature,infrared heati...In order to improve the quality of 3D printed raspberry preserves after post-processing,microwave ovens combining infrared and microwave methods were utilized.The effects of infrared heating temperature,infrared heating time,microwave power,microwave heating time on the center temperature,moisture content,the chroma(C*),the total color difference(ΔE*),shape fidelity,hardness,and the total anthocyanin content of 3D printed raspberry preserves were analyzed by response surface method(RSM).The results showed that under combining with the two methods,infrared heating improved the fidelity and quality degradation of printed products,while microwave heating enhanced the efficiency of infrared heating.Infrared-microwave combination cooking could maintain relatively stable color appearance and shape of 3D printed raspberry preserves.The AHP–CRITIC hybrid weighting method combined with the response surface test to determine the comprehensive weights of the evaluation indicators optimized the process parameters,and the optimal process parameters were obtained:infrared heating temperature of 190℃,infrared heating time of 10 min and 30 s,microwave power of 300 W,and microwave heating time of 2 min and 6 s.The 3D printed raspberry cooking methods obtained under the optimal conditions seldom had color variation,porous structure,uniform texture,and high shape fidelity,which retained the characteristics of personalized manufacturing by 3D printing.This study could provide a reference for the postprocessing and quality control of 3D cooking methods.展开更多
As cathode materials for alkali-ion batteries,sodium manganese oxides have been receiving considerable and continuous attention in recent decades.In this work,the structure and environment-dependent stability of NaMn_...As cathode materials for alkali-ion batteries,sodium manganese oxides have been receiving considerable and continuous attention in recent decades.In this work,the structure and environment-dependent stability of NaMn_(2)O_(4) surface were studied based on the first principles calculations.The surface stability diagram of NaMn_(2)O_(4) involving various different terminations of(100),(110)and(111)surfaces was constructed,and the stability of these different terminations could be compared as a function of chemical environment.It is found that the(100)-MnO and(111)-ONa terminations are two more stable terminations under the investigated chemical conditions.And the surface energies of(110)surfaces are negative under the investigated chemical potential,hence,(110)surfaces are unstable.The surface energy of NaMn_(2)O_(4) as a function of O chemical potential is also investigated under constant Na chemical potential.The structure relaxation indicates that the surface rumpling and surface reconstruction can affect the electronic structure of the surface,thereby reducing surface energy and stabilizing the surface.Furthermore,the Wulff shape of NaMn_(2)O_(4) was also constructed based on Gibbs-Wulff theorem.展开更多
The contact characteristics of the rough tooth surface during the meshing process are significantly affected by the lubrication state.The coupling effect of tooth surface roughness and lubrication on meshing character...The contact characteristics of the rough tooth surface during the meshing process are significantly affected by the lubrication state.The coupling effect of tooth surface roughness and lubrication on meshing characteristics of planetary gear is studied.An improved three-dimensional(3 D)anisotropic tooth surface roughness fractal model is proposed based on the experimental parameters.Considering asperity contact and elastohydrodynamic lubrication(EHL),the contact load and flexibility deformation of the tooth surface are derived,and the deformation compatibility equation of the 3 D loaded tooth contact analysis(3 D-LTCA)method is improved.The asperity of the tooth surface changes the system from EHL to mixed lubrication and reduces the stiffness of the oil film.Compared with the sun planet gear,the asperity has a greater effect on the meshing characteristics of the ring-planet gear.Compared with the proposed method,the comprehensive stiffness obtained by the traditional calculation method considering the lubrication effect is smaller,especially for the ring-planet gear.Compared with roughness,speed and viscosity,the meshing characteristics of planetary gears are most sensitive to torque.展开更多
The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this...The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this paper proposed a high-maneuverability skipping motion strategy for the tandem twin-rotor AAV,inspired by the motion behavior of the flying fish to avoid aquatic and aerial predators near the water surface.The novel tandem twin-rotor AAV was employed as the research subject and a strategybased ADRC control method for validation,comparing it with a strategy-based PID control method.The results indicate that both control methods enable the designed AAV to achieve high stealth and maneuverability near the water surface with robust control stability.The strategy-based ADRC control method exhibits a certain advantage in controlling height,pitch angle,and reducing impact force.This motion strategy will offer an inspiring approach for the practical application of AAVs to some extent.展开更多
A hull structure is prone to local deformation and damage due to the pressure load on the surface.How to simulate surface pressure is an important issue in ship structure test.The loading mode of hydraulic actuator co...A hull structure is prone to local deformation and damage due to the pressure load on the surface.How to simulate surface pressure is an important issue in ship structure test.The loading mode of hydraulic actuator combined with high-pressure flexible bladder was proposed,and the numerical model of the loading device based on flexible bladder was established.The design and analysis method of high-pressure flexible bladder based on aramid-fiber reinforced thermoplastic polyurethane was proposed to break through the surface pressure loading technology of ship structures.The surface pressure loading system based on flexible bladder was developed.The ultimate strength verification test of the box girder under the combined action of bending moment and pressure was carried out to systematically verify the feasibility and applicability of the loading system.The results show that the surface pressure loading technology can be used well for applying uniform pressure to ship structures.Compared with the traditional surface loading methods,the improved device can be applied with horizontal constant pressure load,with rapid response and safe process,and the pressure load is always stable with the increase of the bending moment load during the test.The requirement for uniform loading in the comprehensive strength test of large structural models is satisfied and the accuracy of the test results is improved by this system.展开更多
Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidi...Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidizer ammonium perchlorate(AP)in solid propellants,but also a good performance explosive in itself.However,due to the strong hygroscopicity of ADN,its application in solid propellants and explosives is greatly limited.Solving the hygroscopicity of ADN is the key to realize the wide application of ADN.In this paper,we systematically review the research progress of anti-hygroscopic strategies of ADN coating.The surface coating methods are focusing on solvent volatilization,solvent-non-solvent,melt crystallization and atomic layer deposition technology.The characteristics of the different methods are compared and analyzed,and the basis for the classification and selection of the coating materials are introduced in detail.In addition,the feasibility of material for surface coating of ADN is evaluated by several compatibility analysis methods.It is highly expected that the liquid phase method(solvent volatilization method,solvent-non-solvent method)would be the promising method for future ADN coating because of its effective,safety and facile operation.Furthermore,polymer materials,are the preferred coating materials due to their high viscosity,easy adhesion,good anti-hygroscopic effect,and heat resistance,which make ADN weak hygroscopicity,less sensitive,easier to preserve and good compatibility.展开更多
The 2D sandwich model serves as a potent tool in exploring the influence of surface geometry on the combustion attributes of Ammonium perchlorate/Hydroxyl-terminated polybutadiene(AP/HTPB)propellant under rapid pressu...The 2D sandwich model serves as a potent tool in exploring the influence of surface geometry on the combustion attributes of Ammonium perchlorate/Hydroxyl-terminated polybutadiene(AP/HTPB)propellant under rapid pressure decay.The thickness of the sandwich propellant is derived from slicing the 3D random particle packing,an approach that enables a more effective examination of the micro-flame structure.Comparative analysis of the predicted burning characteristics has been performed with experimental studies.The findings demonstrate a reasonable agreement,thereby validating the precision and soundness of the model.Based on the typical rapid depressurization environment of solid rocket motor(initial combustion pressure is 3 MPa and the maximum depressurization rate is 1000 MPa/s).A-type(a flatter surface),B-type(AP recesses from the combustion surface),and C-type(AP protrudes from the combustion surface)propellant combustion processes are numerically simulated.Upon comparison of the evolution of gas-phase flame between 0.1 and 1 ms,it is discerned that the flame strength and form created by the three sandwich models differ significantly at the beginning stage of depressurization,with the flame structures gradually becoming harmonized over time.Conclusions are drawn by comparison extinction times:the surface geometry plays a pivotal role in the combustion process,with AP protrusion favoring combustion the most.展开更多
A surface Ti-WC composite was fabricated on CP-Ti by surface friction stirring(SFS)using a pinless WC-Cotool at a processing window of 800−2500 r/min and 8−50 mm/min.At 1600 r/min-50 mm/min,a defect-free compositelaye...A surface Ti-WC composite was fabricated on CP-Ti by surface friction stirring(SFS)using a pinless WC-Cotool at a processing window of 800−2500 r/min and 8−50 mm/min.At 1600 r/min-50 mm/min,a defect-free compositelayer with an average hardness of~HV 1170 is formed.The hardness was increased by WC and TiN reinforcingparticles,dissolved Co atoms in Ti,and the formation of ultrafine grains.WC particles were incorporated into the Tisubstrate owing to the intense frictional interaction/heating at the tool-plate interface(~1000℃),which led to strengthloss and wear of the tool.The Williamson-Hall analysis of the XRD peaks of the SFSed sample confirmed a significantlysmall crystallite size(~100 nm).Wear tests showed that the wear resistance of the composite structure was about 4.5times higher than that of the CP-Ti.Friction analysis revealed a significant reduction in average value and fluctuations ofthe friction coefficient.展开更多
Based on the criteria for additional surface acidity generation in composite oxides and composite fluorides proposed by Tanabe and Kemnitz et al.A hypothesis for the origin of additional surface acidity in solid compo...Based on the criteria for additional surface acidity generation in composite oxides and composite fluorides proposed by Tanabe and Kemnitz et al.A hypothesis for the origin of additional surface acidity in solid composites with the same metal cations is proposed.The surface acidsites of We analyze three types of solid composite systems,that is,CrF_(3)/Cr_(2)O_(3),MgF_(2)/MgO,and ZnF_(2)/ZnO,is systematically analyzed,which agrees with experimental results.Accordingly,the origin of additional surface acidity in these solid composites is reasonably explained,and the types of acidic sites are also predicted.展开更多
Polarons are widely considered to play a crucial role in the charge transport and photocatalytic performance of materials,but the mechanisms of their formation and the underlying driving factors remain a matter of con...Polarons are widely considered to play a crucial role in the charge transport and photocatalytic performance of materials,but the mechanisms of their formation and the underlying driving factors remain a matter of controversy.This study delves into the formation of polarons in different crystalline forms of TiO_(2) and their connection with the materials'structure.By employing density functional theory calculations with on-site Coulomb interaction correction(DFT+U),we provide a detailed analysis of the electronic polarization behavior in the anatase and rutile forms of TiO_(2).We focus on the polarization properties of defect-induced and photoexcited excess electrons on various TiO_(2) surfaces.The results reveal that the defect electrons can form small polarons on the anatase TiO_(2)(101)surface,while on the rutile TiO_(2)(110)surface,both small and large polarons(hybrid-state polarons)are formed.Photoexcited electrons are capable of forming both small and large polarons on the surfaces of both crystal types.The analysis indicates that the differences in polaron distribution are primarily determined by the intrinsic properties of the crystals;the structural and symmetry differences between anatase and rutile TiO_(2) lead to the distinct polaron behaviors.Further investigation suggests that the polarization behavior of defect electrons is also related to the arrangement of electron orbitals around the Ti atoms,while the polarization of photoexcited electrons is mainly facilitated by the lattice distortions.These findings elucidate the formation mechanisms of different types of polarons and may contribute to understanding the performance of TiO_(2)in different fields.展开更多
文摘This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only be obtained by some USVs.In order to achieve semi-encirclement tracking of noncooperative targets under maritime security conditions,a fixed-time tracking control method based on dynamic surface control(DSC)is proposed in this paper.Firstly,a novel TACC architecture with decoupled kinematic control law and decoupled kinetic control law was designed to reduce the complexity of control system design.Secondly,the proposed DSC-based target-guided kinematic control law including tracking points pre-allocation strategy and sigmoid artificial potential functions(SigAPFs)can avoid collisions during tracking process and optimize kinematic control output.Finally,a fixed-time TACC system was proposed to achieve fast convergence of kinematic and kinetics errors.The effectiveness of the proposed TACC approach in improving target tracking safety and reducing control output chattering was verified by simulation comparison results.
基金supported by the Education and Teaching Research Project of Universities in Fujian Province(FBJY20230167).
文摘The work takes a new liquid-cooling plate in a power battery with pin fins inside the channel as the object.A mathematical model is established via the central composite design of the response surface to study the relationships among the length,width,height,and spacing of pin fins;the maximum temperature and temperature difference of the battery module;and the pressure drop of the liquid-cooling plate.Model accuracy is verified via variance analysis.The new liquid-cooling plate enables the power battery to work within an optimal temperature range.Appropriately increasing the length,width,and height and reducing the spacing of pin fins could reduce the temperature of the power battery module and improve the temperature uniformity.However,the pressure drop of the liquid-cooling plate increases.The structural parameters of the pin fins are optimized to minimize the maximum temperature and the temperature difference of the battery module as well as the pressure drop of the liquid-cooling plate.The errors between the values predicted and actual by the simulation test are 0.58%,4%,and 0.48%,respectively,which further verifies the model accuracy.The results reveal the influence of the structural parameters of the pin fins inside the liquid-cooling plate on its heat dissipation performance and pressure drop characteristics.A theoretical basis is provided for the design of liquid-cooling plates in power batteries and the optimization of structural parameters.
文摘Since the discovery of carbon dots(CDs)in 2004,the unique photoluminescence phenomenon of CDs has attracted widespread attention.However,the molecular weight of CDs has not been adequately quantified at present,due to CDs are atomically imprecise and their molecular weight distribution is broad.In this paper,a series of Pluronic-modified CDs were prepared and the structure of the CDs was briefly analyzed.Subsequently,a molecular weight measurement method based on colligative properties was developed,and the correction coefficient in the algorithm was briefly analyzed.The calculated molecular weight was applied to the determination of surface adsorption capacity.This work provided a method for averaging the molecular weight of atomically imprecise particulate materials,which is expected to provide new opportunities in related fields.
基金National Key Research and Development Program of China(2022YFE0206300)National Natural Science Foundation of China(U21A2081,22075074,22209047)+2 种基金Guangdong Basic and Applied Basic Research Foundation(2024A1515011620)Hunan Provincial Natural Science Foundation of China(2024JJ5068)Foundation of Yuelushan Center for Industrial Innovation(2023YCII0119)。
文摘Changes to the microstructure of a hard carbon(HC)and its solid electrolyte interface(SEI)can be effective in improving the electrode kinetics.However,achieving fast charging using a simple and inexpensive strategy without sacrificing its initial Coulombic efficiency remains a challenge in sodium ion batteries.A simple liquid-phase coating approach has been used to generate a pitch-derived soft carbon layer on the HC surface,and its effect on the porosity of HC and SEI chemistry has been studied.A variety of structural characterizations show a soft carbon coating can increase the defect and ultra-micropore contents.The increase in ultra-micropore comes from both the soft carbon coatings and the larger pores within the HC that are partially filled by pitch,which provides more Na+storage sites.In-situ FTIR/EIS and ex-situ XPS showed that the soft carbon coating induced the formation of thinner SEI that is richer in NaF from the electrolyte,which stabilized the interface and promoted the charge transfer process.As a result,the anode produced fastcharging(329.8 mAh g^(−1)at 30 mA g^(−1)and 198.6 mAh g^(−1)at 300 mA g^(−1))and had a better cycling performance(a high capacity retention of 81.4%after 100 cycles at 150 mA g^(−1)).This work reveals the critical role of coating layer in changing the pore structure,SEI chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced fast charging capability.
基金Project(BGRIMM-KJSKL-2024-07) supported by the Open Foundation of State Key Laboratory of Mineral Processing,ChinaProjects(52374259,52174239) supported by the National Natural Science Foundation of China。
文摘Surface pretreatment can change the surface properties of minerals,placing them in either a favorable or an unfavorable state for flotation.To solve the separation problem associated with magnesite and dolomite,surface pretreatment experiments with citric acid,tartaric acid,and tannic acid(TA)on magnesite and dolomite as well as flotation experiments on pretreated samples were performed in this study.Experimental results demonstrated that when citric acid and tartaric acid are used for surface pretreatment,the separation effect of magnesite and dolomite is poor.However,when TA is used,the separation effect of magnesite and dolomite improves.SEM and BET analysis indicated that surface pretreatment with TA changes the surface morphology of the two minerals,resulting in additional concave pores on the dolomite surface,and a significant increase in pore size and specific surface area.The adsorption quantity test and contact angle measurement demonstrated that after surface pretreatment with TA,the magnesite adsorption capacity on sodium oleate(NaOL)slightly decreases and the dolomite adsorption capacity on NaOL considerably decreases.XPS detection concluded that the surface pretreatment of TA on the magnesite surface mainly relies on physical adsorption with weak adsorption ability and poor ability to act on Mg sites.The TA surface pretreatment action on the dolomite surface is mainly through chemical adsorption,and it is strongly and selectively adsorbed on the Ca site of dolomite through O.Actual ore rough selection experiments reveal that TA pretreatment successfully removes dolomite from magnesite,resulting in a high-quality magnesite concentrate characterized by a MgO grade of 45.49%and a CaO grade of 0.75%.
基金Projects(51775445,52175435)supported by the National Natural Science Foundation of ChinaProject(CX2023051)supported by the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China。
文摘On-machine measurement(OMM)stands out as a pivotal technology in complex curved surface adaptive machining.However,the complex structure inherent in workpieces poses a significant challenge as the stylus orientation frequently shifts during the measurement process.Consequently,a substantial amount of time is allocated to calibrating pre-travel error and probe movement.Furthermore,the frequent movement of machine tools also increases the influence of machine errors.To enhance both accuracy and efficiency,an optimization strategy for the OMM process is proposed.Based on the kinematic chain of the machine tools,the relationship between the angle combination of rotary axes,the stylus orientation,and the calibration position of pre-travel error is disclosed.Additionally,an OMM efficiency optimization model for complex curved surfaces is developed.This model is solved to produce the optimal efficiency angle combinations for each to-be-measured point.Within each angle combination,the effects of positioning errors on measurement results are addressed by coordinate system offset and measurement result compensation method.Finally,the experiments on an impeller are used to demonstrate the practical utility of the proposed method.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFB1714600)the National Natural Science Foundation of China(Grant No.52175095)the Young Top-Notch Talent Cultivation Program of Hubei Province of China.
文摘This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural features of cellular structures,which stems from the degree of porosity and the distri-bution of the pores.Unlike the phonon-driven surface effect at the nanoscale,the macro-scale surface mechanism in thermal cellular structures is found to be the microstructure-induced changes in the heat conduction path based on fully resolved 3D numerical simulations.The surface region is determined by the microstructure,characterized by the intrinsic length.With the coupling between extrinsic and intrinsic length scales under the surface mechanism,a surface-enriched multiscale method was devel-oped to accurately capture the complex size-dependent thermal conductivity.The principle of scale separation required by classical multiscale methods is not necessary to be satisfied by the proposed multiscale method.The significant potential of the surface-enriched multiscale method was demon-strated through simulations of the effective thermal conductivity of a thin-walled metamaterial struc-ture.The surface-enriched multiscale method offers higher accuracy compared with the classical multiscale method and superior efficiency over high-fidelity finite element methods.
基金Project(52074356)supported by the National Natural Science Foundation of ChinaProject(BGRIMM-KJSKL-2023-06)supported by the Open Foundation of State Key Laboratory of Mineral Processing,China+4 种基金Project(2022RC1183)supported by the Science and Technology Innovation Program of Hunan Province,ChinaProject(kq2009095)supported by the Changsha Science and Technology Project(Outstanding Innovative Youth Training Program),ChinaProject(2023CXQD002)supported by the Innovation Driven Program of Central South University,ChinaProject(B14034)supported by the National“111”Project,ChinaProject(2024ZZTS0655)supported by the Independent Exploration and Innovation Project for Graduate Students of Central South University,China。
文摘The intricate grinding process exposes various cleavage surfaces of mineral particles.This paper systematically investigates the structural characteristics of exposed malachite crystal surfaces and the adsorption behavior and mechanism of hydroxamic acid and water molecules using first-principle density functional theory.The study reveals anisotropic surface energies among crystal surfaces,ranked as(201)>(100)>(110)>(001)>(010)>(201).The adsorption of hydroxamic acid and water molecules on malachite surfaces also exhibited anisotropy.The difference in adsorption strength between hydroxamic acid and water molecules on the six exposed surfaces followed the order of(110)>(100)>(010)>(001)>(201)>(201),and the resistance of water molecules to the adsorption of hydroxamic acid on the six exposed surfaces was(110)>(201)>(010)>(201)>(001)>(100).It indicates that the reagent exhibits a strong competitive advantage in adsorption on the(100)surface,and the hindrance of water molecules to reagent adsorption is relatively small,which is favorable for flotation.This study provides theoretical references and innovative insights for the precise design of flotation reagents,as well as for the meticulous optimization of mineral surface interfaces,with the objective of enhancing flotation separation.
基金Project(52278380)supported by the National Natural Science Foundation of ChinaProject(2023JJ30670)supported by the National Science Foundation of and Technology Major Project of Hunan Province,China。
文摘This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor series.This expansion enables the reasonable construction of a function describing the NS on the SS.Additionally,by directly incorporating the nonlinear Generalized Hoke-Brown(GHB)strength criterion and utilizing the slope factor of safety(FOS)definition,a function of the shear stress on the SS is derived.This function considers the mutual feedback mechanism between the NS and strength parameters of the SS.The stress constraints conditions are then introduced at both ends of the SS based on the spatial stress relation of one point.Determining the slope FOS and stress solution for the SS involves considering the mechanical equilibrium conditions and the stress constraint conditions satisfied by the sliding body.The proposed approach successfully simulates the tension-shear stress zone near the slope top and provides an intuitive description of the concentration effect of compression-shear stress of the SS near the slope toe.Furthermore,compared to other methods,the present method demonstrates superior processing capabilities for the embedded nonlinear GHB strength criterion.
基金supported by the National Key Research and Development Program of China(Grant No.2023YFB3002800).
文摘The primary concern in stealth aircraft design is the very large electrical size objects.However,the computational and storage requirements of these objects present significant obstacles for current highfidelity design methods,particularly when addressing high-dimensional complex engineering design problems.To address these challenges,we developed a surface sensitivity technique based on the multilevel fast multipole algorithm(MLFMA).An access and storage of sparse partial derivative tensor was improved to significantly enhanced the computation performance.The far-field interactions of the surface sensitivity equation were realized by differential the multipole expansion.In addition,we proposed a fast far-field multiplication method to accelerate the multiplication process.The surface mesh derivative with respect to the design variables was calculated by analytical and complex variable methods,substantially improving computational efficiency.These advancements enabled the MLFMAbased surface sensitivity method to millions meshes and large-scale gradients,extending gradientbased optimization for very large electrical size problems.Test cases have verified the effectiveness of this method in optimizing very large electrical objects in terms of both accuracy and efficiency.
基金Supported by the National Natural Science Foundation of China(32072352)。
文摘In order to improve the quality of 3D printed raspberry preserves after post-processing,microwave ovens combining infrared and microwave methods were utilized.The effects of infrared heating temperature,infrared heating time,microwave power,microwave heating time on the center temperature,moisture content,the chroma(C*),the total color difference(ΔE*),shape fidelity,hardness,and the total anthocyanin content of 3D printed raspberry preserves were analyzed by response surface method(RSM).The results showed that under combining with the two methods,infrared heating improved the fidelity and quality degradation of printed products,while microwave heating enhanced the efficiency of infrared heating.Infrared-microwave combination cooking could maintain relatively stable color appearance and shape of 3D printed raspberry preserves.The AHP–CRITIC hybrid weighting method combined with the response surface test to determine the comprehensive weights of the evaluation indicators optimized the process parameters,and the optimal process parameters were obtained:infrared heating temperature of 190℃,infrared heating time of 10 min and 30 s,microwave power of 300 W,and microwave heating time of 2 min and 6 s.The 3D printed raspberry cooking methods obtained under the optimal conditions seldom had color variation,porous structure,uniform texture,and high shape fidelity,which retained the characteristics of personalized manufacturing by 3D printing.This study could provide a reference for the postprocessing and quality control of 3D cooking methods.
基金Project(BK20241969)supported by the Natural Science Foundation of Jiangsu Province,ChinaProject(51971249)supported by the National Natural Science Foundation of China。
文摘As cathode materials for alkali-ion batteries,sodium manganese oxides have been receiving considerable and continuous attention in recent decades.In this work,the structure and environment-dependent stability of NaMn_(2)O_(4) surface were studied based on the first principles calculations.The surface stability diagram of NaMn_(2)O_(4) involving various different terminations of(100),(110)and(111)surfaces was constructed,and the stability of these different terminations could be compared as a function of chemical environment.It is found that the(100)-MnO and(111)-ONa terminations are two more stable terminations under the investigated chemical conditions.And the surface energies of(110)surfaces are negative under the investigated chemical potential,hence,(110)surfaces are unstable.The surface energy of NaMn_(2)O_(4) as a function of O chemical potential is also investigated under constant Na chemical potential.The structure relaxation indicates that the surface rumpling and surface reconstruction can affect the electronic structure of the surface,thereby reducing surface energy and stabilizing the surface.Furthermore,the Wulff shape of NaMn_(2)O_(4) was also constructed based on Gibbs-Wulff theorem.
基金Project(2024A1515240020)supported by the Guangdong Basic and Applied Basic Research Foundation,China。
文摘The contact characteristics of the rough tooth surface during the meshing process are significantly affected by the lubrication state.The coupling effect of tooth surface roughness and lubrication on meshing characteristics of planetary gear is studied.An improved three-dimensional(3 D)anisotropic tooth surface roughness fractal model is proposed based on the experimental parameters.Considering asperity contact and elastohydrodynamic lubrication(EHL),the contact load and flexibility deformation of the tooth surface are derived,and the deformation compatibility equation of the 3 D loaded tooth contact analysis(3 D-LTCA)method is improved.The asperity of the tooth surface changes the system from EHL to mixed lubrication and reduces the stiffness of the oil film.Compared with the sun planet gear,the asperity has a greater effect on the meshing characteristics of the ring-planet gear.Compared with the proposed method,the comprehensive stiffness obtained by the traditional calculation method considering the lubrication effect is smaller,especially for the ring-planet gear.Compared with roughness,speed and viscosity,the meshing characteristics of planetary gears are most sensitive to torque.
基金supported by Southern Marine Science and Guangdong Laboratory(Zhuhai)(Grant No.SML2023SP229)。
文摘The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this paper proposed a high-maneuverability skipping motion strategy for the tandem twin-rotor AAV,inspired by the motion behavior of the flying fish to avoid aquatic and aerial predators near the water surface.The novel tandem twin-rotor AAV was employed as the research subject and a strategybased ADRC control method for validation,comparing it with a strategy-based PID control method.The results indicate that both control methods enable the designed AAV to achieve high stealth and maneuverability near the water surface with robust control stability.The strategy-based ADRC control method exhibits a certain advantage in controlling height,pitch angle,and reducing impact force.This motion strategy will offer an inspiring approach for the practical application of AAVs to some extent.
文摘A hull structure is prone to local deformation and damage due to the pressure load on the surface.How to simulate surface pressure is an important issue in ship structure test.The loading mode of hydraulic actuator combined with high-pressure flexible bladder was proposed,and the numerical model of the loading device based on flexible bladder was established.The design and analysis method of high-pressure flexible bladder based on aramid-fiber reinforced thermoplastic polyurethane was proposed to break through the surface pressure loading technology of ship structures.The surface pressure loading system based on flexible bladder was developed.The ultimate strength verification test of the box girder under the combined action of bending moment and pressure was carried out to systematically verify the feasibility and applicability of the loading system.The results show that the surface pressure loading technology can be used well for applying uniform pressure to ship structures.Compared with the traditional surface loading methods,the improved device can be applied with horizontal constant pressure load,with rapid response and safe process,and the pressure load is always stable with the increase of the bending moment load during the test.The requirement for uniform loading in the comprehensive strength test of large structural models is satisfied and the accuracy of the test results is improved by this system.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.21805139,12102194 and 22005144)the Joint Funds of the National Natural Science Foundation of China(Grant No.U2141202)+1 种基金the Fundamental Research Funds for the Central Universities(Grant No.30921011203)the Young Elite Scientists Sponsorship Program by CAST(YESS Program,2021QNRC001)。
文摘Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidizer ammonium perchlorate(AP)in solid propellants,but also a good performance explosive in itself.However,due to the strong hygroscopicity of ADN,its application in solid propellants and explosives is greatly limited.Solving the hygroscopicity of ADN is the key to realize the wide application of ADN.In this paper,we systematically review the research progress of anti-hygroscopic strategies of ADN coating.The surface coating methods are focusing on solvent volatilization,solvent-non-solvent,melt crystallization and atomic layer deposition technology.The characteristics of the different methods are compared and analyzed,and the basis for the classification and selection of the coating materials are introduced in detail.In addition,the feasibility of material for surface coating of ADN is evaluated by several compatibility analysis methods.It is highly expected that the liquid phase method(solvent volatilization method,solvent-non-solvent method)would be the promising method for future ADN coating because of its effective,safety and facile operation.Furthermore,polymer materials,are the preferred coating materials due to their high viscosity,easy adhesion,good anti-hygroscopic effect,and heat resistance,which make ADN weak hygroscopicity,less sensitive,easier to preserve and good compatibility.
基金supported by the National Natural Science Foundation of China(Grant No.51176076)。
文摘The 2D sandwich model serves as a potent tool in exploring the influence of surface geometry on the combustion attributes of Ammonium perchlorate/Hydroxyl-terminated polybutadiene(AP/HTPB)propellant under rapid pressure decay.The thickness of the sandwich propellant is derived from slicing the 3D random particle packing,an approach that enables a more effective examination of the micro-flame structure.Comparative analysis of the predicted burning characteristics has been performed with experimental studies.The findings demonstrate a reasonable agreement,thereby validating the precision and soundness of the model.Based on the typical rapid depressurization environment of solid rocket motor(initial combustion pressure is 3 MPa and the maximum depressurization rate is 1000 MPa/s).A-type(a flatter surface),B-type(AP recesses from the combustion surface),and C-type(AP protrudes from the combustion surface)propellant combustion processes are numerically simulated.Upon comparison of the evolution of gas-phase flame between 0.1 and 1 ms,it is discerned that the flame strength and form created by the three sandwich models differ significantly at the beginning stage of depressurization,with the flame structures gradually becoming harmonized over time.Conclusions are drawn by comparison extinction times:the surface geometry plays a pivotal role in the combustion process,with AP protrusion favoring combustion the most.
文摘A surface Ti-WC composite was fabricated on CP-Ti by surface friction stirring(SFS)using a pinless WC-Cotool at a processing window of 800−2500 r/min and 8−50 mm/min.At 1600 r/min-50 mm/min,a defect-free compositelayer with an average hardness of~HV 1170 is formed.The hardness was increased by WC and TiN reinforcingparticles,dissolved Co atoms in Ti,and the formation of ultrafine grains.WC particles were incorporated into the Tisubstrate owing to the intense frictional interaction/heating at the tool-plate interface(~1000℃),which led to strengthloss and wear of the tool.The Williamson-Hall analysis of the XRD peaks of the SFSed sample confirmed a significantlysmall crystallite size(~100 nm).Wear tests showed that the wear resistance of the composite structure was about 4.5times higher than that of the CP-Ti.Friction analysis revealed a significant reduction in average value and fluctuations ofthe friction coefficient.
基金The Key Research and Development Program of Zhejiang Province(2021C01003)National Natural Science Foundation of China(52025011,51971202,51872260 and 52171019)The Zhejiang Provincial Natural Science Foundation of China(LD19B030001,Z4080070 and LR23B030004)。
文摘Based on the criteria for additional surface acidity generation in composite oxides and composite fluorides proposed by Tanabe and Kemnitz et al.A hypothesis for the origin of additional surface acidity in solid composites with the same metal cations is proposed.The surface acidsites of We analyze three types of solid composite systems,that is,CrF_(3)/Cr_(2)O_(3),MgF_(2)/MgO,and ZnF_(2)/ZnO,is systematically analyzed,which agrees with experimental results.Accordingly,the origin of additional surface acidity in these solid composites is reasonably explained,and the types of acidic sites are also predicted.
文摘Polarons are widely considered to play a crucial role in the charge transport and photocatalytic performance of materials,but the mechanisms of their formation and the underlying driving factors remain a matter of controversy.This study delves into the formation of polarons in different crystalline forms of TiO_(2) and their connection with the materials'structure.By employing density functional theory calculations with on-site Coulomb interaction correction(DFT+U),we provide a detailed analysis of the electronic polarization behavior in the anatase and rutile forms of TiO_(2).We focus on the polarization properties of defect-induced and photoexcited excess electrons on various TiO_(2) surfaces.The results reveal that the defect electrons can form small polarons on the anatase TiO_(2)(101)surface,while on the rutile TiO_(2)(110)surface,both small and large polarons(hybrid-state polarons)are formed.Photoexcited electrons are capable of forming both small and large polarons on the surfaces of both crystal types.The analysis indicates that the differences in polaron distribution are primarily determined by the intrinsic properties of the crystals;the structural and symmetry differences between anatase and rutile TiO_(2) lead to the distinct polaron behaviors.Further investigation suggests that the polarization behavior of defect electrons is also related to the arrangement of electron orbitals around the Ti atoms,while the polarization of photoexcited electrons is mainly facilitated by the lattice distortions.These findings elucidate the formation mechanisms of different types of polarons and may contribute to understanding the performance of TiO_(2)in different fields.
