In order to investigate the effect of additives and nano-particle on the surface tensions of lithium bromide(Li Br) aqueous solution/ammonia, many experiments were carried out based on Wilhelmy plate method. Firstly, ...In order to investigate the effect of additives and nano-particle on the surface tensions of lithium bromide(Li Br) aqueous solution/ammonia, many experiments were carried out based on Wilhelmy plate method. Firstly, the surface tension of Li Br aqueous solution with 1-octanol was measured and then the comparison between the measured results and previous experimental results was given to verify the measuring accuracy. Some new additives, such as cationic surfactants cetyltrimethyl ammonium chloride(CTAC), and cetyltrimethyl ammonium bromide(CTAB) were chosen in the experiments. The experimental results show that CTAC and CTAB can obviously reduce the surface tension of Li Br aqueous solution/ammonia. In addition, it is found that nano-particles cannot remarkably decrease the surface tension of Li Br aqueous solution/ammonia. However, the mixed addition of additives and nano-particles can remarkably affect the surface tension of Li Br aqueous solution/ammonia. That is to say, additives play more important role in reducing the surface tension of Li Br aqueous solution/ammonia. But nano-particles may enhance the heat transfer in the absorption refrigeration process.展开更多
A novel quantitative structure-property relationship （QSPR） model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. Th...A novel quantitative structure-property relationship （QSPR） model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out （LOO） cross-validated （CV） method. The correlation coefficient （R） and the leave-one-out cross-validation correlation coefficient （Rcv） of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.展开更多
Surface tension of calcium aluminate refining slag was measured by the Slide method at 1823 K.Based on different levels of the MgO content and the mass ratio of CaO to Al_2O_3,the effects of MgO content and the mass r...Surface tension of calcium aluminate refining slag was measured by the Slide method at 1823 K.Based on different levels of the MgO content and the mass ratio of CaO to Al_2O_3,the effects of MgO content and the mass ratio of CaO to Al_2O_3 on surface tension were investigated.The results indicate that surface tension decreased with increasing MgO content(from 0 to 4.86%),followed by an increase with further increasing MgO content up to 11.33%.The trend that surface tension changed with the mass ratio of CaO to Al_2O_3 was the same as the trend that surface tension changed with the MgO content.The surface tension was varied from 0.617 N/m to 0.710 N/m,for the mass ratio of CaO to Al_2O_3 varying between 0.60 and 1.28.An attempt was made to estimate surface tension of CaO-Al_2O_3-MgO slag and its sub-system,and the application showed that the model worked well.展开更多
Surface tensions of slag addition Mg O and Si O2 based on conventional 70%CaF 2-30%Al2O3 and 60%Ca F2-20%Ca O-20%Al2O3(mass fraction) at 1300 °C, 1400 °C and 1500 °C were investigated. Influence mechani...Surface tensions of slag addition Mg O and Si O2 based on conventional 70%CaF 2-30%Al2O3 and 60%Ca F2-20%Ca O-20%Al2O3(mass fraction) at 1300 °C, 1400 °C and 1500 °C were investigated. Influence mechanism of Mg O and Si O2 on slag surface tension was also analyzed. Results indicate that surface tension decreases with the increase of Mg O content in the case of the Mg O content(mass fraction) less than 8%, however, when Mg O content(mass fraction) is from 8% to 30%, surface tension increases with the increase of Mg O content. When Si O2 content(mass fraction) is from 2% to 8%, surface tension decreases with the increase of Si O2 content. Additionally, the relationship between surface tension and optical basicity is a monotonically increasing linear function. Research findings can provide important reference for slag design and the study of slag-metal interfacial tension.展开更多
The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied.The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeab...The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied.The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeability and ore diameter,and the relationship between surface tension and ore diameter.The preferential solution flow happened within the fine ore area when the dump was unsaturated.And it could happen within the coarse ore area when the dump became saturated.The results of experiment show that the outflow of coarse ore area increases sharply with higher applied rate.The outflow of fine ore area is greater than that of coarse ore area when the applied rate is below 3.2 L/min,and the preferential solution flow happens in fine ore area.But the preferential solution flow happens in coarse ore area when the applied rate is higher than 3.2 L/min.The result of the experiment is consistent with the mechanism analyzing.展开更多
BISHOP’s effective stress or two state stress variables are unsatisfactory for unsaturated soils where one of fluid phases is discontinuous, so new expressions of effective stress should be founded. The approach for ...BISHOP’s effective stress or two state stress variables are unsatisfactory for unsaturated soils where one of fluid phases is discontinuous, so new expressions of effective stress should be founded. The approach for derivation was according to the principle of equilibrium of forces (i.e., the stress-sharing principle), and it was firstly validated by demonstrating TERZAGHI’s principle of effective stress. And then, the derivations were subdivided into four parts according to different pore air states: 1) air bubbles were spherical and suspended in pore water; 2) air bubbles were bound on soil skeleton; 3) air bubbles held almost the single section of pore; 4) air phase was continuous. The different formulae of effective stress were presented. Conclusions are drawn as follows: 1) For nearly-saturated soils, the "real" effective stress would be a little smaller than TERZAGHI’s effective stress; 2) For soils in which air phase is discontinuous in the form of bubbles, a new concept of pore air elastic pressure is put forward, and the total stress can be constituted by effective stress, pore water pressure and pore air elastic pressure; 3) For soils in which air phase is continuous, effective stress is equal to the value of the total stress plus suction; 4) Suction can be divided into two parts: one is the effect caused by additional pressure, and the other is the contract action by the "skin".展开更多
In the present study,electrostatic atomization(EA)behavior of several test liquids having much higher viscosities(1 400 mPa·s)than have previously been studied was investigated by spraying at a series of applied ...In the present study,electrostatic atomization(EA)behavior of several test liquids having much higher viscosities(1 400 mPa·s)than have previously been studied was investigated by spraying at a series of applied voltages and flow rates.The results showed that to obtain stable cone-jet mode spraying and hence gain better monodispersity of droplets,electrical conductivity,viscosity and surface tension of the liquid are important controlling factors.The stable cone-jet mode could be easily established for liquids having shear viscosities in the range from 80 to 1 400 mPa·s and surface tensions below 65 mN·m-1.In contrast,methylcellulose aqueous solutions with shear viscosities ranging from 10 to 540 mPa·s and moderate surface tensions(50~56 mN·m-1)generated more complicated spraying modes.However,fine TiO2 powder(a few micrometers in size)could be prepared using the EA method from its precursor solutions.展开更多
基金Project(51206033)supported by the National Natural Science Foundation of ChinaProjects(2011M500652,2013T60354)supported by the China Postdoctoral Science FoundationProject(2011LBH-Z11139)supported by the Heilongjiang Postdoctoral Science Foundation,China
文摘In order to investigate the effect of additives and nano-particle on the surface tensions of lithium bromide(Li Br) aqueous solution/ammonia, many experiments were carried out based on Wilhelmy plate method. Firstly, the surface tension of Li Br aqueous solution with 1-octanol was measured and then the comparison between the measured results and previous experimental results was given to verify the measuring accuracy. Some new additives, such as cationic surfactants cetyltrimethyl ammonium chloride(CTAC), and cetyltrimethyl ammonium bromide(CTAB) were chosen in the experiments. The experimental results show that CTAC and CTAB can obviously reduce the surface tension of Li Br aqueous solution/ammonia. In addition, it is found that nano-particles cannot remarkably decrease the surface tension of Li Br aqueous solution/ammonia. However, the mixed addition of additives and nano-particles can remarkably affect the surface tension of Li Br aqueous solution/ammonia. That is to say, additives play more important role in reducing the surface tension of Li Br aqueous solution/ammonia. But nano-particles may enhance the heat transfer in the absorption refrigeration process.
基金Projects(20775010,21075011) supported by the National Natural Science Foundation of ChinaProject(2008AA05Z405) supported by the National High Technology Research and Development Program of China+2 种基金Project(09JJ3016) supported by Hunan Provincial Natural Science Foundation,ChinaProject(09C066) supported by Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(2010CL01) supported by the Foundation of Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,China
文摘A novel quantitative structure-property relationship （QSPR） model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out （LOO） cross-validated （CV） method. The correlation coefficient （R） and the leave-one-out cross-validation correlation coefficient （Rcv） of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.
基金Project(51204115)supported by the National Natural Science Foundation of ChinaProject(BK20130308)supported by the Basic Research Program of Jiangsu Province,ChinaProject(2014M561710)supported by China Postdoctoral Science Foundation
文摘Surface tension of calcium aluminate refining slag was measured by the Slide method at 1823 K.Based on different levels of the MgO content and the mass ratio of CaO to Al_2O_3,the effects of MgO content and the mass ratio of CaO to Al_2O_3 on surface tension were investigated.The results indicate that surface tension decreased with increasing MgO content(from 0 to 4.86%),followed by an increase with further increasing MgO content up to 11.33%.The trend that surface tension changed with the mass ratio of CaO to Al_2O_3 was the same as the trend that surface tension changed with the MgO content.The surface tension was varied from 0.617 N/m to 0.710 N/m,for the mass ratio of CaO to Al_2O_3 varying between 0.60 and 1.28.An attempt was made to estimate surface tension of CaO-Al_2O_3-MgO slag and its sub-system,and the application showed that the model worked well.
基金Project(51274266)supported by the National Natural Science Foundation of ChinaProject(N120502002)supported by the Fundamental Research Funds for Central Universities of ChinaProject(LR2013009)supported by the Program for Liaoning Excellent Talents in University,China
文摘Surface tensions of slag addition Mg O and Si O2 based on conventional 70%CaF 2-30%Al2O3 and 60%Ca F2-20%Ca O-20%Al2O3(mass fraction) at 1300 °C, 1400 °C and 1500 °C were investigated. Influence mechanism of Mg O and Si O2 on slag surface tension was also analyzed. Results indicate that surface tension decreases with the increase of Mg O content in the case of the Mg O content(mass fraction) less than 8%, however, when Mg O content(mass fraction) is from 8% to 30%, surface tension increases with the increase of Mg O content. When Si O2 content(mass fraction) is from 2% to 8%, surface tension decreases with the increase of Si O2 content. Additionally, the relationship between surface tension and optical basicity is a monotonically increasing linear function. Research findings can provide important reference for slag design and the study of slag-metal interfacial tension.
基金Project(50325415)supported by the National Science Fund for Distinguished Young ScholarsProject (50621603) supported by China Science Fund for Distinguished Group+1 种基金Project (2004CB619200) supported by National Key Fundamental Research and Development Program of ChinaProject (50574099) supported by National Natural Science Foundation of China
文摘The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied.The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeability and ore diameter,and the relationship between surface tension and ore diameter.The preferential solution flow happened within the fine ore area when the dump was unsaturated.And it could happen within the coarse ore area when the dump became saturated.The results of experiment show that the outflow of coarse ore area increases sharply with higher applied rate.The outflow of fine ore area is greater than that of coarse ore area when the applied rate is below 3.2 L/min,and the preferential solution flow happens in fine ore area.But the preferential solution flow happens in coarse ore area when the applied rate is higher than 3.2 L/min.The result of the experiment is consistent with the mechanism analyzing.
基金Project(50878191) supported by the National Natural Science Foundation of ChinaProject(Y12E090030) supported by Zhejiang Provincial Natural Science Foundation, China
文摘BISHOP’s effective stress or two state stress variables are unsatisfactory for unsaturated soils where one of fluid phases is discontinuous, so new expressions of effective stress should be founded. The approach for derivation was according to the principle of equilibrium of forces (i.e., the stress-sharing principle), and it was firstly validated by demonstrating TERZAGHI’s principle of effective stress. And then, the derivations were subdivided into four parts according to different pore air states: 1) air bubbles were spherical and suspended in pore water; 2) air bubbles were bound on soil skeleton; 3) air bubbles held almost the single section of pore; 4) air phase was continuous. The different formulae of effective stress were presented. Conclusions are drawn as follows: 1) For nearly-saturated soils, the "real" effective stress would be a little smaller than TERZAGHI’s effective stress; 2) For soils in which air phase is discontinuous in the form of bubbles, a new concept of pore air elastic pressure is put forward, and the total stress can be constituted by effective stress, pore water pressure and pore air elastic pressure; 3) For soils in which air phase is continuous, effective stress is equal to the value of the total stress plus suction; 4) Suction can be divided into two parts: one is the effect caused by additional pressure, and the other is the contract action by the "skin".
文摘In the present study,electrostatic atomization(EA)behavior of several test liquids having much higher viscosities(1 400 mPa·s)than have previously been studied was investigated by spraying at a series of applied voltages and flow rates.The results showed that to obtain stable cone-jet mode spraying and hence gain better monodispersity of droplets,electrical conductivity,viscosity and surface tension of the liquid are important controlling factors.The stable cone-jet mode could be easily established for liquids having shear viscosities in the range from 80 to 1 400 mPa·s and surface tensions below 65 mN·m-1.In contrast,methylcellulose aqueous solutions with shear viscosities ranging from 10 to 540 mPa·s and moderate surface tensions(50~56 mN·m-1)generated more complicated spraying modes.However,fine TiO2 powder(a few micrometers in size)could be prepared using the EA method from its precursor solutions.
