Soft rock surrounding deep roadway has poor stability and long-term rheological effect. More and larger deformation problems of surrounding rock occur due to adverse supporting measures for such roadways, which not on...Soft rock surrounding deep roadway has poor stability and long-term rheological effect. More and larger deformation problems of surrounding rock occur due to adverse supporting measures for such roadways, which not only affects the engineering safety critically but also improves the maintenance costs. This paper takes the main rail roadway with severely deformation in China＇s Zaoquan coal mine as an example to study the long-term deformation tendency and damage zone by means of in-situ deformation monitoring and acoustic wave testing technique. A three-dimensional finite element model reflecting the engineering geological condition and initial design scheme is established by ABAQUS. Then, on the basis of field monitoring deformation data, the surrounding rock geotechnical and theological parameters of the roadway are obtained by back analysis. A combined supporting technology with U-shaped steel support and anchor-grouting is proposed for the surrounding soft rock. The numerical simulation of the combined supporting technology and in-situ deformation monitoring results show that the soft rock surrounding the roadway has been held effectively.展开更多
Linear failure criterion is widely used in calculation of earth pressure acting on shallow tunnels. However, experimental evidence shows that nonlinear failure criterion is able to represent fairly well the failure of...Linear failure criterion is widely used in calculation of earth pressure acting on shallow tunnels. However, experimental evidence shows that nonlinear failure criterion is able to represent fairly well the failure of almost all types of rocks, A nonlinear Hock-Brown failure criterion is employed to estimate the supporting pressures of shallow tunnels in limit analysis framework. Two failure mechanisms are proposed for calculating the work rate of extemal force and the internal energy dissipation. A tangential line to the nonlinear failure criterion is used to formulate the supporting pressure problem as a nonlinear programming problem. The objective function formulated in this way is minimized with respect to the failure mechanism and the location of tangency point. In order to assess the validity, the supporting pressures for the proposed failure mechanisms are calculated and compared with each other, and the present results are compared with previously published solutions when the nonlinear criterion is reduced to linear criterion. The agreement supports the validity of the proposed failure mechanisms. An experiment is conducted to investigate the influences of the nonlinear criterion on collapse shape and supporting pressures of shallow tunnels.展开更多
Based on the active failure mechanism generated by a spatial discretization technique, the stability of tunnel face was studied. With the help of the spatial discretization technique, not only the anisotropy and inhom...Based on the active failure mechanism generated by a spatial discretization technique, the stability of tunnel face was studied. With the help of the spatial discretization technique, not only the anisotropy and inhomogeneity of the cohesion but also the inhomogeneity of the internal friction angle was taken into account in the analysis of the supporting forces. From the perspective of upper bound theorem, the upper bound solutions of supporting pressure were derived. The influence of the anisotropy and heterogeneity on the supporting forces as well as the failure mechanisms was discussed. The results show that the spatial discretization characteristics of cohesion and internal frictional angle impose a significant effect on the supporting pressure, which indicates that above factors should be considered in the actual engineering.展开更多
A new type of pit supporting structure, which was tested and verified using the sensor monitoring technology, was presented. The new supporting structure is assembled by prefabricated steel structural units. The adjac...A new type of pit supporting structure, which was tested and verified using the sensor monitoring technology, was presented. The new supporting structure is assembled by prefabricated steel structural units. The adjacent steel structural units are jointed with fasteners, and each steel structural unit has a certain radian and is welded by two steel tubes and one piece of steel disc. In order to test and verify the reliability of the new supporting structure, the field tests are designed. The main monitoring programs include the hoop stress of supporting structure, lateral earth pressure, and soil deformation. The monitoring data of the field tests show that the new supporting structure is convenient, reliable and safe.展开更多
Mesoporous carbon supports mitigate platinum(Pt)sulfonic poisoning through nanopore-confined Pt deposition,yet their morphological impacts on oxygen transport remain unclear.This study integrates carbon support morpho...Mesoporous carbon supports mitigate platinum(Pt)sulfonic poisoning through nanopore-confined Pt deposition,yet their morphological impacts on oxygen transport remain unclear.This study integrates carbon support morphology simulation with an enhanced agglomerate model to establish a mathematical framework elucidating pore evolution,Pt utilization,and oxygen transport in catalyst layers.Results demonstrate dominant local mass transport resistance governed by three factors:(1)active site density dictating oxygen flux;(2)ionomer film thickness defining shortest transport path;(3)ionomer-to-Pt surface area ratio modulating practical pathway length.At low ionomer-to-carbon(I/C)ratios,limited active sites elevate resistance(Factor 1 dominant).Higher I/C ratios improve the ionomer coverage but eventually thicken ionomer films,degrading transport(Factors 2–3 dominant).The results indicate that larger carbon particles result in a net increase in local transport resistance by reducing external surface area and increasing ionomer thickness.As the proportion of Pt situated in nanopores or the Pt mass fraction increases,elevated Pt density inside the nanopores exacerbates pore blockage.This leads to the increased transport resistance by reducing active sites,and increasing ionomer thickness and surface area.Lower Pt loading linearly intensifies oxygen flux resistance.The model underscores the necessity to optimize support morphology,Pt distribution,and ionomer content to prevent pore blockage while balancing catalytic activity and transport efficiency.These insights provide a systematic approach for designing high-performance mesoporous carbon catalysts.展开更多
The preferential oxidation of CO(CO-PROX)reaction is a cost-effective method for eliminating trace amounts of CO from the fuel H2.Pt-based catalysts have been extensively studied for COPROX,with their activity influen...The preferential oxidation of CO(CO-PROX)reaction is a cost-effective method for eliminating trace amounts of CO from the fuel H2.Pt-based catalysts have been extensively studied for COPROX,with their activity influenced by the morphology of the support.Hydrothermal synthesis was employed to produce different morphologies ofγ-Al_(2)O_(3):flower-likeγ-Al_(2)O_(3)(f)exposing(110)crystal faces,sheet-likeγ-Al_(2)O_(3)(s)revealing(100)crystal faces,and rod-likeγ-Al_(2)O_(3)(r)displaying(111)crystal faces,followed by loading PtCo nanoparticles.The exposed crystal faces of the support impact the alloying degree of the PtCo nanoparticles,and an increase in the alloying degree correlates with enhanced catalyst reactivity.Pt_(3)Co intermetallic compounds were identified onγ-Al_(2)O_(3)(f)exposing(110)crystal faces,and PtCo/γ-Al_(2)O_(3)(f)showed high catalytic activity in the CO-PROX reaction,achieving 100%CO conversion across a broad temperature range of 50−225°C.In contrast,only partial alloying of PtCo was observed onγ-Al_(2)O_(3)(s).Furthermore,no alloying between Pt and Co occurred in PtCo/γ-Al_(2)O_(3)(r),resulting in a reaction rate at 50°C that was merely 11%of that of PtCo/γ-Al_(2)O_(3)(f).The formation of Pt3Co intermetallic compounds led to a more oxidized state of Pt,which significantly diminished the adsorption of CO on Pt and augmented the active oxygen species,thereby facilitating the selective oxidation of CO.展开更多
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni...With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.展开更多
The stress gradient of surrounding rock and reasonable prestress of support are the keys to ensuring the stability of roadways.The elastic-plastic analytical solution for surrounding rock was derived based on unified ...The stress gradient of surrounding rock and reasonable prestress of support are the keys to ensuring the stability of roadways.The elastic-plastic analytical solution for surrounding rock was derived based on unified strength theory.A model for solving the stress gradient of the surrounding rock with the intermediate principal stress parameter b was established.The correctness and applicability of the solution for the stress gradient in the roadway surrounding rock was verified via multiple methods.Furthermore,the laws of stress,displacement,and the plastic zone of the surrounding rock with different b values and prestresses were revealed.As b increases,the stress gradient in the plastic zone increases,and the displacement and plastic zone radius decrease.As the prestress increases,the peak stress shifts toward the sidewalls,and the stress and stress gradient increments decrease.In addition,the displacement increment and plastic zone increment were proposed to characterize the support effect.The balance point of the plastic zone area appears before that of the displacement zone.The relationship between the stress gradient compensation coefficient and the prestress is obtained.This study provides a research method and idea for determining the reasonable prestress of support in roadways.展开更多
Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam suppor...Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam support system with high strength is developed.The high-strength bearing characteristics and coupling yielding support mechanism of this support system are studied by the mechanical tests of composite members and the combined support system.The test results show that under the coupling effect of support members,the peak stress of the box-shaped support beam in the anchor box beam is reduced by 21.9%,and the average deformation is increased by 135.0%.The ultimate bending bearing capacity of the box-shaped support beam is 3.5 times that of traditional channel beam.The effective compressive stress zone applied by the high prestressed cable is expanded by 26.4%.On this basis,the field support comparison test by the anchor channel beam,the anchor I-shaped beam and the anchor box beam are carried out.Compared with those of the previous two,the surrounding rock convergence of the latter is decreased by 41.2%and 22.2%,respectively.The field test verifies the effectiveness of the anchor box beam support system.展开更多
Zirconium,titanium,and other hexagonally close-packed(HCP)metals and their alloys are representative high specific strength,high reaction enthalpy,and high thermal conductivity structural materials.In this study,two t...Zirconium,titanium,and other hexagonally close-packed(HCP)metals and their alloys are representative high specific strength,high reaction enthalpy,and high thermal conductivity structural materials.In this study,two typical HCP metals,zirconium,and titanium,were applied to reactive materials(RMs)to prepare Zr/PTFE/W RMs and Ti/PTFE/W RMs,validating the feasibility of HCP metal/PTFE/W RMs.The impact response process of typical HCP metal/PTFE/W RMs under high-velocity dynamic loads was studied using shock equations of state(EOS)based on porous mixtures and chemical reaction kinetics equations.An improved hemispherical quasi-sealed test chamber was employed to measure the energy release characteristic curves of 10 types of Zr/PTFE/W RMs and Ti/PTFE/W RMs under impact velocities ranging from 500 m/s to 1300 m/s.The datasets of the impact-induced energy release characteristics of HCP metal/PTFE/W RMs were established.Additionally,the energy release efficiency of HCP metal/PTFE/W RMs under impact was predicted using the support vector regression(SVR)kernel function model.The datasets of Zr/PTFE/W RMs and Ti/PTFE/W RMs with W contents of 0%,25%,50%,and 75%were used as test sets,respectively.The model predictions showed a high degree of agreement with the experimental data,with mean absolute errors(MAE)of 4.8,6.5,4.6,and 4.1,respectively.展开更多
The surrounding rock is prone to large-scale loosening and failure after the excavation of shallow large-span caverns because of the thin overlying strata and large cross-section span.The rational design of bolt suppo...The surrounding rock is prone to large-scale loosening and failure after the excavation of shallow large-span caverns because of the thin overlying strata and large cross-section span.The rational design of bolt support is very important to the safety control of surrounding rock as a common support means.The control mechanism and design method of bolt support for shallow-buried large-span caverns is carried out.The calculation method of bolt prestress and length based on arched failure and collapsed failure mode is established.The influence mechanism of different influencing factors on the bolt prestress and length is clarified.At the same time,the constant resistance energy-absorbing bolt with high strength and high toughness is developed,and the comparative test of mechanical properties is carried out.On this basis,the design method of high prestressed bolt support for shallow-buried large-span caverns is put forward,and the field test is carried out in Qingdao metro station in China.The monitoring results show that the maximum roof settlement is 6.8 mm after the new design method is adopted,and the effective control of the shallow-buried large-span caverns is realized.The research results can provide theoretical and technical support for the safety control of shallow-buried large-span caverns.展开更多
Nowadays,wireless communication devices turn out to be transportable owing to the execution of the current technologies.The antenna is the most important component deployed for communication purposes.The antenna plays...Nowadays,wireless communication devices turn out to be transportable owing to the execution of the current technologies.The antenna is the most important component deployed for communication purposes.The antenna plays an imperative role in receiving and transmitting the signals for any sensor network.Among varied antennas,micro strip fractal antenna(MFA)significantly contributes to increasing antenna gain.This study employs a hybrid optimization method known as the elephant clan updated grey wolf algorithm to introduce an optimized MFA design.This method optimizes antenna characteristics,including directivity and gain.Here,the factors,including length,width,ground plane length,height,and feed offset-X and feed offset-Y,are taken into account to achieve the best performance of gain and directivity.Ultimately,the superiority of the suggested technique over state-of-the-art strategies is calculated for various metrics such as cost and gain.The adopted model converges to a minimal value of 0.2872.Further,the spider monkey optimization(SMO)model accomplishes the worst performance over all other existing models like elephant herding optimization(EHO),grey wolf optimization(GWO),lion algorithm(LA),support vector regressor(SVR),bacterial foraging-particle swarm optimization(BF-PSO)and shark smell optimization(SSO).Effective MFA design is obtained using the suggested strategy regarding various parameters.展开更多
Fengyun meteorological satellites have undergone a series of significant developments over the past 50 years.Two generations,four types,and 21 Fengyun satellites have been developed and launched,with 9 currently opera...Fengyun meteorological satellites have undergone a series of significant developments over the past 50 years.Two generations,four types,and 21 Fengyun satellites have been developed and launched,with 9 currently operational in orbit.The data obtained from Fengyun satellites is employed in a multitude of applications,including weather forecasting,meteorological disaster prevention and reduction,climate change,global environmental monitoring,and space weather.These data products and services are made available to the global community,resulting in tangible social and economic benefits.In 2023,two Fengyun meteorological satellites were successfully launched.This report presents an overview of the two recently launched Fengyun satellites and currently in orbit Fengyun satellites,including an evaluation of their remote sensing instruments since 2022.Additionally,it addresses the subject of Fengyun satellite data archiving,data services,application services,international cooperation,and supporting activities.Furthermore,the development prospects have been outlined.展开更多
Non-pillar mining technology with automatically formed roadway is a new mining method without coal pillar reservation and roadway excavation.The stability control of automatically formed roadway is the key to the succ...Non-pillar mining technology with automatically formed roadway is a new mining method without coal pillar reservation and roadway excavation.The stability control of automatically formed roadway is the key to the successful application of the new method.In order to realize the stability control of the roadway surrounding rock,the mechanical model of the roof and rib support structure is established,and the influence mechanism of the automatically formed roadway parameters on the compound force is revealed.On this basis,the roof and rib support structure technology of confined lightweight concrete is proposed,and its mechanical tests under different eccentricity are carried out.The results show that the bearing capacity of confined lightweight concrete specimens is basically the same as that of ordinary confined concrete specimens.The bearing capacity of confined lightweight concrete specimens under different eccentricities is 1.95 times higher than those of U-shaped steel specimens.By comparing the test results with the theoretical calculated results of the confined concrete,the calculation method of the bearing capacity for the confined lightweight concrete structure is selected.The design method of confined lightweight concrete support structure is established,and is successfully applied in the extra-large mine,Ningtiaota Coal Mine,China.展开更多
To enhance flow stability and reduce hydrodynamic noise caused by fluctuating pressure,a quasiperiodic elastic support skin composed of flexible walls and elastic support elements is proposed for fluid noise reduction...To enhance flow stability and reduce hydrodynamic noise caused by fluctuating pressure,a quasiperiodic elastic support skin composed of flexible walls and elastic support elements is proposed for fluid noise reduction.The arrangement of the elastic support element is determined by the equivalent periodic distance and quasi-periodic coefficient.In this paper,a dynamic model of skin in a fluid environment is established.The influence of equivalent periodic distance and quasi-periodic coefficient on flow stability is investigated.The results suggest that arranging the elastic support elements in accordance with the quasi-periodic law can effectively enhance flow stability.Meanwhile,the hydrodynamic noise calculation results demonstrate that the skin exhibits excellent noise reduction performance,with reductions of 10 dB in the streamwise direction,11 dB in the spanwise direction,and 10 dB in the normal direction.The results also demonstrate that the stability analysis method can serve as a diagnostic tool for flow fields and guide the design of noise reduction structures.展开更多
Engineering shallow,large-span rock tunnels challenges deformation control and escalates construction costs.This study investigates the excavation compensation method(ECM)and its associated technologies to address the...Engineering shallow,large-span rock tunnels challenges deformation control and escalates construction costs.This study investigates the excavation compensation method(ECM)and its associated technologies to address these issues.Utilizing five key technologies,the ECM effectively modulates radial stress post-excavation,redistributes stress in the surrounding rock,and eliminates tensile stress at the excavation face.Pre-tensioning measures further enhance the rock’s residual strength,establishing a new stability equilibrium.Field tests corroborate the method’s effectiveness,demonstrating a crown settlement reduction of 3–8 mm,a nearly 50%decrease compared to conventional construction approaches.Additionally,material consumption and construction duration were reduced by approximately 30%–35%and 1.75 months per 100 m,respectively.Thus,the ECM represents a significant innovation in enhancing the stability and construction efficiency of large-span rock tunnels,marking a novel contribution to the engineering field.展开更多
Due to the long-term plate tectonic movements in southwestern China,the in-situ stress field in deep formations is complex.When passing through deep soft-rock mass under non-hydrostatic high in-situ stress field,tunne...Due to the long-term plate tectonic movements in southwestern China,the in-situ stress field in deep formations is complex.When passing through deep soft-rock mass under non-hydrostatic high in-situ stress field,tunnels will suffer serious asymmetric deformation.There is no available support design method for tunnels under such a situation in existing studies to clarify the support time and support stiffness.This study first analyzed the mechanical behavior of tunnels in non-hydrostatic in-situ stress field and derived the theoretical equations of the ground squeezing curve(GSC)and ground loosening curve(GLC).Then,based on the convergence confinement theory,the support design method of deep soft-rock tunnels under non-hydrostatic high in-situ stress field was established considering both squeezing and loosening pressures.In addition,this method can provide the clear support time and support stiffness of the second layer of initial support.The proposed design method was applied to the Wanhe tunnel of the China-Laos railway in China.Monitoring data indicated that the optimal support scheme had a good effect on controlling the tunnel deformation in non-hydrostatic high in-situ stress field.Field applications showed that the secondary lining could be constructed properly.展开更多
In the process of shield tunneling through soft soil layers,the presence of confined water ahead poses a significant threat to the stability of the tunnel face.Therefore,it is crucial to consider the impact of confine...In the process of shield tunneling through soft soil layers,the presence of confined water ahead poses a significant threat to the stability of the tunnel face.Therefore,it is crucial to consider the impact of confined water on the limit support pressure of the tunnel face.This study employed the finite element method(FEM)to analyze the limit support pressure of shield tunnel face instability within a pressurized water-containing layer.Subsequently,a multiple linear regression approach was applied to derive a concise solution formula for the limit support pressure,incorporating various influencing factors.The analysis yields the following conclusions:1)The influence of confined water on the instability mode of the tunnel face in soft soil layers makes the displacement response of the strata not significant when the face is unstable;2)The limit support pressure increases approximately linearly with the pressure head,shield tunnel diameter,and tunnel burial depth.And inversely proportional to the thickness of the impermeable layer,soil cohesion and internal friction angle;3)Through an engineering case study analysis,the results align well with those obtained from traditional theoretical methods,thereby validating the rationality of the equations proposed in this paper.Furthermore,the proposed equations overcome the limitation of traditional theoretical approaches considering the influence of changes in impermeable layer thickness.It can accurately depict the dynamic variation in the required limit support pressure to maintain the stability of the tunnel face during shield tunneling,thus better reflecting engineering reality.展开更多
基金Projects(51409154,41772299)supported by the National Natural Science Foundation of ChinaProject(J16LG03)supported by the Shandong Province Higher Educational Science and Technology Program,China+1 种基金Projects(2015JQJH106,2014TDJH103)supported by the SDUST Research Fund,ChinaProject(201630576)supported by the Tai’an Scientific and Technologic Development Project,China
文摘Soft rock surrounding deep roadway has poor stability and long-term rheological effect. More and larger deformation problems of surrounding rock occur due to adverse supporting measures for such roadways, which not only affects the engineering safety critically but also improves the maintenance costs. This paper takes the main rail roadway with severely deformation in China＇s Zaoquan coal mine as an example to study the long-term deformation tendency and damage zone by means of in-situ deformation monitoring and acoustic wave testing technique. A three-dimensional finite element model reflecting the engineering geological condition and initial design scheme is established by ABAQUS. Then, on the basis of field monitoring deformation data, the surrounding rock geotechnical and theological parameters of the roadway are obtained by back analysis. A combined supporting technology with U-shaped steel support and anchor-grouting is proposed for the surrounding soft rock. The numerical simulation of the combined supporting technology and in-situ deformation monitoring results show that the soft rock surrounding the roadway has been held effectively.
基金Foundation item： Project（2013CB036004） supported by the National Basic Research Program of China Project（51178468） supported by the National Natural Science Foundation of China
文摘Linear failure criterion is widely used in calculation of earth pressure acting on shallow tunnels. However, experimental evidence shows that nonlinear failure criterion is able to represent fairly well the failure of almost all types of rocks, A nonlinear Hock-Brown failure criterion is employed to estimate the supporting pressures of shallow tunnels in limit analysis framework. Two failure mechanisms are proposed for calculating the work rate of extemal force and the internal energy dissipation. A tangential line to the nonlinear failure criterion is used to formulate the supporting pressure problem as a nonlinear programming problem. The objective function formulated in this way is minimized with respect to the failure mechanism and the location of tangency point. In order to assess the validity, the supporting pressures for the proposed failure mechanisms are calculated and compared with each other, and the present results are compared with previously published solutions when the nonlinear criterion is reduced to linear criterion. The agreement supports the validity of the proposed failure mechanisms. An experiment is conducted to investigate the influences of the nonlinear criterion on collapse shape and supporting pressures of shallow tunnels.
基金Project(2013CB036004) supported by the National Basic Research Program of ChinaProjects(51178468,51378510) supported by the National Natural Science Foundation of China
文摘Based on the active failure mechanism generated by a spatial discretization technique, the stability of tunnel face was studied. With the help of the spatial discretization technique, not only the anisotropy and inhomogeneity of the cohesion but also the inhomogeneity of the internal friction angle was taken into account in the analysis of the supporting forces. From the perspective of upper bound theorem, the upper bound solutions of supporting pressure were derived. The influence of the anisotropy and heterogeneity on the supporting forces as well as the failure mechanisms was discussed. The results show that the spatial discretization characteristics of cohesion and internal frictional angle impose a significant effect on the supporting pressure, which indicates that above factors should be considered in the actual engineering.
基金Project(41202220) supported by the National Natural Science Foundation of ChinaProject(20120022120003) supported by the Research Fund for the Doctoral Program of Higher Education, China+1 种基金Project(2-9-2012-65) supported by the Fundamental Research Funds for the Central Universities, ChinaProject(2013006) supported by the Research Fund for Key Laboratory on Deep GeoDrilling Technology, Ministry of Land and Resources, China
文摘A new type of pit supporting structure, which was tested and verified using the sensor monitoring technology, was presented. The new supporting structure is assembled by prefabricated steel structural units. The adjacent steel structural units are jointed with fasteners, and each steel structural unit has a certain radian and is welded by two steel tubes and one piece of steel disc. In order to test and verify the reliability of the new supporting structure, the field tests are designed. The main monitoring programs include the hoop stress of supporting structure, lateral earth pressure, and soil deformation. The monitoring data of the field tests show that the new supporting structure is convenient, reliable and safe.
基金supported by the Program of Ministry of Science and Technology of China(No.2023YFB2504200)support of Shanghai Rising-Star Program(Grant No.24QB2703200)the Major Science and Technology Projects of Yunnan Province(No.202302AH360001).
文摘Mesoporous carbon supports mitigate platinum(Pt)sulfonic poisoning through nanopore-confined Pt deposition,yet their morphological impacts on oxygen transport remain unclear.This study integrates carbon support morphology simulation with an enhanced agglomerate model to establish a mathematical framework elucidating pore evolution,Pt utilization,and oxygen transport in catalyst layers.Results demonstrate dominant local mass transport resistance governed by three factors:(1)active site density dictating oxygen flux;(2)ionomer film thickness defining shortest transport path;(3)ionomer-to-Pt surface area ratio modulating practical pathway length.At low ionomer-to-carbon(I/C)ratios,limited active sites elevate resistance(Factor 1 dominant).Higher I/C ratios improve the ionomer coverage but eventually thicken ionomer films,degrading transport(Factors 2–3 dominant).The results indicate that larger carbon particles result in a net increase in local transport resistance by reducing external surface area and increasing ionomer thickness.As the proportion of Pt situated in nanopores or the Pt mass fraction increases,elevated Pt density inside the nanopores exacerbates pore blockage.This leads to the increased transport resistance by reducing active sites,and increasing ionomer thickness and surface area.Lower Pt loading linearly intensifies oxygen flux resistance.The model underscores the necessity to optimize support morphology,Pt distribution,and ionomer content to prevent pore blockage while balancing catalytic activity and transport efficiency.These insights provide a systematic approach for designing high-performance mesoporous carbon catalysts.
基金supported by the National Natural Science Foundation of China(22376063,21976057)the Fund of the National Engineering Laboratory for Mobile Source Emission Control Technology(NELMS2020A05)Fundamental Research Funds for the Central Universities.
文摘The preferential oxidation of CO(CO-PROX)reaction is a cost-effective method for eliminating trace amounts of CO from the fuel H2.Pt-based catalysts have been extensively studied for COPROX,with their activity influenced by the morphology of the support.Hydrothermal synthesis was employed to produce different morphologies ofγ-Al_(2)O_(3):flower-likeγ-Al_(2)O_(3)(f)exposing(110)crystal faces,sheet-likeγ-Al_(2)O_(3)(s)revealing(100)crystal faces,and rod-likeγ-Al_(2)O_(3)(r)displaying(111)crystal faces,followed by loading PtCo nanoparticles.The exposed crystal faces of the support impact the alloying degree of the PtCo nanoparticles,and an increase in the alloying degree correlates with enhanced catalyst reactivity.Pt_(3)Co intermetallic compounds were identified onγ-Al_(2)O_(3)(f)exposing(110)crystal faces,and PtCo/γ-Al_(2)O_(3)(f)showed high catalytic activity in the CO-PROX reaction,achieving 100%CO conversion across a broad temperature range of 50−225°C.In contrast,only partial alloying of PtCo was observed onγ-Al_(2)O_(3)(s).Furthermore,no alloying between Pt and Co occurred in PtCo/γ-Al_(2)O_(3)(r),resulting in a reaction rate at 50°C that was merely 11%of that of PtCo/γ-Al_(2)O_(3)(f).The formation of Pt3Co intermetallic compounds led to a more oxidized state of Pt,which significantly diminished the adsorption of CO on Pt and augmented the active oxygen species,thereby facilitating the selective oxidation of CO.
基金supported by the Natural Science Foundation of Shanxi Province(202203021221155)the Foundation of National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal(J23-24-902)。
文摘With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.
基金Project(52274130)supported by the National Natural Science Foundation of ChinaProject(ZR2024ZD22)supported by the Major Basic Research Project of the Shandong Provincial Natural Science Foundation,China+2 种基金Project(2023375)supported by the Guizhou University Research and Innovation Team,ChinaProject(Leading Fund(2023)09)supported by the Natural Science Research Fund of Guizhou University,ChinaProject(JYBSYS2021101)supported by the Open Fund of Key Laboratory of Safe and Effective Coal Mining,Ministry of Education,China。
文摘The stress gradient of surrounding rock and reasonable prestress of support are the keys to ensuring the stability of roadways.The elastic-plastic analytical solution for surrounding rock was derived based on unified strength theory.A model for solving the stress gradient of the surrounding rock with the intermediate principal stress parameter b was established.The correctness and applicability of the solution for the stress gradient in the roadway surrounding rock was verified via multiple methods.Furthermore,the laws of stress,displacement,and the plastic zone of the surrounding rock with different b values and prestresses were revealed.As b increases,the stress gradient in the plastic zone increases,and the displacement and plastic zone radius decrease.As the prestress increases,the peak stress shifts toward the sidewalls,and the stress and stress gradient increments decrease.In addition,the displacement increment and plastic zone increment were proposed to characterize the support effect.The balance point of the plastic zone area appears before that of the displacement zone.The relationship between the stress gradient compensation coefficient and the prestress is obtained.This study provides a research method and idea for determining the reasonable prestress of support in roadways.
基金Project(2023YFC2907600)supported by the National Key Research and Development Program of ChinaProjects(42277174,42477166)supported by the National Natural Science Foundation of China+1 种基金Project(2024JCCXSB01)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(KFJJ24-01M)supported by the State Key Laboratory of Explosion Science and Safety Protection,Beijing Institute of Technology,China。
文摘Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam support system with high strength is developed.The high-strength bearing characteristics and coupling yielding support mechanism of this support system are studied by the mechanical tests of composite members and the combined support system.The test results show that under the coupling effect of support members,the peak stress of the box-shaped support beam in the anchor box beam is reduced by 21.9%,and the average deformation is increased by 135.0%.The ultimate bending bearing capacity of the box-shaped support beam is 3.5 times that of traditional channel beam.The effective compressive stress zone applied by the high prestressed cable is expanded by 26.4%.On this basis,the field support comparison test by the anchor channel beam,the anchor I-shaped beam and the anchor box beam are carried out.Compared with those of the previous two,the surrounding rock convergence of the latter is decreased by 41.2%and 22.2%,respectively.The field test verifies the effectiveness of the anchor box beam support system.
基金sponsored by the National Natural Science Foundation of China(Grant Nos.U2241285,62201267)。
文摘Zirconium,titanium,and other hexagonally close-packed(HCP)metals and their alloys are representative high specific strength,high reaction enthalpy,and high thermal conductivity structural materials.In this study,two typical HCP metals,zirconium,and titanium,were applied to reactive materials(RMs)to prepare Zr/PTFE/W RMs and Ti/PTFE/W RMs,validating the feasibility of HCP metal/PTFE/W RMs.The impact response process of typical HCP metal/PTFE/W RMs under high-velocity dynamic loads was studied using shock equations of state(EOS)based on porous mixtures and chemical reaction kinetics equations.An improved hemispherical quasi-sealed test chamber was employed to measure the energy release characteristic curves of 10 types of Zr/PTFE/W RMs and Ti/PTFE/W RMs under impact velocities ranging from 500 m/s to 1300 m/s.The datasets of the impact-induced energy release characteristics of HCP metal/PTFE/W RMs were established.Additionally,the energy release efficiency of HCP metal/PTFE/W RMs under impact was predicted using the support vector regression(SVR)kernel function model.The datasets of Zr/PTFE/W RMs and Ti/PTFE/W RMs with W contents of 0%,25%,50%,and 75%were used as test sets,respectively.The model predictions showed a high degree of agreement with the experimental data,with mean absolute errors(MAE)of 4.8,6.5,4.6,and 4.1,respectively.
基金Project(2023YFC3805700) supported by the National Key Research and Development Program of ChinaProjects(42477166,42277174) supported by the National Natural Science Foundation of China+2 种基金Project(2024JCCXSB01) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(KFJJ24-01M) supported by the State Key Laboratory of Explosion Science and Safety Protection,Beijing Institute of Technology,ChinaProject(HLCX-2024-04) supported by the Open Foundation of Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources,China。
文摘The surrounding rock is prone to large-scale loosening and failure after the excavation of shallow large-span caverns because of the thin overlying strata and large cross-section span.The rational design of bolt support is very important to the safety control of surrounding rock as a common support means.The control mechanism and design method of bolt support for shallow-buried large-span caverns is carried out.The calculation method of bolt prestress and length based on arched failure and collapsed failure mode is established.The influence mechanism of different influencing factors on the bolt prestress and length is clarified.At the same time,the constant resistance energy-absorbing bolt with high strength and high toughness is developed,and the comparative test of mechanical properties is carried out.On this basis,the design method of high prestressed bolt support for shallow-buried large-span caverns is put forward,and the field test is carried out in Qingdao metro station in China.The monitoring results show that the maximum roof settlement is 6.8 mm after the new design method is adopted,and the effective control of the shallow-buried large-span caverns is realized.The research results can provide theoretical and technical support for the safety control of shallow-buried large-span caverns.
文摘Nowadays,wireless communication devices turn out to be transportable owing to the execution of the current technologies.The antenna is the most important component deployed for communication purposes.The antenna plays an imperative role in receiving and transmitting the signals for any sensor network.Among varied antennas,micro strip fractal antenna(MFA)significantly contributes to increasing antenna gain.This study employs a hybrid optimization method known as the elephant clan updated grey wolf algorithm to introduce an optimized MFA design.This method optimizes antenna characteristics,including directivity and gain.Here,the factors,including length,width,ground plane length,height,and feed offset-X and feed offset-Y,are taken into account to achieve the best performance of gain and directivity.Ultimately,the superiority of the suggested technique over state-of-the-art strategies is calculated for various metrics such as cost and gain.The adopted model converges to a minimal value of 0.2872.Further,the spider monkey optimization(SMO)model accomplishes the worst performance over all other existing models like elephant herding optimization(EHO),grey wolf optimization(GWO),lion algorithm(LA),support vector regressor(SVR),bacterial foraging-particle swarm optimization(BF-PSO)and shark smell optimization(SSO).Effective MFA design is obtained using the suggested strategy regarding various parameters.
基金Supported by National Natural Science Foundation of China(42274217)。
文摘Fengyun meteorological satellites have undergone a series of significant developments over the past 50 years.Two generations,four types,and 21 Fengyun satellites have been developed and launched,with 9 currently operational in orbit.The data obtained from Fengyun satellites is employed in a multitude of applications,including weather forecasting,meteorological disaster prevention and reduction,climate change,global environmental monitoring,and space weather.These data products and services are made available to the global community,resulting in tangible social and economic benefits.In 2023,two Fengyun meteorological satellites were successfully launched.This report presents an overview of the two recently launched Fengyun satellites and currently in orbit Fengyun satellites,including an evaluation of their remote sensing instruments since 2022.Additionally,it addresses the subject of Fengyun satellite data archiving,data services,application services,international cooperation,and supporting activities.Furthermore,the development prospects have been outlined.
基金Project(2023YFC2907600)supported by the National Key Research and Development Program of ChinaProjects(42077267,42277174,52074164)supported by the National Natural Science Foundation of ChinaProject(2024JCCXSB01)supported by the Fundamental Research Funds for the Central Universities,China。
文摘Non-pillar mining technology with automatically formed roadway is a new mining method without coal pillar reservation and roadway excavation.The stability control of automatically formed roadway is the key to the successful application of the new method.In order to realize the stability control of the roadway surrounding rock,the mechanical model of the roof and rib support structure is established,and the influence mechanism of the automatically formed roadway parameters on the compound force is revealed.On this basis,the roof and rib support structure technology of confined lightweight concrete is proposed,and its mechanical tests under different eccentricity are carried out.The results show that the bearing capacity of confined lightweight concrete specimens is basically the same as that of ordinary confined concrete specimens.The bearing capacity of confined lightweight concrete specimens under different eccentricities is 1.95 times higher than those of U-shaped steel specimens.By comparing the test results with the theoretical calculated results of the confined concrete,the calculation method of the bearing capacity for the confined lightweight concrete structure is selected.The design method of confined lightweight concrete support structure is established,and is successfully applied in the extra-large mine,Ningtiaota Coal Mine,China.
基金National Natural Science Foundation of China(Grant Nos.52075111,51775123)Fundamental Research Funds for the Central Universities(Grant No.3072022JC0701)。
文摘To enhance flow stability and reduce hydrodynamic noise caused by fluctuating pressure,a quasiperiodic elastic support skin composed of flexible walls and elastic support elements is proposed for fluid noise reduction.The arrangement of the elastic support element is determined by the equivalent periodic distance and quasi-periodic coefficient.In this paper,a dynamic model of skin in a fluid environment is established.The influence of equivalent periodic distance and quasi-periodic coefficient on flow stability is investigated.The results suggest that arranging the elastic support elements in accordance with the quasi-periodic law can effectively enhance flow stability.Meanwhile,the hydrodynamic noise calculation results demonstrate that the skin exhibits excellent noise reduction performance,with reductions of 10 dB in the streamwise direction,11 dB in the spanwise direction,and 10 dB in the normal direction.The results also demonstrate that the stability analysis method can serve as a diagnostic tool for flow fields and guide the design of noise reduction structures.
基金Projects(42377148,51674265)supported by the National Natural Science Foundation of ChinaProject(2018YFC0603705)supported by the National Key Research and Development Program of China。
文摘Engineering shallow,large-span rock tunnels challenges deformation control and escalates construction costs.This study investigates the excavation compensation method(ECM)and its associated technologies to address these issues.Utilizing five key technologies,the ECM effectively modulates radial stress post-excavation,redistributes stress in the surrounding rock,and eliminates tensile stress at the excavation face.Pre-tensioning measures further enhance the rock’s residual strength,establishing a new stability equilibrium.Field tests corroborate the method’s effectiveness,demonstrating a crown settlement reduction of 3–8 mm,a nearly 50%decrease compared to conventional construction approaches.Additionally,material consumption and construction duration were reduced by approximately 30%–35%and 1.75 months per 100 m,respectively.Thus,the ECM represents a significant innovation in enhancing the stability and construction efficiency of large-span rock tunnels,marking a novel contribution to the engineering field.
基金Project(52178402)supported by the National Natural Science Foundation of ChinaProject(2021-Key-09)supported by the Science and Technology Research and Development Program Project of China Railway Group LimitedProject(2021zzts0216)supported by the Innovation-Driven Project of Central South University,China。
文摘Due to the long-term plate tectonic movements in southwestern China,the in-situ stress field in deep formations is complex.When passing through deep soft-rock mass under non-hydrostatic high in-situ stress field,tunnels will suffer serious asymmetric deformation.There is no available support design method for tunnels under such a situation in existing studies to clarify the support time and support stiffness.This study first analyzed the mechanical behavior of tunnels in non-hydrostatic in-situ stress field and derived the theoretical equations of the ground squeezing curve(GSC)and ground loosening curve(GLC).Then,based on the convergence confinement theory,the support design method of deep soft-rock tunnels under non-hydrostatic high in-situ stress field was established considering both squeezing and loosening pressures.In addition,this method can provide the clear support time and support stiffness of the second layer of initial support.The proposed design method was applied to the Wanhe tunnel of the China-Laos railway in China.Monitoring data indicated that the optimal support scheme had a good effect on controlling the tunnel deformation in non-hydrostatic high in-situ stress field.Field applications showed that the secondary lining could be constructed properly.
基金Project(ZDRW-ZS-2021-3)supported by the Key Deployment Projects of Chinese Academy of SciencesProjects(52179116,51991392)supported by the National Natural Science Foundation of China。
文摘In the process of shield tunneling through soft soil layers,the presence of confined water ahead poses a significant threat to the stability of the tunnel face.Therefore,it is crucial to consider the impact of confined water on the limit support pressure of the tunnel face.This study employed the finite element method(FEM)to analyze the limit support pressure of shield tunnel face instability within a pressurized water-containing layer.Subsequently,a multiple linear regression approach was applied to derive a concise solution formula for the limit support pressure,incorporating various influencing factors.The analysis yields the following conclusions:1)The influence of confined water on the instability mode of the tunnel face in soft soil layers makes the displacement response of the strata not significant when the face is unstable;2)The limit support pressure increases approximately linearly with the pressure head,shield tunnel diameter,and tunnel burial depth.And inversely proportional to the thickness of the impermeable layer,soil cohesion and internal friction angle;3)Through an engineering case study analysis,the results align well with those obtained from traditional theoretical methods,thereby validating the rationality of the equations proposed in this paper.Furthermore,the proposed equations overcome the limitation of traditional theoretical approaches considering the influence of changes in impermeable layer thickness.It can accurately depict the dynamic variation in the required limit support pressure to maintain the stability of the tunnel face during shield tunneling,thus better reflecting engineering reality.
