Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-d...Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-dpe)·7H_(2)O(3),(1,2-bixH)[Cd3(1,4-ndpaH)(1,4-ndpaH_(2))2(H_(2)O)_(2)](4),and[Cd(1,4-ndpaH_(2))(H_(2)O)]·H_(2)O(5),have been synthesized from the selfassembly reactions of 1,4-naphthalenediphosphonic acid(1,4-ndpaH4)with Cd(NO3)2·4H_(2)O by introducing auxiliary ligands with variation of rigidity,such as 4,4'-bipyridine(4,4'-bpy),1,4-bis(1-imidazolyl)benzene(1,4-bib),1,2-di(4-pyridyl)ethylene(1,2-dpe),1,3-di(4-pyridyl)propane(1,3-dpp),and bis(imidazol-1-ylmethyl)benzene(1,2-bix),respectively.Structure resolution by single-crystal X-ray diffraction reveals that compound 1 possesses a layered framework,in which the{Cd3(PO2)2}trimers made up of corner-sharing two{CdO4N2}and one{CdO6}octahedra are connected by phosphonate groups,forming a ribbon,which are cross-linked by 4,4'-bipy ligands,forming a 2D layer.Compound 2 shows a 3D open-framework structure,where chains of corner-sharing{CdO4N}trigonal bipyramids and{PO3C}tetrahedra are cross-linked by 1,4-bib and/or phosphonate groups.A 1D ladder-like chain structure is found in compound 3,where the ladder-like chains made up of corner-sharing{CdO5N}octahedra and{PO3C}tetra hedra are connected by 1,4-ndpaH_(2)^(2-).Both compounds 4 and 5 obtained by the introduction of flexible ligands during the synthesis show a 2D layered structure,which is formed by ligand crosslinking double metal chains.Interestingly,In 4,flexible 1,2-bix was singly protonated,as guest molecules,filled between layer and layer,while flexible ligand 1,3-dpp is absent in 5.Photophysical measurements indicate that compounds 1-5 show ligand-centered emissions.展开更多
This paper, particularly focusing on the pitch of prosodic words,has conducted a contrastive study on the structure of prosodic words in Englishand Mandarin . This paper reports a Mandarin monologue speech corpus-stud...This paper, particularly focusing on the pitch of prosodic words,has conducted a contrastive study on the structure of prosodic words in Englishand Mandarin . This paper reports a Mandarin monologue speech corpus-study, anexperimental phonetic attempt to conduct a study on the pitch of trisyllabic prosodicwords in Mandarin monologue. In addition, taking the characteristics of Englishprosodic words into consideration, the paper makes a contrastive analysis of prosodicwords in English and Mandarin. This study finds that the pitch of trisyllabic prosodicwords in Mandarin is inevitably affected by structural factors. As far as the leftsyllable is concerned, the grammatical category, prosodic hierarchical boundary andthe position of the intonational phrase where the syllable is located, the mid syllableand the right syllable may have influences on the pitch contour of the left syllable.As to the mid syllable, the grammatical category, the left syllable, the right syllableand the position of the intonational phrase where the syllable is located may haveinfluences on the pitch contour of the mid syllable. As for the right syllable, theprosodic hierarchical boundary where the syllable is located and the mid syllable mayhave effects on the pitch contour of the right syllable. Different from the previousfindings of the study on read corpus, this study shows that the mid syllable not onlyhas dissimilatory effects but also has assimilatory effects on the pitch of its precedingsyllable. The left syllable has anticipatory effects on the onset pitch of the mid syllableand the right syllable has coarticulation effects on the offset pitch of the mid syllable.展开更多
This article deals with two important issues in digital filter implementation： roundoff noise and limit cycles. A novel class of robust state-space realizations, called normal realizations, is derived and characteriz...This article deals with two important issues in digital filter implementation： roundoff noise and limit cycles. A novel class of robust state-space realizations, called normal realizations, is derived and characterized. It is seen that these realizations are free of limit cycles. Another interesting property of the normal realizations is that they yield a minimal error propagation gain. The optimal realization problem, defined as to find those normal realizations that minimize roundoff noise gain, is formulated and solved analytically. A design example is presented to demonstrate the behavior of the optimal normal realizations and to compare them with several well-known digital filter realizations in terms of minimizing the roundoff noise and the error propagation.展开更多
文摘Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-dpe)·7H_(2)O(3),(1,2-bixH)[Cd3(1,4-ndpaH)(1,4-ndpaH_(2))2(H_(2)O)_(2)](4),and[Cd(1,4-ndpaH_(2))(H_(2)O)]·H_(2)O(5),have been synthesized from the selfassembly reactions of 1,4-naphthalenediphosphonic acid(1,4-ndpaH4)with Cd(NO3)2·4H_(2)O by introducing auxiliary ligands with variation of rigidity,such as 4,4'-bipyridine(4,4'-bpy),1,4-bis(1-imidazolyl)benzene(1,4-bib),1,2-di(4-pyridyl)ethylene(1,2-dpe),1,3-di(4-pyridyl)propane(1,3-dpp),and bis(imidazol-1-ylmethyl)benzene(1,2-bix),respectively.Structure resolution by single-crystal X-ray diffraction reveals that compound 1 possesses a layered framework,in which the{Cd3(PO2)2}trimers made up of corner-sharing two{CdO4N2}and one{CdO6}octahedra are connected by phosphonate groups,forming a ribbon,which are cross-linked by 4,4'-bipy ligands,forming a 2D layer.Compound 2 shows a 3D open-framework structure,where chains of corner-sharing{CdO4N}trigonal bipyramids and{PO3C}tetrahedra are cross-linked by 1,4-bib and/or phosphonate groups.A 1D ladder-like chain structure is found in compound 3,where the ladder-like chains made up of corner-sharing{CdO5N}octahedra and{PO3C}tetra hedra are connected by 1,4-ndpaH_(2)^(2-).Both compounds 4 and 5 obtained by the introduction of flexible ligands during the synthesis show a 2D layered structure,which is formed by ligand crosslinking double metal chains.Interestingly,In 4,flexible 1,2-bix was singly protonated,as guest molecules,filled between layer and layer,while flexible ligand 1,3-dpp is absent in 5.Photophysical measurements indicate that compounds 1-5 show ligand-centered emissions.
文摘This paper, particularly focusing on the pitch of prosodic words,has conducted a contrastive study on the structure of prosodic words in Englishand Mandarin . This paper reports a Mandarin monologue speech corpus-study, anexperimental phonetic attempt to conduct a study on the pitch of trisyllabic prosodicwords in Mandarin monologue. In addition, taking the characteristics of Englishprosodic words into consideration, the paper makes a contrastive analysis of prosodicwords in English and Mandarin. This study finds that the pitch of trisyllabic prosodicwords in Mandarin is inevitably affected by structural factors. As far as the leftsyllable is concerned, the grammatical category, prosodic hierarchical boundary andthe position of the intonational phrase where the syllable is located, the mid syllableand the right syllable may have influences on the pitch contour of the left syllable.As to the mid syllable, the grammatical category, the left syllable, the right syllableand the position of the intonational phrase where the syllable is located may haveinfluences on the pitch contour of the mid syllable. As for the right syllable, theprosodic hierarchical boundary where the syllable is located and the mid syllable mayhave effects on the pitch contour of the right syllable. Different from the previousfindings of the study on read corpus, this study shows that the mid syllable not onlyhas dissimilatory effects but also has assimilatory effects on the pitch of its precedingsyllable. The left syllable has anticipatory effects on the onset pitch of the mid syllableand the right syllable has coarticulation effects on the offset pitch of the mid syllable.
基金the National Nature Science Foundation of China (60774021)
文摘This article deals with two important issues in digital filter implementation： roundoff noise and limit cycles. A novel class of robust state-space realizations, called normal realizations, is derived and characterized. It is seen that these realizations are free of limit cycles. Another interesting property of the normal realizations is that they yield a minimal error propagation gain. The optimal realization problem, defined as to find those normal realizations that minimize roundoff noise gain, is formulated and solved analytically. A design example is presented to demonstrate the behavior of the optimal normal realizations and to compare them with several well-known digital filter realizations in terms of minimizing the roundoff noise and the error propagation.
