The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, iono...The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, ionomer, and Pt nanoparticles, all immersed together and sprayed with a micron-level thickness of CLs. They have a performance trade-off where increasing the Pt loading leads to higher performance of abundant triple-phase boundary areas but increases the electrode cost. Major challenges must be overcome before realizing its wide commercialization. Literature research revealed that it is impossible to achieve performance and durability targets with only high-performance catalysts, so the controllable design of CLs architecture in MEAs for PEMFCs must now be the top priority to meet industry goals. From this perspective, a 3D ordered electrode circumvents this issue with a support-free architecture and ultrathin thickness while reducing noble metal Pt loadings. Herein, we discuss the motivation in-depth and summarize the necessary CLs structural features for designing ultralow Pt loading electrodes. Critical issues that remain in progress for 3D ordered CLs must be studied and characterized. Furthermore, approaches for 3D ordered CLs architecture electrode development, involving material design, structure optimization, preparation technology, and characterization techniques, are summarized and are expected to be next-generation CLs for PEMFCs. Finally, the review concludes with perspectives on possible research directions of CL architecture to address the significant challenges in the future.展开更多
This study explored the potential of polysaccharides from Actium lappa(ALPs)as natural wall materials for producing ALP-based nanoparticles to deliver poorly water-soluble oleanolic acid(OA)and ursolic acid(UA).Encaps...This study explored the potential of polysaccharides from Actium lappa(ALPs)as natural wall materials for producing ALP-based nanoparticles to deliver poorly water-soluble oleanolic acid(OA)and ursolic acid(UA).Encapsulating OA+UA with ALPs(ALP:OA+UA,50:1;OA:UA,1:1)changed the crystalline nature to a more amorphous state through hydrogen bonding and involving O-H/C-O/O-C-O groups.ALP-OA/UA nanoparticles had a particle size and zeta potential(in water)of 199.1 nm/-7.15 mV,with a narrow unimodal size distribution,and excellent pH,salt solution,temperature and storage stability.Compared with ALPs,ALPOA/UA nanoparticles showed enhanced anti-inflammatory activity(especially at a dose of 100μg/mL)in a CuSO-induced zebrafish inflammation model via down-regulating the NF-κB signalling pathway and gene expression of associated transcription factors and cytokines(TNF-α,IL-1βand IL-8).Therefore,ALP-based nanoparticles are natural and anti-inflammatory carriers for hydrophobic bioactive molecules.展开更多
To solve the problems of shear degradation and injection difficulties in conventional polymer flooding,the capsule polymer flooding for enhanced oil recovery(EOR)was proposed.The flow and oil displacement mechanisms o...To solve the problems of shear degradation and injection difficulties in conventional polymer flooding,the capsule polymer flooding for enhanced oil recovery(EOR)was proposed.The flow and oil displacement mechanisms of this technique were analyzed using multi-scale flow experiments and simulation technology.It is found that the capsule polymer flooding has the advantages of easy injection,shear resistance,controllable release in reservoir,and low adsorption retention,and it is highly capable of long-distance migration to enable viscosity increase in deep reservoirs.The higher degree of viscosity increase by capsule polymer,the stronger the ability to suppress viscous fingering,resulting in a more uniform polymer front and a larger swept range.The release performance of capsule polymer is mainly sensitive to temperature.Higher temperatures result in faster viscosity increase by capsule polymer solution.The salinity has little impact on the rate of viscosity increase.The capsule polymer flooding is suitable for high-water-cut reservoirs for which conventional polymer flooding techniques are less effective,offshore reservoirs by polymer flooding in largely spaced wells,and medium to low permeability reservoirs where conventional polymers cannot be injected efficiently.Capsule polymer flooding should be customized specifically,with the capsule particle size and release time to be determined depending on target reservoir conditions to achieve the best displacement effect.展开更多
For dispersed ceria-zirconia-based solid solutions prepared via the polymerized complex method and annealed at 700 ℃, effects of bulk doping by Ca, Mn, Co, Bi or Nb cations and surface modification by Mn and Pt on th...For dispersed ceria-zirconia-based solid solutions prepared via the polymerized complex method and annealed at 700 ℃, effects of bulk doping by Ca, Mn, Co, Bi or Nb cations and surface modification by Mn and Pt on their structural features, surface/bulk oxygen reactivity and catalytic activity in methane combustion are considered. With up to 20 mol% doping, a structural type of homogeneous solid solutions of anion-deficient fluorite with disordered anion vacancies is formed. Doping by transition metal cations or Pt increases the mobility and reactivity of the surface/bulk oxygen. A broad variation in specific rates of methane combustion for the studied systems was observed, suggesting structural sensitivity of this reaction. In general, there is no universal relationship between the oxygen mobility, the reactivity and the catalytic activity in methane combustion, which is explained by the factor of specific methane activation on surface active sites. For the Pt-promoted samples, Pt efficiency in methane activation depends on the Pt-support interaction, and the most favorable ones being mixed Pt/MnOx and Pt/NbOx clusters on the surface of the supports that exhibit high lattice oxygen mobilities.展开更多
In terms of the characteristic topology parameters of climate complex networks, the spatial connection structural complexity of the circulation system and the influence of four teleconnection patterns are quantitative...In terms of the characteristic topology parameters of climate complex networks, the spatial connection structural complexity of the circulation system and the influence of four teleconnection patterns are quantitatively described. Results of node degrees for the Northern Hemisphere （NH） mid-high latitude （30° N-90°N） circulation system （NHS） networks with and without the Arctic Oscillations （AO）, the North Atlantic Oscillations （NAO） and the Pacific-North American pattern （PNA） demonstrate that the teleconnections greatly shorten the mean shortest path length of the networks, thus being advantageous to the rapid transfer of local fluctuation information over the network and to the stability of the NHS. The impact of the AO on the NHS connection structure is most important and the impact of the NAO is the next important. The PNA is a relatively independent teleconnection, and its role in the NHS is mainly manifested in the connection between the NHS and the tropical circulation system （TRS）. As to the Southern Hemisphere mid-high latitude （30°S-90°S） circulation system （SHS）, the impact of the Antarctic Arctic Oscillations （AAO） on the structural stability of the system is most important. In addition, there might be a stable correlation dipole （AACD） in the SHS, which also has important influence on the structure of the SHS networks.展开更多
Using finite element method,influence of diesel cylinder head structure on fatigue strength is investigated.A simplified head model with function characteristics is built for thermal-mechanical simulation.From the sim...Using finite element method,influence of diesel cylinder head structure on fatigue strength is investigated.A simplified head model with function characteristics is built for thermal-mechanical simulation.From the simulation results,the influence of valve bridge structure and roof transition fillet dimension on fatigue strength are obtained.And a new valve bridge structure which can effectively improve the fatigue life is proposed.展开更多
基金funded by the Natural Science Foundation of Shandong Province, China (ZR2023MB049)the China Postdoctoral Science Foundation (2020M670483)the Science Foundation of Weifang University (2023BS11)。
文摘The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, ionomer, and Pt nanoparticles, all immersed together and sprayed with a micron-level thickness of CLs. They have a performance trade-off where increasing the Pt loading leads to higher performance of abundant triple-phase boundary areas but increases the electrode cost. Major challenges must be overcome before realizing its wide commercialization. Literature research revealed that it is impossible to achieve performance and durability targets with only high-performance catalysts, so the controllable design of CLs architecture in MEAs for PEMFCs must now be the top priority to meet industry goals. From this perspective, a 3D ordered electrode circumvents this issue with a support-free architecture and ultrathin thickness while reducing noble metal Pt loadings. Herein, we discuss the motivation in-depth and summarize the necessary CLs structural features for designing ultralow Pt loading electrodes. Critical issues that remain in progress for 3D ordered CLs must be studied and characterized. Furthermore, approaches for 3D ordered CLs architecture electrode development, involving material design, structure optimization, preparation technology, and characterization techniques, are summarized and are expected to be next-generation CLs for PEMFCs. Finally, the review concludes with perspectives on possible research directions of CL architecture to address the significant challenges in the future.
基金supported by the Shandong Provincial Natural Science Foundation of China(ZR2019BC100)Science,Education and Industry Integration Innovation Pilot Project of Qilu University of Technology(Shandong Academy of Sciences)(2020KJC-ZD10)Incubation Program of Youth Innovation in Shandong Province。
文摘This study explored the potential of polysaccharides from Actium lappa(ALPs)as natural wall materials for producing ALP-based nanoparticles to deliver poorly water-soluble oleanolic acid(OA)and ursolic acid(UA).Encapsulating OA+UA with ALPs(ALP:OA+UA,50:1;OA:UA,1:1)changed the crystalline nature to a more amorphous state through hydrogen bonding and involving O-H/C-O/O-C-O groups.ALP-OA/UA nanoparticles had a particle size and zeta potential(in water)of 199.1 nm/-7.15 mV,with a narrow unimodal size distribution,and excellent pH,salt solution,temperature and storage stability.Compared with ALPs,ALPOA/UA nanoparticles showed enhanced anti-inflammatory activity(especially at a dose of 100μg/mL)in a CuSO-induced zebrafish inflammation model via down-regulating the NF-κB signalling pathway and gene expression of associated transcription factors and cytokines(TNF-α,IL-1βand IL-8).Therefore,ALP-based nanoparticles are natural and anti-inflammatory carriers for hydrophobic bioactive molecules.
基金Supported by the Joint Funds of the National Natural Science Foundation of China(U21B2070)Natural Science Foundation of China(52374061)。
文摘To solve the problems of shear degradation and injection difficulties in conventional polymer flooding,the capsule polymer flooding for enhanced oil recovery(EOR)was proposed.The flow and oil displacement mechanisms of this technique were analyzed using multi-scale flow experiments and simulation technology.It is found that the capsule polymer flooding has the advantages of easy injection,shear resistance,controllable release in reservoir,and low adsorption retention,and it is highly capable of long-distance migration to enable viscosity increase in deep reservoirs.The higher degree of viscosity increase by capsule polymer,the stronger the ability to suppress viscous fingering,resulting in a more uniform polymer front and a larger swept range.The release performance of capsule polymer is mainly sensitive to temperature.Higher temperatures result in faster viscosity increase by capsule polymer solution.The salinity has little impact on the rate of viscosity increase.The capsule polymer flooding is suitable for high-water-cut reservoirs for which conventional polymer flooding techniques are less effective,offshore reservoirs by polymer flooding in largely spaced wells,and medium to low permeability reservoirs where conventional polymers cannot be injected efficiently.Capsule polymer flooding should be customized specifically,with the capsule particle size and release time to be determined depending on target reservoir conditions to achieve the best displacement effect.
文摘For dispersed ceria-zirconia-based solid solutions prepared via the polymerized complex method and annealed at 700 ℃, effects of bulk doping by Ca, Mn, Co, Bi or Nb cations and surface modification by Mn and Pt on their structural features, surface/bulk oxygen reactivity and catalytic activity in methane combustion are considered. With up to 20 mol% doping, a structural type of homogeneous solid solutions of anion-deficient fluorite with disordered anion vacancies is formed. Doping by transition metal cations or Pt increases the mobility and reactivity of the surface/bulk oxygen. A broad variation in specific rates of methane combustion for the studied systems was observed, suggesting structural sensitivity of this reaction. In general, there is no universal relationship between the oxygen mobility, the reactivity and the catalytic activity in methane combustion, which is explained by the factor of specific methane activation on surface active sites. For the Pt-promoted samples, Pt efficiency in methane activation depends on the Pt-support interaction, and the most favorable ones being mixed Pt/MnOx and Pt/NbOx clusters on the surface of the supports that exhibit high lattice oxygen mobilities.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.40930952 and 40705031)the Special Scientific Research Project for Public Interest,China (Grant Nos.GYHY201006021 and GYHY201106016)the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (Grant No.2007BAC29B01)
文摘In terms of the characteristic topology parameters of climate complex networks, the spatial connection structural complexity of the circulation system and the influence of four teleconnection patterns are quantitatively described. Results of node degrees for the Northern Hemisphere （NH） mid-high latitude （30° N-90°N） circulation system （NHS） networks with and without the Arctic Oscillations （AO）, the North Atlantic Oscillations （NAO） and the Pacific-North American pattern （PNA） demonstrate that the teleconnections greatly shorten the mean shortest path length of the networks, thus being advantageous to the rapid transfer of local fluctuation information over the network and to the stability of the NHS. The impact of the AO on the NHS connection structure is most important and the impact of the NAO is the next important. The PNA is a relatively independent teleconnection, and its role in the NHS is mainly manifested in the connection between the NHS and the tropical circulation system （TRS）. As to the Southern Hemisphere mid-high latitude （30°S-90°S） circulation system （SHS）, the impact of the Antarctic Arctic Oscillations （AAO） on the structural stability of the system is most important. In addition, there might be a stable correlation dipole （AACD） in the SHS, which also has important influence on the structure of the SHS networks.
基金Supported by the National Basic Research Program of China(613570303)
文摘Using finite element method,influence of diesel cylinder head structure on fatigue strength is investigated.A simplified head model with function characteristics is built for thermal-mechanical simulation.From the simulation results,the influence of valve bridge structure and roof transition fillet dimension on fatigue strength are obtained.And a new valve bridge structure which can effectively improve the fatigue life is proposed.
