To address the challenges associated with difficult casing running,limited annular space,and poor cementing quality in the completion of ultra-deep wells,the extreme line casing offers an effective solution over conve...To address the challenges associated with difficult casing running,limited annular space,and poor cementing quality in the completion of ultra-deep wells,the extreme line casing offers an effective solution over conventional casings.However,due to its smaller size,the joint strength of extreme line casing is reduced,which may cause failure when running in the hole.To address this issue,this study focuses on the CST-ZTΦ139.7 mm×7.72 mm extreme line casing and employs the elastic-plastic mechanics to establish a comprehensive analysis of the casing joint,taking into account the influence of geometric and material nonlinearities.A finite element model is developed to analyze the forces and deformations of the extreme line casing joint under axial tension and external collapse load.The model investigates the stress distribution of each thread tooth subjected to various tensile forces and external pressures.Additionally,the tensile strength and crushing strength of the extreme line casing joint are determined through both analytical and experimental approaches.The findings reveal that,under axial tensile load,the bearing surface of each thread tooth experiences uneven stress,with relatively high equivalent stress at the root of each thread tooth.The end thread teeth are valuable spots for failure.It is observed that the critical fracture axial load of thread decreases linearly with the increase of thread tooth sequence.Under external pressure,the circumferential stress is highest at the small end of the external thread,leading to yield deformation.The tensile strength of the joint obtained from the finite element model exhibits a relative error of less than 7%compared to the analytical and experimental values,proving the reliability of the finite element model.The tensile strength of the joint is 3091.9 k N.Moreover,in terms of anti-collapse capability,the joints demonstrate higher resistance to collapse compared to the casing body,which is consistent with the test results where the pipe body experiences collapse and failure while the joints remain intact during the experiment.The failure load of the casing body under external collapse pressure is 87.4 MPa.The present study provides a basic understanding of the mechanical strengths of extreme line casing joint.展开更多
Background Despite high relapse rate among methamphetamine (MA) abusers, there still have been little empirical data to date detecting the risk factors related to craving and relapse from the perspective of MA abusers...Background Despite high relapse rate among methamphetamine (MA) abusers, there still have been little empirical data to date detecting the risk factors related to craving and relapse from the perspective of MA abusers. Therefore, the aim of this study was to use qualitative research methods exploring the strengths, weaknesses, opportunities and threat factors that could facilitate or impede individuals' abstinence in a real-life context from the perspectives of MA abusers. Aim To use qualitative research methods exploring the strengths, weaknesses, opportunities and threat factors relating to individuals' abstinence in a real-life context. Method Semistructured interviews were conducted with 32 MA abusers recruited in Shanghai guided by open-ended questions on narrating the real-life catalysts and inhibitors related to craving, initiation, relapse and abstinence. All data were transcribed verbatim and analysed using a strengths, weaknesses, opportunities and threats (SWOT) analysis. Results The results of the SWOT analysis revealed that contextual factors including peer influence, prevalence and availability of MA, familiar venue of MA use, discrimination, sexual behaviours, alcohol, emotional states and their attitudes towards smoking MA were important factors that contribute to reinitiation and relapse. Surveillance systems, antidrug social workers, vocational skills trainings, moving to another city and family responsibility might serve as counter measures targeti叩 those mentioned weaknesses and threats above. Conclusion This SWOT analysis highlights the complex nature of relapse. Comprehensive interventions strengtheni叩 coping skills such as virtual reality techniques are desperately needed to facilitate individuals1 sustained abstinence.展开更多
The development of clean and sustainable energy sources has received widespread interest in the past few decades due to the rolling energy demands while extenuating the rising tiers of greenhouse gases and environment...The development of clean and sustainable energy sources has received widespread interest in the past few decades due to the rolling energy demands while extenuating the rising tiers of greenhouse gases and environmental pollution.Due to their intermittent nature,these green and sustainable sources require appropriate energy storage systems.Amongst different energy storage technologies,electrochemical energy storage devices,particularly supercapacitors(SCs),have fascinated global attention for their utilization in electric vehicles,power supports,portable electronics,and many others application requiring electric energy devices for their operation.Thus,the growth of SCs in the commercial market has squeezed requirements,and further developments are obligatory for their effective industrialization.In the meantime,SCs also face technical complications and contests for their introduction in industrial settings because of their low energy density and high Levelized cost.The present study combines core strengths,weaknesses,opportunities,and threats(SWOT)analysis of SCs with new perspectives and recent ideas.The challenges and the future progressive prospects of SCs are also presented in detail.This review will afford consistent direction and new superhighways for the further development of SCs as standalone and complementary energy storage systems.展开更多
The dipole-length, dipole-velocity and dipole-acceleration absorption oscillator strengths for the 1s^22s-1s^2np (3 ≤ n ≤9) transitions of lithium-like systems from Z = 11 to 20 are calculated by using the energie...The dipole-length, dipole-velocity and dipole-acceleration absorption oscillator strengths for the 1s^22s-1s^2np (3 ≤ n ≤9) transitions of lithium-like systems from Z = 11 to 20 are calculated by using the energies and the multiconfiguration interaction wave functions obtained from a full core plus correlation method, in which relativistic and mass-polarization effects on the energy, as the first-order perturbation corrections, are included. The results of three forms are in good agreement with each other, and closely agree with the experimental data available in the literature. Based on the quantum defects obtained with quantum defect theory (QDT), the discrete oscillator strengths for the transitions from the ground state to highly excited states 1s^2np (n ≥ 10) and oscillator strength densities corresponding to the bound-free transitions are obtained for these ions.展开更多
The transition energies, E1 transitional oscillator strengths of the spin-allowed as well as the spin-forbidden and the corresponding transition rates, and complete M1, E2, M2 forbidden transition rates for 1s^(2), 1s...The transition energies, E1 transitional oscillator strengths of the spin-allowed as well as the spin-forbidden and the corresponding transition rates, and complete M1, E2, M2 forbidden transition rates for 1s^(2), 1s2s, and 1s2p states of He I, are investigated using the multi-configuration Dirac–Hartree–Fock method. In the subsequent relativistic configuration interaction computations, the Breit interaction and the QED effect are considered as perturbation, separately. Our transition energies, oscillator strengths, and transition rates are in good agreement with the experimental and other theoretical results. As a result, the QED effect is not important for helium atoms, however, the effect of the Breit interaction plays a significant role in the transition energies, the oscillator strengths and transition rates.展开更多
The scattering matrices of e+N^(+)with J^(π)=1.5^(+)in discrete energy regions are calculated using the eigenchannel R-matrix method.We obtain good parameters of multichannel quantum defect theory(MQDT)that vary smoo...The scattering matrices of e+N^(+)with J^(π)=1.5^(+)in discrete energy regions are calculated using the eigenchannel R-matrix method.We obtain good parameters of multichannel quantum defect theory(MQDT)that vary smoothly as the function of the energy resulting from the analytical continuation property of the scattering matrices.By employing the MQDT,all discrete energy levels for N could be calculated accurately without missing anyone.The MQDT parameters(i.e.,scattering matrices)can be calibrated with the available precise spectroscopy values.In this work,the optical oscillator strengths for the transition between the ground state and Rydberg series are obtained,which provide rich data for the diagnostic analysis of plasma.展开更多
By performing density functional theory plus U calculations, we systematically study the structural, electronic, and magnetic properties of U02 under uniaxial tensile strain. The results show that the ideal tensile st...By performing density functional theory plus U calculations, we systematically study the structural, electronic, and magnetic properties of U02 under uniaxial tensile strain. The results show that the ideal tensile strengths along the [100], [110], and [111] directions are 93.6, 2Z7, and 16.4 GPa at strains of 0.44, 0.24, and 0.16, respectively. After electronic-structure investigation for tensile stain along the [001] direction, we find that the strong mixed ionic/covalent character of U-O bond is weakened by the tensile strain and there will occur an insulator to metal transition at strain over 0.30.展开更多
Figuring out rock strength plays essential roles in the sub ground mining activities,such as oil and gas well drilling and hydraulic fracturing,coal mining,tunneling,and other civil engineering scenarios.To help under...Figuring out rock strength plays essential roles in the sub ground mining activities,such as oil and gas well drilling and hydraulic fracturing,coal mining,tunneling,and other civil engineering scenarios.To help understand the effects of the mineralogical composition on evaluating the rock strength,this research tries to establish indirect prediction models of rock strength by specific input mineral contents for common sedimentary rocks.Using rock samples collected from the outcrops in the Sichuan Basin,uniaxial compression tests have been conducted to sandstone,carbonate,and shale cores.Combining with statistical analysis,the experimental data prove it true that the mineralogical composition can be utilized to predict the rock strength under specific conditions but the effects of mineralogical composition on the rock strength highly depend on the rock lithologies.According to the statistical analysis results,the predicted values of rock strengths by the mineral contents can get high accuracies in sandstone and carbonate rocks while no evidences can be found in shale rocks.The best indicator for predicting rock strength should be the quartz content for the sandstone rocks and the dolomite content for the carbonate rocks.Especially,to improve the evaluation accuracy,the rock strengths of sandstones can be obtained by substituting the mineral contents of quartz and clays,and those of carbonates can be calculated by the mineral contents of dolomite and calcite.Noticeably,the research data point out a significant contrast of quartz content in evaluating the rock strength of the sandstone rocks and the carbonate rocks.Increasing quartz content helps increase the sandstone strength but decrease the carbonate strength.As for shale rocks,no relationship exists between the rock strength and the mineralogical composition(e.g.,the clay fractions).To provide more evidences,detailed discussion also provides the readers more glances into the framework of the rock matrix,which can be further studied in the future.These findings can help understand the effects of mineralogical composition on the rock strengths,explain the contrasts in the rock strength of the responses to the same mineral content(e.g.,the quartz content),and provide another indirect method for evaluating the rock strength of common sedimentary rocks.展开更多
The valence-shell excitations of krypton atom have been investigated by fast electron impact with an angle-resolved electron-energy-loss spectrometer. The generalized oscillator strengths for some higher mixed valence...The valence-shell excitations of krypton atom have been investigated by fast electron impact with an angle-resolved electron-energy-loss spectrometer. The generalized oscillator strengths for some higher mixed valence-shell excitations in 4d, 4f, 5p, 5d, 6s, 6p, 7s ←4p of krypton atom have been determined. Their profiles are discussed, and the generalized oscillator strengths for the electric monopole and quadrupole excitations in 5p ← 4p are compared with the calculations of Amusia et al. (Phys. Rev. A 67 022703 (2003)). The differences between the experimental results and theoretical calculations show that more studies are needed.展开更多
The finite element analysis of mismatched welded jo ints with a 30°groove angle was performed to study the mechanical behavior of D MWJs (dissimilar metal welded joints). It is concluded that the distribution of...The finite element analysis of mismatched welded jo ints with a 30°groove angle was performed to study the mechanical behavior of D MWJs (dissimilar metal welded joints). It is concluded that the distribution of stress triaxiality in the DMWJs is uneven, especially near the fusion lines. The degree of creep strength mismatch has remarkable effect on the distribution. Th e higher the level of mismatch is, the more uneven the distribution is and the e asier for premature failure to occur in the joint.展开更多
In the paper, the finite element method (FEM) , engineering calculationmethod (ECM) and empirical fromular method (EFM) were used to calculatethe strengths of fillet joints in an Al-alloy vehicle. The results obtained...In the paper, the finite element method (FEM) , engineering calculationmethod (ECM) and empirical fromular method (EFM) were used to calculatethe strengths of fillet joints in an Al-alloy vehicle. The results obtained withdifferent calculation methods were analysed, and then each method wasreviewed and assessed. FEM is accurate, but complicated, and its results haveno strength reserve; ECM and EFM are simple and convenient, butconservative.展开更多
More and more non-native English speaking teachers teach with native English speaking teachers in Chinese context or other non-English speaking countries. It is worthwhile to evaluate their strengths and constraints. ...More and more non-native English speaking teachers teach with native English speaking teachers in Chinese context or other non-English speaking countries. It is worthwhile to evaluate their strengths and constraints. The current paper discusses their differences in term of linguistic teaching characteristics, social culture teaching characteristics and pedagogical teaching characteristics. It concludes that two groups of teachers can be successful language teachers with the equal chances on their own terms and can make up for their constraints by applying certain patterns of collaboration.展开更多
In Orientalism,the author Edward W.Said stated that the Orient is negatively defined and serves to support the West'ssuperiority and strength.Citing a number of discourses and texts in the book,he broke the bounda...In Orientalism,the author Edward W.Said stated that the Orient is negatively defined and serves to support the West'ssuperiority and strength.Citing a number of discourses and texts in the book,he broke the boundary between knowledge and poli-tics,and further examined how the knowledge that the Western colonial powers shaped about the Orient assisted to make a de-praved picture of the colonies,to justify their colonial ambition and suppression.Nevertheless,although Said attempted to explainthe selection of the oriental area in his discussion,a vast area of the Far East,such as China and Japan is excluded.Furthermore,he regarded the Orient as a completely passive colony,and negated any resistance from the Orient.展开更多
Due to the continuously increasing building and construction industry,sand has become one of the most questioned raw materials worldwide.However,the available amount of sand suitable for concrete production is orders ...Due to the continuously increasing building and construction industry,sand has become one of the most questioned raw materials worldwide.However,the available amount of sand suitable for concrete production is orders of magnitude lower that the demand and consumption.Even though desert sand is sufficiently available,it is not usable for realizing stable concrete due to its surface shape.Against this background,the suitability of energy-efficient‘cold'dielectric barrier discharge plasma operated at atmospheric pressure for improving the properties of concrete produced from desert sand was investigated in this contribution.It is shown that such plasma treatment allows for a certain roughening and re-shaping of sand grains.As a result,the mass flow of treated sand is decreased due to an improved wedging of sand grains.This leads to a certain increase in compressive strength of concrete samples.Even though this increase is marginal,the suitability of the applied type of plasma for modification of the geometry and surface chemistry of sand grains was proven,showing its basic potential for the treatment and preconditioning of sand used for concrete,mortar or plastering.展开更多
Understanding the anchorage performance of en-echelon joints under cyclic shear loading is crucial for optimizing support strategies in jointed rock masses.This study examines the anchorage effects on enechelon joints...Understanding the anchorage performance of en-echelon joints under cyclic shear loading is crucial for optimizing support strategies in jointed rock masses.This study examines the anchorage effects on enechelon joints with various orientations using laboratory cyclic shear tests.By comparing unbolted and bolted en-echelon joints,we analyze shear zone damage,shear properties,dilatancy,energy absorption,and acoustic emission characteristics to evaluate anchoring effects across shear cycles and joint orientations.Results reveal that bolted en-echelon joints experience more severe shear zone damage after cycles,with bolt deformation correlating to shear zone width.Bolted en-echelon joints exhibit faster shear strength deterioration and higher cumulative strength loss compared to unbolted ones,with losses ranging from 20.04%to 72.76%.The compressibility of en-echelon joints reduces the anchoring effect during shear cycles,leading to lower shear strength of bolted en-echelon joints in later stages of shear cycles compared to unbolted ones.Bolts reinforce en-echelon joints more effectively at non-positive angles,with the best performance observed at 0°and-60°.Anchorage accelerates the transition from rolling friction to sliding friction in the shear zone,enhancing energy absorption,which is crucial for rock projects under dynamic shear loading.Additionally,rock bolts expedite the transition of the cumulative AE hits and cumulative AE energy curves from rapid to steady growth,indicating that strong bolt-rock interactions accelerate crack initiation,propagation,and energy release.展开更多
We report a comprehensive study on low-lying parity doublet states of ^(224)Rn by mixing both quadrupole-and octupoleshaped configurations in multireference covariant density functional theory,in which broken symmetri...We report a comprehensive study on low-lying parity doublet states of ^(224)Rn by mixing both quadrupole-and octupoleshaped configurations in multireference covariant density functional theory,in which broken symmetries in configurations are restored using projection techniques.The low-lying energy spectrum is reasonably reproduced when the shape fluctuations in both the quadrupole and octupole shapes are considered.Electric octupole transition strength in ^(224)Rn is found to be B(E3;3_(1)^(-)→0_(1)^(+))=43 W.u.,comparable to that in ^(224)Ra,whose data are 42(3)W.u..Our results indicate that ^(224)Rn shares similar low-energy structure with ^(224)Ra despite the excitation energy of first 3^(−)state of the former nucleus is higher than that of the latter.This study suggests ^(224)Rn is a candidate for the search for permanent electric dipole moment.展开更多
The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high ...The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high electrical and mechanical properties remains challenging,which heavily depends on the tube-tube interac-tions of CNTs.Herein,we develop a novel strategy based on metal-organic decomposition(MOD)to fabricate a flexible silver-carbon nanotube(Ag-CNT)film.The Ag particles are introduced in situ into the CNT film through annealing of MOD,leading to enhanced tube-tube interactions.As a result,the electrical conductivity of Ag-CNT film is up to 6.82×10^(5) S m^(-1),and the EMI shielding effectiveness of Ag-CNT film with a thickness of~7.8μm exceeds 66 dB in the ultra-broad frequency range(3-40 GHz).The tensile strength and Young’s modulus of Ag-CNT film increase from 30.09±3.14 to 76.06±6.20 MPa(~253%)and from 1.12±0.33 to 8.90±0.97 GPa(~795%),respectively.Moreover,the Ag-CNT film exhibits excellent near-field shield-ing performance,which can effectively block wireless transmission.This innovative approach provides an effective route to further apply macroscopic CNT assemblies to future portable and wearable electronic devices.展开更多
Casing wear and casing corrosion are serious problems affecting casing integrity failure in deep and ultra-deep wells.This paper aims to predict the casing burst strength with considerations of both wear and corrosion...Casing wear and casing corrosion are serious problems affecting casing integrity failure in deep and ultra-deep wells.This paper aims to predict the casing burst strength with considerations of both wear and corrosion.Firstly,the crescent wear shape is simplified into three categories according to common mathematical models.Then,based on the mechano-electrochemical(M-E)interaction,the prediction model of corrosion depth is built with worn depth as the initial condition,and the prediction models of burst strength of the worn casing and corroded casing are obtained.Secondly,the accuracy of different prediction models is validated by numerical simulation,and the main influence factors on casing strength are obtained.At last,the theoretical models are applied to an ultra-deep well in Northwest China,and the dangerous well sections caused by wear and corrosion are predicted,and the corrosion rate threshold to ensure the safety of casing is obtained.The results show that the existence of wear defects results in a stress concentration and enhanced M-E interaction on corrosion depth growth.The accuracy of different mathematical models is different:the slot ring model is most accurate for predicting corrosion depth,and the eccentric model is most accurate for predicting the burst strength of corroded casing.The burst strength of the casing will be overestimated by more than one-third if the M-E interaction is neglected,so the coupling effect of wear and corrosion should be sufficiently considered in casing integrity evaluation.展开更多
Aqueous zinc-ion batteries are promising due to inherent safety,low cost,low toxicity,and high volumetric capacity.However,issues of dendrites and side reactions between zinc metal anode and the electrolyte need to be...Aqueous zinc-ion batteries are promising due to inherent safety,low cost,low toxicity,and high volumetric capacity.However,issues of dendrites and side reactions between zinc metal anode and the electrolyte need to be solved for extended storage and cycle life.Here,we proposed that an electrolyte additive with an intermediate chelation strength of zinc ion—strong enough to exclude water molecules from the zinc metal-electrolyte interface and not too strong to cause a significant energy barrier for zinc ion dissociation—can benefit the electrochemical stability by suppressing hydrogen evolution reaction,overpotential growth,and den-drite formation.Penta-sodium diethylene-triaminepentaacetic acid salt was selected for such a purpose.It has a suitable chelating ability in aqueous solutions to adjust solvation sheath and can be readily polarized under electrical loading conditions to further improve the passivation.Zn||Zn symmetric cells can be stably operated over 3500 h at 1 mA cm^(-2).Zn||NH4V4O10 full cells with the additive show great cycling stability with 84.6%capacity retention after 500 cycles at 1 A g^(-1).Since the additive not only reduces H2 evolution and corrosion but also modifies Zn2+diffusion and deposition,highlyreversible Zn electrodes can be achieved as verified by the experimental results.Our work offers a practical approach to the logical design of reliable electrolytes for high-performance aqueous batteries.展开更多
基金financially supported by National Natural Science foundation of China(Grant No.52104006)Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(Grant No.2020CX040202)。
文摘To address the challenges associated with difficult casing running,limited annular space,and poor cementing quality in the completion of ultra-deep wells,the extreme line casing offers an effective solution over conventional casings.However,due to its smaller size,the joint strength of extreme line casing is reduced,which may cause failure when running in the hole.To address this issue,this study focuses on the CST-ZTΦ139.7 mm×7.72 mm extreme line casing and employs the elastic-plastic mechanics to establish a comprehensive analysis of the casing joint,taking into account the influence of geometric and material nonlinearities.A finite element model is developed to analyze the forces and deformations of the extreme line casing joint under axial tension and external collapse load.The model investigates the stress distribution of each thread tooth subjected to various tensile forces and external pressures.Additionally,the tensile strength and crushing strength of the extreme line casing joint are determined through both analytical and experimental approaches.The findings reveal that,under axial tensile load,the bearing surface of each thread tooth experiences uneven stress,with relatively high equivalent stress at the root of each thread tooth.The end thread teeth are valuable spots for failure.It is observed that the critical fracture axial load of thread decreases linearly with the increase of thread tooth sequence.Under external pressure,the circumferential stress is highest at the small end of the external thread,leading to yield deformation.The tensile strength of the joint obtained from the finite element model exhibits a relative error of less than 7%compared to the analytical and experimental values,proving the reliability of the finite element model.The tensile strength of the joint is 3091.9 k N.Moreover,in terms of anti-collapse capability,the joints demonstrate higher resistance to collapse compared to the casing body,which is consistent with the test results where the pipe body experiences collapse and failure while the joints remain intact during the experiment.The failure load of the casing body under external collapse pressure is 87.4 MPa.The present study provides a basic understanding of the mechanical strengths of extreme line casing joint.
基金National Key R&D Program of China (2017YFC1310400), National Nature Science Foundation of China (U150222& 81501148)Shanghai Municipal Health and Family Planning Commission (2014ZYJB0002)+3 种基金Shanghai Health and Family Planni叩 Commission Clinical Research Project (20184Y0134)Program of Shanghai Academic Research Leader (17XD1403300)Shanghai Key Laboratory of Psychotic Disorders (13DZ2260500)Qihang Project of Shanghai Mental Health Center (2018-QH-02).
文摘Background Despite high relapse rate among methamphetamine (MA) abusers, there still have been little empirical data to date detecting the risk factors related to craving and relapse from the perspective of MA abusers. Therefore, the aim of this study was to use qualitative research methods exploring the strengths, weaknesses, opportunities and threat factors that could facilitate or impede individuals' abstinence in a real-life context from the perspectives of MA abusers. Aim To use qualitative research methods exploring the strengths, weaknesses, opportunities and threat factors relating to individuals' abstinence in a real-life context. Method Semistructured interviews were conducted with 32 MA abusers recruited in Shanghai guided by open-ended questions on narrating the real-life catalysts and inhibitors related to craving, initiation, relapse and abstinence. All data were transcribed verbatim and analysed using a strengths, weaknesses, opportunities and threats (SWOT) analysis. Results The results of the SWOT analysis revealed that contextual factors including peer influence, prevalence and availability of MA, familiar venue of MA use, discrimination, sexual behaviours, alcohol, emotional states and their attitudes towards smoking MA were important factors that contribute to reinitiation and relapse. Surveillance systems, antidrug social workers, vocational skills trainings, moving to another city and family responsibility might serve as counter measures targeti叩 those mentioned weaknesses and threats above. Conclusion This SWOT analysis highlights the complex nature of relapse. Comprehensive interventions strengtheni叩 coping skills such as virtual reality techniques are desperately needed to facilitate individuals1 sustained abstinence.
基金supported by the Japan Society for the Promotion of Science(JSPS)KAKENHI Grant Number JP22F22368。
文摘The development of clean and sustainable energy sources has received widespread interest in the past few decades due to the rolling energy demands while extenuating the rising tiers of greenhouse gases and environmental pollution.Due to their intermittent nature,these green and sustainable sources require appropriate energy storage systems.Amongst different energy storage technologies,electrochemical energy storage devices,particularly supercapacitors(SCs),have fascinated global attention for their utilization in electric vehicles,power supports,portable electronics,and many others application requiring electric energy devices for their operation.Thus,the growth of SCs in the commercial market has squeezed requirements,and further developments are obligatory for their effective industrialization.In the meantime,SCs also face technical complications and contests for their introduction in industrial settings because of their low energy density and high Levelized cost.The present study combines core strengths,weaknesses,opportunities,and threats(SWOT)analysis of SCs with new perspectives and recent ideas.The challenges and the future progressive prospects of SCs are also presented in detail.This review will afford consistent direction and new superhighways for the further development of SCs as standalone and complementary energy storage systems.
基金Project supported by the National Natural Science Foundation of China (Grant No 10774063)
文摘The dipole-length, dipole-velocity and dipole-acceleration absorption oscillator strengths for the 1s^22s-1s^2np (3 ≤ n ≤9) transitions of lithium-like systems from Z = 11 to 20 are calculated by using the energies and the multiconfiguration interaction wave functions obtained from a full core plus correlation method, in which relativistic and mass-polarization effects on the energy, as the first-order perturbation corrections, are included. The results of three forms are in good agreement with each other, and closely agree with the experimental data available in the literature. Based on the quantum defects obtained with quantum defect theory (QDT), the discrete oscillator strengths for the transitions from the ground state to highly excited states 1s^2np (n ≥ 10) and oscillator strength densities corresponding to the bound-free transitions are obtained for these ions.
基金Supported by the National Key Research and Development Program of China (Grant No. 2017YFA0402300)the National Natural Science Foundation of China (Grant Nos. 11774344 and 11474033)。
文摘The transition energies, E1 transitional oscillator strengths of the spin-allowed as well as the spin-forbidden and the corresponding transition rates, and complete M1, E2, M2 forbidden transition rates for 1s^(2), 1s2s, and 1s2p states of He I, are investigated using the multi-configuration Dirac–Hartree–Fock method. In the subsequent relativistic configuration interaction computations, the Breit interaction and the QED effect are considered as perturbation, separately. Our transition energies, oscillator strengths, and transition rates are in good agreement with the experimental and other theoretical results. As a result, the QED effect is not important for helium atoms, however, the effect of the Breit interaction plays a significant role in the transition energies, the oscillator strengths and transition rates.
基金Project supported by the Science Challenge Project(Grant No.TZ2016005)the National Key Research and Development Program of China(Grant Nos.2017YFA0403200 and 2017YFA0402300)the CAEP Foundation(Grant No.CX2019022)。
文摘The scattering matrices of e+N^(+)with J^(π)=1.5^(+)in discrete energy regions are calculated using the eigenchannel R-matrix method.We obtain good parameters of multichannel quantum defect theory(MQDT)that vary smoothly as the function of the energy resulting from the analytical continuation property of the scattering matrices.By employing the MQDT,all discrete energy levels for N could be calculated accurately without missing anyone.The MQDT parameters(i.e.,scattering matrices)can be calibrated with the available precise spectroscopy values.In this work,the optical oscillator strengths for the transition between the ground state and Rydberg series are obtained,which provide rich data for the diagnostic analysis of plasma.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11104170 and 51071032
文摘By performing density functional theory plus U calculations, we systematically study the structural, electronic, and magnetic properties of U02 under uniaxial tensile strain. The results show that the ideal tensile strengths along the [100], [110], and [111] directions are 93.6, 2Z7, and 16.4 GPa at strains of 0.44, 0.24, and 0.16, respectively. After electronic-structure investigation for tensile stain along the [001] direction, we find that the strong mixed ionic/covalent character of U-O bond is weakened by the tensile strain and there will occur an insulator to metal transition at strain over 0.30.
基金supported by National Key Research and Development Program of China(2019YFA0708302)National Natural Science Foundation of China(Grant No.52004296,and Grant No.52274016)+1 种基金the Foundation of State Key Laboratory of Petroleum Resources and Prospecting(PRP/DX-2206)Science Foundation of China University of Petroleum-Beijing(No.2462022YXZZ007,No.2462022BJRC012).
文摘Figuring out rock strength plays essential roles in the sub ground mining activities,such as oil and gas well drilling and hydraulic fracturing,coal mining,tunneling,and other civil engineering scenarios.To help understand the effects of the mineralogical composition on evaluating the rock strength,this research tries to establish indirect prediction models of rock strength by specific input mineral contents for common sedimentary rocks.Using rock samples collected from the outcrops in the Sichuan Basin,uniaxial compression tests have been conducted to sandstone,carbonate,and shale cores.Combining with statistical analysis,the experimental data prove it true that the mineralogical composition can be utilized to predict the rock strength under specific conditions but the effects of mineralogical composition on the rock strength highly depend on the rock lithologies.According to the statistical analysis results,the predicted values of rock strengths by the mineral contents can get high accuracies in sandstone and carbonate rocks while no evidences can be found in shale rocks.The best indicator for predicting rock strength should be the quartz content for the sandstone rocks and the dolomite content for the carbonate rocks.Especially,to improve the evaluation accuracy,the rock strengths of sandstones can be obtained by substituting the mineral contents of quartz and clays,and those of carbonates can be calculated by the mineral contents of dolomite and calcite.Noticeably,the research data point out a significant contrast of quartz content in evaluating the rock strength of the sandstone rocks and the carbonate rocks.Increasing quartz content helps increase the sandstone strength but decrease the carbonate strength.As for shale rocks,no relationship exists between the rock strength and the mineralogical composition(e.g.,the clay fractions).To provide more evidences,detailed discussion also provides the readers more glances into the framework of the rock matrix,which can be further studied in the future.These findings can help understand the effects of mineralogical composition on the rock strengths,explain the contrasts in the rock strength of the responses to the same mineral content(e.g.,the quartz content),and provide another indirect method for evaluating the rock strength of common sedimentary rocks.
基金Project supported by the National Natural Science Foundation of China (Grant No 10474089).
文摘The valence-shell excitations of krypton atom have been investigated by fast electron impact with an angle-resolved electron-energy-loss spectrometer. The generalized oscillator strengths for some higher mixed valence-shell excitations in 4d, 4f, 5p, 5d, 6s, 6p, 7s ←4p of krypton atom have been determined. Their profiles are discussed, and the generalized oscillator strengths for the electric monopole and quadrupole excitations in 5p ← 4p are compared with the calculations of Amusia et al. (Phys. Rev. A 67 022703 (2003)). The differences between the experimental results and theoretical calculations show that more studies are needed.
文摘The finite element analysis of mismatched welded jo ints with a 30°groove angle was performed to study the mechanical behavior of D MWJs (dissimilar metal welded joints). It is concluded that the distribution of stress triaxiality in the DMWJs is uneven, especially near the fusion lines. The degree of creep strength mismatch has remarkable effect on the distribution. Th e higher the level of mismatch is, the more uneven the distribution is and the e asier for premature failure to occur in the joint.
文摘In the paper, the finite element method (FEM) , engineering calculationmethod (ECM) and empirical fromular method (EFM) were used to calculatethe strengths of fillet joints in an Al-alloy vehicle. The results obtained withdifferent calculation methods were analysed, and then each method wasreviewed and assessed. FEM is accurate, but complicated, and its results haveno strength reserve; ECM and EFM are simple and convenient, butconservative.
文摘More and more non-native English speaking teachers teach with native English speaking teachers in Chinese context or other non-English speaking countries. It is worthwhile to evaluate their strengths and constraints. The current paper discusses their differences in term of linguistic teaching characteristics, social culture teaching characteristics and pedagogical teaching characteristics. It concludes that two groups of teachers can be successful language teachers with the equal chances on their own terms and can make up for their constraints by applying certain patterns of collaboration.
文摘In Orientalism,the author Edward W.Said stated that the Orient is negatively defined and serves to support the West'ssuperiority and strength.Citing a number of discourses and texts in the book,he broke the boundary between knowledge and poli-tics,and further examined how the knowledge that the Western colonial powers shaped about the Orient assisted to make a de-praved picture of the colonies,to justify their colonial ambition and suppression.Nevertheless,although Said attempted to explainthe selection of the oriental area in his discussion,a vast area of the Far East,such as China and Japan is excluded.Furthermore,he regarded the Orient as a completely passive colony,and negated any resistance from the Orient.
基金funded by the Bundesministerium für Bildung und Forschung(Nos.13FH6I06IA and 13FH6I08IA)。
文摘Due to the continuously increasing building and construction industry,sand has become one of the most questioned raw materials worldwide.However,the available amount of sand suitable for concrete production is orders of magnitude lower that the demand and consumption.Even though desert sand is sufficiently available,it is not usable for realizing stable concrete due to its surface shape.Against this background,the suitability of energy-efficient‘cold'dielectric barrier discharge plasma operated at atmospheric pressure for improving the properties of concrete produced from desert sand was investigated in this contribution.It is shown that such plasma treatment allows for a certain roughening and re-shaping of sand grains.As a result,the mass flow of treated sand is decreased due to an improved wedging of sand grains.This leads to a certain increase in compressive strength of concrete samples.Even though this increase is marginal,the suitability of the applied type of plasma for modification of the geometry and surface chemistry of sand grains was proven,showing its basic potential for the treatment and preconditioning of sand used for concrete,mortar or plastering.
基金financially supported by the National Natural Science Foundation of China (No.42172292)Taishan Scholars Project Special Funding,and Shandong Energy Group (No.SNKJ2022A01-R26)funded by the China Scholarship Council (CSC No.202006220274)。
文摘Understanding the anchorage performance of en-echelon joints under cyclic shear loading is crucial for optimizing support strategies in jointed rock masses.This study examines the anchorage effects on enechelon joints with various orientations using laboratory cyclic shear tests.By comparing unbolted and bolted en-echelon joints,we analyze shear zone damage,shear properties,dilatancy,energy absorption,and acoustic emission characteristics to evaluate anchoring effects across shear cycles and joint orientations.Results reveal that bolted en-echelon joints experience more severe shear zone damage after cycles,with bolt deformation correlating to shear zone width.Bolted en-echelon joints exhibit faster shear strength deterioration and higher cumulative strength loss compared to unbolted ones,with losses ranging from 20.04%to 72.76%.The compressibility of en-echelon joints reduces the anchoring effect during shear cycles,leading to lower shear strength of bolted en-echelon joints in later stages of shear cycles compared to unbolted ones.Bolts reinforce en-echelon joints more effectively at non-positive angles,with the best performance observed at 0°and-60°.Anchorage accelerates the transition from rolling friction to sliding friction in the shear zone,enhancing energy absorption,which is crucial for rock projects under dynamic shear loading.Additionally,rock bolts expedite the transition of the cumulative AE hits and cumulative AE energy curves from rapid to steady growth,indicating that strong bolt-rock interactions accelerate crack initiation,propagation,and energy release.
基金supported by the National Natural Science Foundation of China (Nos. 12465020, 12005802, and 12005109)the Jiangxi Provincial Natural Science Foundation (20202BAB211008)+3 种基金the Jiangxi Normal University (JXNU) Initial Research Foundation Grant to Doctor (12019504)the Young Talents Program under JXNU (12019870)the PhD Foundation of Chongqing Normal University (No. 23XLB010)the Science and Technology Research Program of Chongqing Municipal Education Commission (No. KJQN202300509)
文摘We report a comprehensive study on low-lying parity doublet states of ^(224)Rn by mixing both quadrupole-and octupoleshaped configurations in multireference covariant density functional theory,in which broken symmetries in configurations are restored using projection techniques.The low-lying energy spectrum is reasonably reproduced when the shape fluctuations in both the quadrupole and octupole shapes are considered.Electric octupole transition strength in ^(224)Rn is found to be B(E3;3_(1)^(-)→0_(1)^(+))=43 W.u.,comparable to that in ^(224)Ra,whose data are 42(3)W.u..Our results indicate that ^(224)Rn shares similar low-energy structure with ^(224)Ra despite the excitation energy of first 3^(−)state of the former nucleus is higher than that of the latter.This study suggests ^(224)Rn is a candidate for the search for permanent electric dipole moment.
基金The authors gratefully acknowledge financial support from the National Natural Science Foundation of China(52103090)the Natural Science Foundation of Guangdong Province(2022A1515011780)Autonomous deployment project of China National Key Laboratory of Materials for Integrated Circuits(NKLJC-Z2023-B03).
文摘The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high electrical and mechanical properties remains challenging,which heavily depends on the tube-tube interac-tions of CNTs.Herein,we develop a novel strategy based on metal-organic decomposition(MOD)to fabricate a flexible silver-carbon nanotube(Ag-CNT)film.The Ag particles are introduced in situ into the CNT film through annealing of MOD,leading to enhanced tube-tube interactions.As a result,the electrical conductivity of Ag-CNT film is up to 6.82×10^(5) S m^(-1),and the EMI shielding effectiveness of Ag-CNT film with a thickness of~7.8μm exceeds 66 dB in the ultra-broad frequency range(3-40 GHz).The tensile strength and Young’s modulus of Ag-CNT film increase from 30.09±3.14 to 76.06±6.20 MPa(~253%)and from 1.12±0.33 to 8.90±0.97 GPa(~795%),respectively.Moreover,the Ag-CNT film exhibits excellent near-field shield-ing performance,which can effectively block wireless transmission.This innovative approach provides an effective route to further apply macroscopic CNT assemblies to future portable and wearable electronic devices.
文摘Casing wear and casing corrosion are serious problems affecting casing integrity failure in deep and ultra-deep wells.This paper aims to predict the casing burst strength with considerations of both wear and corrosion.Firstly,the crescent wear shape is simplified into three categories according to common mathematical models.Then,based on the mechano-electrochemical(M-E)interaction,the prediction model of corrosion depth is built with worn depth as the initial condition,and the prediction models of burst strength of the worn casing and corroded casing are obtained.Secondly,the accuracy of different prediction models is validated by numerical simulation,and the main influence factors on casing strength are obtained.At last,the theoretical models are applied to an ultra-deep well in Northwest China,and the dangerous well sections caused by wear and corrosion are predicted,and the corrosion rate threshold to ensure the safety of casing is obtained.The results show that the existence of wear defects results in a stress concentration and enhanced M-E interaction on corrosion depth growth.The accuracy of different mathematical models is different:the slot ring model is most accurate for predicting corrosion depth,and the eccentric model is most accurate for predicting the burst strength of corroded casing.The burst strength of the casing will be overestimated by more than one-third if the M-E interaction is neglected,so the coupling effect of wear and corrosion should be sufficiently considered in casing integrity evaluation.
基金This work is financially supported by National Natural Science Foundation of China(NSFC-No.52173257 and 52372064).
文摘Aqueous zinc-ion batteries are promising due to inherent safety,low cost,low toxicity,and high volumetric capacity.However,issues of dendrites and side reactions between zinc metal anode and the electrolyte need to be solved for extended storage and cycle life.Here,we proposed that an electrolyte additive with an intermediate chelation strength of zinc ion—strong enough to exclude water molecules from the zinc metal-electrolyte interface and not too strong to cause a significant energy barrier for zinc ion dissociation—can benefit the electrochemical stability by suppressing hydrogen evolution reaction,overpotential growth,and den-drite formation.Penta-sodium diethylene-triaminepentaacetic acid salt was selected for such a purpose.It has a suitable chelating ability in aqueous solutions to adjust solvation sheath and can be readily polarized under electrical loading conditions to further improve the passivation.Zn||Zn symmetric cells can be stably operated over 3500 h at 1 mA cm^(-2).Zn||NH4V4O10 full cells with the additive show great cycling stability with 84.6%capacity retention after 500 cycles at 1 A g^(-1).Since the additive not only reduces H2 evolution and corrosion but also modifies Zn2+diffusion and deposition,highlyreversible Zn electrodes can be achieved as verified by the experimental results.Our work offers a practical approach to the logical design of reliable electrolytes for high-performance aqueous batteries.