The behavior of saturated aqueous Na Cl solutions under a constant external electric field（E） was studied by molecular dynamics（MD） simulation. Our dynamic MD simulations indicated that the irreversible nucleation...The behavior of saturated aqueous Na Cl solutions under a constant external electric field（E） was studied by molecular dynamics（MD） simulation. Our dynamic MD simulations indicated that the irreversible nucleation process towards crystallization is accelerated by a moderate E but retarded or even prohibited under a stronger E, which can be understood by the competition between self-diffusion and drift motion. The former increases with E, thereby accelerating the nucleation process, whereas the latter pulls oppositely charged ions apart under a stronger E, thereby decelerating nucleation.Additionally, our steady-state MD simulations indicated that a first-order phase transition occurs in saturated solutions at a certain threshold Ec. The magnitude of Ec increases with concentration because larger clusters form more easily when the solution is more concentrated and require a stronger E to dissociate.展开更多
In the case of three-layered(air-seawater-seabed)model,the analytical expressions of the static electric and static magnetic field produced by the static electric dipole located in seawater were derived by using the m...In the case of three-layered(air-seawater-seabed)model,the analytical expressions of the static electric and static magnetic field produced by the static electric dipole located in seawater were derived by using the mirror image theory.Combined with the distribution of the underwater electric potential measured in laboratory,an electric dipole model for physical scale of ship was established and the distribution characteristics of an actual ship' s corrosion related magnetic field were obtained.Based on established models,theoretical analysis and calculation were made to catch out the distribution characteristics of static magnetic field related with corrosion and anticorrosion,which can not be measured directly in seawater.The results show that the static magnetic field related with corrosion and anticorrosion is a kind of noteworthy obstacle signal for degaussed ships.展开更多
Using the second Green formula, the boundary problem of Laplace equation satisfied by potential function of static electric field is transformed to the problem of the boundary integral equation, and then a boundary in...Using the second Green formula, the boundary problem of Laplace equation satisfied by potential function of static electric field is transformed to the problem of the boundary integral equation, and then a boundary integral equation approach is established by partitioning boundary using linear boundary element.展开更多
基金Project supported by the National Basic Research Program of China(Grant No.2013CB932804)the National Natural Science Foundation of China(Grant Nos.91227115+1 种基金11274319and 11421063)
文摘The behavior of saturated aqueous Na Cl solutions under a constant external electric field（E） was studied by molecular dynamics（MD） simulation. Our dynamic MD simulations indicated that the irreversible nucleation process towards crystallization is accelerated by a moderate E but retarded or even prohibited under a stronger E, which can be understood by the competition between self-diffusion and drift motion. The former increases with E, thereby accelerating the nucleation process, whereas the latter pulls oppositely charged ions apart under a stronger E, thereby decelerating nucleation.Additionally, our steady-state MD simulations indicated that a first-order phase transition occurs in saturated solutions at a certain threshold Ec. The magnitude of Ec increases with concentration because larger clusters form more easily when the solution is more concentrated and require a stronger E to dissociate.
基金Sponsored by National Defense Pre-research Foundation(51444070105JB11)
文摘In the case of three-layered(air-seawater-seabed)model,the analytical expressions of the static electric and static magnetic field produced by the static electric dipole located in seawater were derived by using the mirror image theory.Combined with the distribution of the underwater electric potential measured in laboratory,an electric dipole model for physical scale of ship was established and the distribution characteristics of an actual ship' s corrosion related magnetic field were obtained.Based on established models,theoretical analysis and calculation were made to catch out the distribution characteristics of static magnetic field related with corrosion and anticorrosion,which can not be measured directly in seawater.The results show that the static magnetic field related with corrosion and anticorrosion is a kind of noteworthy obstacle signal for degaussed ships.
文摘Using the second Green formula, the boundary problem of Laplace equation satisfied by potential function of static electric field is transformed to the problem of the boundary integral equation, and then a boundary integral equation approach is established by partitioning boundary using linear boundary element.
