Perovskite solar cells(PSCs) have emerged as one of the most promising candidates for photovoltaic applications. Low-cost, low-temperature solution processes including coating and printing techniques makes PSCs promis...Perovskite solar cells(PSCs) have emerged as one of the most promising candidates for photovoltaic applications. Low-cost, low-temperature solution processes including coating and printing techniques makes PSCs promising for the greatly potential commercialization due to the scalability and compatibility with large-scale, roll-to-roll manufacturing processes. In this review, we focus on the solution deposition of charge transport layers and perovskite absorption layer in both mesoporous and planar structural PSC devices. Furthermore, the most recent design strategies via solution deposition are presented as well, which have been explored to enlarge the active area, enhance the crystallization and passivate the defects, leading to the performance improvement of PSC devices.展开更多
The development of high-performance non-fullerene acceptors with extended exciton diffusion lengths has positioned the sequential layer-by-layer(LBL)solution processing technique as a promising approach for fabricatin...The development of high-performance non-fullerene acceptors with extended exciton diffusion lengths has positioned the sequential layer-by-layer(LBL)solution processing technique as a promising approach for fabricating high-performance and large-area organic solar cells(OSCs).This method allows for the independent dissolution and deposition of donor and acceptor materials,enabling precise morphology control.In this review,we provide a comprehensive overview of the LBL processing technique,focusing on the morphology of the active layer.The swelling intercalation phase-separation(SIPS)model is introduced as the mainstream theory of morphology evolution,with a detailed discussion on vertical phase separation.We summarize recent strategies for morphology optimization.Additionally,we review the progress in LBL-based large-area device and module fabrication,as well as green processing approaches.Finally,we highlight current challenges and future prospects,paving the way for the commercialization of LBL-processed OSCs.展开更多
随着市场竞争愈发激烈、全球环境日益恶化以及公众环保意识的提高,绿色采购问题受到了广泛关注。现有研究绝大多数聚焦于考虑绿色准则的供应商选择问题,以实现可持续经营。然而,在综合考虑时间、价格和成本等因素的前提下,从适应性强的...随着市场竞争愈发激烈、全球环境日益恶化以及公众环保意识的提高,绿色采购问题受到了广泛关注。现有研究绝大多数聚焦于考虑绿色准则的供应商选择问题,以实现可持续经营。然而,在综合考虑时间、价格和成本等因素的前提下,从适应性强的供应商处获得适当的产品,对于企业来说更为可行和经济,即供应商选择和订单分配。为了解决上述关键问题,提出了一种模糊环境下的多准则群体决策方法。提出了一种基于理想解相似性偏好排序和层次分析法(technique for order of preference by similarity to ideal solution and analytic hierarchy process,TOPSIS-AHP)的模糊排序方法,该方法可根据企业战略灵活调整传统准则和绿色准则的权重。在双目标优化模型中引入供应商排名进行订货,在实现采购绩效最大化的同时,最大限度地降低采购成本。结果表明:所提方法能够有效评价供应商绩效,并优化候选供应商之间的订单分配。展开更多
In recent years JSC "Krastsvetmet" has successfully developed the production of chemically pure compounds of precious metals.Currently methods have been developed and facilities have been provided for indust...In recent years JSC "Krastsvetmet" has successfully developed the production of chemically pure compounds of precious metals.Currently methods have been developed and facilities have been provided for industrial production of the following platinum metals compounds:Rhodium(Ⅲ) chloride hydrate,rhodium(Ⅲ) chloride solution,rhodium(Ⅲ) nitrate solution,rhodium(Ⅲ) iodide,rhodium(Ⅲ) sulfate,hydrated rhodium(Ⅲ) oxide,ammonium hexachlororodiate,rhodium(Ⅲ) phosphate solution,rhodium electrolytes;Iridium(Ⅳ) chloride hydrate,iridium(Ⅲ) chloride hydrate,ammonium hexachloroiridate(Ⅳ),hexa chloriridium acid solution,hexachloriridium crystalline acid;Ruthenium(Ⅲ) chloride hydrate,ruthenium(Ⅳ) hydroxide chloride,ruthenium(Ⅳ) hydroxide chloride solution,ammonium hexachlororuthenate,ruthenium(Ⅲ) chloride solution,potassium,diaquaoctachloronitrido diruthenate.The quality of the production meets the requirements of Russian and foreign consumers.展开更多
基金Projects(51673214,51673218,61774170)supported by the National Natural Science Foundation of ChinaProject(2017YFA0206600)supported by the National Key Research and Development Program of China。
文摘Perovskite solar cells(PSCs) have emerged as one of the most promising candidates for photovoltaic applications. Low-cost, low-temperature solution processes including coating and printing techniques makes PSCs promising for the greatly potential commercialization due to the scalability and compatibility with large-scale, roll-to-roll manufacturing processes. In this review, we focus on the solution deposition of charge transport layers and perovskite absorption layer in both mesoporous and planar structural PSC devices. Furthermore, the most recent design strategies via solution deposition are presented as well, which have been explored to enlarge the active area, enhance the crystallization and passivate the defects, leading to the performance improvement of PSC devices.
基金Project(22408404)supported by the National Natural Science Foundation of China。
文摘The development of high-performance non-fullerene acceptors with extended exciton diffusion lengths has positioned the sequential layer-by-layer(LBL)solution processing technique as a promising approach for fabricating high-performance and large-area organic solar cells(OSCs).This method allows for the independent dissolution and deposition of donor and acceptor materials,enabling precise morphology control.In this review,we provide a comprehensive overview of the LBL processing technique,focusing on the morphology of the active layer.The swelling intercalation phase-separation(SIPS)model is introduced as the mainstream theory of morphology evolution,with a detailed discussion on vertical phase separation.We summarize recent strategies for morphology optimization.Additionally,we review the progress in LBL-based large-area device and module fabrication,as well as green processing approaches.Finally,we highlight current challenges and future prospects,paving the way for the commercialization of LBL-processed OSCs.
基金National Key Research and Development Program of China Under Grant(2020YFB1712203)。
文摘随着市场竞争愈发激烈、全球环境日益恶化以及公众环保意识的提高,绿色采购问题受到了广泛关注。现有研究绝大多数聚焦于考虑绿色准则的供应商选择问题,以实现可持续经营。然而,在综合考虑时间、价格和成本等因素的前提下,从适应性强的供应商处获得适当的产品,对于企业来说更为可行和经济,即供应商选择和订单分配。为了解决上述关键问题,提出了一种模糊环境下的多准则群体决策方法。提出了一种基于理想解相似性偏好排序和层次分析法(technique for order of preference by similarity to ideal solution and analytic hierarchy process,TOPSIS-AHP)的模糊排序方法,该方法可根据企业战略灵活调整传统准则和绿色准则的权重。在双目标优化模型中引入供应商排名进行订货,在实现采购绩效最大化的同时,最大限度地降低采购成本。结果表明:所提方法能够有效评价供应商绩效,并优化候选供应商之间的订单分配。
文摘In recent years JSC "Krastsvetmet" has successfully developed the production of chemically pure compounds of precious metals.Currently methods have been developed and facilities have been provided for industrial production of the following platinum metals compounds:Rhodium(Ⅲ) chloride hydrate,rhodium(Ⅲ) chloride solution,rhodium(Ⅲ) nitrate solution,rhodium(Ⅲ) iodide,rhodium(Ⅲ) sulfate,hydrated rhodium(Ⅲ) oxide,ammonium hexachlororodiate,rhodium(Ⅲ) phosphate solution,rhodium electrolytes;Iridium(Ⅳ) chloride hydrate,iridium(Ⅲ) chloride hydrate,ammonium hexachloroiridate(Ⅳ),hexa chloriridium acid solution,hexachloriridium crystalline acid;Ruthenium(Ⅲ) chloride hydrate,ruthenium(Ⅳ) hydroxide chloride,ruthenium(Ⅳ) hydroxide chloride solution,ammonium hexachlororuthenate,ruthenium(Ⅲ) chloride solution,potassium,diaquaoctachloronitrido diruthenate.The quality of the production meets the requirements of Russian and foreign consumers.
