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Silicon-based optoelectronic heterogeneous integration for optical interconnection 被引量:1
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作者 李乐良 李贵柯 +5 位作者 张钊 刘剑 吴南健 王开友 祁楠 刘力源 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期1-9,共9页
The performance of optical interconnection has improved dramatically in recent years.Silicon-based optoelectronic heterogeneous integration is the key enabler to achieve high performance optical interconnection,which ... The performance of optical interconnection has improved dramatically in recent years.Silicon-based optoelectronic heterogeneous integration is the key enabler to achieve high performance optical interconnection,which not only provides the optical gain which is absent from native Si substrates and enables complete photonic functionalities on chip,but also improves the system performance through advanced heterogeneous integrated packaging.This paper reviews recent progress of silicon-based optoelectronic heterogeneous integration in high performance optical interconnection.The research status,development trend and application of ultra-low loss optical waveguides,high-speed detectors,high-speed modulators,lasers and 2D,2.5D,3D and monolithic integration are focused on. 展开更多
关键词 silicon-based heterogeneous integration heterogeneous integrated materials heterogeneous integrated packaging optical interconnection
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Constructing high-toughness polyimide binder with robust polarity and ion-conductive mechanisms ensuring long-term operational stability of silicon-based anodes 被引量:1
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作者 Yongjun Kang Nanxi Dong +5 位作者 Fangzhou Liu Daolei Lin Bingxue Liu Guofeng Tian Shengli Qi Dezhen Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期580-591,I0014,共13页
Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utiliz... Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utilization as a lithium-ion anode.Herein,a functionalized high-toughness polyimide(PDMI) is synthesized by copolymerizing the 4,4'-Oxydiphthalic anhydride(ODPA) with 4,4'-oxydianiline(ODA),2,3-diaminobenzoic acid(DABA),and 1,3-bis(3-aminopropyl)-tetramethyl disiloxane(DMS).The combination of rigid benzene rings and flexible oxygen groups(-O-) in the PDMI molecular chain via a rigidness/softness coupling mechanism contributes to high toughness.The plentiful polar carboxyl(-COOH) groups establish robust bonding strength.Rapid ionic transport is achieved by incorporating the flexible siloxane segment(Si-O-Si),which imparts high molecular chain motility and augments free volume holes to facilitate lithium-ion transport(9.8 × 10^(-10) cm^(2) s^(-1) vs.16 × 10^(-10) cm^(2) s~(-1)).As expected,the SiO_x@PDMI-1.5 electrode delivers brilliant long-term cycle performance with a remarkable capacity retention of 85% over 500 cycles at 1.3 A g^(-1).The well-designed functionalized polyimide also significantly enhances the electrochemical properties of Si nanoparticles electrode.Meanwhile,the assembled SiO_x@PDMI-1.5/NCM811 full cell delivers a high retention of 80% after 100 cycles.The perspective of the binder design strategy based on polyimide modification delivers a novel path toward high-capacity electrodes for high-energy-density batteries. 展开更多
关键词 Polyimide binder High toughness Robust ionic transport silicon-based anodes Lithium-ion batteries
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Pyrolysis-Gas Chromatography/Mass Spectrometry for Microstructure and Pyrolysis Pathway of Polyester-Polyether Multiblock Copolymer
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作者 罗爱芹 叶玲 +2 位作者 傅若农 谢桂阳 王显伦 《Journal of Beijing Institute of Technology》 EI CAS 2001年第1期45-50,共6页
The composition and sequence distribution of monomeric units in polyester polyether multiblock copolymer were studied by pyrolysis? gas chromatography (PGC) and pyrolysis gas chromatography/mass spectrometry (PGC/M... The composition and sequence distribution of monomeric units in polyester polyether multiblock copolymer were studied by pyrolysis? gas chromatography (PGC) and pyrolysis gas chromatography/mass spectrometry (PGC/MS). PGC was applied to study the F t curve of the multiblock copolymer and PGC/MS was used to separate and identify the pyrolyzates. DTA experiment was used to study the decomposition temperature. The results show that the beginning point of elastomer’s decomposition was about 300?℃ and the decomposition temperature of most of the sample was 550?℃. Many pyrolyzates were produced because of the breaking of weak bonds in the sample. The possible microstructure was verified and the pyrolysis pathway of the copolymer was investigated. 展开更多
关键词 thermoplastic elastomer polyester polyether multiblock copolymer pyrolysis gas chromatography/mass spectrometry copolymer pyrolysis pathway MICROSTRUCTURE pyrolyzates
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Regulating the Solvation Structure of Li^(+) Enables Chemical Prelithiation of Silicon-Based Anodes Toward High-Energy Lithium-Ion Batteries 被引量:9
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作者 Wenjie He Hai Xu +5 位作者 Zhijie Chen Jiang Long Jing Zhang Jiangmin Jiang Hui Dou Xiaogang Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第7期293-305,共13页
The solvation structure of Li^(+) in chemical prelithiation reagent plays a key role in improving the low initial Coulombic efficiency(ICE) and poor cycle performance of silicon-based materials. Never theless, the che... The solvation structure of Li^(+) in chemical prelithiation reagent plays a key role in improving the low initial Coulombic efficiency(ICE) and poor cycle performance of silicon-based materials. Never theless, the chemical prelithiation agent is difficult to dope active Li^(+) in silicon-based anodes because of their low working voltage and sluggish Li^(+) diffusion rate. By selecting the lithium–arene complex reagent with 4-methylbiphenyl as an anion ligand and 2-methyltetrahydrofuran as a solvent, the as-prepared micro-sized Si O/C anode can achieve an ICE of nearly 100%. Interestingly, the best prelithium efficiency does not correspond to the lowest redox half-potential(E_(1/2)), and the prelithiation efficiency is determined by the specific influencing factors(E_(1/2), Li^(+) concentration, desolvation energy, and ion diffusion path). In addition, molecular dynamics simulations demonstrate that the ideal prelithiation efficiency can be achieved by choosing appropriate anion ligand and solvent to regulate the solvation structure of Li^(+). Furthermore, the positive effect of prelithiation on cycle performance has been verified by using an in-situ electrochemical dilatometry and solid electrolyte interphase film characterizations. 展开更多
关键词 Lithium-ion batteries silicon-based anodes Prelithiation Molecular dynamics simulations Solvation structure
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Novel Silica Gel Supported Polyether Ionic Liquids: Efficient Catalysts Applied in Transformation of Carbon Dioxide 被引量:1
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作者 Guo Liying Jin Xianchao +1 位作者 Wang Yirong Wang Haozhi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2018年第4期60-66,共7页
Three new catalysts based on the silica gel supported polyether ionic liquids(ILs), i.e., [HO-PECH-MIM]ClSi, [H2N-PECH-MIM]Cl-Si, and [HOOC-PECH-MIM]Cl-Si, were prepared, and their chemical structures were characteriz... Three new catalysts based on the silica gel supported polyether ionic liquids(ILs), i.e., [HO-PECH-MIM]ClSi, [H2N-PECH-MIM]Cl-Si, and [HOOC-PECH-MIM]Cl-Si, were prepared, and their chemical structures were characterized by infrared(IR) spectroscopy and nuclear magnetic resonance(NMR) spectroscopy. Thermogravimetric analyzer(TG), X-ray diffractometer(XRD) and scanning electron microscope(SEM) were used to evaluate their thermal stability,crystalline structure and apparent morphology, respectively. Surface areas of the prepared catalysts were calculated by the Brunauer-Emmett-Teller(BET) method. The catalytic reaction for the synthesis of propylene carbonate(PC) using CO_2 and propylene oxide(PO) in the presence of the prepared catalysts was studied. The influences of times of recycling and catalyst structure on catalytic performance were also investigated. The experimental results showed that the silica gel supported polyether ILs catalysts successfully prepared under mild condition could possess the advantages of high activity, excellent thermal stability, good selectivity and easy recycling, while the phase transition of the liquid polyether ILs catalysts was also achieved. When the reaction temperature was 90 °C, the CO_2 pressure was 2.0 MPa and the dosage of the catalyst was 2.5%, [HOOC-PECH-MIM]Cl-Si was found to have the best catalytic performance in the catalytic process, with the conversion rate reaching 100% and the selectivity equating to 98.2%. The conversion rate and selectivity still could reach more than 90% even after the catalyst was reused for 15 times. 展开更多
关键词 .polyether IONIC liquids SILICA GEL catalyst CO2
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Multifunctional silicon-based light emitting device in standard complementary metal oxide semiconductor technology 被引量:2
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作者 王伟 黄北举 +1 位作者 董赞 陈弘达 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第1期677-683,共7页
A three-terminal silicon-based light emitting device is proposed and fabricated in standard 0.35 μm complementary metal-oxide-semiconductor technology. This device is capable of versatile working modes: it can emit ... A three-terminal silicon-based light emitting device is proposed and fabricated in standard 0.35 μm complementary metal-oxide-semiconductor technology. This device is capable of versatile working modes: it can emit visible to near infra-red (NIR) light (the spectrum ranges from 500 nm to 1000 nm) in reverse bias avalanche breakdown mode with working voltage between 8.35 V-12 V and emit NIR light (the spectrum ranges from 900 nm to 1300 nm) in the forward injection mode with working voltage below 2 V. An apparent modulation effect on the light intensity from the polysilicon gate is observed in the forward injection mode. Furthermore, when the gate oxide is broken down, NIR light is emitted from the polysilicon/oxide/silicon structure. Optoelectronic characteristics of the device working in different modes are measured and compared. The mechanisms behind these different emissions are explored. 展开更多
关键词 optoelectronic integrated circuit complementary metal-oxide-semiconductor technology silicon-based light emitting device ELECTROLUMINESCENCE
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Micro-Mechanism of Silicon-Based Waveguide Surface Smoothing in Hydrogen Annealing 被引量:1
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作者 段倩倩 任馨宇 +5 位作者 菅傲群 张辉 冀健龙 张强 张文栋 桑胜波 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第12期110-114,共5页
The micro-mechanism of the silicon-based waveguide surface smoothing is investigated systematically to explore the effects of silicon-hydrogen bonds on high-temperature hydrogen annealing waveguides. The effect of sil... The micro-mechanism of the silicon-based waveguide surface smoothing is investigated systematically to explore the effects of silicon-hydrogen bonds on high-temperature hydrogen annealing waveguides. The effect of silicon- hydrogen bonds on the surface migration movement of silicon atoms and the waveguide surface topography are revealed. The micro-migration from an upper state to a lower state of silicon atoms is driven by silicon- hydrogen bonding, which is the key to ameliorate the rough surface morphology of the silicon-based waveguide. The process of hydrogen annealing is experimentally validated based on the simulated parameters. The surface roughness declines from 1.523nm to 0.461 nm. 展开更多
关键词 of on Micro-Mechanism of silicon-based Waveguide Surface Smoothing in Hydrogen Annealing in IS
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Design Technologies for Silicon-Based High-Efficiency RF Power Amplifiers:A Brief Overview 被引量:1
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作者 Ruili Wu Jerry Lopez +1 位作者 Yan Li Donald Y.C.Lie 《ZTE Communications》 2011年第3期28-35,共8页
This paper presents a brief overview of several promising design technologies for high efficiency silicon-based radio frequency (RF) power amplifiers (PAs) as well as the use of these technologies in mobile broadb... This paper presents a brief overview of several promising design technologies for high efficiency silicon-based radio frequency (RF) power amplifiers (PAs) as well as the use of these technologies in mobile broadband wireless communications. Four important aspects of PA design are addressed in this paper. First, we look at class-E PA design equations and provide an example of a class-E PA that achieves efficiency of 65-70% at 2.4 GHz. Then, we discuss state-of-the-art envelope tracking (ET) design for monolithic wideband RF mobile transmitter applications. A brief overview of Doherty PA design for the next-generation wireless handset applications is then given. Towards the end of the paper, we discuss an inherently broadband and highly efficient class-J PA design targeting future multi-band multi-standard wireless communication protocols. 展开更多
关键词 radio frequency power amplifier silicon-based power amplifier envelope tracking class-E amplifier broadband PA class-J Doherty power amplifier
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Alkylation of Isobutane and Isobutene in Acidic Polyether Ionic Liquids 被引量:2
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作者 Yu Fengli Gu Yulong +1 位作者 Liu Qichun Xie Congxia 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2019年第3期29-35,共7页
The Br?nsted-acidic polyether ionic liquids(ILs)with different polymerization degrees(n value)were prepared via the reaction of tetramethylguanidine and epoxy ethane,followed by successive reactions with 1,3-propane s... The Br?nsted-acidic polyether ionic liquids(ILs)with different polymerization degrees(n value)were prepared via the reaction of tetramethylguanidine and epoxy ethane,followed by successive reactions with 1,3-propane sultone and trifluoromethanesulfonic acid(TfOH).The prepared ILs were characterized by infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy,and their thermal stability was determined by thermal gravimetry.The synthesized polyether ILs coupled with TfOH were used to catalyze the alkylation reaction of isobutane and isobutene for the preparation of alkylate gasoline.The polyether ILs could improve the substrate dissolution and promote the separation of the catalyst from the products.The ideal IL(n=94)was determined.The optimized alkylation reaction conditions covered:a VTfOH/VIL ratio of 0.35,a reaction temperature of 40℃,a reaction time of 50 min,and a stirring speed of 800 r/min.The conversion of isobutene was 92.4%and the selectivity for the C8-product was 81.6%.Under optimal conditions,the catalyst life was determined and TfOH showed improved cyclic performance in the polyether ILs.After 8 operating cycles,the catalytic activity of the catalyst showed negligible decline. 展开更多
关键词 ALKYLATION ALKYLATE gasoline tri fluoromethanesulfonic acid polyether-based ionic liquid ISOBUTENE
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Low insertion loss silicon-based spatial light modulator with high reflective materials outside Fabry–Perot cavity
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作者 Li-Fei Tian Ying-Xin Kuang +1 位作者 Zhong-Chao Fan Zhi-Yong Li 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第10期376-380,共5页
The extinction ratio and insertion loss of spatial light modulator are subject to the material problem, thus limiting its applications. One reflection-type silicon-based spatial light modulator with high reflective ma... The extinction ratio and insertion loss of spatial light modulator are subject to the material problem, thus limiting its applications. One reflection-type silicon-based spatial light modulator with high reflective materials outside the Fabry-Perot cavity is demonstrated in this paper. The reflectivity values of the outside-cavity materials with different film layer numbers are simulated. The reflectivity values of 6-pair Ta2O5/SiO2 films at 1550 nm are experimentally verified to be as high as 99.9%. The surfaces of 6-pair Ta2O5/SiO2 films are smooth: their root-mean-square roughness values are as small as 0.53 nm. The insertion loss of the device at 1550 nm is only 1.2 dB. The high extinction ratio of the device at 1550 nm and 11 V is achieved to be 29.7 dB. The spatial light modulator has a high extinction ratio and low insertion loss for applications. 展开更多
关键词 spatial light modulator HIGH REFLECTIVE materials silicon-based FABRY-PEROT cavity
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High-performing silicon-based germanium Schottky photodetector with ITO transparent electrode
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作者 Zhiwei Huang Shaoying Ke +4 位作者 Jinrong Zhou Yimo Zhao Wei Huang Songyan Chen Cheng Li 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第3期447-453,共7页
A near-infrared germanium(Ge)Schottky photodetector(PD)with an ultrathin silicon(Si)barrier enhancement layer between the indium-doped tin oxide(ITO)electrode and Ge epilayer on Si or silicon-on-insulator(SOI)is propo... A near-infrared germanium(Ge)Schottky photodetector(PD)with an ultrathin silicon(Si)barrier enhancement layer between the indium-doped tin oxide(ITO)electrode and Ge epilayer on Si or silicon-on-insulator(SOI)is proposed and fabricated.The well-behaved ITO/Si cap/Ge Schottky junctions without intentional doping process for the Ge epilayer are formed on the Si and SOI substrates.The Si-and SOI-based ITO/Si cap/Ge Schottky PDs exhibit low dark current densities of 33 mA/cm2 and 44 mA/cm2,respectively.Benefited from the high transmissivity of ITO electrode and the reflectivity of SOI substrate,an optical responsivity of 0.19 A/W at 1550 nm wavelength is obtained for the SOI-based ITO/Si cap/Ge Schottky PD.These complementary metal–oxide–semiconductor(CMOS)compatible Si(or SOI)-based ITO/Si cap/Ge Schottky PDs are quite useful for detecting near-infrared wavelengths with high efficiency. 展开更多
关键词 silicon-based Schottky photodetector germanium epilayer indium-doped tin oxide
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Research Towards Terahertz Power Amplifiers in Silicon-Based Process
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作者 CHEN Jixin ZHOU Peigen +3 位作者 YU Jiayang LI Zekun LI Huanbo PENG Lin 《ZTE Communications》 2023年第2期88-94,共7页
In view of the existing design challenges for Terahertz(THz)power amplifiers(PAs),the common design methods and the efforts of the State Key Laboratory of Millimeter Wave,Southeast University,China in the development ... In view of the existing design challenges for Terahertz(THz)power amplifiers(PAs),the common design methods and the efforts of the State Key Laboratory of Millimeter Wave,Southeast University,China in the development of silicon-based THz PAs,mainly including silicon-based PAs with operating frequencies covering 100–300 GHz,are summarized in this paper.Particularly,we design an LC-balun-based two-stage differential cascode PA with a center frequency of 150 GHz and an output power of 14 dBm.Based on a Marchand balun,we report a 220 GHz three-stage differential cascode PA with a saturated output power of 9.5 dBm.To further increase the output power of THz PA,based on a four-way differential power combining technique,we report a 211–263 GHz dual-LC-tank-based broadband PA with a recorded 14.7 dBm Psat and 16.4 dB peak gain.All the above circuits are designed in a standard 130 nm silicon germanium(SiGe)BiCMOS process. 展开更多
关键词 power amplifier power combining SIGE silicon-based TERAHERTZ
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Studies on microdomain structure in segmented polyether polyurethaneureas by positron annihilation lifetime and small-angle X-ray scattering 被引量:1
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作者 YinChuan-Yuan GuQing-Chao 《Nuclear Science and Techniques》 SCIE CAS CSCD 1997年第4期221-224,共4页
Studiesonmicrodomainstructureinsegmentedpolyetherpolyurethaneureasbypositronannihilationlifetimeandsmalangle... StudiesonmicrodomainstructureinsegmentedpolyetherpolyurethaneureasbypositronannihilationlifetimeandsmalangleXrayscatering?.. 展开更多
关键词 聚醚聚氨酯-脲 微观区结构 X射线散射
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含能聚醚黏合剂的柔性链结构设计的研究进展
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作者 彭肖玥 王宇 +3 位作者 孙倩 王亚 李雅楠 郑文芳 《含能材料》 北大核心 2025年第2期198-211,共14页
含能聚醚黏合剂作为推进剂的骨架和基体,是促进推进剂的能量水平、力学性能、加工性能等不断改善的基础。然而,聚醚中的极性含能基团阻碍了分子链的运动,降低了高分子链的柔顺性,导致力学性能下降,制约了高能固体推进剂的发展。对含能... 含能聚醚黏合剂作为推进剂的骨架和基体,是促进推进剂的能量水平、力学性能、加工性能等不断改善的基础。然而,聚醚中的极性含能基团阻碍了分子链的运动,降低了高分子链的柔顺性,导致力学性能下降,制约了高能固体推进剂的发展。对含能聚醚进行共聚改性,引入柔性链段提高柔顺性是获得结构多样、性能可调聚醚的有效方法。本研究介绍了近年来含能聚醚引入不同类型的柔性链段,从主链柔性链段、侧链柔性链段两个角度展开综述,阐释其对含能聚醚黏合剂力学性能和加工性能的影响,并对含能聚醚黏合剂的柔性链结构设计研究进行了展望,为设计开发新型含能黏合剂提供方向。 展开更多
关键词 聚醚类黏合剂 高分子链 柔顺性 固体推进剂
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国产聚醚型消泡剂在天然气净化装置的应用及效果评价
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作者 卫博尧 王红梅 +2 位作者 任发俊 高春华 刘仁杰 《石油与天然气化工》 北大核心 2025年第1期31-37,共7页
目的研究国产消泡剂在天然气净化装置的适用性,解决靖边气田天然气净化装置使用进口聚醚改性有机硅型消泡剂KS-604导致生产运行成本较高的问题。方法从18种国产消泡剂中优选出聚醚型消泡剂A-604,通过对国产聚醚型消泡剂A-604与装置目前... 目的研究国产消泡剂在天然气净化装置的适用性,解决靖边气田天然气净化装置使用进口聚醚改性有机硅型消泡剂KS-604导致生产运行成本较高的问题。方法从18种国产消泡剂中优选出聚醚型消泡剂A-604,通过对国产聚醚型消泡剂A-604与装置目前使用的进口有机硅型消泡剂KS-604进行室内实验和现场应用试验评价,研究消泡剂A-604在现场装置的使用效果。结果国产消泡剂A-604和进口消泡剂KS-604的性能相当,消泡剂A-604在现场装置中留存时间更长,抑泡能力较强,但其在加量较低时的消泡效果比KS-604略差。将现场装置A-604消泡剂的加注方案调整为2 L/次后,拦液频次平均为每4天1次,最低为每7天1次。结论如果将进口消泡剂KS-604更换为国产消泡剂A-604,在消泡效果接近的前提下,单套天然气净化装置每月可节省费用约1.1万元,全厂每年可节省约132万元。消泡剂A-604可作为进口消泡剂KS-604的替代产品,能大大降低生产运行成本。 展开更多
关键词 天然气净化 醇胺法 聚醚型消泡剂 发泡 拦液 抑泡
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功能聚醚砜的合成及其用于膜的亲水改性研究
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作者 宋梦园 何春菊 《化工新型材料》 北大核心 2025年第2期72-76,共5页
以双酚S、2,2-二(3-氨基-4-羟苯基)-六氟丙烷、4,4-二羟基二苯砜为原料,通过Williamson法制备一种含氨基的聚醚砜共聚物,通过与异氰酸酯-磺丙基甜菜碱反应得到两性离子聚合物;将其与聚醚砜(PES)共混溶解,经非溶剂致相分离法制膜。得到... 以双酚S、2,2-二(3-氨基-4-羟苯基)-六氟丙烷、4,4-二羟基二苯砜为原料,通过Williamson法制备一种含氨基的聚醚砜共聚物,通过与异氰酸酯-磺丙基甜菜碱反应得到两性离子聚合物;将其与聚醚砜(PES)共混溶解,经非溶剂致相分离法制膜。得到的共混膜渗透性提升1.18倍,蛋白截留率保持95%以上,具备良好的抗污性和力学性能。 展开更多
关键词 聚醚砜 分离膜 两性离子 抗污
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聚醚嵌段超支化氨基硅氧烷的合成及应用研究
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作者 彭佳钰 王海峰 +1 位作者 钟磊 邢智童 《针织工业》 北大核心 2025年第3期41-45,共5页
以二乙烯三胺(EDTA)和自制的线性双端环氧聚醚改性硅氧烷(EPMS)为原料,通过亲核开环加成,制备出聚醚嵌段超支化氨基硅氧烷(HB-PAS),再通过碱催化扩链制备有机硅柔软剂。探讨反应条件对产物HB-PAS环氧基转化率以及黏度的影响,优化合成工... 以二乙烯三胺(EDTA)和自制的线性双端环氧聚醚改性硅氧烷(EPMS)为原料,通过亲核开环加成,制备出聚醚嵌段超支化氨基硅氧烷(HB-PAS),再通过碱催化扩链制备有机硅柔软剂。探讨反应条件对产物HB-PAS环氧基转化率以及黏度的影响,优化合成工艺,用红外光谱表征产物结构。结果表明:EPMS与EDTA摩尔比为1.0∶1.6,反应温度为70℃,反应6 h时,转化率达99.0%,产物黏度为3 500 mPa·s;质量比mHB-PAS∶mD4=1∶3,催化剂KOH用量0.2%,125℃反应6 h得到柔软剂,并将该柔软剂应用于棉针织物,用量为20 g/L,手感可提升1~2级,色变小,经10次洗涤后手感降低不明显。 展开更多
关键词 聚醚嵌段超支化氨基硅氧烷 碱催化扩链 棉针织物 柔软剂
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PI/MWCNT复合上浆剂改善CF/PEEK复合材料的力学和电磁屏蔽性能
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作者 何艺 杨雪勤 +7 位作者 任宏亮 阳泽濠 袁婷 范翊 蒋民强 刘勇 张辉 俞建勇 《东华大学学报(自然科学版)》 北大核心 2025年第1期103-112,共10页
碳纤维增强聚醚醚酮(CF/PEEK)复合材料正由单一力学结构材料向兼具电磁屏蔽性能的功能一体化材料发展。然而,碳纤维(CF)和聚醚醚酮(PEEK)界面结合差、电磁屏蔽填料在树脂基体中易团聚的问题限制了CF/PEEK复合材料的力学性能和电磁屏蔽... 碳纤维增强聚醚醚酮(CF/PEEK)复合材料正由单一力学结构材料向兼具电磁屏蔽性能的功能一体化材料发展。然而,碳纤维(CF)和聚醚醚酮(PEEK)界面结合差、电磁屏蔽填料在树脂基体中易团聚的问题限制了CF/PEEK复合材料的力学性能和电磁屏蔽性能。通过制备含醚酮结构的聚酰亚胺(PI)和多壁碳纳米管(MWCNT)的复合上浆剂,对CF表面改性,成功获得了力学与电磁屏蔽性能并优的CF/PEEK复合材料。研究发现,当复合上浆剂中MWCNT的质量分数为0.075%时,CF/PEEK复合材料的层间剪切强度(ILSS)、弯曲强度和弯曲模量分别为79 MPa、994 MPa和62 GPa,较未改性前分别提高38.6%、33.6%和17.0%。这得益于PI与PEEK之间的π-π相互作用,以及引入MWCNT提升CF表面粗糙度所带来的界面铆接效应。此外,改性后CF的电导率为180 S/cm,CF/PEEK复合材料在X波段的平均电磁屏蔽效能(EMI)达到42.6 dB,较未改性前分别提升59.3%和65.8%。这主要归因于CF和MWCNT构建的导电网络能够强反射电磁波并实现欧姆损耗。采用PI/MWCNT上浆剂处理CF表面,为开发高性能的CF/PEEK复合材料提供了简便有效的方法,具有广阔的应用前景。 展开更多
关键词 碳纤维复合材料 聚醚醚酮 界面改性 电磁屏蔽 力学性能
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聚醚多元醇的合成探究
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作者 郑伟平 朱忠朋 +3 位作者 陶志平 赵杰 伏朝林 贾丹丹 《石油炼制与化工》 CAS 北大核心 2025年第1期154-159,共6页
通过选用合适的进料方式,以氢氧化钾为催化剂,催化环氧单体和醇或酚发生聚合反应,可制备不饱和度低、相对分子质量分布较窄的聚醚多元醇(简称聚醚)。催化剂用量和反应温度较大程度上影响着反应的收率和产品的品质,因此控制合适的催化剂... 通过选用合适的进料方式,以氢氧化钾为催化剂,催化环氧单体和醇或酚发生聚合反应,可制备不饱和度低、相对分子质量分布较窄的聚醚多元醇(简称聚醚)。催化剂用量和反应温度较大程度上影响着反应的收率和产品的品质,因此控制合适的催化剂用量和反应温度是聚醚制备的关键。不同的酚和醇作为起始剂时,随着链长的增加,其反应活性逐渐降低,需较多的催化剂和较长的反应时间以实现高的反应收率。和环氧丙烷相比,环氧丁烷因位阻的增加,其反应活性有所降低,需较多的催化剂方可制备设定相对分子质量的聚醚产物。当环氧丙烷和环氧丁烷同时作为反应的环氧单体时,可通过调节二者的进料比例,共聚制备结构多变的聚醚产物。采用本方法制备的聚醚产物溴值低,相对分子质量分布宽度指数基本在1.10以下,且产物经后处理后,可使水质量分数保持在0.2%以下,钾离子质量分数在1μg/g以下,产品品质较高。 展开更多
关键词 聚醚多元醇 氢氧化钾 环氧丙烷 环氧丁烷
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RF detection of split-gate modes in Si-MOS quantum dots
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作者 Ning Chu Sheng-Kai Zhu +5 位作者 Ao-Ran Li Chu Wang Wei-Zhu Liao Gang Cao Hai-Ou Li Guo-Ping Guo 《Chinese Physics B》 2025年第4期296-302,共7页
Radio frequency(RF)reflectometry is an effective and sensitive technique for detecting charge signal in semiconductor quantum dots,and its measurement bandwidth can reach the MHz level.However,in accumulation mode dev... Radio frequency(RF)reflectometry is an effective and sensitive technique for detecting charge signal in semiconductor quantum dots,and its measurement bandwidth can reach the MHz level.However,in accumulation mode devices,the presence of parasitic capacitance makes RF reflectometry more difficult.The universal approach is relocating the ion implantation region approximately 10μm from the center of the single-electron transistor(SET)and optimizing the design of the accumulation gates.But,this method puts forward more stringent requirements for micro-nano fabrication processing.Here,we propose a split-gate structure that enables RF reflectometry when the ion-implanted region and the ohmic contact are farther from the SET center.In Si-MOS devices,we employ a split-gate structure to achieve RF detection,with the ion-implanted region located 150μm away from the center of the SET.Within an integration time of 140 nanoseconds,we achieved a readout fidelity exceeding 99.8%and a detection bandwidth of over 2 MHz.This is an alternative solution for micro-nano fabrication processing that cannot achieve ion implantation areas closer to the center of the chip,and is applicable to various silicon-based semiconductor systems. 展开更多
关键词 silicon-based quantum computing Si-MOS radio-frequency readout
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