Polypropylene was cracked thermally and catalytically in the presence of kaoline and silica alumina in a semi batch reactor in the temperature range 400℃～550℃ in order to obtain suitable liquid fuels.The dependenci...Polypropylene was cracked thermally and catalytically in the presence of kaoline and silica alumina in a semi batch reactor in the temperature range 400℃～550℃ in order to obtain suitable liquid fuels.The dependencies between process temperatures,types of catalyst,feed compositions and product yields of the obtained fuel fractions were found.It was observed that up to 450℃ thermal cracking temperature,the major product of pyrolysis was liquid oil and the major product at other higher temperatures(475℃～550℃) are viscous liquid or wax and the highest yield of pyrolysis product is 82.85% by weight at 500℃.Use of kaoline and silica alumina decreased the reaction time and increased the yield of liquid fraction.Again the major pyrolysis product in catalytic pyrolysis at all temperatures was low viscous liquid oil.Silica alumina was found better as compared to kaoline in liquid yield and in reducing the reaction temperature.The maximum oil yield using silica alumina and kaoline catalyst are 91% and 89.5% respectively.On the basis of the obtained results hypothetical continuous process of waste polypropylene plastics processing for engine fuel production can be presented.展开更多
Fly ash was used to prepare alumina and silica white, The 3 stages of the process are as follows: ammonium sulfate calcining, acid leaching and alkali dissolution. The optimum conditions for the experiments to determi...Fly ash was used to prepare alumina and silica white, The 3 stages of the process are as follows: ammonium sulfate calcining, acid leaching and alkali dissolution. The optimum conditions for the experiments to determine are as follows: molar ratio of (NH4)2SO4/Al2O3 is 6, the calcining time is 2h, he H2SO4 concentration is 20%, the leaching temperature is 80℃ and dissolution duration is 2h, the ratio of solution and solid reaction material is 6 for ammonium sulfate calcining and acid leaching stage, reaction time 30min, ratio of liquid to ore 5∶1, alkali concentration 45% and reaction temperature 95 ℃for the alkali dissolution stage. Under these conditions, the total leaching efficiencies of Al2O3 and SiO2 are 78.86% and 95%, respectively. The quality of the main products alumina and silica white can meet the national standards of GB/T24487-2009 and GB10517-89, respectively.展开更多
文摘Polypropylene was cracked thermally and catalytically in the presence of kaoline and silica alumina in a semi batch reactor in the temperature range 400℃～550℃ in order to obtain suitable liquid fuels.The dependencies between process temperatures,types of catalyst,feed compositions and product yields of the obtained fuel fractions were found.It was observed that up to 450℃ thermal cracking temperature,the major product of pyrolysis was liquid oil and the major product at other higher temperatures(475℃～550℃) are viscous liquid or wax and the highest yield of pyrolysis product is 82.85% by weight at 500℃.Use of kaoline and silica alumina decreased the reaction time and increased the yield of liquid fraction.Again the major pyrolysis product in catalytic pyrolysis at all temperatures was low viscous liquid oil.Silica alumina was found better as compared to kaoline in liquid yield and in reducing the reaction temperature.The maximum oil yield using silica alumina and kaoline catalyst are 91% and 89.5% respectively.On the basis of the obtained results hypothetical continuous process of waste polypropylene plastics processing for engine fuel production can be presented.
文摘Fly ash was used to prepare alumina and silica white, The 3 stages of the process are as follows: ammonium sulfate calcining, acid leaching and alkali dissolution. The optimum conditions for the experiments to determine are as follows: molar ratio of (NH4)2SO4/Al2O3 is 6, the calcining time is 2h, he H2SO4 concentration is 20%, the leaching temperature is 80℃ and dissolution duration is 2h, the ratio of solution and solid reaction material is 6 for ammonium sulfate calcining and acid leaching stage, reaction time 30min, ratio of liquid to ore 5∶1, alkali concentration 45% and reaction temperature 95 ℃for the alkali dissolution stage. Under these conditions, the total leaching efficiencies of Al2O3 and SiO2 are 78.86% and 95%, respectively. The quality of the main products alumina and silica white can meet the national standards of GB/T24487-2009 and GB10517-89, respectively.
