Nano-fibrous polyaniline was synthesized on stainless steel electrode in 0.5mol·L-1 H2SO4 solution by pulse galvanostatic method. The effects of synthetic conditions of pulse galvanostatic method on the electroac...Nano-fibrous polyaniline was synthesized on stainless steel electrode in 0.5mol·L-1 H2SO4 solution by pulse galvanostatic method. The effects of synthetic conditions of pulse galvanostatic method on the electroactivity of polyaniline were investigated. The results show that the electroactivity of polyaniline film strongly depends on the synthetic conditions, such as the ratio of “on time” to “off time”(ton/toff), frequency, monomer concentration, temperature and mean current density. Different electroactivities of polyaniline are caused by different morphologies of polyaniline. The nano-fibrous polyaniline has higher electroactivity than polyaniline with other morphologies. Under the following conditions: mean current density of pulse galvanostatic method 13mA·cm-2, ton/toff 1, frequency 200Hz, monomer concentration 0.3mol·L-1 and temperature 20℃, nano-fibrous polyaniline film with the highest electroactivity can be obtained.展开更多
This thesis puts forward a conjecture that, owing to some unknown special character of light, it is impossible to determine whether the speed of light is variable by the interference method. To verify the hypothesis ...This thesis puts forward a conjecture that, owing to some unknown special character of light, it is impossible to determine whether the speed of light is variable by the interference method. To verify the hypothesis of the invariance of light speed, a new method must be found to take accurate measurement of the infinitesimal change in the travelling time of light. The thesis suggests the adoption of high frequency laser pulse technology to carry out the measurement. On the basis of this idea a new discriminating experiment is proposed to test the hypothesis of the invariance of light speed. The thesis also makes some forecast of the future prospects of this experiment and of the future development of the theory of special relativity.展开更多
基金Project(50473022) supported by the National Natural Science Foundation project supported by the State Key Laboratoryof Chemo/Biosensing and Chemometrics of China
文摘Nano-fibrous polyaniline was synthesized on stainless steel electrode in 0.5mol·L-1 H2SO4 solution by pulse galvanostatic method. The effects of synthetic conditions of pulse galvanostatic method on the electroactivity of polyaniline were investigated. The results show that the electroactivity of polyaniline film strongly depends on the synthetic conditions, such as the ratio of “on time” to “off time”(ton/toff), frequency, monomer concentration, temperature and mean current density. Different electroactivities of polyaniline are caused by different morphologies of polyaniline. The nano-fibrous polyaniline has higher electroactivity than polyaniline with other morphologies. Under the following conditions: mean current density of pulse galvanostatic method 13mA·cm-2, ton/toff 1, frequency 200Hz, monomer concentration 0.3mol·L-1 and temperature 20℃, nano-fibrous polyaniline film with the highest electroactivity can be obtained.
文摘This thesis puts forward a conjecture that, owing to some unknown special character of light, it is impossible to determine whether the speed of light is variable by the interference method. To verify the hypothesis of the invariance of light speed, a new method must be found to take accurate measurement of the infinitesimal change in the travelling time of light. The thesis suggests the adoption of high frequency laser pulse technology to carry out the measurement. On the basis of this idea a new discriminating experiment is proposed to test the hypothesis of the invariance of light speed. The thesis also makes some forecast of the future prospects of this experiment and of the future development of the theory of special relativity.
