Synergic catalytic effect between active sites and supports greatly determines the catalytic activity for the aerobic oxidative desulfurization of fuel oils.In this work,Ni-doped Co-based bimetallic metal-organic fram...Synergic catalytic effect between active sites and supports greatly determines the catalytic activity for the aerobic oxidative desulfurization of fuel oils.In this work,Ni-doped Co-based bimetallic metal-organic framework(CoNi-MOF)is fabricated to disperse N-hydroxyphthalimide(NHPI),in which the whole catalyst provides plentiful synergic catalytic effect to improve the performance of oxidative desulfurization(ODS).As a bimetallic MOF,the second metal Ni doping results in the flower-like morphology and the modification of electronic properties,which ensure the exposure of NHPI and strengthen the synergistic effect of the overall catalyst.Compared with the monometallic Co-MOF and naked NHPI,the NHPI@CoNi-MOF triggers the efficient activation of molecular oxygen and improves the ODS performance without an initiator.The sulfur removal of dibenzothiophene-based model oil reaches 96.4%over the NHPI@CoNi-MOF catalyst in 8 h of reaction.Furthermore,the catalytic product of this aerobic ODS reaction is sulfone,which is adsorbed on the catalyst surface due to the difference in polarity.This work provides new insight and strategy for the design of a strong synergic catalytic effect between NHPI and bimetallic supports toward high-activity aerobic ODS materials.展开更多
An idea is presented about the development of a data processing and analysis system for ICF experiments, which is based on an object oriented framework. The design and preliminary implementation of the data processing...An idea is presented about the development of a data processing and analysis system for ICF experiments, which is based on an object oriented framework. The design and preliminary implementation of the data processing and analysis framework based on the ROOT system have been completed. Software for unfolding soft X-ray spectra has been developed to test the functions of this framework.展开更多
Tubular hydroforming has attracted increased attention in the vehicle industry recently. This paper covers a complete hydroforming process design for an instrum ent panel frame by finite element simulation using the e...Tubular hydroforming has attracted increased attention in the vehicle industry recently. This paper covers a complete hydroforming process design for an instrum ent panel frame by finite element simulation using the explicit code LS-DYNA. The manufacturing process for the instrument panel frame consists of tube pre-be nding and final hydroforming. To accomplish hydroforming process design successf ully, a thorough investigation of proper combination of process parameters such as internal hydraulic pressure and axial feeding is carried out by finite element simulation to predict the tube wall thickness and shape. An optimized process parameter combination is obtained and verified by the instrument panel frame hyd roforming experiment. The experiment shows that designed process parameters can be used in real production through FEA simulation, but tubular thinned amplitu de by FEA is less than that with the experiment.展开更多
A principle and method of constructing the digital acquisition system is presented in this work,which is convenient for the study on the theories and algorithms of digital nuclear signal processing.The hardware system...A principle and method of constructing the digital acquisition system is presented in this work,which is convenient for the study on the theories and algorithms of digital nuclear signal processing.The hardware system of the digital acquisition system consists of front-end controller,waveform digitizer and PC workstation,on which the software system has been developed based on Visual C++under Windows environment.The alterable-frequency sampling(AFS)algorithm and the alterable-frequency trapezoidal filter(AFTF)algorithm have also been studied in the real-time environment,along with a digital nuclear spectrum acquisition system being set up based on the new algorithms and theγ-ray spectra of 241Am being shown.A useful experimental platform could be provided by this work for the successive work such as the development of global digitized nuclear measurement system and the study of digital nuclear signal processing.展开更多
This paper aims at providing an effective modeling methods for more and more mobile business applications. First a high level Petri nets method-Xml nets is introduced, which combines the advantage of Petri nets and XM...This paper aims at providing an effective modeling methods for more and more mobile business applications. First a high level Petri nets method-Xml nets is introduced, which combines the advantage of Petri nets and XML. Petri nets have strict mathematics and intuitionistic diagram ex- pression way, rich system describing means and system behavior analytical technology, and the re- lated powerful supporting tools. XML, as an extensible markup language, is already a information description de facto standard. XML nets could be utilized to model both the controlling flow and the data flow of mobile business process effectively, which consequently enables the analysis and optimi- zation of the mobile business processes and could be utilized to simulate the execution of the mobile business process with the Petri nets tools to improve the system execution efficiency. In this paper, to demonstrate the modeling of the controlling flow and data flow of mobile business process, an in- strument repair business case is modeled with XML nets.展开更多
基金This work was financially supported by the National Natural Science Foundation of China(Nos.21978119,22202088)Key Research and Development Plan of Hainan Province(ZDYF2022SHFZ285)Jiangsu Funding Program for Excellent Postdoctoral Talent(2022ZB636)。
文摘Synergic catalytic effect between active sites and supports greatly determines the catalytic activity for the aerobic oxidative desulfurization of fuel oils.In this work,Ni-doped Co-based bimetallic metal-organic framework(CoNi-MOF)is fabricated to disperse N-hydroxyphthalimide(NHPI),in which the whole catalyst provides plentiful synergic catalytic effect to improve the performance of oxidative desulfurization(ODS).As a bimetallic MOF,the second metal Ni doping results in the flower-like morphology and the modification of electronic properties,which ensure the exposure of NHPI and strengthen the synergistic effect of the overall catalyst.Compared with the monometallic Co-MOF and naked NHPI,the NHPI@CoNi-MOF triggers the efficient activation of molecular oxygen and improves the ODS performance without an initiator.The sulfur removal of dibenzothiophene-based model oil reaches 96.4%over the NHPI@CoNi-MOF catalyst in 8 h of reaction.Furthermore,the catalytic product of this aerobic ODS reaction is sulfone,which is adsorbed on the catalyst surface due to the difference in polarity.This work provides new insight and strategy for the design of a strong synergic catalytic effect between NHPI and bimetallic supports toward high-activity aerobic ODS materials.
基金This project supported by the National High-Tech Research and Development Plan (863-804-3)
文摘An idea is presented about the development of a data processing and analysis system for ICF experiments, which is based on an object oriented framework. The design and preliminary implementation of the data processing and analysis framework based on the ROOT system have been completed. Software for unfolding soft X-ray spectra has been developed to test the functions of this framework.
文摘Tubular hydroforming has attracted increased attention in the vehicle industry recently. This paper covers a complete hydroforming process design for an instrum ent panel frame by finite element simulation using the explicit code LS-DYNA. The manufacturing process for the instrument panel frame consists of tube pre-be nding and final hydroforming. To accomplish hydroforming process design successf ully, a thorough investigation of proper combination of process parameters such as internal hydraulic pressure and axial feeding is carried out by finite element simulation to predict the tube wall thickness and shape. An optimized process parameter combination is obtained and verified by the instrument panel frame hyd roforming experiment. The experiment shows that designed process parameters can be used in real production through FEA simulation, but tubular thinned amplitu de by FEA is less than that with the experiment.
基金Supported by National Natural Science Foundation of China(NSFC)projects(No.1075111)
文摘A principle and method of constructing the digital acquisition system is presented in this work,which is convenient for the study on the theories and algorithms of digital nuclear signal processing.The hardware system of the digital acquisition system consists of front-end controller,waveform digitizer and PC workstation,on which the software system has been developed based on Visual C++under Windows environment.The alterable-frequency sampling(AFS)algorithm and the alterable-frequency trapezoidal filter(AFTF)algorithm have also been studied in the real-time environment,along with a digital nuclear spectrum acquisition system being set up based on the new algorithms and theγ-ray spectra of 241Am being shown.A useful experimental platform could be provided by this work for the successive work such as the development of global digitized nuclear measurement system and the study of digital nuclear signal processing.
基金Supported by the Beijing Natural Science Foundation(9133020)the National Natural Science Foundation of China(70972007)+1 种基金National Sciences Foundation Committee and General Administration of Civil Aviation of China(60672180)Beijing Municipal Natural Science Foundation(9102015)
文摘This paper aims at providing an effective modeling methods for more and more mobile business applications. First a high level Petri nets method-Xml nets is introduced, which combines the advantage of Petri nets and XML. Petri nets have strict mathematics and intuitionistic diagram ex- pression way, rich system describing means and system behavior analytical technology, and the re- lated powerful supporting tools. XML, as an extensible markup language, is already a information description de facto standard. XML nets could be utilized to model both the controlling flow and the data flow of mobile business process effectively, which consequently enables the analysis and optimi- zation of the mobile business processes and could be utilized to simulate the execution of the mobile business process with the Petri nets tools to improve the system execution efficiency. In this paper, to demonstrate the modeling of the controlling flow and data flow of mobile business process, an in- strument repair business case is modeled with XML nets.
