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First-principles study on the structure-property relationship of AlX and InX(X=N,P,As,Sb)
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作者 HE Zhihao DING Jiafu +1 位作者 WANG Yunjie SU Xin 《无机化学学报》 北大核心 2025年第5期1007-1019,共13页
This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materi... This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications. 展开更多
关键词 aluminium‑based semiconductor indium‑based semiconductor first principle electronic structure optical property
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Localization and tracking of multiple quadrotors with collision avoidance:Theory and experiment
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作者 Guang Yang Juntong Qi +4 位作者 Mingming Wang Yan Peng Chong Wu Yuan Ping Hailong Huang 《Defence Technology(防务技术)》 2025年第8期338-350,共13页
Multiple quadrotors target encirclement is widely used in the intelligent field,as it can effectively monitor and control target behavior.However,it faces the danger of collision,as well as difficulties in localizatio... Multiple quadrotors target encirclement is widely used in the intelligent field,as it can effectively monitor and control target behavior.However,it faces the danger of collision,as well as difficulties in localization and tracking.Therefore,we propose a complete target encirclement method.Firstly,based on Hooke's law,a collision avoidance controller is designed to maintain a safe flying distance among quadrotors.Then,based on the consensus theory,a formation tracking controller is designed to meet the requirements of formation transformation and encirclement tasks,and a stability proof based on Lyapunov was provided.Besides,the target detection is designed based on YOLOv5s,and the target location model is constructed based on the principle of pinhole projection and triangle similarity.Finally,we conducted experiments on the built platform,with 3 reconnaissance quadrotors detecting and localization 3 target vehicles and 7 hunter quadrotors tracking them.The results show that the minimum average error for localization targets with reconnaissance quadrotors can reach 0.1354 m,while the minimum average error for tracking with hunter quadrotors is only 0.2960 m.No quadrotors collision occurred in the whole formation transformation and tracking experiment.In addition,compared with the advanced methods,the proposed method has better performance. 展开更多
关键词 Multiple quadrotors Collision avoidance Target localization TRACKING Outdoor experiments
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Experimental and numerical study on external explosions of cylindrical versus spherical charges at tunnel entrance
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作者 Dan Luo Jinsheng Hu +4 位作者 Anbao Wang Xiao Yu Mengmeng Zhang Meili Yao Chun Li 《Defence Technology(防务技术)》 2025年第4期227-243,共17页
Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical cha... Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel. 展开更多
关键词 Cylindrical charges Tunnel blast wave Equivalent coefficient Empirical formula experiment and numerical simulation
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Dynamics and experiments of a tendon-actuated flexible robotic arm for capturing a floating target
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作者 Xin Xia Yunpeng Sun Jialiang Sun 《Defence Technology(防务技术)》 2025年第5期216-241,共26页
Reusable and flexible capturing of space debris is highly required in future aerospace technologies.A tendon-actuated flexible robotic arm is therefore proposed for capturing floating targets in this paper.Firstly,an ... Reusable and flexible capturing of space debris is highly required in future aerospace technologies.A tendon-actuated flexible robotic arm is therefore proposed for capturing floating targets in this paper.Firstly,an accurate dynamic model of the flexible robotic arm is established by using the absolute nodal coordinate formulation(ANCF)in the framework of the arbitrary Lagrangian-Eulerian(ALE)description and the natural coordinate formulation(NCF).The contact and self-contact dynamics of the flexible robotic arm when bending and grasping an object are considered via a fast contact detection approach.Then,the dynamic simulations of the flexible robotic arm for capturing floating targets are carried out to study the influence of the position,size,and mass of the target object on the grasping performance.Finally,a principle prototype of the tendon-actuated flexible robotic arm is manufactured to validate the dynamic model.The corresponding grasping experiments for objects of various shapes are also conducted to illustrate the excellent performance of the flexible robotic arm. 展开更多
关键词 Tendon-actuated flexible robotic arm Dynamic modeling Contact dynamics ALE-ANCF variable-length cable element Capturing experiments
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First‑principles study on electronic structure,optical and magnetic properties of rare earth elements X(X=Sc,Y,La,Ce,Eu)doped with two‑dimensional GaSe 被引量:3
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作者 QIU Shenhao XIAO Qingquan +1 位作者 TANG Huazhu XIE Quan 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第11期2250-2258,共9页
The electronic structure,magnetic,and optical properties of two-dimensional(2D)GaSe doped with rare earth elements X(X=Sc,Y,La,Ce,Eu)were calculated using the first-principles plane wave method based on den-sity funct... The electronic structure,magnetic,and optical properties of two-dimensional(2D)GaSe doped with rare earth elements X(X=Sc,Y,La,Ce,Eu)were calculated using the first-principles plane wave method based on den-sity functional theory.The results show that intrinsic 2D GaSe is a p-type nonmagnetic semiconductor with an indi-rect bandgap of 2.6611 eV.The spin-up and spin-down channels of Sc-,Y-,and La-doped 2D GaSe are symmetric,they are non-magnetic semiconductors.The magnetic moments of Ce-and Eu-doped 2D GaSe are 0.908μ_(B)and 7.163μ_(B),which are magnetic semiconductors.Impurity energy levels appear in both spin-up and spin-down chan-nels of Eu-doped 2D GaSe,which enhances the probability of electron transition.Compared with intrinsic 2D GaSe,the static dielectric constant of the doped 2D GaSe increases,and the polarization ability is strengthened.The ab-sorption spectrum of the doped 2D GaSe shifts in the low-energy direction,and the red-shift phenomenon occurs,which extends the absorption spectral range.The optical reflection coefficient of the doped 2D GaSe is improved in the low energy region,and the improvement of Eu-doped 2D GaSe is the most obvious. 展开更多
关键词 first principle two-dimensional GaSe electronic structure magnetic property optical property
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Redox mechanism of geobattery and related electrical signals using a novel real-time self-potential monitoring experimental platform 被引量:2
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作者 XIE Jing CUI Yi-an +4 位作者 ZHANG Li-juan GUO You-jun CHEN Hang ZHANG Peng-fei LIU Jian-xin 《Journal of Central South University》 CSCD 2024年第11期4155-4173,共19页
Controlled laboratory experiments are proved to be a valuable tool for investigating changes in underground physical properties and the related response of surface geophysical signals.The self-potential(SP)method is w... Controlled laboratory experiments are proved to be a valuable tool for investigating changes in underground physical properties and the related response of surface geophysical signals.The self-potential(SP)method is widely used in mineral resource exploration due to its direct correlation with underground electrochemical gradients.This paper presented the design and construction of an experimental platform based on a multi-channel SP monitoring system.The proposed platform was used to monitor the anodizing corrosion process of different metal blocks from a laboratory perspective,record the real-time SP signal generated by the redox reaction,as well as investigate the geobattery mechanism associated with the natural polarization process of metal mineral resources.The experimental results demonstrate that the constructed SP monitoring platform effectively captures time-series SP signals and provides direct laboratory evidence for the geobattery model.The measured SP data were quantitatively interpreted using the simulated annealing algorithm,and the inversion results closely match the real model.This finding highlights the potential of the SP method as a promising tool for determining the location and spatial distribution of underground polarizers.The study holds reference value for the exploration and exploitation of mineral resources in both terrestrial and marine environments. 展开更多
关键词 SELF-POTENTIAL real-time monitoring laboratory experiment geobattery mechanism quantitative inversion
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Principles of Shiology——Revealing the Basic Rules of Human Shiance 被引量:1
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作者 Liu Guangwei 《Journal of Northeast Agricultural University(English Edition)》 CAS 2024年第1期83-96,共14页
The objective principles of shiology are mainly reflected in three fields as food acquisition, eaters' health and shiance order. Most of the objective principles in the field of food acquisition have been revealed... The objective principles of shiology are mainly reflected in three fields as food acquisition, eaters' health and shiance order. Most of the objective principles in the field of food acquisition have been revealed by agronomy and foodstuff science. This research mainly focuses on 10 principles in the field of eaters' health and shiance order and in addition, there are also five lemmas that extend from the above principles. The 10 principles are the core theory of the shiology knowledge system, which play an important role in the objective principles revealed by human beings and constitute one of the basic principles of human civilization. Compared with the scientific principles of mathematics, physics, chemistry and economics, the principles of shiology have three characteristics as popularity, practicability and survivability. The principles of shiology in the field of eaters' health are all around us, and everyone can understand and master them. Using the principles of shiology can improve the healthy life span of 8 billion people. The principles of shiology in the field of shiance order is an important tool of social governance, which can reduce human social conflicts, reduce social involution, improve overall efficiency of social operation, and maintain the sustainable development of human beings. 展开更多
关键词 principle of shiology RULE shiance eater eating matter eatology
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Mechanical heterogeneity characterization of coal materials based on nano-indentation experiments
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作者 ZHANG Qi LI Xiang-chun +3 位作者 LI Biao MENG Jun-qing NIE Bai-sheng LU Wei-dong 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第9期3142-3155,共14页
To investigate the complex macro-mechanical properties of coal from a micro-mechanical perspective,we have conducted a series of micro-mechanical experiments on coal using a nano-indentation instrument.These experimen... To investigate the complex macro-mechanical properties of coal from a micro-mechanical perspective,we have conducted a series of micro-mechanical experiments on coal using a nano-indentation instrument.These experiments were conducted under both dynamic and static loading conditions,allowing us to gather the micro-mechanical parameters of coal for further analysis of its micro-mechanical heterogeneity using the box counting statistical method and the Weibull model.The research findings indicate that the load–displacement curves of the coal mass under the two different loading modes exhibit noticeable discreteness.This can be attributed to the stress concentration phenomenon caused by variations in the mechanical properties of the micro-units during the loading process of the coal mass.Consequently,there are significant fluctuations in the micro-mechanical parameters of the coal mass.Moreover,the mechanical heterogeneity of the coal at the nanoscale was confirmed based on the calculation results of the standard deviation coefficient and Weibull modulus of the coal body’s micromechanical parameters.These results reveal the influence of microstructural defects and minerals on the uniformity of the stress field distribution within the loaded coal body,as well as on the ductility characteristics of the micro-defect structure.Furthermore,there is a pronounced heterogeneity in the micromechanical parameters.Furthermore,we have established a relationship between the macro and micro elastic modulus of coal by applying the Mori-Tanaka homogenization method.This relationship holds great significance for revealing the micro-mechanical failure mechanism of coal. 展开更多
关键词 nano-indentation experiment MICROMECHANICS heterogeneity characterization COAL
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Optimal Order-of-Addition Experiments under a Prior Constraint
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作者 ZHANG Yunzhi ZHANG Wenchao +1 位作者 WANG Xiaodi CHEN Xueping 《应用概率统计》 CSCD 北大核心 2024年第6期957-974,共18页
The order-of-addition experiments are widely used in many fields,including food and industrial production,but the relative research under prior constraints is limited.The purpose of this paper is to select an optimal ... The order-of-addition experiments are widely used in many fields,including food and industrial production,but the relative research under prior constraints is limited.The purpose of this paper is to select an optimal sequence under the restriction that component i is added before component j,while it is unachievable to compare all sequences when the number of components m is large.To achieve this,a constrained PWO model is first provided,and then the D-optimal designs for order-of addition experiments with minimal-points via the modified threshold accepting algorithm is established.The effectiveness of the proposed method is demonstrated through a job scheduling problem with a prior constraint for teaching cases. 展开更多
关键词 design of experiment orthogonal array threshold acceptance algorithm teaching cases
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Ballistic limit velocity of small caliber projectiles against SS400 steel plates:Live fire experiments and empirical models
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作者 Jong-Hwan Kim Seungwon Baik +1 位作者 Jirui Fu Joon-Hyuk Park 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第11期22-34,共13页
This study presents the ballistic limit velocity of small caliber projectiles against SS400 steel plate derived from live-fire ballistic experiments. Four different small caliber projectiles were tested against SS400 ... This study presents the ballistic limit velocity of small caliber projectiles against SS400 steel plate derived from live-fire ballistic experiments. Four different small caliber projectiles were tested against SS400 steel plates of 9 mm, 10 mm, and 12 mm thicknesses. The ballistic limit velocity was calculated using two standard methods, MIL-STD-662F and NIJ-STD-0101.06, and additionally using a support vector machine algorithm. The results show a linear relationship between the plate thickness and ballistic limit velocity. Further, the relative penetration performance among five different small caliber projectiles was analyzed using the Penetration Performance Ratio(PPR) introduced in this study, which suggests the potential of PPR to predict the ballistic limit velocity of other untested materials and/or different projectiles. 展开更多
关键词 Live fire ballistic experiment SS400 Ballistic limit velocity Small caliber projectile
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Marine Predator Algorithm-based Sliding Mode Control of a Novel Motion Simulator for High Column Sloshing Experiments
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作者 DU Zun-feng CHEN Xiang-yu +2 位作者 BAI Hao ZHU Hai-ming HAN Mu-xuan 《船舶力学》 EI CSCD 北大核心 2024年第12期1835-1848,共14页
Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Slidi... Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Sliding Mode Controller(MPA-SMC)are proposed for such sloshing experiments.The simulator consists of a Stewart platform and a steel framework.The Stewart platform is located at the column's center of gravity(CoG)and supported by the steel framework.The platform's hydraulic servo system is controlled by a sliding mode controller with parameters optimized by MPA to improve robustness and precision.A numerical sloshing experiment is conducted using the proposed device and controller.The results show that the novel motion simulator has lower torque during the column sloshes,and the proposed controller performs better than a well-tuned PID controller in terms of target tracking precision and anti-interference capability. 展开更多
关键词 regeneration column sloshing experiment motion simulator Stewart platform sliding mode control marine predator algorithm
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公共图书馆数字体验区的沉浸式体验:分析框架及用户测试 被引量:2
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作者 陈则谦 张天雄 赵蕊 《图书情报知识》 北大核心 2025年第2期94-104,166,共12页
[目的/意义]为用户提供沉浸式体验是公共图书馆数字体验区建设的方向和目标,认识和优化沉浸式体验是完善数字体验区建设,引领公共图书馆高质量发展的重要路径。[研究设计/方法]基于沉浸理论、用户体验理论和数字体验区的特点,构建由包... [目的/意义]为用户提供沉浸式体验是公共图书馆数字体验区建设的方向和目标,认识和优化沉浸式体验是完善数字体验区建设,引领公共图书馆高质量发展的重要路径。[研究设计/方法]基于沉浸理论、用户体验理论和数字体验区的特点,构建由包裹性、交互性、叙事性和平衡性构成的沉浸式体验分析框架,结合用户体验地图对公共图书馆数字体验区的沉浸式体验进行用户测试。[结论/发现]公共图书馆数字体验区沉浸式体验的总体效果一般,在交互性、叙事性和包裹性上表现一般,平衡性较差。空间规划不合理、数字设备不可及、体验项目不完善是影响体验效果的主要因素。[创新/价值]构建了适合公共图书馆数字体验区沉浸式体验的分析框架,为提升“新型数字阅读体验型”“数字阅读+纸质阅览体验型”和“趣味娱乐体验型”数字体验区的沉浸式体验效果提供参考,助力公共图书馆数字体验区建设实践。 展开更多
关键词 公共图书馆 数字体验区 沉浸式体验 用户体验地图
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论违约救济的填平原则——以《民法典》第584条为中心 被引量:5
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作者 王利明 《政法论丛》 北大核心 2025年第1期38-53,共16页
填平原则是违约救济的基本原则,该原则的正当性体现为维护矫正正义、保护交易预期、救济受害人的损失。填平原则包括积极功能和消极功能两方面,就积极功能而言,该原则确立了实际损失赔偿与可得利益损失赔偿可以并存。在适用填平原则时,... 填平原则是违约救济的基本原则,该原则的正当性体现为维护矫正正义、保护交易预期、救济受害人的损失。填平原则包括积极功能和消极功能两方面,就积极功能而言,该原则确立了实际损失赔偿与可得利益损失赔偿可以并存。在适用填平原则时,要明确实际损失与可得利益损失并存的具体情形,填平原则的消极功能有利于合理限制违约损害赔偿的范围,妥当平衡双方当事人的利益。填平原则的适用范围不限于法定损害赔偿,可扩张适用于合同司法终止后的违约责任承担、获利返还责任、违约金调整、定金责任与损害赔偿的并用等情形。 展开更多
关键词 违约救济 填平原则 衡平原则 预防违约原则 效率违约
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修改《监察法》的原理、原则与建言 被引量:2
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作者 吴建雄 邝山子 《河南社会科学》 北大核心 2025年第1期37-45,共9页
与时俱进修改《监察法》,蕴含着具有“发生学”意义的政理、哲理和法理。其政理为“保持自我革命引领社会革命高度自觉”,其哲理为“党风廉政建设和反腐败斗争永远在路上”,其法理为“以良法引领推进腐败治理能力现代化”。修改《监察... 与时俱进修改《监察法》,蕴含着具有“发生学”意义的政理、哲理和法理。其政理为“保持自我革命引领社会革命高度自觉”,其哲理为“党风廉政建设和反腐败斗争永远在路上”,其法理为“以良法引领推进腐败治理能力现代化”。修改《监察法》的基本原则,应坚持以政治为统领、以人民为本位、以问题为导向、以系统为理路。新修《监察法》充分吸收了学术界研究成果和实务部门探索出的成功经验,体现了惩治腐败与保障人权相结合、程序公正与实体公正并重的法治原则,增强了监察全覆盖的有效性和反腐败工作的实效性。其进一步完善可通过未来修改《监察法实施条例》的方式,从党的领导、纪监一体、监司衔接、行贿惩治等方面入手。 展开更多
关键词 修改监察法 基本原理 基本原则 思路建言
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数字试验测试验证标准体系 被引量:1
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作者 陶飞 马昕 +31 位作者 张辰源 易航 刘蔚然 魏宇鹏 邹孝付 王子同 任羿 陶岚 葛军 丁露 卓兰 韩丽 弓志强 谭永华 郄永军 周文 李建双 杨春霞 许鸿杰 蔺文杰 刘广 孙波 李海旭 阎德劲 李少伟 罗谦 王敬贤 罗英 尚政国 刘志新 易贤 张文丰 《计算机集成制造系统》 北大核心 2025年第1期1-19,共19页
数字试验测试验证(Digital Experiment,Testing,and Validation,D-ETV)是利用“数力”和“智力”更好地了解产品或系统基本属性和性能特征的方法,是实现高质高效研制运维的重要支撑手段。然而,在物理试验测试验证(Physical Experiment,T... 数字试验测试验证(Digital Experiment,Testing,and Validation,D-ETV)是利用“数力”和“智力”更好地了解产品或系统基本属性和性能特征的方法,是实现高质高效研制运维的重要支撑手段。然而,在物理试验测试验证(Physical Experiment,Testing,and Validation,P-ETV)向D-ETV演化的过程中,因缺乏基础共性标准参考,导致不同人员对D-ETV的理解与认识存在差异;因缺乏关键技术标准参考,导致D-ETV实现难;因缺乏通用支撑、安全、行业应用等标准参考,导致D-ETV实施难。针对上述问题,首先从D-ETV有何用、如何用、何处用3个角度对D-ETV标准需求进行分析。在作者团队前期提出的D-ETV通用流程“D”模型及关键技术基础上,进一步建立并完善“析-定-建-测-评-融”D-ETV理论体系。面向航空航天、工程机械、船舶、电子信息、汽车等领域的国家重大需求,与相关研究院所和企业共同尝试探索建立一套D-ETV标准体系,包括基础共性、关键技术、通用支撑、安全和行业应用5类标准。期望相关工作为D-ETV理论研究、标准研制、行业应用提供参考,助力我国试验测试验证向数字化、智能化、服务化方向发展,进而为我国装备高质量发展提供支撑。 展开更多
关键词 数字试验测试验证 标准体系 数字试验 数字测试 数字验证 数字鉴定
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重塑全球化共识:基于中国道路的静态与动态比较优势理论分析 被引量:1
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作者 余宇新 张瑾 《上海交通大学学报(哲学社会科学版)》 北大核心 2025年第1期92-106,共15页
针对贫富差距扩大与全球经济供需结构失衡的问题,本文通过梳理全球化共识的演变历程,融合了静态与动态比较优势理论,重新解构全球化红利的分配逻辑以适应技术革新的现实背景,提出“共享繁荣,共谋发展”的新全球化共识框架。这一共识强... 针对贫富差距扩大与全球经济供需结构失衡的问题,本文通过梳理全球化共识的演变历程,融合了静态与动态比较优势理论,重新解构全球化红利的分配逻辑以适应技术革新的现实背景,提出“共享繁荣,共谋发展”的新全球化共识框架。这一共识强调市场导向与尊重国家自主选择权的合作模式,旨在达成国际合作的最大公约数,进而推动全球化向深度与广度拓展。本研究对于应对“逆全球化”趋势,缓解国际经济秩序的动荡,提供了理论支撑与实践指导。 展开更多
关键词 华盛顿共识 全球化共识 静态比较优势原理 动态比较优势原理 全球化红利
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甲烷在钠基蒙脱土吸附的第一性原理研究 被引量:1
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作者 方志杰 李博 +4 位作者 宋昌辉 刘美玲 何秋芝 刘翔 莫曼 《原子与分子物理学报》 CAS 北大核心 2025年第2期8-14,共7页
随着经济的发展,能源需求日益增加,为了弥补国内少油缺气短板,页岩气的开发成为近期新能源的热点,探索页岩气储存规律是页岩气能源开发的关键所在.本文采用密度泛函理论的第一性原理方法,计算甲烷(CH_(4))在钠基蒙脱土表面和层间的吸附... 随着经济的发展,能源需求日益增加,为了弥补国内少油缺气短板,页岩气的开发成为近期新能源的热点,探索页岩气储存规律是页岩气能源开发的关键所在.本文采用密度泛函理论的第一性原理方法,计算甲烷(CH_(4))在钠基蒙脱土表面和层间的吸附能,对比吸附前后的态密度和物理结构以及差分电荷密度.结果表明:钠基蒙脱土表面吸附中,甲烷最佳选择是桥位,吸附能为-0.08eV,被吸附后甲烷的键长和键角变化率均小于0.96%.层间吸附中,伴随着甲烷吸附量增加,纳基蒙脱土体积向c轴方向线性增加,a、b轴方向则变化不大.总态密度随着吸附量的增加,总能级数量也增加,甲烷分子的分波态密度峰向低能级移动.本文的研究成果,从原子角度分析了甲烷在蒙脱石表面以及层间的吸附能力,为解释页岩气在页岩储存规律提供理论依据. 展开更多
关键词 钠基蒙脱土 第一性原理 甲烷 吸附 态密度
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掺杂元素X(B、Al、Sn、Co)对IDB-X/Diamond界面结合性能的影响
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作者 简小刚 姚文山 +4 位作者 张毅 梁晓伟 胡吉博 陈哲 陈茂林 《金刚石与磨料磨具工程》 北大核心 2025年第1期37-45,共9页
基于量子力学第一性原理,建立了IDB-B/Diamond、IDB-Al/Diamond、IDB-Sn/Diamond和IDB-Co/Diamond 4种膜基界面模型,计算了膜基界面结合能、差分电荷密度和布居数,以探究孕镶金刚石钻头(impregnated diamond bits,IDB)基体中的常用元素X... 基于量子力学第一性原理,建立了IDB-B/Diamond、IDB-Al/Diamond、IDB-Sn/Diamond和IDB-Co/Diamond 4种膜基界面模型,计算了膜基界面结合能、差分电荷密度和布居数,以探究孕镶金刚石钻头(impregnated diamond bits,IDB)基体中的常用元素X(X=B、Al、Sn、Co)对IDB-X/Diamond膜基结合强度的影响机制。计算结果表明:膜基界面结合能大小为W_(ad-B)>W_(ad-Al)>W_(ad-Co)>W_(ad-Sn);B、Al是增强膜基结合强度的有益元素,因为B、Al原子的电荷主要转移到掺杂位点附近的C1~C3原子,其与C1~C3原子的键合作用强;Sn、Co会削弱膜基结合强度,这是由于Sn、Co原子与C1~C3原子的键合作用弱,同时膜基界面间的其他C原子因俘获电荷而相斥。压痕对比的实验结果与仿真结论相符。 展开更多
关键词 第一性原理 金刚石涂层 膜基结合 电荷转移 布居数 压痕实验
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基于认知负荷理论的计算机组成原理实验教学设计与应用 被引量:1
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作者 杨磊 司国东 +3 位作者 王春桃 黄沛杰 肖克辉 杜治国 《实验室研究与探索》 北大核心 2025年第1期177-181,共5页
计算机组成原理实验教学能提高学生系统设计及应用创新能力,但因其实验原理抽象、知识点多,实验平台复杂等特点也让学生在实验过程中产生较高的认知负荷。为解决高认知负荷对实验教学造成的负面影响,基于认知负荷理论对实验进行教学设计... 计算机组成原理实验教学能提高学生系统设计及应用创新能力,但因其实验原理抽象、知识点多,实验平台复杂等特点也让学生在实验过程中产生较高的认知负荷。为解决高认知负荷对实验教学造成的负面影响,基于认知负荷理论对实验进行教学设计,分析学生学习需要因材施教控制学生内部认知负荷,优化实验教材设计及呈现方式降低学生外部认知负荷,激发学生学习兴趣以提高学生相关认知负荷,提升实验教学效果。教学实践表明,新型教学设计有效降低学生实验过程中的认知负荷总量,计算机系统设计及创新能力得到较高的提升。此方法也可为其他实验课程教学改革提供参考。 展开更多
关键词 计算机组成原理 认知负荷理论 实验教学 成效研究
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碳排放权交易能否促进企业节能减排——基于碳排放权交易试点政策的一项准自然实验 被引量:1
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作者 杜兴强 张心舒 +2 位作者 谢裕慧 曾泉 章永奎 《管理科学学报》 北大核心 2025年第7期22-38,共17页
本研究基于碳排放权交易试点政策、构建了一项准自然实验,检验了宏观层面的碳排放权交易对微观企业节能减排的影响.基于2010年-2017年中国上市公司的节能减排数据和多时点双重差分模型,本研究发现参与碳排放权交易试点的企业的节能减排... 本研究基于碳排放权交易试点政策、构建了一项准自然实验,检验了宏观层面的碳排放权交易对微观企业节能减排的影响.基于2010年-2017年中国上市公司的节能减排数据和多时点双重差分模型,本研究发现参与碳排放权交易试点的企业的节能减排绩效显著更高,表明碳排放权交易机制有助于企业的节能减排.进一步,CEO的海外经历强化了碳排放权交易机制与企业节能减排绩效之间的正向关系.此外,碳排放权交易机制对企业节能减排的促进作用在污染行业和市场竞争程度较高的行业中更为突出,碳排放权交易机制对企业的绿色创新和产业链的环保协作均具有显著的促进作用,且碳排放权交易机制能够抑制公司层面的碳排放.本研究的发现可以为碳排放权交易机制的治理作用提供重要参考. 展开更多
关键词 碳排放权交易 企业节能减排 CEO海外经历 准自然实验 多时点双重差分模型
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