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Effects of Nano-Aluminium on The Combustion of A PolyNIMMO-Based Propellant
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作者 Clive Woodley Peter Henning 《火炸药学报》 EI CAS CSCD 北大核心 2014年第6期7-11,共5页
Propellants containing micro-aluminium particles have been shown to produce faster burn rates than conventional gun propellants.However,they are also more abrasive than conventional propellants.Nano-material propellan... Propellants containing micro-aluminium particles have been shown to produce faster burn rates than conventional gun propellants.However,they are also more abrasive than conventional propellants.Nano-material propellants have been reported to give similar benefits to micron-material propellants but without the disadvantage of increased abrasion.Tests were conducted to compare the burn rates,ignitability and wear rates of a propellant loaded with 0% aluminium,15% micro-aluminium and 15%nano-aluminium.Closed vessel tests showed a burn rate increase of 39% in the range 30-250 MPa,and 70% at low pressure(50-100MPa)for the nano-aluminium propellant compared with the baseline propellant.The micro-aluminium propellant showed only a 10%increase in the burn rate compared with the standard propellant.The ignition delay for the nano-aluminium propellant was slightly shorter than that of the baseline propellant.Substantially increased wear rates were measured for the micro-aluminium propellant.The nano-aluminium propellant showed reduced wear rates compared with the micro-aluminium propellant but these were still substantially greater than those for the baseline propellant. 展开更多
关键词 physical chemistry closed vessel burn rate nano-aluminium wear and erosion poly(nitratomethyl methyl oxetane) base propellant
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APNIMMO/RDX光固化发射药热分解性能及燃烧性能
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作者 李曼曼 徐明辉 +3 位作者 郭志罡 岳春晖 王琼林 杨伟涛 《含能材料》 北大核心 2025年第4期347-354,共8页
为探究新型含能光固化黏结剂端丙烯酸酯基聚3⁃硝酸酯甲基⁃3⁃甲基氧杂环丁烷(APNIMMO)对RDX基光固化发射药热分解性能和燃烧性能的影响,设计并利用3D打印制备了一种高能APNIMMO/RDX发射药样品,采用差示扫描量热仪(DSC)和热分析红外气质... 为探究新型含能光固化黏结剂端丙烯酸酯基聚3⁃硝酸酯甲基⁃3⁃甲基氧杂环丁烷(APNIMMO)对RDX基光固化发射药热分解性能和燃烧性能的影响,设计并利用3D打印制备了一种高能APNIMMO/RDX发射药样品,采用差示扫描量热仪(DSC)和热分析红外气质联用仪(TG⁃DSC⁃FTIR⁃GC)研究了APNIMMO/RDX光固化发射药的热分解过程和相关分解动力学参数,并通过密闭爆发器研究了APNIMMO/RDX光固化发射药的燃烧性能。结果表明:APNIMMO/RDX光固化发射药的热失重分为两个主要阶段,热失重和气体产物逸出主要集中在第Ⅰ阶段(158.9~234.3℃),此阶段APNIMMO/RDX的热分解起始于APNIMMO的分解放热,并促进RDX的熔融分解,导致RDX分解提前,这也导致了APNIMMO/RDX的临界爆炸温度(Tpe)要低于纯RDX;第Ⅱ阶段(234.3℃至测试结束温度)表现为既无放热也无吸热的“热中性”状态,这一阶段主要是APNIMMO侧链硝酸酯基完全分解后主链的缓慢分解。燃烧性能结果表明APNIMMO/RDX发射药燃速系数较低,压力指数偏高,中止燃烧试验样品表面存在大量孔穴,分析认为在APNIMMO/RDX发射药体系中,由于RDX含量较多,且在高压下RDX的燃速比APNIMMO黏结剂要大,两者间燃速的差异导致燃烧产生的热量和压力沿着形成的孔穴深入整个发射药内部,该过程受压力影响较大,因此压力指数偏高。 展开更多
关键词 端丙烯酸酯基聚3⁃硝酸酯甲基⁃3⁃甲基氧杂环丁烷(APNIMMO) 光固化黏结剂 发射药 热分解性能 燃烧性能
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