Biomass conversion offers an efficient approach to alleviate the energy and environmental issues.Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has attracted tremendous attention in the latest few years for ...Biomass conversion offers an efficient approach to alleviate the energy and environmental issues.Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has attracted tremendous attention in the latest few years for the mild synthesis conditions and high conversion efficiency to obtain 2,5-furan dicarboxylic acid(FDCA),but there still remain problems such as limited yield,short cycle life,and ambiguous reaction mechanism.Despite many reviews highlighting a variety of electrocatalysts for electrochemical oxidation of HMF,a detailed discussion of the structural modulation of catalyst and the underlying catalytic mechanism is still lacking.We herein provide a comprehensive summary of the recent development of electrochemical oxidation of HMF to FDCA,particularly focusing on the mechanism studies as well as the advanced strategies developed to regulate the structure and optimize the performance of the electrocatalysts,including heterointerface construction,defect engineering,single-atom engineering,and in situ reconstruction.Experimental characterization techniques and theoretical calculation methods for mechanism and active site studies are elaborated,and challenges and future directions of electrochemical oxidation of HMF are also prospected.This review will provide guidance for designing advanced catalysts and deepening the understanding of the reaction mechanism beneath electrochemical oxidation of HMF to FDCA.展开更多
Emulsifier-free poly（methyl methacrylate-styrene） [P（MMA-St）] nanospheres with an average particle size of 100 nm were synthesized in an isopropyl alcoholwater medium by a solvothermal method. Then, through radica...Emulsifier-free poly（methyl methacrylate-styrene） [P（MMA-St）] nanospheres with an average particle size of 100 nm were synthesized in an isopropyl alcoholwater medium by a solvothermal method. Then, through radical graft copolymerization of thermo-sensitive mono- mer N-isopropylacrylamide （NIPAm） and hydrophilic monomer acrylic acid （AA） onto the surface of P（MMA- St） nanospheres at 80 ℃, a series of thermo-sensitive polymer nanospheres, named SD-SEAL with different lower critical solution temperatures （LCST）, were prepared by adjusting the mole ratio of NIPAm to AA. The products were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, thermogravimetric analysis, particle size distribution, and specific surface area analysis. The temperature-sensitive behavior was studied by light transmittance tests, while the sealing performance was investigated by pressure transmission tests with Lungmachi Formation shales. The experimental results showed that the synthesized nanoparticles are sensitive to temperature and had apparent LCST values which increased with an increase in hydrophilic monomer AA. When the temperature was higher than its LCST value, SD- SEAL played a dual role of physical plugging and chemical inhibition, slowed down pressure transmission, and reduced shale permeability remarkably. The plugged layer of shale was changed to being hydrophobic, which greatly improved the shale stability展开更多
March is a right party time for friends to get together to enjoy the smell of early spring. Moreover, people would like to take off the thick winter coat to showcase their colorful attitude towards the warm spring sun...March is a right party time for friends to get together to enjoy the smell of early spring. Moreover, people would like to take off the thick winter coat to showcase their colorful attitude towards the warm spring sunshine. Here, an annual fashion feast in Beijing not only could provide you a visual inspiration of trend, but also would tell you what’s the most "in" factors in the coming season.展开更多
The main intent of this study is to investigate the accuracy of short-duration traffic counts conducted during winter months. The investigation is based on 11-year sample data collected using permanent traffic counter...The main intent of this study is to investigate the accuracy of short-duration traffic counts conducted during winter months. The investigation is based on 11-year sample data collected using permanent traffic counters at various locations in Alberta, Canada. Four types of road sites： commuter, regional commuter, rural long-distance, and recreational sites are studied. The sample data consti- tute six different durations of counts （12-, 24-, 48-, 72-, 96-h, and 1 week） taken during summer and winter months. The coefficient of variation （CV） is used as the relative measure of deviation for counts of different dura- tions to measure the accuracy of short-period traffic counts. The study results indicate that 48-h count seems to be the most cost-effective counting interval during both summer and winter months. It is also found that the lowest values of CV result for counts taken at commuter sites, and the highest values are observed for recreational sites. Frequent changes in temperature and other weather events cause significant variation in traffic volume, which results in an increase in CV values for counts taken during winter months. The application of an adjustment factor to remove the effect of cold and snow from short-period counts is also included in this study. Introduced adjustment factors can reduce the values of CV for all counts taken during winter months. The findings of this study can lead highway agencies to improve the cost-effectiveness of their short- period traffic counting programs.展开更多
基金National Natural Science Foundation of China(22272150,22302177)Major Program of Zhejiang Provincial Natural Science Foundation of China(LD22B030002)+2 种基金Zhejiang Provincial Ten Thousand Talent Program(2021R51009)Public Technology Application Project of Jinhua City(2022-4-067)Self Designed Scientific Research of Zhejiang Normal University(2021ZS0604)。
文摘Biomass conversion offers an efficient approach to alleviate the energy and environmental issues.Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has attracted tremendous attention in the latest few years for the mild synthesis conditions and high conversion efficiency to obtain 2,5-furan dicarboxylic acid(FDCA),but there still remain problems such as limited yield,short cycle life,and ambiguous reaction mechanism.Despite many reviews highlighting a variety of electrocatalysts for electrochemical oxidation of HMF,a detailed discussion of the structural modulation of catalyst and the underlying catalytic mechanism is still lacking.We herein provide a comprehensive summary of the recent development of electrochemical oxidation of HMF to FDCA,particularly focusing on the mechanism studies as well as the advanced strategies developed to regulate the structure and optimize the performance of the electrocatalysts,including heterointerface construction,defect engineering,single-atom engineering,and in situ reconstruction.Experimental characterization techniques and theoretical calculation methods for mechanism and active site studies are elaborated,and challenges and future directions of electrochemical oxidation of HMF are also prospected.This review will provide guidance for designing advanced catalysts and deepening the understanding of the reaction mechanism beneath electrochemical oxidation of HMF to FDCA.
基金financial support from the National Science Foundation of China (Nos. 51374233, 51474235)the Postdoctoral Innovative Project Foundation of Shandong Province (No. 201602027)+2 种基金the Qingdao Postdoctoral Applied Research Project (No. 2015242)the Fundamental Research Funds for the Central Universities (No. 15CX06021A)the Graduate Student Innovation Project from China University of Petroleum (East China) (No. YCX2015011)
文摘Emulsifier-free poly（methyl methacrylate-styrene） [P（MMA-St）] nanospheres with an average particle size of 100 nm were synthesized in an isopropyl alcoholwater medium by a solvothermal method. Then, through radical graft copolymerization of thermo-sensitive mono- mer N-isopropylacrylamide （NIPAm） and hydrophilic monomer acrylic acid （AA） onto the surface of P（MMA- St） nanospheres at 80 ℃, a series of thermo-sensitive polymer nanospheres, named SD-SEAL with different lower critical solution temperatures （LCST）, were prepared by adjusting the mole ratio of NIPAm to AA. The products were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, thermogravimetric analysis, particle size distribution, and specific surface area analysis. The temperature-sensitive behavior was studied by light transmittance tests, while the sealing performance was investigated by pressure transmission tests with Lungmachi Formation shales. The experimental results showed that the synthesized nanoparticles are sensitive to temperature and had apparent LCST values which increased with an increase in hydrophilic monomer AA. When the temperature was higher than its LCST value, SD- SEAL played a dual role of physical plugging and chemical inhibition, slowed down pressure transmission, and reduced shale permeability remarkably. The plugged layer of shale was changed to being hydrophobic, which greatly improved the shale stability
文摘March is a right party time for friends to get together to enjoy the smell of early spring. Moreover, people would like to take off the thick winter coat to showcase their colorful attitude towards the warm spring sunshine. Here, an annual fashion feast in Beijing not only could provide you a visual inspiration of trend, but also would tell you what’s the most "in" factors in the coming season.
文摘The main intent of this study is to investigate the accuracy of short-duration traffic counts conducted during winter months. The investigation is based on 11-year sample data collected using permanent traffic counters at various locations in Alberta, Canada. Four types of road sites： commuter, regional commuter, rural long-distance, and recreational sites are studied. The sample data consti- tute six different durations of counts （12-, 24-, 48-, 72-, 96-h, and 1 week） taken during summer and winter months. The coefficient of variation （CV） is used as the relative measure of deviation for counts of different dura- tions to measure the accuracy of short-period traffic counts. The study results indicate that 48-h count seems to be the most cost-effective counting interval during both summer and winter months. It is also found that the lowest values of CV result for counts taken at commuter sites, and the highest values are observed for recreational sites. Frequent changes in temperature and other weather events cause significant variation in traffic volume, which results in an increase in CV values for counts taken during winter months. The application of an adjustment factor to remove the effect of cold and snow from short-period counts is also included in this study. Introduced adjustment factors can reduce the values of CV for all counts taken during winter months. The findings of this study can lead highway agencies to improve the cost-effectiveness of their short- period traffic counting programs.
