In order to study the structure transition during calcination, nano-titania powders prepared by hydrolyzing precipitation approach and calcined at 300, 400, 500, 600 and 700 ℃ were characterized by XRD, TEM and elect...In order to study the structure transition during calcination, nano-titania powders prepared by hydrolyzing precipitation approach and calcined at 300, 400, 500, 600 and 700 ℃ were characterized by XRD, TEM and electron diffraction(ED), respectively. The results show that titania powders calcined below 500 ℃ are almost composed of anatase, rutile appears below 500 ℃ and its ratio increases gradually with increase of calcin temperature; nano-titania particles are smaller than 40 nm mostly and the dispersion is related to calcining temperature; the inter-planar distances of nano-anatase single crystalline change gradually when calcing temperature increases to 500 ℃; so do that of nano-rutile single crystalline when calcining temperature charges from 600 to 700 ℃. The conclusions can be drawn that the temperature of transformation from anatase to rutile is below 500 ℃ and the process carries on gradually. Both inter-planar distances and the structure of nano-titania transform gradually with increasing calcing temperature.展开更多
为准确模拟桥址随机车流荷载,提出基于可变元胞与跟驰理论的元胞自动机(cellular automata,CA)模型。首先,重新定义元胞构成,提出以车辆为核心的动态可变元胞,并将精确的轴间距和轴重信息融入车辆元胞,实现车辆荷载的精确模拟;然后,引...为准确模拟桥址随机车流荷载,提出基于可变元胞与跟驰理论的元胞自动机(cellular automata,CA)模型。首先,重新定义元胞构成,提出以车辆为核心的动态可变元胞,并将精确的轴间距和轴重信息融入车辆元胞,实现车辆荷载的精确模拟;然后,引入跟驰理论,提出基于跟驰理论的状态演化规则,推导每辆车的专有加速度,实现车辆微观交互的模拟;最后,提出基于实测动态称重系统(weigh in motion,WIM)数据的发车规则,依据WIM数据,重构任意时段的实际车队,并建立基于车头时距的发车规则,重现车辆通过WIM时的运动状态。基于所提出的发车规则和动态演化规则,实现车辆从进入道路到驶离道路全过程时空位置的准确模拟,结合融入精确轴载的车辆元胞,实现随机车流荷载的模拟。基于实测WIM数据验证所提模型的可行性和先进性。结果表明:可变元胞可以精确模拟车辆荷载;提出的状态演化规则可以根据不同车辆的运动状态计算得到每辆车的专属加速度,准确模拟每辆车在自由行驶和跟驰行驶时的不同运动状态;新发车规则可以重构任意时段的实测车队,结合新状态演化规则,可以实现桥址任意时段随机车流的模拟。结合精细化车辆荷载模拟和合理的车流模拟,可实现桥址随机车流荷载模拟。展开更多
文摘In order to study the structure transition during calcination, nano-titania powders prepared by hydrolyzing precipitation approach and calcined at 300, 400, 500, 600 and 700 ℃ were characterized by XRD, TEM and electron diffraction(ED), respectively. The results show that titania powders calcined below 500 ℃ are almost composed of anatase, rutile appears below 500 ℃ and its ratio increases gradually with increase of calcin temperature; nano-titania particles are smaller than 40 nm mostly and the dispersion is related to calcining temperature; the inter-planar distances of nano-anatase single crystalline change gradually when calcing temperature increases to 500 ℃; so do that of nano-rutile single crystalline when calcining temperature charges from 600 to 700 ℃. The conclusions can be drawn that the temperature of transformation from anatase to rutile is below 500 ℃ and the process carries on gradually. Both inter-planar distances and the structure of nano-titania transform gradually with increasing calcing temperature.
文摘为准确模拟桥址随机车流荷载,提出基于可变元胞与跟驰理论的元胞自动机(cellular automata,CA)模型。首先,重新定义元胞构成,提出以车辆为核心的动态可变元胞,并将精确的轴间距和轴重信息融入车辆元胞,实现车辆荷载的精确模拟;然后,引入跟驰理论,提出基于跟驰理论的状态演化规则,推导每辆车的专有加速度,实现车辆微观交互的模拟;最后,提出基于实测动态称重系统(weigh in motion,WIM)数据的发车规则,依据WIM数据,重构任意时段的实际车队,并建立基于车头时距的发车规则,重现车辆通过WIM时的运动状态。基于所提出的发车规则和动态演化规则,实现车辆从进入道路到驶离道路全过程时空位置的准确模拟,结合融入精确轴载的车辆元胞,实现随机车流荷载的模拟。基于实测WIM数据验证所提模型的可行性和先进性。结果表明:可变元胞可以精确模拟车辆荷载;提出的状态演化规则可以根据不同车辆的运动状态计算得到每辆车的专属加速度,准确模拟每辆车在自由行驶和跟驰行驶时的不同运动状态;新发车规则可以重构任意时段的实测车队,结合新状态演化规则,可以实现桥址任意时段随机车流的模拟。结合精细化车辆荷载模拟和合理的车流模拟,可实现桥址随机车流荷载模拟。
