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A series of iridium(Ⅲ)complexes with fluorophenyl isoquinoline ligand and low-efficiency roll-off properties:A density functional theory study
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作者 QIN Zhengkun PAN Zicong +2 位作者 TIAN Hui ZHANG Wanyi SONG Mingxing 《无机化学学报》 北大核心 2025年第6期1235-1244,共10页
We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic ligh... We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic lightemitting diode(OLED)materials.By utilizing electronic structure,frontier molecular orbitals,minimum single-line absorption,triplet excited states,and emission spectral data derived from the density functional theory,the usefulness of these Ir(Ⅲ)complexes,including(piq)_(2)Ir(acac),(piq)_(2)Ir(tmd),(piq)_(2)Ir(tpip),(fpiq)_(2)Ir(acac),(fpiq)_(2)Ir(tmd),and(fpiq)_(2)Ir(tpip),in OLEDs was examined,where piq=1-phenylisoquinoline,fpiq=1-(4-fluorophenyl)isoquinoline,acac=(3Z)-4-hydroxypent-3-en-2-one,tmd=(4Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one,and tpip=tetraphenylimido-diphosphonate.These complexes all have low-efficiency roll-off properties,especially(fpiq)_(2)Ir(tpip).Some researchers have successfully synthesized complexes extremely similar to(piq)_(2)Ir(acac)through the Suzuki-Miyaura coupling reaction. 展开更多
关键词 density functional theory organic light-emitting diodes luminescent materials Ir(Ⅲ)complexes
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Enhancing energy density in planar micro-supercapacitors:The role of few-layer graphite/carbon black/NiCo_(2)O_(4) composite materials
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作者 ZHANG Wanggang HUANG Lei +3 位作者 WANG Menghu WANG Jian WEI Aili LIU Yiming 《燃料化学学报(中英文)》 北大核心 2025年第5期646-662,共17页
The advancement of planar micro-supercapacitors(PMSCs)for micro-electromechanical systems(MEMS)has been significantly hindered by the challenge of achieving high energy and power densities.This study addresses this is... The advancement of planar micro-supercapacitors(PMSCs)for micro-electromechanical systems(MEMS)has been significantly hindered by the challenge of achieving high energy and power densities.This study addresses this issue by leveraging screen-printing technology to fabricate high-performance PMSCs using innovative composite ink.The ink,a synergistic blend of few-layer graphene(Gt),carbon black(CB),and NiCo_(2)O_(4),was meticulously mixed to form a conductive and robust coating that enhanced the capacitive performance of the PMSCs.The optimized ink formulation and printing process result in a micro-supercapacitor with an exceptional areal capacitance of 18.95 mF/cm^(2)and an areal energy density of 2.63μW·h/cm^(2)at a current density of 0.05 mA/cm^(2),along with an areal power density of 0.025 mW/cm^(2).The devices demonstrated impressive durability with a capacitance retention rate of 94.7%after a stringent 20000-cycle test,demonstrating their potential for long-term applications.Moreover,the PMSCs displayed excellent mechanical flexibility,with a capacitance decrease of only 3.43%after 5000 bending cycles,highlighting their suitability for flexible electronic devices.The ease of integrating these PMSCs into series and parallel configurations for customized power further underscores their practicality for integrated power supply solutions in various technologies. 展开更多
关键词 graphite/carbon black composite NiCo_(2)O_(4) screen printing planar micro-supercapacitor energy density mechanical flexibility
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Taming of trinitromethyl-oxadiazole to access high density and high oxygen balance via a dual modulation strategy
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作者 Jinya Zhang Teng Fei +4 位作者 Jingwei Meng Jinxiong Cai Lei Zhang Siping Pang Chunlin He 《Defence Technology(防务技术)》 2025年第1期142-149,共8页
Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involv... Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials. 展开更多
关键词 Energetic materials High oxygen balance High density Dual modulation Trinitromethyl group
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Managing cotton canopy architecture for machine picking cotton via high plant density and plant growth retardants
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作者 LAKSHMANAN Sankar SOMASUNDARAM Selvaraj +4 位作者 SHRI RANGASAMI Silambiah ANANTHARAJU Pokkharu VIJAYALAKSHMI Dhashnamurthi RAGAVAN Thiruvengadam DHAMODHARAN Paramasivam 《Journal of Cotton Research》 2025年第1期102-114,共13页
Machine picking in cotton is an emerging practice in India,to solve the problems of labour shortages and production costs increasing.Cotton production has been declining in recent years;however,the high density planti... Machine picking in cotton is an emerging practice in India,to solve the problems of labour shortages and production costs increasing.Cotton production has been declining in recent years;however,the high density planting system(HDPS)offers a viable method to enhance productivity by increasing plant populations per unit area,optimizing resource utilization,and facilitating machine picking.Cotton is an indeterminate plant that produce excessive vegeta-tive growth in favorable soil fertility and moisture conditions,which posing challenges for efficient machine picking.To address this issue,the application of plant growth retardants(PGRs)is essential for controlling canopy architecture.PGRs reduce internode elongation,promote regulated branching,and increase plant compactness,making cotton plants better suited for machine picking.PGRs application also optimizes photosynthates distribution between veg-etative and reproductive growth,resulting in higher yields and improved fibre quality.The integration of HDPS and PGRs applications results in an optimal plant architecture for improving machine picking efficiency.However,the success of this integration is determined by some factors,including cotton variety,environmental conditions,and geographical variations.These approaches not only address yield stagnation and labour shortages but also help to establish more effective and sustainable cotton farming practices,resulting in higher cotton productivity. 展开更多
关键词 COTTON High density planting system Plant growth retardant Canopy management Defoliators Machine picking Yield improvement
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Graded density impactor design via machine learning and numerical simulation:Achieve controllable stress and strain rate
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作者 Yahui Huang Ruizhi Zhang +6 位作者 Shuaixiong Liu Jian Peng Yong Liu Han Chen Jian Zhang Guoqiang Luo Qiang Shen 《Defence Technology(防务技术)》 2025年第9期262-273,共12页
The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to ... The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to achieving controllable stress-strain rate loading.In this study,we have,for the first time,combined one-dimensional fluid computational software with machine learning methods.We first elucidated the mechanisms by which GDI structures control stress and strain rates.Subsequently,we constructed a machine learning model to create a structure-property response surface.The results show that altering the loading velocity and interlayer thickness has a pronounced regulatory effect on stress and strain rates.In contrast,the impedance distribution index and target thickness have less significant effects on stress regulation,although there is a matching relationship between target thickness and interlayer thickness.Compared with traditional design methods,the machine learning approach offers a10^(4)—10^(5)times increase in efficiency and the potential to achieve a global optimum,holding promise for guiding the design of GDI. 展开更多
关键词 Machine learning Numerical simulation Graded density impactor Controllable stress-strain rate loading Response surface methodology
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High density dislocations enhance creep ageing response and mechanical properties in 2195 alloy sheet 被引量:1
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作者 WEI Shuo MA Pei-pei +3 位作者 CHEN Long-hui YANG Jian-shi ZHAN Li-hua LIU Chun-hui 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第7期2194-2209,共16页
The creep strain of conventionally treated 2195 alloy is very low,increasing the difficulty of manufacturing Al-Cu-Li alloy sheet parts by creep age forming.Therefore,finding a solution to improve the creep formabilit... The creep strain of conventionally treated 2195 alloy is very low,increasing the difficulty of manufacturing Al-Cu-Li alloy sheet parts by creep age forming.Therefore,finding a solution to improve the creep formability of Al-Cu-Li alloy is vital.A thorough comparison of the effects of cryo-deformation and ambient temperature large pre-deformation(LPD)on the creep ageing response in the 2195 alloy sheet at 160℃with different stresses has been made.The evolution of dislocations and precipitates during creep ageing of LPD alloys are revealed by X-ray diffraction and transmission electron microscopy.High-quality 2195 alloy sheet largely pre-deformed by 80%without edge-cracking is obtained by cryo-rolling at liquid nitrogen temperature,while severe edge-cracking occurs during room temperature rolling.The creep formability and strength of the 2195 alloy are both enhanced by introducing pre-existing dislocations with a density over 1.4×10^(15)m^(−2).At 160℃and 150 MPa,creep strain and creep-aged strength generally increases by 4−6 times and 30−50 MPa in the LPD sample,respectively,compared to conventional T3 alloy counterpart.The elongation of creep-aged LPD sample is low but remains relevant for application.The high-density dislocations,though existing in the form of dislocation tangles,promote the formation of refined T1 precipitates with a uniform dispersion. 展开更多
关键词 creep ageing Al-Cu-Li alloy high dislocation density cryogenic rolling dislocation strengthening
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Artificial intelligence models based on non-contrast chest CT for measuring bone mineral density 被引量:1
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作者 DUAN Wei YANG Guoqing +6 位作者 LI Yang SHI Feng YANG Lian XIONG Xin CHEN Bei LI Yong FU Quanshui 《中国医学影像技术》 CSCD 北大核心 2024年第8期1231-1235,共5页
Objective To observe the value of artificial intelligence(AI)models based on non-contrast chest CT for measuring bone mineral density(BMD).Methods Totally 380 subjects who underwent both non-contrast chest CT and quan... Objective To observe the value of artificial intelligence(AI)models based on non-contrast chest CT for measuring bone mineral density(BMD).Methods Totally 380 subjects who underwent both non-contrast chest CT and quantitative CT(QCT)BMD examination were retrospectively enrolled and divided into training set(n=304)and test set(n=76)at a ratio of 8∶2.The mean BMD of L1—L3 vertebrae were measured based on QCT.Spongy bones of T5—T10 vertebrae were segmented as ROI,radiomics(Rad)features were extracted,and machine learning(ML),Rad and deep learning(DL)models were constructed for classification of osteoporosis(OP)and evaluating BMD,respectively.Receiver operating characteristic curves were drawn,and area under the curves(AUC)were calculated to evaluate the efficacy of each model for classification of OP.Bland-Altman analysis and Pearson correlation analysis were performed to explore the consistency and correlation of each model with QCT for measuring BMD.Results Among ML and Rad models,ML Bagging-OP and Rad Bagging-OP had the best performances for classification of OP.In test set,AUC of ML Bagging-OP,Rad Bagging-OP and DL OP for classification of OP was 0.943,0.944 and 0.947,respectively,with no significant difference(all P>0.05).BMD obtained with all the above models had good consistency with those measured with QCT(most of the differences were within the range of Ax-G±1.96 s),which were highly positively correlated(r=0.910—0.974,all P<0.001).Conclusion AI models based on non-contrast chest CT had high efficacy for classification of OP,and good consistency of BMD measurements were found between AI models and QCT. 展开更多
关键词 OSTEOPOROSIS bone density tomography X-ray computed artificial intelligence
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High-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer based on probability density evolution method 被引量:1
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作者 Mingming Wang Linfang Qian +3 位作者 Guangsong Chen Tong Lin Junfei Shi Shijie Zhou 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期209-221,共13页
This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is establi... This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is established considering the flexible deformation of the barrel and the interaction between the projectile and the barrel.Subsequently,the accuracy of the dynamic model is verified based on the external ballistic projectile attitude test platform.Furthermore,the probability density evolution method(PDEM)is developed to high-dimensional uncertainty quantification of projectile motion.The engineering example highlights the results of the proposed method are consistent with the results obtained by the Monte Carlo Simulation(MCS).Finally,the influence of parameter uncertainty on the projectile disturbance at muzzle under different working conditions is analyzed.The results show that the disturbance of the pitch angular,pitch angular velocity and pitch angular of velocity decreases with the increase of launching angle,and the random parameter ranges of both the projectile and coupling model have similar influence on the disturbance of projectile angular motion at muzzle. 展开更多
关键词 Truck-mounted howitzer Projectile motion Uncertainty quantification Probability density evolution method
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Method for triangular fuzzy multiple attribute decision making based on two-dimensional density operator method 被引量:1
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作者 LIN Youliang LI Wu +1 位作者 LIU Gang HUANG Dong 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2024年第1期178-185,共8页
Aiming at the triangular fuzzy(TF)multi-attribute decision making(MADM)problem with a preference for the distribution density of attribute(DDA),a decision making method with TF number two-dimensional density(TFTD)oper... Aiming at the triangular fuzzy(TF)multi-attribute decision making(MADM)problem with a preference for the distribution density of attribute(DDA),a decision making method with TF number two-dimensional density(TFTD)operator is proposed based on the density operator theory for the decision maker(DM).Firstly,a simple TF vector clustering method is proposed,which considers the feature of TF number and the geometric distance of vectors.Secondly,the least deviation sum of squares method is used in the program model to obtain the density weight vector.Then,two TFTD operators are defined,and the MADM method based on the TFTD operator is proposed.Finally,a numerical example is given to illustrate the superiority of this method,which can not only solve the TF MADM problem with a preference for the DDA but also help the DM make an overall comparison. 展开更多
关键词 fuzzy decision making CLUSTERING density operator multi-attribute decision making(MADM)
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Exploring the impact of high density planting system and deficit irrigation in cotton(Gossypium hirsutum L.):a comprehensive review 被引量:1
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作者 MANIBHARATHI Sekar SOMASUNDARAM Selvaraj +3 位作者 PARASURAMAN Panneerselvam SUBRAMANIAN Alagesan RAVICHANDRAN Veerasamy MANIKANDA BOOPATHI Narayanan 《Journal of Cotton Research》 CAS 2024年第3期302-317,共16页
Lessons learned from past experiences push for an alternate way of crop production.In India,adopting high density planting system(HDPS)to boost cotton yield is becoming a growing trend.HDPS has recently been considere... Lessons learned from past experiences push for an alternate way of crop production.In India,adopting high density planting system(HDPS)to boost cotton yield is becoming a growing trend.HDPS has recently been considered a replacement for the current Indian production system.It is also suitable for mechanical harvesting,which reducing labour costs,increasing input use efficiency,timely harvesting timely,maintaining cotton quality,and offering the potential to increase productivity and profitability.This technology has become widespread in globally cotton growing regions.Water management is critical for the success of high density cotton planting.Due to the problem of freshwater availability,more crops should be produced per drop of water.In the high-density planting system,optimum water application is essential to control excessive vegetative growth and improve the translocation of photoassimilates to reproductive organs.Deficit irrigation is a tool to save water without compromising yield.At the same time,it consumes less water than the normal evapotranspiration of crops.This review comprehensively documents the importance of growing cotton under a high-density planting system with deficit irrigation.Based on the current research and combined with cotton production reality,this review discusses the application and future development of deficit irrigation,which may provide theoretical guidance for the sustainable advancement of cotton planting systems. 展开更多
关键词 Deficit irrigation High density planting system Ultra narrow row Cost saving Mechanical harvesting Yield optimization
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A density functional theory study of polarons on different TiO_(2) surfaces
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作者 SHI Zhiqun GONG Xueqing 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第12期1877-1888,I0011-I0013,共15页
Polarons are widely considered to play a crucial role in the charge transport and photocatalytic performance of materials,but the mechanisms of their formation and the underlying driving factors remain a matter of con... Polarons are widely considered to play a crucial role in the charge transport and photocatalytic performance of materials,but the mechanisms of their formation and the underlying driving factors remain a matter of controversy.This study delves into the formation of polarons in different crystalline forms of TiO_(2) and their connection with the materials'structure.By employing density functional theory calculations with on-site Coulomb interaction correction(DFT+U),we provide a detailed analysis of the electronic polarization behavior in the anatase and rutile forms of TiO_(2).We focus on the polarization properties of defect-induced and photoexcited excess electrons on various TiO_(2) surfaces.The results reveal that the defect electrons can form small polarons on the anatase TiO_(2)(101)surface,while on the rutile TiO_(2)(110)surface,both small and large polarons(hybrid-state polarons)are formed.Photoexcited electrons are capable of forming both small and large polarons on the surfaces of both crystal types.The analysis indicates that the differences in polaron distribution are primarily determined by the intrinsic properties of the crystals;the structural and symmetry differences between anatase and rutile TiO_(2) lead to the distinct polaron behaviors.Further investigation suggests that the polarization behavior of defect electrons is also related to the arrangement of electron orbitals around the Ti atoms,while the polarization of photoexcited electrons is mainly facilitated by the lattice distortions.These findings elucidate the formation mechanisms of different types of polarons and may contribute to understanding the performance of TiO_(2)in different fields. 展开更多
关键词 POLARON surface defect PHOTOEXCITATION TiO_(2) density functional theory
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不同直径毛管中水密度变化特性及其对土壤水密度变化的启示 被引量:1
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作者 李超 程东会 +4 位作者 马成龙 乔晓英 黄梦楠 王一式 杨银科 《地学前缘》 北大核心 2025年第1期440-448,共9页
土壤水的密度存在较大的变化范围,但目前还没有一个完整的理论来全面描述这种变化规律。本文利用微米直径的石英管模拟多孔介质的孔隙系统,采用质量-体积法测量了直径在50~530μm之间的8个不同直径石英管中水的密度。结果表明:当石英管... 土壤水的密度存在较大的变化范围,但目前还没有一个完整的理论来全面描述这种变化规律。本文利用微米直径的石英管模拟多孔介质的孔隙系统,采用质量-体积法测量了直径在50~530μm之间的8个不同直径石英管中水的密度。结果表明:当石英管直径小于75μm时,水的密度大于体相水的密度,最高密度为1.19 g/cm^(3);而直径为100~250μm时,水的密度略小于体相水,最低为0.98 g/cm^(3)。水密度随石英管径而变化的规律可以用类似纳兰-琼斯势的经验公式来表达。研究表明:能使水密度增大或减小的水化作用、水-固界面作用、毛细作用或空化机制均不能解释石英管中出现的水密度变化。分析认为,毛管中的复杂的水动力学和流变学,特别是管嘴的剪切增稠及其逆过程可能是不同直径石英管中水密度变化的物理机制。该机制不同于解释土壤水密度变化的传统理论,为土壤水密度变化研究提供了一个崭新的视角。如果把石英管中水密度变化规律与基于多孔介质毛管束概念的土壤含水率模型结合,可以预测不同含水率土壤中水的密度。进一步的研究应该从流变学基本理论出发,建立剪切速率与黏度和黏度与密度之间的定量关系,从理论上构建毛管水和土壤水密度变化模型。 展开更多
关键词 微米直径石英管 高密度水 低密度水 剪切增稠 土壤水密度变化
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基于K互近邻与核密度估计的DPC算法 被引量:2
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作者 周玉 夏浩 +1 位作者 刘虹瑜 白磊 《北京航空航天大学学报》 北大核心 2025年第6期1978-1990,共13页
快速搜索和发现密度峰值聚类(DPC)算法是一种基于密度的聚类算法。该算法不需要迭代和过多的设定参数,但由于计算局部密度时没有考虑数据的局部结构,导致无法识别簇密度小的聚类中心。针对此问题,提出基于K互近邻(KN)和核密度估计(KDE)... 快速搜索和发现密度峰值聚类(DPC)算法是一种基于密度的聚类算法。该算法不需要迭代和过多的设定参数,但由于计算局部密度时没有考虑数据的局部结构,导致无法识别簇密度小的聚类中心。针对此问题,提出基于K互近邻(KN)和核密度估计(KDE)的DPC(KKDPC)算法。通过K近邻和核密度估计方法得到数据点的K互近邻数量和局部核密度;将K互近邻数量与局部核密度进行加和获得新的局部密度;根据数据点的局部密度得到相对距离,并通过构建决策图选取聚类中心及分配非中心点。利用人工数据集和真实数据集进行实验,并与DPC、基于密度的噪声空间聚类应用(DBSCAN)、K-means、模糊C均值聚类算法(FCM)、基于K近邻的DPC(DPCKNN)、近邻优化DPC(DPC-NNO)、基于模糊加权共享邻居的DPC(DPC-FWSN)算法进行对比。通过计算调整互信息(AMI)、调整兰德指数(ARI)、归一化互信息(NMI)来验证KKDPC算法的性能。实验结果表明:KKDPC算法能更加准确地识别聚类中心,有效地提高聚类精度。 展开更多
关键词 聚类算法 密度峰值 K近邻 K互近邻 核密度估计
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New density clustering-based approach for failure mode and effect analysis considering opinion evolution and bounded confidence
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作者 WANG Jian ZHU Jingyi +1 位作者 SHI Hua LIU Huchen 《Journal of Systems Engineering and Electronics》 CSCD 2024年第6期1491-1506,共16页
Failure mode and effect analysis(FMEA)is a preven-tative risk evaluation method used to evaluate and eliminate fail-ure modes within a system.However,the traditional FMEA method exhibits many deficiencies that pose ch... Failure mode and effect analysis(FMEA)is a preven-tative risk evaluation method used to evaluate and eliminate fail-ure modes within a system.However,the traditional FMEA method exhibits many deficiencies that pose challenges in prac-tical applications.To improve the conventional FMEA,many modified FMEA models have been suggested.However,the majority of them inadequately address consensus issues and focus on achieving a complete ranking of failure modes.In this research,we propose a new FMEA approach that integrates a two-stage consensus reaching model and a density peak clus-tering algorithm for the assessment and clustering of failure modes.Firstly,we employ the interval 2-tuple linguistic vari-ables(I2TLVs)to express the uncertain risk evaluations provided by FMEA experts.Then,a two-stage consensus reaching model is adopted to enable FMEA experts to reach a consensus.Next,failure modes are categorized into several risk clusters using a density peak clustering algorithm.Finally,the proposed FMEA is illustrated by a case study of load-bearing guidance devices of subway systems.The results show that the proposed FMEA model can more easily to describe the uncertain risk information of failure modes by using the I2TLVs;the introduction of an endogenous feedback mechanism and an exogenous feedback mechanism can accelerate the process of consensus reaching;and the density peak clustering of failure modes successfully improves the practical applicability of FMEA. 展开更多
关键词 failure mode and effect analysis(FMEA) interval 2-tuple linguistic variable(I2TLV) consensus reaching density peak clustering algorithm
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黄土高原退耕刺槐中龄林密度和空间结构对灌草多样性的影响 被引量:3
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作者 王宇 王冬梅 +3 位作者 王彦辉 云慧雅 张梦棋 张莹莹 《生态学报》 北大核心 2025年第2期822-836,共15页
为了在理解林分密度和空间结构参数对林下灌草多样性的影响基础上科学指导黄土高原退耕还林工程早期栽植的刺槐(Robinia pseudoacacia)中龄林经营,于甘肃省泾川县官山林场选择了生长在残塬顶部退耕梯田相似立地上的林龄18—25 a的4个密... 为了在理解林分密度和空间结构参数对林下灌草多样性的影响基础上科学指导黄土高原退耕还林工程早期栽植的刺槐(Robinia pseudoacacia)中龄林经营,于甘肃省泾川县官山林场选择了生长在残塬顶部退耕梯田相似立地上的林龄18—25 a的4个密度梯度的刺槐中龄人工林,建立了样地共12个,调查角尺度、混交度、密集度、开敞度和大小比数等林分空间结构参数,同时调查计算林下灌木、草本层的Simpson指数、Gini多样性指数、Shannon-Wiener指数、Pielou均匀度指数及Patrick指数等林下植物多样性指标,运用Person相关性分析和灰色关联度分析探究刺槐中龄人工林密度和空间结构参数与林下灌木层和草本层植物多样性的关系,并确定主要影响因子。结果表明:(1)林下植物物种总数随林分密度增加呈先增后减的变化,在密度1300—1700株/hm^(2)时,林下植物物种总数和草本层多样性指数均达到最大。(2)林分密度主要影响刺槐林的透光性、分布格局和混交程度,密度<1300株/hm^(2)时林分透光性最好;密度1300—1700株/hm^(2)时,57%的刺槐林木呈随机分布,此时分布格局最接近天然状态;密度>2100株/hm^(2)时,林分的混交程度最高。(3)Person相关性分析表明,开敞度和灌木层Simpson指数、物种丰富度指数呈极显著正相关(P<0.01),混交度和草本层物种丰富度指数、Gini指数呈显著正相关(P<0.05)。灰色关联度分析表明,当林分密度<1300、1300—1700、>1700株/hm^(2)时,影响林下灌草多样性的主要因子分别是混交度、开敞度、胸径大小比数。(4)对在研究立地条件上退耕栽植的刺槐中龄林,可将1300—1700株/hm^(2)作为考虑林下植物多样性的合理经营密度范围。可以基于研究结果,针对性地优化刺槐人工中龄林的林分密度和空间结构,促进林下灌草层发育,提高林下植物多样性和森林的多功能性。 展开更多
关键词 黄土高原 林分空间结构 林下植被多样性 林分密度
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稻蛙种养模式下放养密度对黑斑蛙生长性能、血清激素和抗氧化指标及肠道菌群的影响 被引量:2
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作者 韩光明 覃宝利 +5 位作者 吴雷明 张家宏 寇祥明 王守红 徐荣 马林杰 《动物营养学报》 北大核心 2025年第2期1162-1172,共11页
本试验旨在研究稻蛙种养模式下放养密度对黑斑蛙生长性能、血清激素和抗氧化指标及肠道菌群的影响。以初始体重为(8.12±0.03)g的黑斑蛙幼蛙为研究对象,设置5个放养密度,M1、M2、M3、M4、M5组放养密度分别为6、12、24、48和96只/m^(... 本试验旨在研究稻蛙种养模式下放养密度对黑斑蛙生长性能、血清激素和抗氧化指标及肠道菌群的影响。以初始体重为(8.12±0.03)g的黑斑蛙幼蛙为研究对象,设置5个放养密度,M1、M2、M3、M4、M5组放养密度分别为6、12、24、48和96只/m^(2)(即0.4万、0.8万、1.6万、3.2万和6.4万只/亩),每组3个重复,养殖80 d。结果显示:1)放养密度超过24只/m^(2)时,黑斑蛙的成活率出现显著下降(P<0.05);M3组黑斑蛙的末均重、增重率和特定生长率最高,且饲料系数显著低于M4和M5组(P<0.05)。2)各组之间血清皮质醇、胰岛素样生长因子-Ⅰ、甲状腺素含量以及超氧化物歧化酶、谷胱甘肽过氧化物酶、过氧化氢酶活性与丙二醛含量无显著差异(P>0.05),但M3组的血清总抗氧化能力显著高于M5组(P<0.05)。3)随着黑斑蛙放养密度的增加,肠道菌群的Chao1、Faith_pd、Observed_species、Shannon指数均出现上升的趋势,其中M5组显著高于M1组(P<0.05)。4)在门水平上,与M1和M2组比较,M4组肠道菌群中厚壁菌门(Firmicutes)的相对丰度显著下降(P<0.05),拟杆菌门(Bacteroidetes)的相对丰度显著升高(P<0.05);在属水平上,随着黑斑蛙放养密度的增加,肠道菌群中拟杆菌属(Bacteroides)的相对丰度呈上升趋势,乳球菌属(Lactococcus)的相对丰度呈下降趋势,罗姆布茨菌属(Romboutsia)和阿克曼菌属(Akkermansia)的相对丰度呈先上升后下降的趋势。综上可知,在本试验条件下,黑斑蛙放养密度过高不利于个体生长,适当增加放养密度可以提高肠道菌群多样性;在稻蛙种养模式下,建议黑斑蛙的放养密度为12~24只/m^(2)(即0.8万~1.6万只/亩)。 展开更多
关键词 黑斑蛙 放养密度 血清激素 抗氧化指标 肠道菌群
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甲烷在钠基蒙脱土吸附的第一性原理研究 被引量:1
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作者 方志杰 李博 +4 位作者 宋昌辉 刘美玲 何秋芝 刘翔 莫曼 《原子与分子物理学报》 CAS 北大核心 2025年第2期8-14,共7页
随着经济的发展,能源需求日益增加,为了弥补国内少油缺气短板,页岩气的开发成为近期新能源的热点,探索页岩气储存规律是页岩气能源开发的关键所在.本文采用密度泛函理论的第一性原理方法,计算甲烷(CH_(4))在钠基蒙脱土表面和层间的吸附... 随着经济的发展,能源需求日益增加,为了弥补国内少油缺气短板,页岩气的开发成为近期新能源的热点,探索页岩气储存规律是页岩气能源开发的关键所在.本文采用密度泛函理论的第一性原理方法,计算甲烷(CH_(4))在钠基蒙脱土表面和层间的吸附能,对比吸附前后的态密度和物理结构以及差分电荷密度.结果表明:钠基蒙脱土表面吸附中,甲烷最佳选择是桥位,吸附能为-0.08eV,被吸附后甲烷的键长和键角变化率均小于0.96%.层间吸附中,伴随着甲烷吸附量增加,纳基蒙脱土体积向c轴方向线性增加,a、b轴方向则变化不大.总态密度随着吸附量的增加,总能级数量也增加,甲烷分子的分波态密度峰向低能级移动.本文的研究成果,从原子角度分析了甲烷在蒙脱石表面以及层间的吸附能力,为解释页岩气在页岩储存规律提供理论依据. 展开更多
关键词 钠基蒙脱土 第一性原理 甲烷 吸附 态密度
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固废漆渣在聚乙烯防水板材中的应用研究 被引量:1
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作者 范兆荣 谷亚新 +2 位作者 刘阳 王晓丹 刘运学 《中国塑料》 北大核心 2025年第6期84-88,共5页
以高密度聚乙烯(PE-HD)为基体树脂,固废漆渣为填充改性剂,硅烷偶联剂(KH-560)作为界面改性剂制得漆渣改性PE-HD防水板材。研究了漆渣的用量和硅烷偶联剂对聚乙烯防水板材的疏水性能和力学性能的影响。结果表明,漆渣与PE-HD共混制得的防... 以高密度聚乙烯(PE-HD)为基体树脂,固废漆渣为填充改性剂,硅烷偶联剂(KH-560)作为界面改性剂制得漆渣改性PE-HD防水板材。研究了漆渣的用量和硅烷偶联剂对聚乙烯防水板材的疏水性能和力学性能的影响。结果表明,漆渣与PE-HD共混制得的防水板,其断裂伸长率随着漆渣掺量的增加而显著降低,拉伸强度和接触角度数在漆渣掺量不超过4%时缓慢增大,漆渣掺量超过4%时迅速降低;改性后的PE-HD防水板热老化性能受漆渣影响不大;硅烷偶联剂的加入对改善改性后PE-HD防水板的断裂伸长率更有利。 展开更多
关键词 固废漆渣 防水板材 高密度聚乙烯
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基于NOD样受体3炎性小体通路对利拉鲁肽在氧化低密度脂蛋白诱导内皮细胞损伤的作用机制研究 被引量:1
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作者 陈玲 徐锐 +2 位作者 程新春 张占英 徐红 《中国全科医学》 CAS 北大核心 2025年第5期601-606,共6页
背景动脉粥样硬化是世界范围内引起心脑血管疾病最主要的原因,炎症是目前研究热点,其中NOD样受体3(NLRP3)是研究最为深入的炎症小体。胰高糖素样肽1(GLP-1)受体激动剂有抗动脉粥样硬化作用,具体机制尚不明确。目的研究利拉鲁肽通过拮抗... 背景动脉粥样硬化是世界范围内引起心脑血管疾病最主要的原因,炎症是目前研究热点,其中NOD样受体3(NLRP3)是研究最为深入的炎症小体。胰高糖素样肽1(GLP-1)受体激动剂有抗动脉粥样硬化作用,具体机制尚不明确。目的研究利拉鲁肽通过拮抗氧化低密度脂蛋白(ox-LDL)诱导的内皮细胞损伤的作用机制。方法2022-03-25—05-19培养人脐静脉内皮细胞(HUVEC),取HUVEC加空白血清作为对照组,100μg/mL的ox-LDL干预HUVEC 48 h作为模型组,100μg/mL的ox-LDL干预HUVEC 24 h后分别加入100、200、400 nmol/L利拉鲁肽处理24 h作为利拉鲁肽低浓度组、利拉鲁肽中浓度组、利拉鲁肽高浓度组。CCK-8法计算细胞增殖率。通过扫描电镜观察焦亡细胞形态。检测乳酸脱氢酶(LDH)活力。酶联免疫吸附试验(ELISA)检测白介素(IL)-1β、IL-18表达水平。蛋白质免疫印迹试验(Western blot)检测NLRP3、接头蛋白凋亡相关斑点样蛋白(ASC)、天冬氨酸蛋白水解酶1(Caspase-1)、焦亡执行蛋白(GSDMD)、N端结构域的焦亡执行蛋白(N-GSDMD)表达水平。结果模型组、利拉鲁肽低浓度组和利拉鲁肽中浓度组细胞增殖率低于对照组,利拉鲁肽低浓度组、利拉鲁肽中浓度组、利拉鲁肽高浓度组细胞增殖率高于模型组(P<0.05)。细胞扫描电镜结果示模型组细胞焦亡明显,利拉鲁肽低浓度组、利拉鲁肽中浓度组、利拉鲁肽高浓度组细胞焦亡情况明显改善。模型组、利拉鲁肽低浓度组LDH活力高于对照组,利拉鲁肽低浓度组、利拉鲁肽中浓度组、利拉鲁肽高浓度组低于模型组(P<0.05)。模型组、利拉鲁肽低浓度组IL-1β表达水平高于对照组,利拉鲁肽中浓度组、利拉鲁肽高浓度组IL-1β表达水平低于模型组(P<0.05);模型组IL-18表达水平高于对照组,利拉鲁肽低浓度组、利拉鲁肽中浓度组、利拉鲁肽高浓度组IL-18表达水平低于模型组(P<0.05)。模型组NLRP3、ASC、Caspase-1、GSDMD、N-GSDMD表达水平高于对照组,利拉鲁肽低浓度组ASC、Caspase-1表达水平高于对照组,利拉鲁肽中浓度组NLRP3、ASC表达水平低于模型组,利拉鲁肽高浓度组NLRP3、ASC、Caspase-1表达水平低于模型组(P<0.05)。结论利拉鲁肽显著抑制ox-LDL诱导的内皮细胞NLRP3炎性小体活化,并且能够抑制内皮细胞的焦亡,具有抗动脉粥样硬化作用。 展开更多
关键词 动脉粥样硬化 利拉鲁肽 内皮细胞 氧化低密度脂蛋白 NOD样受体3
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全舍饲圈养不同饲养密度种鹅生产性能观察 被引量:1
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作者 刘健 李世维 +7 位作者 苗博涵 刘心怡 郑赛超 牛晖 杨朋坤 张立恒 台运山 陈新科 《中国家禽》 北大核心 2025年第3期157-162,共6页
为探讨全舍饲条件下饲养密度对反季节种鹅生产性能影响,试验选用健康种鹅4415只,按照1只/m^(2)、1.5只/m^(2)、2只/m^(2)养殖密度,随机分为3个试验组,种鹅分别为965只、1520只、1930只,设置公母配比1∶4,每组3个重复;试验过程中记录种... 为探讨全舍饲条件下饲养密度对反季节种鹅生产性能影响,试验选用健康种鹅4415只,按照1只/m^(2)、1.5只/m^(2)、2只/m^(2)养殖密度,随机分为3个试验组,种鹅分别为965只、1520只、1930只,设置公母配比1∶4,每组3个重复;试验过程中记录种鹅的产蛋率、采食量、种蛋受精率和孵化率等生产性能指标,并进行统计分析。结果显示:随着饲养密度的升高,种鹅的产蛋率、种蛋受精率、采食量均显著下降(P<0.05);受精蛋孵化率和死淘率各组之间差异不显著(P>0.05)。研究表明,在全舍饲圈养反季节生产条件下,种鹅饲养密度控制在1~1.5只/m^(2)为宜。 展开更多
关键词 种鹅 全舍饲 饲养密度 生产性能
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