The laboratory scale experiments for determining the influence on the distribution of phosphorus by.adding Al-containing component in melting furnace were conducted. It is found that the addition of Al-containing comp...The laboratory scale experiments for determining the influence on the distribution of phosphorus by.adding Al-containing component in melting furnace were conducted. It is found that the addition of Al-containing component in melting furnace increased the amount of phosphorus in slag phase. Thermodynamic analysis of the industrial sludge melting process with the addition of different Al-containing components was also carried out. The compositions of slag and the gas in three different zones in melting furnace were obtained. The results also demonstrate that increasing the mole ratio Al/P of charged materials is an effective way to fix more phosphorus in slap, which can help reduce the amount of H3PO4 precipitate from guy in the waste heat boiler later.展开更多
Extracting vanadium and removing phosphorus simultaneously by adding CaO containing materials to V-bearing hot metal were investigated under the condition of simulating the process of vanadium extraction with insuffic...Extracting vanadium and removing phosphorus simultaneously by adding CaO containing materials to V-bearing hot metal were investigated under the condition of simulating the process of vanadium extraction with insufficiently supplying oxygen in converter. Through preliminary experiments, 3 h and 1375 °C were chosen as the optimum holding time and reaction temperature for formal experiments, respectively. The results of the formal experiments suggest that making basic slag can extract vanadium and remove phosphorus simultaneously. The vanadium extraction rate(ηV) and phosphorus removal rate(ηP) both increase with an increase in the basicity of the original slag materials and the Fe2O3 contents. The vanadium distribution ratio)(V L′is about an order of magnitude greater than the phosphorus distribution ratio),(P L′but the latter is more sensitive to slag basicity than the former. The phosphorus distribution ratio is beyond 6 when the basicity of the original slag materials is beyond 1, which indicates a much better performance of phosphorus removal compared to the phosphorus removal in the current process. Therefore, it is very feasible to properly raise slag basicity to remove phosphorus with consideration of the grade of vanadium slag. The relations between ηV and ηP, and between L′V and L′P are linear under the experimental conditions.展开更多
文摘The laboratory scale experiments for determining the influence on the distribution of phosphorus by.adding Al-containing component in melting furnace were conducted. It is found that the addition of Al-containing component in melting furnace increased the amount of phosphorus in slag phase. Thermodynamic analysis of the industrial sludge melting process with the addition of different Al-containing components was also carried out. The compositions of slag and the gas in three different zones in melting furnace were obtained. The results also demonstrate that increasing the mole ratio Al/P of charged materials is an effective way to fix more phosphorus in slap, which can help reduce the amount of H3PO4 precipitate from guy in the waste heat boiler later.
基金Project(41603004)supported by the Independent Research Program of State Key Laboratory of Advanced Metallurgy(University of Science and Technology Beijing),China
文摘Extracting vanadium and removing phosphorus simultaneously by adding CaO containing materials to V-bearing hot metal were investigated under the condition of simulating the process of vanadium extraction with insufficiently supplying oxygen in converter. Through preliminary experiments, 3 h and 1375 °C were chosen as the optimum holding time and reaction temperature for formal experiments, respectively. The results of the formal experiments suggest that making basic slag can extract vanadium and remove phosphorus simultaneously. The vanadium extraction rate(ηV) and phosphorus removal rate(ηP) both increase with an increase in the basicity of the original slag materials and the Fe2O3 contents. The vanadium distribution ratio)(V L′is about an order of magnitude greater than the phosphorus distribution ratio),(P L′but the latter is more sensitive to slag basicity than the former. The phosphorus distribution ratio is beyond 6 when the basicity of the original slag materials is beyond 1, which indicates a much better performance of phosphorus removal compared to the phosphorus removal in the current process. Therefore, it is very feasible to properly raise slag basicity to remove phosphorus with consideration of the grade of vanadium slag. The relations between ηV and ηP, and between L′V and L′P are linear under the experimental conditions.
