水气二相流与诸多领域的实际工程问题密切相关.对二相流运动进行高精度的数值模拟是计算流体力学研究的难点和热点.针对开敞水域的自由表面流运动问题,将水和空气均视为不可压缩流体,采用五阶加权基本无震荡(weighted essentially non-o...水气二相流与诸多领域的实际工程问题密切相关.对二相流运动进行高精度的数值模拟是计算流体力学研究的难点和热点.针对开敞水域的自由表面流运动问题,将水和空气均视为不可压缩流体,采用五阶加权基本无震荡(weighted essentially non-oscillatory,WENO)格式求解描述流体运动的纳维斯托克斯(Navier–Stokes,NS)方程,利用以加权线性界面算法改进的多维双曲正切函数界面捕捉法(tangent of hyperbola for interface capturing with weighed line interface calculation,THINC/WLIC)追踪水气界面,建立WENO–THINC/WLIC水气二相流运动数值模型.模型采用分步计算法离散求解控制方程,通过压力投影法求解压强场,并利用三阶总变差递减(total variation diminishing,TVD)龙格库塔(Runge–Kutta,RK)法对时间项进行离散求解.通过对环境速度场下Zalesak’s disk和shearing vortex界面运动问题,线性液舱晃荡问题以及溃坝问题的模拟结果与理论分析或试验结果的比较,对所建立的水气二相流数值模型的适用性及模拟精度进行了验证.结果表明,本模型的模拟结果与物理模型或理论分析结果吻合良好,能较为准确地再现不可压缩水气二相流运动现象.鉴于WENO格式和THINC法本身在算法及应用等方面仍在不断改进,本研究提出的WENO–THINC耦合模型为后续更高精度的二相流计算模型开发提供了一种研究思路.展开更多
建立了一种可用于水产品及食用油中氟乐灵残留量分析的分散型固相萃取-气相色谱-负化学离子源质谱方法。水产品及食用油经乙腈提取，4℃冷藏后，采用分散型固相萃取法净化，由气相色谱-负化学离子源质谱选择离子监测技术进行测定与确证...建立了一种可用于水产品及食用油中氟乐灵残留量分析的分散型固相萃取-气相色谱-负化学离子源质谱方法。水产品及食用油经乙腈提取，4℃冷藏后，采用分散型固相萃取法净化，由气相色谱-负化学离子源质谱选择离子监测技术进行测定与确证，同位素内标法定量。在1～40μg / L 范围内氟乐灵农药的线性关系良好；方法定量限（LOQ）为0.02μg / kg；对鳗鱼、烤鳗、梭子蟹、小龙虾、猪油和橄榄油等6种复杂基质进行1.0、2.0和3.0μg / kg 等3个水平的添加回收试验，平均回收率均处于80％～100％之间，RSD≤10.3％；无干扰现象出现。该方法可作为水产品及食用油中氟乐灵残留检测的确证方法。展开更多
The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate（Al2（SO4）3） and ammonium carbonate（（NH4）2CO3）. The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and...The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate（Al2（SO4）3） and ammonium carbonate（（NH4）2CO3）. The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and ammonium nitrate, as well as multiplex catalysts （AT） on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al2O3 seeds and the mixture of α-Al2O3 and ammonium nitrate can lower the phase transformation temperature of α-Al2O3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al2O3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly.展开更多
The heat transfer performance of the phase change materials used in free cooling and air conditioning applications is low,due to the poor thermal conductivity of the materials.The recent phenomenal advancement in nano...The heat transfer performance of the phase change materials used in free cooling and air conditioning applications is low,due to the poor thermal conductivity of the materials.The recent phenomenal advancement in nano technology provides an opportunity for an appreciable enhancement in the thermal conductivity of the phase change materials.In order to explore the possibilities of using nano technology for various applications,a detailed parametric study is carried out,to analyse the heat transfer enhancement potential with the thermal conductivity of the conventional phase change materials and nano enhanced phase change materials under various flow conditions of the heat transfer fluid.Initially,the theoretical equation,used to determine the time for outward cylindrical solidification of the phase change material,is validated with the experimental results.It is inferred from the parametric studies,that for paraffinic phase change materials with air as the heat transfer fluid,the first step should be to increase the heat transfer coefficient to the maximum extent,before making any attempt to increase the thermal conductivity of the phase change materials,with the addition of nano particles.When water is used as the phase change material,the addition of nano particles is recommended to achieve better heat transfer,when a liquid is used as the heat transfer fluid.展开更多
文摘水气二相流与诸多领域的实际工程问题密切相关.对二相流运动进行高精度的数值模拟是计算流体力学研究的难点和热点.针对开敞水域的自由表面流运动问题,将水和空气均视为不可压缩流体,采用五阶加权基本无震荡(weighted essentially non-oscillatory,WENO)格式求解描述流体运动的纳维斯托克斯(Navier–Stokes,NS)方程,利用以加权线性界面算法改进的多维双曲正切函数界面捕捉法(tangent of hyperbola for interface capturing with weighed line interface calculation,THINC/WLIC)追踪水气界面,建立WENO–THINC/WLIC水气二相流运动数值模型.模型采用分步计算法离散求解控制方程,通过压力投影法求解压强场,并利用三阶总变差递减(total variation diminishing,TVD)龙格库塔(Runge–Kutta,RK)法对时间项进行离散求解.通过对环境速度场下Zalesak’s disk和shearing vortex界面运动问题,线性液舱晃荡问题以及溃坝问题的模拟结果与理论分析或试验结果的比较,对所建立的水气二相流数值模型的适用性及模拟精度进行了验证.结果表明,本模型的模拟结果与物理模型或理论分析结果吻合良好,能较为准确地再现不可压缩水气二相流运动现象.鉴于WENO格式和THINC法本身在算法及应用等方面仍在不断改进,本研究提出的WENO–THINC耦合模型为后续更高精度的二相流计算模型开发提供了一种研究思路.
文摘建立了一种可用于水产品及食用油中氟乐灵残留量分析的分散型固相萃取-气相色谱-负化学离子源质谱方法。水产品及食用油经乙腈提取，4℃冷藏后，采用分散型固相萃取法净化，由气相色谱-负化学离子源质谱选择离子监测技术进行测定与确证，同位素内标法定量。在1～40μg / L 范围内氟乐灵农药的线性关系良好；方法定量限（LOQ）为0.02μg / kg；对鳗鱼、烤鳗、梭子蟹、小龙虾、猪油和橄榄油等6种复杂基质进行1.0、2.0和3.0μg / kg 等3个水平的添加回收试验，平均回收率均处于80％～100％之间，RSD≤10.3％；无干扰现象出现。该方法可作为水产品及食用油中氟乐灵残留检测的确证方法。
文摘The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate（Al2（SO4）3） and ammonium carbonate（（NH4）2CO3）. The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and ammonium nitrate, as well as multiplex catalysts （AT） on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al2O3 seeds and the mixture of α-Al2O3 and ammonium nitrate can lower the phase transformation temperature of α-Al2O3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al2O3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly.
文摘The heat transfer performance of the phase change materials used in free cooling and air conditioning applications is low,due to the poor thermal conductivity of the materials.The recent phenomenal advancement in nano technology provides an opportunity for an appreciable enhancement in the thermal conductivity of the phase change materials.In order to explore the possibilities of using nano technology for various applications,a detailed parametric study is carried out,to analyse the heat transfer enhancement potential with the thermal conductivity of the conventional phase change materials and nano enhanced phase change materials under various flow conditions of the heat transfer fluid.Initially,the theoretical equation,used to determine the time for outward cylindrical solidification of the phase change material,is validated with the experimental results.It is inferred from the parametric studies,that for paraffinic phase change materials with air as the heat transfer fluid,the first step should be to increase the heat transfer coefficient to the maximum extent,before making any attempt to increase the thermal conductivity of the phase change materials,with the addition of nano particles.When water is used as the phase change material,the addition of nano particles is recommended to achieve better heat transfer,when a liquid is used as the heat transfer fluid.
