Mesoporous molecular sieves Al-MCM-41 with n（SiO2）/n（Al2O3） ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction（XRD） patterns and the N2 physical sorption,the as-synthesized Al-MCM-41 exhibite...Mesoporous molecular sieves Al-MCM-41 with n（SiO2）/n（Al2O3） ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction（XRD） patterns and the N2 physical sorption,the as-synthesized Al-MCM-41 exhibited typical hexagonal structure,large surface areas and narrow pore distribution.The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with methyl tert-butyl-ether（MTBE） was then investigated.The effects of temperature,weight hourly space velocity（WHSV） and the feed ratio n（MTBE）/n（p-cresol） on p-cresol conversion and product selectivity were examined.The results showed that mesoporous HAl-MCM-41 molecular sieves（n（SiO2）/n（Al2O3） = 20） is an efficient catalyst with high activity,selectivity and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.展开更多
文摘Mesoporous molecular sieves Al-MCM-41 with n（SiO2）/n（Al2O3） ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction（XRD） patterns and the N2 physical sorption,the as-synthesized Al-MCM-41 exhibited typical hexagonal structure,large surface areas and narrow pore distribution.The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with methyl tert-butyl-ether（MTBE） was then investigated.The effects of temperature,weight hourly space velocity（WHSV） and the feed ratio n（MTBE）/n（p-cresol） on p-cresol conversion and product selectivity were examined.The results showed that mesoporous HAl-MCM-41 molecular sieves（n（SiO2）/n（Al2O3） = 20） is an efficient catalyst with high activity,selectivity and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.
基金supported by the National Natural Science Foundation of China(21776236,21676225)Natural Science Foundation of Hunan Province(2018JJ2384)+1 种基金the Scientific Research Foundation of Huaihua University(HHUY2017-08)Collaborative Innovation Centre of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization
