The identification of timber properties is important for safe application.Near Infrared Spectroscopy(NIRS)technology is widely-used because of its simplicity,efficiency,and positive environmental attributes.However,in...The identification of timber properties is important for safe application.Near Infrared Spectroscopy(NIRS)technology is widely-used because of its simplicity,efficiency,and positive environmental attributes.However,in its application,weak signals are extracted from complex,overlapping and changing information.This study focused on the stability of NIR modeling.The Orthogonal Partial Least Squares(OPLS)and Successive Projections Algorithm(SPA)eliminates noise and extracts effective spectra,and an ensemble learning method MIX-PLS,is applied to establish the model.The elastic modulus of timber is taken as an example,and 201 wood samples of three species,Xylosmacongesta(Lour.)Merr.,Acer pictum subsp.mono,and Betula pendula,samples were divided into three groups to investigate modelling performance.The results show that OPLS can preprocess the near-infrared spectroscopy information according to the target object in the face of the system error and reduce errors to minimum.SPA finally selects 13 spectral bands,simplifies the NIR spectral data and improves model accuracy.The Pearson's correlation coefficient of Calibration(Rc)and the Pearson's correlation coefficient of Prediction(Rp)of Mix Partial Least Squares(MIX-PLS)were 0.95 and 0.90,and Root Mean Square Error of Calibration(RMSEC)and Root Mean Square Error of Prediction(RMSEP)are 2.075 and 6.001,respectively,which shows the model has good generalization abilities.展开更多
为探究萌芽期大蒜挥发性物质的差异,采用电子鼻、捕集阱顶空-气质联用仪(Trap head space-gas chromatography-mass spectrometry,HS-Trap-GC-MS)结合正交偏最小二乘法判别分析(Orthogonal partial least squares discriminant analysis...为探究萌芽期大蒜挥发性物质的差异,采用电子鼻、捕集阱顶空-气质联用仪(Trap head space-gas chromatography-mass spectrometry,HS-Trap-GC-MS)结合正交偏最小二乘法判别分析(Orthogonal partial least squares discriminant analysis,OPLS-DA)、香气活度值、差异性热图、相关性分析分析大蒜萌芽在0、24、48、72、96 h挥发性物质的差异。电子鼻结合OPLS-DA建立预测模型其预测能力达96.00%。GC-MS分析表明:含硫化合物是不同萌芽期大蒜的主要共有挥发性物质,含硫化合物的相对含量随萌芽时间的延长而呈递减趋势,而种类呈现出递增趋势;二烯丙基二硫醚是样品在萌芽过程中含量降低最多的物质。二烯丙基四硫醚、烯丙硫醇是样品共有关键化合物。差异性热图分析显示:除共有物质含量差异外,硫化丙烯、己醛、叠氮二羧酸二叔丁酯、丙烯醇、6-甲基-2-庚炔、5-甲基噻二唑、2-亚乙基-1,3-二硫烷、2-丙-2-炔基磺酰基丙烷、2,5-二甲基噻吩、2,5-二甲基呋喃、1-戊烯-3-醇、1,3-二噻烷的缺失进一步加大了未萌芽和萌芽大蒜气味的差异。萌芽大蒜主要共有挥发性物质的种类随萌芽时间的延长呈现递增趋势。大蒜主要挥发性物质与电子鼻大多数传感器存在显著相关性。大蒜的气味强度会随萌芽时间的延长而逐步减弱。展开更多
基金supported financially by the China State Forestry Administration“948”projects(2015-4-52)Heilongjiang Natural Science Foundation(C2017005)。
文摘The identification of timber properties is important for safe application.Near Infrared Spectroscopy(NIRS)technology is widely-used because of its simplicity,efficiency,and positive environmental attributes.However,in its application,weak signals are extracted from complex,overlapping and changing information.This study focused on the stability of NIR modeling.The Orthogonal Partial Least Squares(OPLS)and Successive Projections Algorithm(SPA)eliminates noise and extracts effective spectra,and an ensemble learning method MIX-PLS,is applied to establish the model.The elastic modulus of timber is taken as an example,and 201 wood samples of three species,Xylosmacongesta(Lour.)Merr.,Acer pictum subsp.mono,and Betula pendula,samples were divided into three groups to investigate modelling performance.The results show that OPLS can preprocess the near-infrared spectroscopy information according to the target object in the face of the system error and reduce errors to minimum.SPA finally selects 13 spectral bands,simplifies the NIR spectral data and improves model accuracy.The Pearson's correlation coefficient of Calibration(Rc)and the Pearson's correlation coefficient of Prediction(Rp)of Mix Partial Least Squares(MIX-PLS)were 0.95 and 0.90,and Root Mean Square Error of Calibration(RMSEC)and Root Mean Square Error of Prediction(RMSEP)are 2.075 and 6.001,respectively,which shows the model has good generalization abilities.
