Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,t...Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,thermal management,displays,and camouflage.However,typical inorganic EC materials,such as tungsten oxides(WO_(3)),of⁃ten suffer from slow ion diffusion kinetics and limited optical contrast within the aqueous Zn^(2+)electrolyte because of the large size and strong Coulombic interactions of the Zn^(2+),which limits their wide applicability.Here,ordered WO_(3)nanowire films,constructed by a one-step grazing angle deposition method,is demonstrated to boost the response speed and optical contrast during EC phenomena.Compared with dense films,the ordered WO_(3)nanowire films with a porosity of 44.6%demonstrate anti-reflective property and excellent comprehensive EC performance,including fast response time(3.6 s and 1.2 s for coloring and bleaching,respectively),large optical contrast(66.6%at 700 nm)and high col⁃oration efficiency(64.3 cm^(2)·C^(-1)).A large-area prototype EC device(17 cm×12 cm)with fast color-switching is also successfully achieved.Mechanistic studies show that the improved performance is mainly due to the ordered porous nanowire structures,which provides direct electron transfer paths and sufficient interfacial contacts,thus simultaneously enhancing the electrochemical activity and fast redox kinetics.This study provides a simple and effective strategy to im⁃prove the performance of tungsten oxide-based aqueous zinc ion EC materials and devices.展开更多
为了客观评价地下空间开发地质适宜性并为评价工作提供一种新思路和参考,提出了一种基于三角模糊数的模糊层次分析法(fuzzy analytic hierarchy process based on triangular fuzzy numbers,FAHP)和优劣解距离法(technique for order pr...为了客观评价地下空间开发地质适宜性并为评价工作提供一种新思路和参考,提出了一种基于三角模糊数的模糊层次分析法(fuzzy analytic hierarchy process based on triangular fuzzy numbers,FAHP)和优劣解距离法(technique for order preference by similarity to ideal solution,TOPSIS)相结合的评价方法。通过地质调查研究构建基于土体工程地质性质、水文地质条件、不良地质作用、地形地貌等影响因素为主的层次分析关系模型。基于专家判别利用FAHP计算各评价因素的权重,以各评价指标层的分级临界值作为典型评价样本,利用TOPSIS法对适宜性等级进行非等分划分,基于区间值优化的TOPSIS法建立最终评价模型,通过ArcGIS的空间分析功能等确定每个评价单元适宜性等级。该方法与传统方法相比一定程度上减少了评价过程中专家评判的过多主观影响,评价过程更倾向于定量化,结果更为客观。利用该方法对无锡市区浅层地下空间开发地质适宜性进行评价,评价结果与实际工程经验相符,证明了该方法的有效性,因此该方法对地下空间开发适宜性评价工作具有一定借鉴意义。展开更多
Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometri...Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms,thus exhibiting superior electrocata-lytic activity and durability.However,quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging.Herein,a series of ternary Pt_(2)NiCo interme-tallic catalysts(o-Pt_(2)NiCo)with different ordering degree were synthesized by annealing temperature modulation.Among them,the o-Pt_(2)NiCo which annealed at 800℃for two hours exhibits the highest ordering degree and the optimal ORR ac-tivity,which the mass activity of o-Pt_(2)NiCo is 1.8 times and 2.8 times higher than that of disordered Pt_(2)NiCo alloy and Pt/C.Furthermore,the o-Pt_(2)NiCo still maintains 70.8%mass activity after 30,000 potential cycles.Additionally,the ORR activity test results for Pt_(2)NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity.This work provides a prospective design direction for ternary Pt-based electrocatalysts.展开更多
Geometry optimization of p-C_(6)H_(4)-connected cyclo[20]carbon(p-C_(6)H_(4)-C_(20))was carried out at M062X/6-311G(d,p)level,three kinds of bond orders(Mayer,Laplacian,and Wiberg),electron-hole distributions,localize...Geometry optimization of p-C_(6)H_(4)-connected cyclo[20]carbon(p-C_(6)H_(4)-C_(20))was carried out at M062X/6-311G(d,p)level,three kinds of bond orders(Mayer,Laplacian,and Wiberg),electron-hole distributions,localized orbital locators(LOL),and infrared(IR)spectrum were also performed at the same level.Based on TD-DFT M062X/6-311G(d,p)method,the first 20 excited states and ultraviolet(UV)spectra of p-C_(6)H_(4)-C_(20) were calculated.Calculation results of π-electron delocalization analyses prove thatπ-electron delocalization of p-C_(6)H_(4)-C_(20) is more likely to occur on shorter C-C bonds rather than longer C-C bonds,and inside/outside of the ring plane rather than above/below the ring plane.Two absorption peaks of p-C_(6)H_(4)-C_(20) locate at about 319 nm and 236 nm,respectively.展开更多
Hollow multi-shelled structure(HoMS)is the novel multifunctional structural system,which are con-structed with nanoparticles as structural units,featuring two or more shells,multiple interfaces,and numerous chan-nels ...Hollow multi-shelled structure(HoMS)is the novel multifunctional structural system,which are con-structed with nanoparticles as structural units,featuring two or more shells,multiple interfaces,and numerous chan-nels and demonstrating outstanding properties in energy conversion and mass transfer.In recent years,owing to the breakthroughs in synthetic methods,the diversity of composition and structure of HoMS has been greatly enriched,showing broad application prospects in energy,catalysis,environment and other fields.This review focuses on the research status of HoMS for catalytic applications.Firstly,the new synthesis method for HoMS,namely the sequen-tial templating approach,is introduced from both practical and theoretical perspectives.Then,it summarizes and discusses the structure-performance relationship between the shell structure and catalytic performance.The unique temporal-spatial ordering property of mass transport in HoMS and the major breakthroughs it brings in catalytic applications are discussed.Finally,it looks forward to the opportunities and challenges in the development of HoMS.展开更多
In this paper,a new technique is introduced to construct higher-order iterative methods for solving nonlinear systems.The order of convergence of some iterative methods can be improved by three at the cost of introduc...In this paper,a new technique is introduced to construct higher-order iterative methods for solving nonlinear systems.The order of convergence of some iterative methods can be improved by three at the cost of introducing only one additional evaluation of the function in each step.Furthermore,some new efficient methods with a higher-order of convergence are obtained by using only a single matrix inversion in each iteration.Analyses of convergence properties and computational efficiency of these new methods are made and testified by several numerical problems.By comparison,the new schemes are more efficient than the corresponding existing ones,particularly for large problem sizes.展开更多
In this paper,we establish common fixed point theorems for expansive map?pings on b-metric-like space and coincidence point for f-weakly isotone increasing mappings in partially ordered b-metric-like space.The main re...In this paper,we establish common fixed point theorems for expansive map?pings on b-metric-like space and coincidence point for f-weakly isotone increasing mappings in partially ordered b-metric-like space.The main results generalize and extend several well-known comparable results from the existing literature.Moreover,some examples are provided to illustrate the main results.展开更多
In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-...In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-band.Two separate EIOs are coupled through a specific single-gap coupling field supported by a designed gap waveguide with length Lg,which form the phase-locked EIOs based on the commonly-resonated system.As a whole system,the system has been focused on with mode analysis based on different single-gap coupling fields,mode hopping,which present the variation of phase difference between the two-beam-wave interactions when changing Lg.To demonstrate the effectiveness of the proposed circuit system in producing the phase locking,we conducted particle-in-cell(PIC)simulations to show that the interesting mode hopping occurs with the phase difference of O and r between the output signals from two output ports,corresponding to the excitation of the TMn mode with different n.Simulation results show that 1)the oscillator can deliver two times of the output power obtained from one single oscillator at 220 GHz,2)the two EIOs can still deliver output signals with phase difference of O and when the currents of the two beams are different or the fabrication errors of the two EIO cavities are taken into account.The proposed scheme is promising in extending to phase locking between multiple EIOs,and generating higher power at millimeter-wave and higher frequencies.展开更多
Higher-order band topology not only enriches our understanding of topological phases but also unveils pioneering lower-dimensional boundary states,which harbors substantial potential for next-generation device applica...Higher-order band topology not only enriches our understanding of topological phases but also unveils pioneering lower-dimensional boundary states,which harbors substantial potential for next-generation device applications.The distinct electronic configurations and tunable attributes of two-dimensional materials position them as a quintessential platform for the realization of second-order topological insulators(SOTIs).This article provides an overview of the research progress in SOTIs within the field of two-dimensional electronic materials,focusing on the characterization of higher-order topological properties and the numerous candidate materials proposed in theoretical studies.These endeavors not only enhance our understanding of higher-order topological states but also highlight potential material systems that could be experimentally realized.展开更多
In a high heat flux ablative environment,the surface temperature of aircraft rises rapidly,leading to traditional high thermal conductivity materials being ineffective at protecting internal metal components.In this s...In a high heat flux ablative environment,the surface temperature of aircraft rises rapidly,leading to traditional high thermal conductivity materials being ineffective at protecting internal metal components.In this study,continuous carbon fiber reinforced Li_(2)O-Al_(2)O_(3)-SiO_(2)(C_(f)/LAS)glass ceramic composites doped with SiC particles(SiC_(p))were prepared by slurry immersion winding and hot pressing sintering.Effect of matrix crystallinity on ablative properties of the composites under ultra-high heat flux was investigated.By utilizing heat absorption and low thermal conductivity characteristics associated with SiO_(2)gasification within composite materials,both surface and internal temperatures of these materials are effectively reduced,thereby ensuring the safe operation of aircraft and electronic devices.Results indicate that the average linear ablation rate of composites doped with 10%(in mass)of SiC_(p)significantly decreases at a heat flux of 20 MW/m^(2).Transmission electron microscope observation reveals that the doped glass matrix exhibits increased crystallinity,reduced internal stress,and minimized lattice distortion,thereby enhancing the composites’high-temperature performance.However,excessive SiC_(p)doping leads to reduced crystallinity and deteriorated ablation performance.Ultimately,the average linear ablation rate of C_(f)/LAS composites with 10%(in mass)SiC_(p)at 20 MW/m^(2)heat flux is comparable to that of commercial carbon/carbon composites,accompanied by providing lower thermal conductivity and higher bending strength.This novel high-performance C_(f)/LAS composite is cost-effective,short-cycled,and suitable for mass production,offering promising potential for widespread application in ablation-resistant components of hypersonic vehicles.展开更多
The precise characterization of hypersonic glide vehicle(HGV) maneuver laws in complex flight scenarios still faces challenges. Non-stationary changes in flight state due to abrupt changes in maneuver modes place high...The precise characterization of hypersonic glide vehicle(HGV) maneuver laws in complex flight scenarios still faces challenges. Non-stationary changes in flight state due to abrupt changes in maneuver modes place high demands on the accuracy of modeling methods. To address this issue, a novel maneuver laws modeling and analysis method based on higher order multi-resolution dynamic mode decomposition(HMDMD) is proposed in this work. A joint time-space-frequency decomposition of the vehicle's state sequence in the complex flight scenario is achieved with the higher order Koopman assumption and standard multi-resolution dynamic mode decomposition, and an approximate dynamic model is established. The maneuver laws can be reconstructed and analyzed with extracted multi-scale spatiotemporal modes with clear physical meaning. Based on the dynamic model of HGV, two flight scenarios are established with constant angle of attack and complex maneuver laws, respectively. Simulation results demonstrate that the maneuver laws obtained using the HMDMD method are highly consistent with those derived from the real dynamic model, the modeling accuracy is better than other common modeling methods, and the method has strong interpretability.展开更多
基金Supported by Jilin Provincial Scientific and Technological Development Program(20230508109RC,20230201051GX,20220201091GX)National Natural Science Foundation of China(62035013,61275235)。
文摘Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,thermal management,displays,and camouflage.However,typical inorganic EC materials,such as tungsten oxides(WO_(3)),of⁃ten suffer from slow ion diffusion kinetics and limited optical contrast within the aqueous Zn^(2+)electrolyte because of the large size and strong Coulombic interactions of the Zn^(2+),which limits their wide applicability.Here,ordered WO_(3)nanowire films,constructed by a one-step grazing angle deposition method,is demonstrated to boost the response speed and optical contrast during EC phenomena.Compared with dense films,the ordered WO_(3)nanowire films with a porosity of 44.6%demonstrate anti-reflective property and excellent comprehensive EC performance,including fast response time(3.6 s and 1.2 s for coloring and bleaching,respectively),large optical contrast(66.6%at 700 nm)and high col⁃oration efficiency(64.3 cm^(2)·C^(-1)).A large-area prototype EC device(17 cm×12 cm)with fast color-switching is also successfully achieved.Mechanistic studies show that the improved performance is mainly due to the ordered porous nanowire structures,which provides direct electron transfer paths and sufficient interfacial contacts,thus simultaneously enhancing the electrochemical activity and fast redox kinetics.This study provides a simple and effective strategy to im⁃prove the performance of tungsten oxide-based aqueous zinc ion EC materials and devices.
文摘为了客观评价地下空间开发地质适宜性并为评价工作提供一种新思路和参考,提出了一种基于三角模糊数的模糊层次分析法(fuzzy analytic hierarchy process based on triangular fuzzy numbers,FAHP)和优劣解距离法(technique for order preference by similarity to ideal solution,TOPSIS)相结合的评价方法。通过地质调查研究构建基于土体工程地质性质、水文地质条件、不良地质作用、地形地貌等影响因素为主的层次分析关系模型。基于专家判别利用FAHP计算各评价因素的权重,以各评价指标层的分级临界值作为典型评价样本,利用TOPSIS法对适宜性等级进行非等分划分,基于区间值优化的TOPSIS法建立最终评价模型,通过ArcGIS的空间分析功能等确定每个评价单元适宜性等级。该方法与传统方法相比一定程度上减少了评价过程中专家评判的过多主观影响,评价过程更倾向于定量化,结果更为客观。利用该方法对无锡市区浅层地下空间开发地质适宜性进行评价,评价结果与实际工程经验相符,证明了该方法的有效性,因此该方法对地下空间开发适宜性评价工作具有一定借鉴意义。
基金supported by the National Natural Science Foundation(22279036)the Innovation and Talent Recruitment Base of New Energy Chemistry and Device(B21003).
文摘Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms,thus exhibiting superior electrocata-lytic activity and durability.However,quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging.Herein,a series of ternary Pt_(2)NiCo interme-tallic catalysts(o-Pt_(2)NiCo)with different ordering degree were synthesized by annealing temperature modulation.Among them,the o-Pt_(2)NiCo which annealed at 800℃for two hours exhibits the highest ordering degree and the optimal ORR ac-tivity,which the mass activity of o-Pt_(2)NiCo is 1.8 times and 2.8 times higher than that of disordered Pt_(2)NiCo alloy and Pt/C.Furthermore,the o-Pt_(2)NiCo still maintains 70.8%mass activity after 30,000 potential cycles.Additionally,the ORR activity test results for Pt_(2)NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity.This work provides a prospective design direction for ternary Pt-based electrocatalysts.
文摘Geometry optimization of p-C_(6)H_(4)-connected cyclo[20]carbon(p-C_(6)H_(4)-C_(20))was carried out at M062X/6-311G(d,p)level,three kinds of bond orders(Mayer,Laplacian,and Wiberg),electron-hole distributions,localized orbital locators(LOL),and infrared(IR)spectrum were also performed at the same level.Based on TD-DFT M062X/6-311G(d,p)method,the first 20 excited states and ultraviolet(UV)spectra of p-C_(6)H_(4)-C_(20) were calculated.Calculation results of π-electron delocalization analyses prove thatπ-electron delocalization of p-C_(6)H_(4)-C_(20) is more likely to occur on shorter C-C bonds rather than longer C-C bonds,and inside/outside of the ring plane rather than above/below the ring plane.Two absorption peaks of p-C_(6)H_(4)-C_(20) locate at about 319 nm and 236 nm,respectively.
文摘Hollow multi-shelled structure(HoMS)is the novel multifunctional structural system,which are con-structed with nanoparticles as structural units,featuring two or more shells,multiple interfaces,and numerous chan-nels and demonstrating outstanding properties in energy conversion and mass transfer.In recent years,owing to the breakthroughs in synthetic methods,the diversity of composition and structure of HoMS has been greatly enriched,showing broad application prospects in energy,catalysis,environment and other fields.This review focuses on the research status of HoMS for catalytic applications.Firstly,the new synthesis method for HoMS,namely the sequen-tial templating approach,is introduced from both practical and theoretical perspectives.Then,it summarizes and discusses the structure-performance relationship between the shell structure and catalytic performance.The unique temporal-spatial ordering property of mass transport in HoMS and the major breakthroughs it brings in catalytic applications are discussed.Finally,it looks forward to the opportunities and challenges in the development of HoMS.
基金Supported by the National Natural Science Foundation of China(12061048)NSF of Jiangxi Province(20232BAB201026,20232BAB201018)。
文摘In this paper,a new technique is introduced to construct higher-order iterative methods for solving nonlinear systems.The order of convergence of some iterative methods can be improved by three at the cost of introducing only one additional evaluation of the function in each step.Furthermore,some new efficient methods with a higher-order of convergence are obtained by using only a single matrix inversion in each iteration.Analyses of convergence properties and computational efficiency of these new methods are made and testified by several numerical problems.By comparison,the new schemes are more efficient than the corresponding existing ones,particularly for large problem sizes.
基金Supported by the National Natural Science Foundation of China(12001249)the Natural Science Foundation of Jiangxi Province(20232BAB211004)the Educational Commission Science Programm of Jiangxi Province(GJJ2200523)。
文摘In this paper,we establish common fixed point theorems for expansive map?pings on b-metric-like space and coincidence point for f-weakly isotone increasing mappings in partially ordered b-metric-like space.The main results generalize and extend several well-known comparable results from the existing literature.Moreover,some examples are provided to illustrate the main results.
基金Supported in part by the National Natural Science Foundation of China(62401125)the Natural Science Foundation of Sichuan Province(2023NSFSC1376)the Fundamental Research Funds for the Central Universities(ZYGX2024J008)。
文摘In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-band.Two separate EIOs are coupled through a specific single-gap coupling field supported by a designed gap waveguide with length Lg,which form the phase-locked EIOs based on the commonly-resonated system.As a whole system,the system has been focused on with mode analysis based on different single-gap coupling fields,mode hopping,which present the variation of phase difference between the two-beam-wave interactions when changing Lg.To demonstrate the effectiveness of the proposed circuit system in producing the phase locking,we conducted particle-in-cell(PIC)simulations to show that the interesting mode hopping occurs with the phase difference of O and r between the output signals from two output ports,corresponding to the excitation of the TMn mode with different n.Simulation results show that 1)the oscillator can deliver two times of the output power obtained from one single oscillator at 220 GHz,2)the two EIOs can still deliver output signals with phase difference of O and when the currents of the two beams are different or the fabrication errors of the two EIO cavities are taken into account.The proposed scheme is promising in extending to phase locking between multiple EIOs,and generating higher power at millimeter-wave and higher frequencies.
基金supported by the National Natu-ral Science Foundation of China(Grants No.12174220 and No.12074217)the Shandong Provincial Science Foundation for Excellent Young Scholars(Grant No.ZR2023YQ001)+1 种基金the Taishan Young Scholar Program of Shandong Provincethe Qilu Young Scholar Pro-gram of Shandong University.
文摘Higher-order band topology not only enriches our understanding of topological phases but also unveils pioneering lower-dimensional boundary states,which harbors substantial potential for next-generation device applications.The distinct electronic configurations and tunable attributes of two-dimensional materials position them as a quintessential platform for the realization of second-order topological insulators(SOTIs).This article provides an overview of the research progress in SOTIs within the field of two-dimensional electronic materials,focusing on the characterization of higher-order topological properties and the numerous candidate materials proposed in theoretical studies.These endeavors not only enhance our understanding of higher-order topological states but also highlight potential material systems that could be experimentally realized.
基金National Natural Science Foundation of China(U23A6014,52103357)。
文摘In a high heat flux ablative environment,the surface temperature of aircraft rises rapidly,leading to traditional high thermal conductivity materials being ineffective at protecting internal metal components.In this study,continuous carbon fiber reinforced Li_(2)O-Al_(2)O_(3)-SiO_(2)(C_(f)/LAS)glass ceramic composites doped with SiC particles(SiC_(p))were prepared by slurry immersion winding and hot pressing sintering.Effect of matrix crystallinity on ablative properties of the composites under ultra-high heat flux was investigated.By utilizing heat absorption and low thermal conductivity characteristics associated with SiO_(2)gasification within composite materials,both surface and internal temperatures of these materials are effectively reduced,thereby ensuring the safe operation of aircraft and electronic devices.Results indicate that the average linear ablation rate of composites doped with 10%(in mass)of SiC_(p)significantly decreases at a heat flux of 20 MW/m^(2).Transmission electron microscope observation reveals that the doped glass matrix exhibits increased crystallinity,reduced internal stress,and minimized lattice distortion,thereby enhancing the composites’high-temperature performance.However,excessive SiC_(p)doping leads to reduced crystallinity and deteriorated ablation performance.Ultimately,the average linear ablation rate of C_(f)/LAS composites with 10%(in mass)SiC_(p)at 20 MW/m^(2)heat flux is comparable to that of commercial carbon/carbon composites,accompanied by providing lower thermal conductivity and higher bending strength.This novel high-performance C_(f)/LAS composite is cost-effective,short-cycled,and suitable for mass production,offering promising potential for widespread application in ablation-resistant components of hypersonic vehicles.
基金supported by the National Natural Science Foundation of China (Grant No. 12302056)the Postdoctoral Fellowship Program of CPSF:GZC20233445。
文摘The precise characterization of hypersonic glide vehicle(HGV) maneuver laws in complex flight scenarios still faces challenges. Non-stationary changes in flight state due to abrupt changes in maneuver modes place high demands on the accuracy of modeling methods. To address this issue, a novel maneuver laws modeling and analysis method based on higher order multi-resolution dynamic mode decomposition(HMDMD) is proposed in this work. A joint time-space-frequency decomposition of the vehicle's state sequence in the complex flight scenario is achieved with the higher order Koopman assumption and standard multi-resolution dynamic mode decomposition, and an approximate dynamic model is established. The maneuver laws can be reconstructed and analyzed with extracted multi-scale spatiotemporal modes with clear physical meaning. Based on the dynamic model of HGV, two flight scenarios are established with constant angle of attack and complex maneuver laws, respectively. Simulation results demonstrate that the maneuver laws obtained using the HMDMD method are highly consistent with those derived from the real dynamic model, the modeling accuracy is better than other common modeling methods, and the method has strong interpretability.
