Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices stability.However,the strategies of suppressing photoinduced ph...Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices stability.However,the strategies of suppressing photoinduced phase segregation and related mechanisms have not been fully disclosed.Here,we report a new passivation agent 4-aminotetrahydrothiopyran hydrochloride(4-ATpHCl)with multifunctional groups for the interface treatment of a 1.77-eV wide-bandgap perovskite film.4-ATpH^(+)impeded halogen ion migration by anchoring on the perovskite surface,leading to the inhibition of phase segregation and thus the passivation of defects,which is ascribed to the interaction of 4-ATpH^(+)with perovskite and the formation of low-dimensional perovskites.Finally,the champion device achieved an efficiency of 19.32%with an open-circuit voltage(V_(OC))of 1.314 V and a fill factor of 83.32%.Moreover,4-ATpHCl modified device exhibited significant improved stability as compared with control one.The target device maintained 80%of its initial efficiency after 519 h of maximum power output(MPP)tracking under 1 sun illumination,however,the control device showed a rapid decrease in efficiency after 267 h.Finally,an efficiency of 27.38%of the champion 4-terminal all-perovskite tandem solar cell was achieved by mechanically stacking this wide-bandgap top subcell with a 1.25-eV low-bandgap perovskite bottom subcell.展开更多
Traditional single-satellite passive localization algorithms are influenced by frequency and angle measurement accuracies,resulting in error estimation of emitter position on the order of kilometers.Subsequently,a sin...Traditional single-satellite passive localization algorithms are influenced by frequency and angle measurement accuracies,resulting in error estimation of emitter position on the order of kilometers.Subsequently,a single-satellite localization algorithm based on passive synthetic aper-ture(PSA)was introduced,enabling high-precision positioning.However,its estimation of azimuth and range distance is considerably affected by the residual frequency offset(RFO)of uncoopera-tive system transceivers.Furthermore,it requires data containing a satellite flying over the radia-tion source for RFO search.After estimating the RFO,an accurate estimation of azimuth and range distance can be carried out,which is difficult to achieve in practical situations.An LFM radar source passive localization algorithm based on range migration is proposed to address the dif-ficulty in estimating frequency offset.The algorithm first provides a rough estimate of the pulse repetition time(PRT).It processes intercepted signals through range compression,range interpola-tion,and polynomial fitting to obtain range migration observations.Subsequently,it uses the changing information of range migration and an accurate PRT to formulate a system of nonlinear equations,obtaining the emitter position and a more accurate PRT through a two-step localization algorithm.Frequency offset only induces a fixed offset in range migration,which does not affect the changing information.This algorithm can also achieve high-precision localization in squint scenar-ios.Finally,the effectiveness of this algorithm is verified through simulations.展开更多
Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust...Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium,and the initial He concentration and thermal driving mechanism of mantle-derived helium,in the Ledong Diapir area,the Yinggehai Basin,in order to understand the genetic source,migration and accumulation mechanisms of helium under deep thermal fluid activities.The average content of mantle-derived He is only 0.0014%,the ^(3)He/^(4)He value is(0.002–2.190)×10^(−6),and the R/Ra value ranges from 0.01 to 1.52,indicating the contribution of mantle-derived He is 0.09%–19.84%,while the proportion of crust-derived helium can reach over 80%.Quantitative analysis indicates that the crust-derived helium is dominated by external input,followed by in-situ production,in the Ledong diapir area.The crust-derived helium exhibits an in-situ 4 He yield rate of(7.66–7.95)×10^(−13)cm^(3)/(a·g),an in-situ 4 He yield of(4.10–4.25)×10^(−4)cm^(3)/g,and an external 4 He influx of(5.84–9.06)×10^(−2)cm^(3)/g.These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions.The ratio of initial mole volume of 3 He to enthalpy(W)is(0.004–0.018)×10^(−11) cm^(3)/J,and the heat contribution from the deep mantle(X_(M))accounts for 7.63%–36.18%,indicating that deep hot fluid activities drive the migration of mantle-derived 3 He.The primary helium migration depends on advection,while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation.From deep to shallow layers,the CO_(2/3) He value rises from 1.34×10^(9)to 486×10^(9),indicating large amount of CO_(2)has escaped.Under the influence of deep thermal fluid,helium migration and accumulation mechanisms include:deep heat driven diffusion,advection release,vertical hydrothermal degassing,shallow lateral migration,accumulation in traps far from faults,partial pressure balance and sealing capability.展开更多
Cementitious gangue-fly ash backfill(CGB)is used as a green mining technology worldwide.However,under the coupled effects of geological stress and groundwater,the metal elements in the CGB tend to migrate into nearby ...Cementitious gangue-fly ash backfill(CGB)is used as a green mining technology worldwide.However,under the coupled effects of geological stress and groundwater,the metal elements in the CGB tend to migrate into nearby strata,which can consequently result in pollution of the groundwater environment.In this paper,the influence of initial pH and stress damage on the migration behavior of metal elements in CGB is quantitatively studied through the multi-physical field coupling model of stress-permeability-con centration.The enhanced Nemerow index evaluation method is used to comprehensively evaluate the impact of these metal elements migration behaviors on the groundwater environment.The research results show that:(1)When the stress damage of the CGB increases from 0.76 to 0.95,the Darcy velocity at the bottom of the CGB first increases,then decreases,and finally stabilizes at 2.01×10^(-7)m/s.The longest time to reach the maximum Darcy velocity is 3 a.(2)When the damage of the CGB is 0.95,the farthest migration distances of Al,Cr,Mn,Fe,Ba,and Pb are 40.5,34.0,29.8,32.9,38.8 and 32.1 m,respectively.(3)The alkaline environment stimulates the migration of Al,Cr,Fe,Mn,and Pb,whereas Ba migrates farther under acidic conditions.The farthest migration distance of Ba is 31.6 m under pH 3.(4)The enhanced Nemerow index indicates that when stress damage increases from 0.76 to 0.95,the areas with poor water quality increase from 0 to 1.71%,and no area is classified as very poor grade.When the initial pH changes from 3 to 11,100%of the region is classified as fair or above.The initial pH of the CGB has a relatively slight influence on the groundwater environment.This study provides experimental data and theoretical basis for the environmental evaluation of CGB.展开更多
Offshore carbon dioxide(CO_(2)) storage is an effective method for reducing greenhouse gas emissions. However, when using traditional seismic wave methods to monitor the migration of sequestration CO_(2) plumes, the c...Offshore carbon dioxide(CO_(2)) storage is an effective method for reducing greenhouse gas emissions. However, when using traditional seismic wave methods to monitor the migration of sequestration CO_(2) plumes, the characteristics of wave velocity changes tend to become insignificant beyond a certain limit. In contrast, the controllable source electromagnetic method(CSEM) remains highly sensitive to resistivity changes. By simulating different CO_(2) plume migration conditions, we established the relevant models and calculated the corresponding electric field response characteristic curves, allowing us to analyze the CSEM's ability to monitor CO_(2) plumes. We considered potential scenarios for the migration and diffusion of offshore CO_(2) storage, including various burial depths, vertical extension diffusion, lateral extension diffusion,multiple combinations of lateral intervals, and electric field components. We also obtained differences in resistivity inversion imaging obtained by CSEM to evaluate its feasibility in monitoring and to analyze all the electric field(Ex, Ey, and Ez) response characteristics. CSEM has great potential in monitoring CO_(2) plume migration in offshore saltwater reservoirs due to its high sensitivity and accuracy. Furthermore, changes in electromagnetic field response reflect the transport status of CO_(2) plumes, providing an important basis for monitoring and evaluating CO_(2)transport behavior during storage processes.展开更多
The geological storage of carbon dioxide(CO_(2)) is a crucial technology for mitigating climate change. Offshore deep saline aquifers have elicited increased attention due to their remarkable potential for storing CO_...The geological storage of carbon dioxide(CO_(2)) is a crucial technology for mitigating climate change. Offshore deep saline aquifers have elicited increased attention due to their remarkable potential for storing CO_(2). During long-term storage, CO_(2) migration in a deep saline aquifer needs special attention to prevent it from reaching risk points and leading to security issues. In this paper, a mechanism model is established according to the geological characteristics of saline aquifers in an offshore sedimentary basin in China. The CO_(2) migration over 100 years is simulated considering geological changes such as permeability, dip angle, thickness, and salinity. The effects of injection conditions on the CO_(2) migration range are also investigated. Results reveal that the migration range of CO_(2) in the injection period exceeds 70%, even if the postinjection period's duration is five times longer than that of the injection period. As the values of the above geological parameters increase, the migration range of CO_(2) increases, and permeability has a particularly substantial influence. Moreover, the influences of injection rate and well type are considerable. At high injection rates, CO_(2) has a greater likelihood of displacing brine in a piston-like scheme. CO_(2) injected by long horizontal wells migrates farther compared with that injected by vertical wells. In general, the plane migration range is within 3 000 m, although variations in the reservoir and injection parameters of the studied offshore saline aquifers are considered. This paper can offer references for the site selection and injection well deployment of CO_(2) saline aquifer storage. According to the studied offshore aquifers, a distance of at least 3 000 m from potential leakage points, such as spill points, active faults, and old abandoned wells, must be maintained.展开更多
Recently,researchers have proposed an emitter localization method based on passive synthetic aperture.However,the unknown residual frequency offset(RFO)between the transmit-ter and the receiver causes the received Dop...Recently,researchers have proposed an emitter localization method based on passive synthetic aperture.However,the unknown residual frequency offset(RFO)between the transmit-ter and the receiver causes the received Doppler signal to shift,which affects the localization accu-racy.To solve this issue,this paper proposes a RFO estimation method based on range migration fitting.Due to the high frequency modulation slope of the linear frequency modulation(LFM)-mod-ulation radar signal,it is not affected by RFO in range compression.Therefore,the azimuth time can be estimated by fitting the peak value position of the pulse compression in range direction.Then,the matched filters are designed under different RFOs.When the zero-Doppler time obtained by the matched filters is consistent with the estimated azimuth time,the given RFO is the real RFO between the transceivers.The simulation results show that the estimation error of azimuth distance does not exceed 20 m when the received signal duration is not less than 3 s,the pulse repe-tition frequency(PRF)of the transmitter radar signal is not less than 1 kHz,the range detection is not larger than 1000 km,and the signal noise ratio(SNR)is not less than-5 dB.展开更多
Increasing data indicate that cancer cell migration is regulated by extracellular matrixes and their surrounding biochemical microenvironment,playing a crucial role in pathological processes such as tumor invasion and...Increasing data indicate that cancer cell migration is regulated by extracellular matrixes and their surrounding biochemical microenvironment,playing a crucial role in pathological processes such as tumor invasion and metastasis.However,conventional two-dimensional cell culture and animal models have limitations in studying the influence of tumor microenvironment on cancer cell migration.Fortunately,the further development of microfluidic technology has provided solutions for the study of such questions.We utilize microfluidic chip to build a random collagen fiber microenvironment(RFM)model and an oriented collagen fiber microenvironment(OFM)model that resemble early stage and late stage breast cancer microenvironments,respectively.By combining cell culture,biochemical concentration gradient construction,and microscopic imaging techniques,we investigate the impact of different collagen fiber biochemical microenvironments on the migration of breast cancer MDA-MB-231-RFP cells.The results show that MDA-MB-231-RFP cells migrate further in the OFM model compared to the RFM model,with significant differences observed.Furthermore,we establish concentration gradients of the anticancer drug paclitaxel in both the RFM and OFM models and find that paclitaxel significantly inhibits the migration of MDA-MB-231-RFP cells in the RFM model,with stronger inhibition on the high concentration side compared to the low concentration side.However,the inhibitory effect of paclitaxel on the migration of MDA-MB-231-RFP cells in the OFM model is weak.These findings suggest that the oriented collagen fiber microenvironment resembling the late-stage tumor microenvironment is more favorable for cancer cell migration and that the effectiveness of anticancer drugs is diminished.The RFM and OFM models constructed in this study not only provide a platform for studying the mechanism of cancer development,but also serve as a tool for the initial measurement of drug screening.展开更多
Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical char...Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical characteristics of light hydrocarbons on the migration features,dissolution and escape of natural gas from the Dongsheng gas field in the Ordos Basin is revealed,and the effect of migration on specific light hydrocarbon indexes is further discussed.The study indicates that,natural gas from the Lower Shihezi Formation(Pix)in the Dongsheng gas field displays higher iso-C5-7contents than n-C5-7contents,and the C6-7light hydrocarbons are composed of paraffins with extremely low aromatic contents(<0.4%),whereas the C7light hydrocarbons are dominated by methylcyclohexane,suggesting the characteristics of coal-derived gas with the influence by secondary alterations such as dissolution.The natural gas from the Dongsheng gas field has experienced free-phase migration from south to north and different degrees of dissolution after charging,and the gas in the Shiguhao area to the north of the Borjianghaizi fault has experienced apparent diffusion loss after accumulation.Long-distance migration in free phase results in the decrease of the relative contents of the methylcyclohexane in C7 light hydrocarbons and the toluene/n-heptane ratio,as well as the increase of the n-heptane/methylcyclohexane ratio and heptane values.The dissolution causes the increase of isoheptane values of the light hydrocarbons,whereas the diffusion loss of natural gas in the Shiguhao area results in the increase of n-C5-7contents compared to the iso-C5-7contents.展开更多
Compared with the transverse isotropic(TI)medium,the orthorhombic anisotropic medium has both horizontal and vertical symmetry axes and it can be approximated as a set of vertical fissures developed in a group of hori...Compared with the transverse isotropic(TI)medium,the orthorhombic anisotropic medium has both horizontal and vertical symmetry axes and it can be approximated as a set of vertical fissures developed in a group of horizontal strata.Although the full-elastic orthorhombic anisotropic wave equation can accurately simulate seismic wave propagation in the underground media,a huge computational cost is required in seismic modeling,migration,and inversion.The conventional coupled pseudo-acoustic wave equations based on acoustic approximation can be used to significantly reduce the cost of calculation.However,these equations usually suffer from unwanted shear wave artifacts during wave propagation,and the presence of these artifacts can significantly degrade the imaging quality.To solve these problems,we derived a new pure P-wave equation for orthorhombic media that eliminates shear wave artifacts while compromising computational efficiency and accuracy.In addition,the derived equation involves pseudo-differential operators and it must be solved by 3D FFT algorithms.In order to reduce the number of 3D FFT,we utilized the finite difference and pseudo-spectral methods to conduct 3D forward modeling.Furthermore,we simplified the equation by using elliptic approximation and implemented 3D reverse-time migration(RTM).Forward modeling tests on several homogeneous and heterogeneous models confirm that the accuracy of the new equation is better than that of conventional methods.3D RTM imaging tests on three-layer and SEG/EAGE 3D salt models confirm that the ORT media have better imaging quality.展开更多
With the advancements of software defined network(SDN)and network function virtualization(NFV),service function chain(SFC)placement becomes a crucial enabler for flexible resource scheduling in low earth orbit(LEO)sat...With the advancements of software defined network(SDN)and network function virtualization(NFV),service function chain(SFC)placement becomes a crucial enabler for flexible resource scheduling in low earth orbit(LEO)satellite networks.While due to the scarcity of bandwidth resources and dynamic topology of LEO satellites,the static SFC placement schemes may cause performance degradation,resource waste and even service failure.In this paper,we consider migration and establish an online migration model,especially considering the dynamic topology.Given the scarcity of bandwidth resources,the model aims to maximize the total number of accepted SFCs while incurring as little bandwidth cost of SFC transmission and migration as possible.Due to its NP-hardness,we propose a heuristic minimized dynamic SFC migration(MDSM)algorithm that only triggers the migration procedure when new SFCs are rejected.Simulation results demonstrate that MDSM achieves a performance close to the upper bound with lower complexity.展开更多
A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass ...A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass (Mr), conformation parameter (Rc) of peptides and electrophoretic condition parameter(A). The conformation parameter is introduced to characterize multifarious shapes owing to the complex conlormation and the various kinds of macromolecules, where Rc≥1/3. The parameters A and Rc can be obtained from experimental data. The times of migration of the nine standard peptides were measured in pH 2.5buffer on different electrophoretic conditions in CZE. The experimental results agreed well with the theoretical prediction.展开更多
The aim of this paper is to review the major points of contention concerning secondary petroleum migration, to discuss the nature and primary controls of the positions of petroleum migration pathways in sedimentary ba...The aim of this paper is to review the major points of contention concerning secondary petroleum migration, to discuss the nature and primary controls of the positions of petroleum migration pathways in sedimentary basins, and to illustrate the importance of preferential petroleum migration pathways for the formation of large oil/gas fields away from generative kitchens. There is competition between the driving force （buoyancy） and the restraining force （capillary pressure controlled largely by permeability contrast） in controlling the positions of petroleum migration pathways in heterogeneous carrier beds. At a large scale, there is a critical angle of dip of the carrier beds which determines the relative importance of structural morphology or permeability contrasts in controlling the positions of petroleum migration pathways in heterogeneous carrier beds. Maximum-driving-force-controlled migration pathways occur in carrier beds with an angle of dip greater than the critical dip and the positions of petroleum migration pathways are controlled mainly by the morphology of the sealing surfaces. Minimum-restraining-force-determined migration pathways occur in carrier beds with an angle of dip smaller than the critical angle where permeability contrasts would exert a more important influence on the positions of petroleum migration pathways. Preferential petroleum migration pathways （PPMP）, defined as very restricted portions of carrier-beds that focus or concentrate petroleum from a large area of the generative kitchen, determine the distribution of oil and gas in sedimentary basins. The focusing of petroleum originating from a large area of the generative kitchens into restricted channels seems to be essential not only for long-range petroleum migration in hydrostatic conditions, but also for the formation of large oil or gas fields. Regions may miss out on petroleum migration because of its three-dimensional behavior, and two-dimensional migration modeling may be misleading in predicting petroleum occurrences in certain circumstances.展开更多
Simultaneous-source acquisition has been recog- nized as an economic and efficient acquisition method, but the direct imaging of the simultaneous-source data produces migration artifacts because of the interference of...Simultaneous-source acquisition has been recog- nized as an economic and efficient acquisition method, but the direct imaging of the simultaneous-source data produces migration artifacts because of the interference of adjacent sources. To overcome this problem, we propose the regularized least-squares reverse time migration method （RLSRTM） using the singular spectrum analysis technique that imposes sparseness constraints on the inverted model. Additionally, the difference spectrum theory of singular values is presented so that RLSRTM can be implemented adaptively to eliminate the migration artifacts. With numerical tests on a fiat layer model and a Marmousi model, we validate the superior imaging quality, efficiency and convergence of RLSRTM compared with LSRTM when dealing with simultaneoussource data, incomplete data and noisy data.展开更多
Gas extraction practice has been proven for the clear majority of coal mines in China to be unfavorable using drill holes in the coal seam. Rather, mining-induced fractures in the goaf should be utilized for gas extra...Gas extraction practice has been proven for the clear majority of coal mines in China to be unfavorable using drill holes in the coal seam. Rather, mining-induced fractures in the goaf should be utilized for gas extraction. To study gas migration in mining-induced fractures, one mining face of 10 th Mine in Pingdingshan Coalmine Group in Henan, China, has been selected as the case study for this work. By establishing the mathematical model of gas migration under the influence of coal seam mining, discrete element software UDEC and Multiphysics software COMSOL are employed to model gas migration in mining-induced fractures above the goaf. The results show that as the working face advances, the goaf overburden gradually forms a mining-induced fracture network in the shape of a trapezoid, the size of which increases with the distance of coal face advance. Compared with gas migration in the overburden matrix, the gas flow in the fracture network due to mining is far greater. The largest mining-induced fracture is located at the upper end of the trapezoidal zone, which results in the largest gas flux in the network. When drilling for gas extraction in a mining-induced fracture field, the gas concentration is reduced in the whole region during the process of gas drainage, and the rate of gas concentration drops faster in the fractured zone. It is shown that with gas drainage, the gas flow velocity in the mininginduced fracture network is faster.展开更多
The lower Cambrian Niutitang Formation hydrocarbon source rocks at the Dingshan- Lintanchang structure in the southeast Sichuan Basin were of medium-good quality with two excellent hydrocarbon-generating centers devel...The lower Cambrian Niutitang Formation hydrocarbon source rocks at the Dingshan- Lintanchang structure in the southeast Sichuan Basin were of medium-good quality with two excellent hydrocarbon-generating centers developed in the periphery areas, with a possibility of forming a medium to large-sized oil-gas field. Good reservoir rocks were the upper Sinian （Dengying Formation） dolomites. The mudstone in the lower Cambrian Niutitang Formation with a good sealing capacity was the cap rock. The widely occurring bitumen in the Dengying Formation indicates that a paleo oil pool was once formed in the study area. The first stage of paleo oil pool formation was maturation of the lower Cambrian source rocks during the late Ordovician. Hydrocarbon generation from the lower Cambrian source rocks stopped due to the Devonian-Carboniferous uplifting. The lower Cambrian source rocks then restarted generation of large quantities of hydrocarbons after deposition of the middle Permian sediments. This was the second stage of the paleo oil pool formation. The oil in the paleo oil pool began to crack during the late Triassic and a paleo gas pool was formed. This paleo gas pool was destroyed during the Yanshan-Himalayan folding, uplifting and denudation. Bitumen can be widely seen in the Dengying Formation in wells and outcrops in the Sichuan Basin and its periphery areas. This provides strong evidence that the Dengying Formation in the Sichuan Basin and its periphery areas was once an ultra-large structural-lithologic oil-gas field, which was damaged during the Yanshan-Himalayan period.展开更多
Understanding hydrocarbon migration and accumulation mechanisms is one of the key scientif ic problems that should be solved for effective hydrocarbon exploration in the superimposed basins developed in northwest Chin...Understanding hydrocarbon migration and accumulation mechanisms is one of the key scientif ic problems that should be solved for effective hydrocarbon exploration in the superimposed basins developed in northwest China. The northwest striking No.1 slope break zone, which is a representative of superimposed basins in the Tarim Basin, can be divided into five parts due to the intersection of the northeast strike-slip faults. Controlled by the tectonic framework, the types and properties of reservoirs and the hydrocarbon compositions can also be divided into five parts from east to west. Anomalies of all the parameters were found on the fault intersection zone and weakened up-dip along the structural ridge away from it. Thus, it can be inferred that the intersection zone is the hydrocarbon charging position. This new conclusion differs greatly from the traditional viewpoint, which believes that the hydrocarbon migrates and accumulates along the whole plane of the No.1 slope break zone. The viewpoint is further supported by the evidence from the theory of main pathway systems, obvious improvement of the reservoir quality （2-3 orders of magnitude at the intersection zone） and the formation mechanisms of the fault intersection zone. Differential hydrocarbon migration and entrapment exists in and around the strike- slip faults. This is controlled by the internal structure of faults. It is concluded that the more complicated the fault structure is, the more significant the effects will be. If there is a deformation band, it will hinder the cross fault migration due to the common feature of two to four orders of magnitude reduction in permeability. Otherwise, hydrocarbons tend to accumulate in the up-dip structure under the control of buoyancy. Further research on the internal fault structure should be emphasized.展开更多
Noble gases in natural gas, from Xiaoquan, Xinchang, Hexingchang and Fenggu gas reservoirs in the middle part of the western Sichuan Depression, China, were analysed. Results show that the volume content of crustal no...Noble gases in natural gas, from Xiaoquan, Xinchang, Hexingchang and Fenggu gas reservoirs in the middle part of the western Sichuan Depression, China, were analysed. Results show that the volume content of crustal noble gases accounts for 97.9% to 99.7% of the total noble gas content, indicating that the noble gases in the study area are very largely derived from the crust. Moreover, the 40Ar time-accumulating effect of source rocks is used to determine the complex relationship between gases and source rocks in this area, and the results agree well with that from analysis of source rock light hydrocarbons. Due to the short migration distance, the separation of 4He and 40Ar is not significant in Xujiahe natural gas and Lower and Middle Jurassic natural gas, so it is difficult to trace natural gas migration. However, this separation characteristic of 4He and 40Ar in Middle and Upper Jurassic natural gas is significant, which indicates that natural gas migration was from the Middle Jurassic to Upper Jurassic formations. In addition, the variation trends of 3He/4He ratio and δ13C1 value indicates that natural gas migration is from the Xujiahe formation to the Jurassic layer in the study area.展开更多
Conventional seismic exploration method based on post-stack data usually fails to identify the distribution of fractured and caved carbonate reservoirs in the Tarim Basin,so the rich pre-stack information should be ap...Conventional seismic exploration method based on post-stack data usually fails to identify the distribution of fractured and caved carbonate reservoirs in the Tarim Basin,so the rich pre-stack information should be applied to the prediction of carbonate reservoirs.Amplitude-preserved seismic data processing is the foundation.In this paper,according to the feature of desert seismic data （including weak reflection,fast attenuation of high frequency components,strong coherent noises,low S/N and resolution）,a set of amplitude-preserved processing techniques is applied and a reasonable processing flow is formed to obtain the high quality data.After implementing a set of pre-stack amplitude-preserved processing,we test and define the kernel parameters of amplitude-preserved Kirchhoff PSTM （pre-stack time migration） and subsequent gathers processing,in order to obtain the amplitude-preserved gathers used to the isotropic pre-stack inversion for the identification of caved reservoirs.The AVO characteristics of obtained gathers fit well with the synthetic gathers from logging data,and it proves that the processing above is amplitudepreserved.The azimuthal processing techniques,including azimuth division and binning enlargement,are implemented for amplitude-preserved azimuthal gathers with the uniform fold.They can be used in the anisotropic inversion to detect effective fractures.The processing techniques and flows are applied to the field seismic data,and are proved available for providing the amplitude-preserved gathers for carbonate reservoir prediction in the Tarim Basin.展开更多
The fault system of Liaodong Bay developed extensively under the control of the Tanlu Fault. The fault system can be grouped into strike-slip faults of grade Ⅰ, trunk faults of grade Ⅱand branch faults （induced fau...The fault system of Liaodong Bay developed extensively under the control of the Tanlu Fault. The fault system can be grouped into strike-slip faults of grade Ⅰ, trunk faults of grade Ⅱand branch faults （induced faults） of grade Ⅲ respectively based on its developmental scale. The faults of grade Ⅰ and Ⅱwere deep, early and large while the faults of grade Ⅲwere shallow, late and small. The formation, evolution and distribution features played a significant role in controlling the migration of oil and gas in both horizontal and vertical directions. The fluid transfer in the fault system occurred in the process of faulting. The strike-slip and trunk faults moved actively forming predominant pathways for oil and gas migration. The branch faults, with weak activity, generally controlled the development of traps and were beneficial for the accumulation and preservation of oil and gas. The faults of grade Ⅰ and Ⅱ formed the major migration pathways for oil and gas, but their fault activity rates appeared to vary along their strikes. The zones with a relatively low fault activity rate might be favorable for oil and gas accumulation. When the activities of strike-slip, trunk, and branch faults came to a halt, the fault seal behavior had a vitally important effect on the accumulation of oil and gas. The controlling role of the fault over fluid distribution was further analyzed by calculating the fault activity quantitatively.展开更多
基金financially supported by the National Key R&D Program of China (2022YFB4200304)the National Natural Science Foundation of China (52303347)+3 种基金the Fundamental Research Funds for the Central Universities (YJ2021157)the Engineering Featured Team Fund of Sichuan University (2020SCUNG102)open foundation of Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, Guangxi University (2022GXYSOF05)the support from the National Natural Science Foundation of China (E30853YM19)
文摘Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices stability.However,the strategies of suppressing photoinduced phase segregation and related mechanisms have not been fully disclosed.Here,we report a new passivation agent 4-aminotetrahydrothiopyran hydrochloride(4-ATpHCl)with multifunctional groups for the interface treatment of a 1.77-eV wide-bandgap perovskite film.4-ATpH^(+)impeded halogen ion migration by anchoring on the perovskite surface,leading to the inhibition of phase segregation and thus the passivation of defects,which is ascribed to the interaction of 4-ATpH^(+)with perovskite and the formation of low-dimensional perovskites.Finally,the champion device achieved an efficiency of 19.32%with an open-circuit voltage(V_(OC))of 1.314 V and a fill factor of 83.32%.Moreover,4-ATpHCl modified device exhibited significant improved stability as compared with control one.The target device maintained 80%of its initial efficiency after 519 h of maximum power output(MPP)tracking under 1 sun illumination,however,the control device showed a rapid decrease in efficiency after 267 h.Finally,an efficiency of 27.38%of the champion 4-terminal all-perovskite tandem solar cell was achieved by mechanically stacking this wide-bandgap top subcell with a 1.25-eV low-bandgap perovskite bottom subcell.
基金supported by the National Natural Science Foun-dation of China(No.62027801)。
文摘Traditional single-satellite passive localization algorithms are influenced by frequency and angle measurement accuracies,resulting in error estimation of emitter position on the order of kilometers.Subsequently,a single-satellite localization algorithm based on passive synthetic aper-ture(PSA)was introduced,enabling high-precision positioning.However,its estimation of azimuth and range distance is considerably affected by the residual frequency offset(RFO)of uncoopera-tive system transceivers.Furthermore,it requires data containing a satellite flying over the radia-tion source for RFO search.After estimating the RFO,an accurate estimation of azimuth and range distance can be carried out,which is difficult to achieve in practical situations.An LFM radar source passive localization algorithm based on range migration is proposed to address the dif-ficulty in estimating frequency offset.The algorithm first provides a rough estimate of the pulse repetition time(PRT).It processes intercepted signals through range compression,range interpola-tion,and polynomial fitting to obtain range migration observations.Subsequently,it uses the changing information of range migration and an accurate PRT to formulate a system of nonlinear equations,obtaining the emitter position and a more accurate PRT through a two-step localization algorithm.Frequency offset only induces a fixed offset in range migration,which does not affect the changing information.This algorithm can also achieve high-precision localization in squint scenar-ios.Finally,the effectiveness of this algorithm is verified through simulations.
基金Supported by the National Natural Science Foundation of China(41821002,42272163,42072167)Laoshan Laboratory Science and Technology Innovation Project(LSKJ202203403)Hainan Branch Project of CNOOC(KJZH-2021-0003-00).
文摘Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium,and the initial He concentration and thermal driving mechanism of mantle-derived helium,in the Ledong Diapir area,the Yinggehai Basin,in order to understand the genetic source,migration and accumulation mechanisms of helium under deep thermal fluid activities.The average content of mantle-derived He is only 0.0014%,the ^(3)He/^(4)He value is(0.002–2.190)×10^(−6),and the R/Ra value ranges from 0.01 to 1.52,indicating the contribution of mantle-derived He is 0.09%–19.84%,while the proportion of crust-derived helium can reach over 80%.Quantitative analysis indicates that the crust-derived helium is dominated by external input,followed by in-situ production,in the Ledong diapir area.The crust-derived helium exhibits an in-situ 4 He yield rate of(7.66–7.95)×10^(−13)cm^(3)/(a·g),an in-situ 4 He yield of(4.10–4.25)×10^(−4)cm^(3)/g,and an external 4 He influx of(5.84–9.06)×10^(−2)cm^(3)/g.These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions.The ratio of initial mole volume of 3 He to enthalpy(W)is(0.004–0.018)×10^(−11) cm^(3)/J,and the heat contribution from the deep mantle(X_(M))accounts for 7.63%–36.18%,indicating that deep hot fluid activities drive the migration of mantle-derived 3 He.The primary helium migration depends on advection,while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation.From deep to shallow layers,the CO_(2/3) He value rises from 1.34×10^(9)to 486×10^(9),indicating large amount of CO_(2)has escaped.Under the influence of deep thermal fluid,helium migration and accumulation mechanisms include:deep heat driven diffusion,advection release,vertical hydrothermal degassing,shallow lateral migration,accumulation in traps far from faults,partial pressure balance and sealing capability.
基金supported by the National Natural Science Foundation of China(Nos.52274149 and 52474162)the Fundamental Research Funds for the Central Universities(Nos.2024JCCXNY04 and 2023YQTD02)+1 种基金the Ph.D.Top Innovative Talents Fund of CUMTB(No.BBJ2024013)the Yue Qi Young Scholar Project(No.2020QN03)。
文摘Cementitious gangue-fly ash backfill(CGB)is used as a green mining technology worldwide.However,under the coupled effects of geological stress and groundwater,the metal elements in the CGB tend to migrate into nearby strata,which can consequently result in pollution of the groundwater environment.In this paper,the influence of initial pH and stress damage on the migration behavior of metal elements in CGB is quantitatively studied through the multi-physical field coupling model of stress-permeability-con centration.The enhanced Nemerow index evaluation method is used to comprehensively evaluate the impact of these metal elements migration behaviors on the groundwater environment.The research results show that:(1)When the stress damage of the CGB increases from 0.76 to 0.95,the Darcy velocity at the bottom of the CGB first increases,then decreases,and finally stabilizes at 2.01×10^(-7)m/s.The longest time to reach the maximum Darcy velocity is 3 a.(2)When the damage of the CGB is 0.95,the farthest migration distances of Al,Cr,Mn,Fe,Ba,and Pb are 40.5,34.0,29.8,32.9,38.8 and 32.1 m,respectively.(3)The alkaline environment stimulates the migration of Al,Cr,Fe,Mn,and Pb,whereas Ba migrates farther under acidic conditions.The farthest migration distance of Ba is 31.6 m under pH 3.(4)The enhanced Nemerow index indicates that when stress damage increases from 0.76 to 0.95,the areas with poor water quality increase from 0 to 1.71%,and no area is classified as very poor grade.When the initial pH changes from 3 to 11,100%of the region is classified as fair or above.The initial pH of the CGB has a relatively slight influence on the groundwater environment.This study provides experimental data and theoretical basis for the environmental evaluation of CGB.
基金Supported by Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (2019BT02H594)Sanya Technology Innovation Special Project (2022KJCX08)。
文摘Offshore carbon dioxide(CO_(2)) storage is an effective method for reducing greenhouse gas emissions. However, when using traditional seismic wave methods to monitor the migration of sequestration CO_(2) plumes, the characteristics of wave velocity changes tend to become insignificant beyond a certain limit. In contrast, the controllable source electromagnetic method(CSEM) remains highly sensitive to resistivity changes. By simulating different CO_(2) plume migration conditions, we established the relevant models and calculated the corresponding electric field response characteristic curves, allowing us to analyze the CSEM's ability to monitor CO_(2) plumes. We considered potential scenarios for the migration and diffusion of offshore CO_(2) storage, including various burial depths, vertical extension diffusion, lateral extension diffusion,multiple combinations of lateral intervals, and electric field components. We also obtained differences in resistivity inversion imaging obtained by CSEM to evaluate its feasibility in monitoring and to analyze all the electric field(Ex, Ey, and Ez) response characteristics. CSEM has great potential in monitoring CO_(2) plume migration in offshore saltwater reservoirs due to its high sensitivity and accuracy. Furthermore, changes in electromagnetic field response reflect the transport status of CO_(2) plumes, providing an important basis for monitoring and evaluating CO_(2)transport behavior during storage processes.
基金Supported by the Science and Technology Research Project of China Petroleum&Chemical Corporation (No. P22175)。
文摘The geological storage of carbon dioxide(CO_(2)) is a crucial technology for mitigating climate change. Offshore deep saline aquifers have elicited increased attention due to their remarkable potential for storing CO_(2). During long-term storage, CO_(2) migration in a deep saline aquifer needs special attention to prevent it from reaching risk points and leading to security issues. In this paper, a mechanism model is established according to the geological characteristics of saline aquifers in an offshore sedimentary basin in China. The CO_(2) migration over 100 years is simulated considering geological changes such as permeability, dip angle, thickness, and salinity. The effects of injection conditions on the CO_(2) migration range are also investigated. Results reveal that the migration range of CO_(2) in the injection period exceeds 70%, even if the postinjection period's duration is five times longer than that of the injection period. As the values of the above geological parameters increase, the migration range of CO_(2) increases, and permeability has a particularly substantial influence. Moreover, the influences of injection rate and well type are considerable. At high injection rates, CO_(2) has a greater likelihood of displacing brine in a piston-like scheme. CO_(2) injected by long horizontal wells migrates farther compared with that injected by vertical wells. In general, the plane migration range is within 3 000 m, although variations in the reservoir and injection parameters of the studied offshore saline aquifers are considered. This paper can offer references for the site selection and injection well deployment of CO_(2) saline aquifer storage. According to the studied offshore aquifers, a distance of at least 3 000 m from potential leakage points, such as spill points, active faults, and old abandoned wells, must be maintained.
基金supported in part by the National Natural Foundation of China(No.62027801).
文摘Recently,researchers have proposed an emitter localization method based on passive synthetic aperture.However,the unknown residual frequency offset(RFO)between the transmit-ter and the receiver causes the received Doppler signal to shift,which affects the localization accu-racy.To solve this issue,this paper proposes a RFO estimation method based on range migration fitting.Due to the high frequency modulation slope of the linear frequency modulation(LFM)-mod-ulation radar signal,it is not affected by RFO in range compression.Therefore,the azimuth time can be estimated by fitting the peak value position of the pulse compression in range direction.Then,the matched filters are designed under different RFOs.When the zero-Doppler time obtained by the matched filters is consistent with the estimated azimuth time,the given RFO is the real RFO between the transceivers.The simulation results show that the estimation error of azimuth distance does not exceed 20 m when the received signal duration is not less than 3 s,the pulse repe-tition frequency(PRF)of the transmitter radar signal is not less than 1 kHz,the range detection is not larger than 1000 km,and the signal noise ratio(SNR)is not less than-5 dB.
基金support from the National Natural Science Foundation of China(Grant Nos.11974066,12174041,12104134,T2350007,and 12347178)the Fundamental and Advanced Research Program of Chongqing(Grant No.cstc2019jcyj-msxm X0477)+3 种基金the Natural Science Foundation of Chongqing(Grant No.CSTB2022NSCQMSX1260)the Science and Technology Research Program of Chongqing Municipal Education Commission(Grant No.KJQN202301333)the Scientific Research Fund of Chongqing University of Arts and Sciences(Grant Nos.R2023HH03 and P2022HH05)College Students’Innovation and Entrepreneurship Training Program of Chongqing Municipal(Grant No.S202310642002)。
文摘Increasing data indicate that cancer cell migration is regulated by extracellular matrixes and their surrounding biochemical microenvironment,playing a crucial role in pathological processes such as tumor invasion and metastasis.However,conventional two-dimensional cell culture and animal models have limitations in studying the influence of tumor microenvironment on cancer cell migration.Fortunately,the further development of microfluidic technology has provided solutions for the study of such questions.We utilize microfluidic chip to build a random collagen fiber microenvironment(RFM)model and an oriented collagen fiber microenvironment(OFM)model that resemble early stage and late stage breast cancer microenvironments,respectively.By combining cell culture,biochemical concentration gradient construction,and microscopic imaging techniques,we investigate the impact of different collagen fiber biochemical microenvironments on the migration of breast cancer MDA-MB-231-RFP cells.The results show that MDA-MB-231-RFP cells migrate further in the OFM model compared to the RFM model,with significant differences observed.Furthermore,we establish concentration gradients of the anticancer drug paclitaxel in both the RFM and OFM models and find that paclitaxel significantly inhibits the migration of MDA-MB-231-RFP cells in the RFM model,with stronger inhibition on the high concentration side compared to the low concentration side.However,the inhibitory effect of paclitaxel on the migration of MDA-MB-231-RFP cells in the OFM model is weak.These findings suggest that the oriented collagen fiber microenvironment resembling the late-stage tumor microenvironment is more favorable for cancer cell migration and that the effectiveness of anticancer drugs is diminished.The RFM and OFM models constructed in this study not only provide a platform for studying the mechanism of cancer development,but also serve as a tool for the initial measurement of drug screening.
基金Supported by the National Natural Science Foundation of China(42172149,U2244209)Sinopec Science and Technology Research Project(P23230,P22132)。
文摘Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical characteristics of light hydrocarbons on the migration features,dissolution and escape of natural gas from the Dongsheng gas field in the Ordos Basin is revealed,and the effect of migration on specific light hydrocarbon indexes is further discussed.The study indicates that,natural gas from the Lower Shihezi Formation(Pix)in the Dongsheng gas field displays higher iso-C5-7contents than n-C5-7contents,and the C6-7light hydrocarbons are composed of paraffins with extremely low aromatic contents(<0.4%),whereas the C7light hydrocarbons are dominated by methylcyclohexane,suggesting the characteristics of coal-derived gas with the influence by secondary alterations such as dissolution.The natural gas from the Dongsheng gas field has experienced free-phase migration from south to north and different degrees of dissolution after charging,and the gas in the Shiguhao area to the north of the Borjianghaizi fault has experienced apparent diffusion loss after accumulation.Long-distance migration in free phase results in the decrease of the relative contents of the methylcyclohexane in C7 light hydrocarbons and the toluene/n-heptane ratio,as well as the increase of the n-heptane/methylcyclohexane ratio and heptane values.The dissolution causes the increase of isoheptane values of the light hydrocarbons,whereas the diffusion loss of natural gas in the Shiguhao area results in the increase of n-C5-7contents compared to the iso-C5-7contents.
基金supported by the Marine S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology(No.2021QNLM020001)the Major Scientific and Technological Projects of Shandong Energy Group(No.SNKJ2022A06-R23)+2 种基金the Funds of Creative Research Groups of China(No.41821002)National Natural Science Foundation of China Outstanding Youth Science Fund Project(Overseas)(No.ZX20230152)the Major Scientific and Technological Projects of CNPC(No.ZD2019-183-003)。
文摘Compared with the transverse isotropic(TI)medium,the orthorhombic anisotropic medium has both horizontal and vertical symmetry axes and it can be approximated as a set of vertical fissures developed in a group of horizontal strata.Although the full-elastic orthorhombic anisotropic wave equation can accurately simulate seismic wave propagation in the underground media,a huge computational cost is required in seismic modeling,migration,and inversion.The conventional coupled pseudo-acoustic wave equations based on acoustic approximation can be used to significantly reduce the cost of calculation.However,these equations usually suffer from unwanted shear wave artifacts during wave propagation,and the presence of these artifacts can significantly degrade the imaging quality.To solve these problems,we derived a new pure P-wave equation for orthorhombic media that eliminates shear wave artifacts while compromising computational efficiency and accuracy.In addition,the derived equation involves pseudo-differential operators and it must be solved by 3D FFT algorithms.In order to reduce the number of 3D FFT,we utilized the finite difference and pseudo-spectral methods to conduct 3D forward modeling.Furthermore,we simplified the equation by using elliptic approximation and implemented 3D reverse-time migration(RTM).Forward modeling tests on several homogeneous and heterogeneous models confirm that the accuracy of the new equation is better than that of conventional methods.3D RTM imaging tests on three-layer and SEG/EAGE 3D salt models confirm that the ORT media have better imaging quality.
基金supported in part by the National Natural Science Foundation of China(NSFC)under grant numbers U22A2007 and 62171010the Open project of Satellite Internet Key Laboratory in 2022(Project 3:Research on Spaceborne Lightweight Core Network and Intelligent Collaboration)the Beijing Natural Science Foundation under grant number L212003.
文摘With the advancements of software defined network(SDN)and network function virtualization(NFV),service function chain(SFC)placement becomes a crucial enabler for flexible resource scheduling in low earth orbit(LEO)satellite networks.While due to the scarcity of bandwidth resources and dynamic topology of LEO satellites,the static SFC placement schemes may cause performance degradation,resource waste and even service failure.In this paper,we consider migration and establish an online migration model,especially considering the dynamic topology.Given the scarcity of bandwidth resources,the model aims to maximize the total number of accepted SFCs while incurring as little bandwidth cost of SFC transmission and migration as possible.Due to its NP-hardness,we propose a heuristic minimized dynamic SFC migration(MDSM)algorithm that only triggers the migration procedure when new SFCs are rejected.Simulation results demonstrate that MDSM achieves a performance close to the upper bound with lower complexity.
文摘A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass (Mr), conformation parameter (Rc) of peptides and electrophoretic condition parameter(A). The conformation parameter is introduced to characterize multifarious shapes owing to the complex conlormation and the various kinds of macromolecules, where Rc≥1/3. The parameters A and Rc can be obtained from experimental data. The times of migration of the nine standard peptides were measured in pH 2.5buffer on different electrophoretic conditions in CZE. The experimental results agreed well with the theoretical prediction.
基金supported by the National Natural Science Foundation of China (grant No. 90914006)Program for Changjiang Scholars and Innovative Research Team in the University (IRT0658)
文摘The aim of this paper is to review the major points of contention concerning secondary petroleum migration, to discuss the nature and primary controls of the positions of petroleum migration pathways in sedimentary basins, and to illustrate the importance of preferential petroleum migration pathways for the formation of large oil/gas fields away from generative kitchens. There is competition between the driving force （buoyancy） and the restraining force （capillary pressure controlled largely by permeability contrast） in controlling the positions of petroleum migration pathways in heterogeneous carrier beds. At a large scale, there is a critical angle of dip of the carrier beds which determines the relative importance of structural morphology or permeability contrasts in controlling the positions of petroleum migration pathways in heterogeneous carrier beds. Maximum-driving-force-controlled migration pathways occur in carrier beds with an angle of dip greater than the critical dip and the positions of petroleum migration pathways are controlled mainly by the morphology of the sealing surfaces. Minimum-restraining-force-determined migration pathways occur in carrier beds with an angle of dip smaller than the critical angle where permeability contrasts would exert a more important influence on the positions of petroleum migration pathways. Preferential petroleum migration pathways （PPMP）, defined as very restricted portions of carrier-beds that focus or concentrate petroleum from a large area of the generative kitchen, determine the distribution of oil and gas in sedimentary basins. The focusing of petroleum originating from a large area of the generative kitchens into restricted channels seems to be essential not only for long-range petroleum migration in hydrostatic conditions, but also for the formation of large oil or gas fields. Regions may miss out on petroleum migration because of its three-dimensional behavior, and two-dimensional migration modeling may be misleading in predicting petroleum occurrences in certain circumstances.
基金financial support from the National Natural Science Foundation of China (Grant Nos. 41104069, 41274124)National Key Basic Research Program of China (973 Program) (Grant No. 2014CB239006)+2 种基金National Science and Technology Major Project (Grant No. 2011ZX05014-001-008)the Open Foundation of SINOPEC Key Laboratory of Geophysics (Grant No. 33550006-15-FW2099-0033)the Fundamental Research Funds for the Central Universities (Grant No. 16CX06046A)
文摘Simultaneous-source acquisition has been recog- nized as an economic and efficient acquisition method, but the direct imaging of the simultaneous-source data produces migration artifacts because of the interference of adjacent sources. To overcome this problem, we propose the regularized least-squares reverse time migration method （RLSRTM） using the singular spectrum analysis technique that imposes sparseness constraints on the inverted model. Additionally, the difference spectrum theory of singular values is presented so that RLSRTM can be implemented adaptively to eliminate the migration artifacts. With numerical tests on a fiat layer model and a Marmousi model, we validate the superior imaging quality, efficiency and convergence of RLSRTM compared with LSRTM when dealing with simultaneoussource data, incomplete data and noisy data.
基金financially supported by the National Key Research and Development Program (No. 2016YFC0801402)the National Natural Science Foundation of China (No. 51374236)Chongqing Research Program of Basic Research and Frontier Technology of China (No. cstc2015jcyj BX0076)
文摘Gas extraction practice has been proven for the clear majority of coal mines in China to be unfavorable using drill holes in the coal seam. Rather, mining-induced fractures in the goaf should be utilized for gas extraction. To study gas migration in mining-induced fractures, one mining face of 10 th Mine in Pingdingshan Coalmine Group in Henan, China, has been selected as the case study for this work. By establishing the mathematical model of gas migration under the influence of coal seam mining, discrete element software UDEC and Multiphysics software COMSOL are employed to model gas migration in mining-induced fractures above the goaf. The results show that as the working face advances, the goaf overburden gradually forms a mining-induced fracture network in the shape of a trapezoid, the size of which increases with the distance of coal face advance. Compared with gas migration in the overburden matrix, the gas flow in the fracture network due to mining is far greater. The largest mining-induced fracture is located at the upper end of the trapezoidal zone, which results in the largest gas flux in the network. When drilling for gas extraction in a mining-induced fracture field, the gas concentration is reduced in the whole region during the process of gas drainage, and the rate of gas concentration drops faster in the fractured zone. It is shown that with gas drainage, the gas flow velocity in the mininginduced fracture network is faster.
基金supported by the National Basic Research Program of China (No. 2005CB422106)
文摘The lower Cambrian Niutitang Formation hydrocarbon source rocks at the Dingshan- Lintanchang structure in the southeast Sichuan Basin were of medium-good quality with two excellent hydrocarbon-generating centers developed in the periphery areas, with a possibility of forming a medium to large-sized oil-gas field. Good reservoir rocks were the upper Sinian （Dengying Formation） dolomites. The mudstone in the lower Cambrian Niutitang Formation with a good sealing capacity was the cap rock. The widely occurring bitumen in the Dengying Formation indicates that a paleo oil pool was once formed in the study area. The first stage of paleo oil pool formation was maturation of the lower Cambrian source rocks during the late Ordovician. Hydrocarbon generation from the lower Cambrian source rocks stopped due to the Devonian-Carboniferous uplifting. The lower Cambrian source rocks then restarted generation of large quantities of hydrocarbons after deposition of the middle Permian sediments. This was the second stage of the paleo oil pool formation. The oil in the paleo oil pool began to crack during the late Triassic and a paleo gas pool was formed. This paleo gas pool was destroyed during the Yanshan-Himalayan folding, uplifting and denudation. Bitumen can be widely seen in the Dengying Formation in wells and outcrops in the Sichuan Basin and its periphery areas. This provides strong evidence that the Dengying Formation in the Sichuan Basin and its periphery areas was once an ultra-large structural-lithologic oil-gas field, which was damaged during the Yanshan-Himalayan period.
基金supported by the National 973 Basic Research Program (Grant No.2006CB202308)the Major National Science & Technology Program (2008ZX05008-004-012)
文摘Understanding hydrocarbon migration and accumulation mechanisms is one of the key scientif ic problems that should be solved for effective hydrocarbon exploration in the superimposed basins developed in northwest China. The northwest striking No.1 slope break zone, which is a representative of superimposed basins in the Tarim Basin, can be divided into five parts due to the intersection of the northeast strike-slip faults. Controlled by the tectonic framework, the types and properties of reservoirs and the hydrocarbon compositions can also be divided into five parts from east to west. Anomalies of all the parameters were found on the fault intersection zone and weakened up-dip along the structural ridge away from it. Thus, it can be inferred that the intersection zone is the hydrocarbon charging position. This new conclusion differs greatly from the traditional viewpoint, which believes that the hydrocarbon migrates and accumulates along the whole plane of the No.1 slope break zone. The viewpoint is further supported by the evidence from the theory of main pathway systems, obvious improvement of the reservoir quality （2-3 orders of magnitude at the intersection zone） and the formation mechanisms of the fault intersection zone. Differential hydrocarbon migration and entrapment exists in and around the strike- slip faults. This is controlled by the internal structure of faults. It is concluded that the more complicated the fault structure is, the more significant the effects will be. If there is a deformation band, it will hinder the cross fault migration due to the common feature of two to four orders of magnitude reduction in permeability. Otherwise, hydrocarbons tend to accumulate in the up-dip structure under the control of buoyancy. Further research on the internal fault structure should be emphasized.
基金supported by the National Natural Science Foundation of China (41172119)
文摘Noble gases in natural gas, from Xiaoquan, Xinchang, Hexingchang and Fenggu gas reservoirs in the middle part of the western Sichuan Depression, China, were analysed. Results show that the volume content of crustal noble gases accounts for 97.9% to 99.7% of the total noble gas content, indicating that the noble gases in the study area are very largely derived from the crust. Moreover, the 40Ar time-accumulating effect of source rocks is used to determine the complex relationship between gases and source rocks in this area, and the results agree well with that from analysis of source rock light hydrocarbons. Due to the short migration distance, the separation of 4He and 40Ar is not significant in Xujiahe natural gas and Lower and Middle Jurassic natural gas, so it is difficult to trace natural gas migration. However, this separation characteristic of 4He and 40Ar in Middle and Upper Jurassic natural gas is significant, which indicates that natural gas migration was from the Middle Jurassic to Upper Jurassic formations. In addition, the variation trends of 3He/4He ratio and δ13C1 value indicates that natural gas migration is from the Xujiahe formation to the Jurassic layer in the study area.
基金financially supported by National Basic Research Program of China(No.2011CB201100)
文摘Conventional seismic exploration method based on post-stack data usually fails to identify the distribution of fractured and caved carbonate reservoirs in the Tarim Basin,so the rich pre-stack information should be applied to the prediction of carbonate reservoirs.Amplitude-preserved seismic data processing is the foundation.In this paper,according to the feature of desert seismic data （including weak reflection,fast attenuation of high frequency components,strong coherent noises,low S/N and resolution）,a set of amplitude-preserved processing techniques is applied and a reasonable processing flow is formed to obtain the high quality data.After implementing a set of pre-stack amplitude-preserved processing,we test and define the kernel parameters of amplitude-preserved Kirchhoff PSTM （pre-stack time migration） and subsequent gathers processing,in order to obtain the amplitude-preserved gathers used to the isotropic pre-stack inversion for the identification of caved reservoirs.The AVO characteristics of obtained gathers fit well with the synthetic gathers from logging data,and it proves that the processing above is amplitudepreserved.The azimuthal processing techniques,including azimuth division and binning enlargement,are implemented for amplitude-preserved azimuthal gathers with the uniform fold.They can be used in the anisotropic inversion to detect effective fractures.The processing techniques and flows are applied to the field seismic data,and are proved available for providing the amplitude-preserved gathers for carbonate reservoir prediction in the Tarim Basin.
文摘The fault system of Liaodong Bay developed extensively under the control of the Tanlu Fault. The fault system can be grouped into strike-slip faults of grade Ⅰ, trunk faults of grade Ⅱand branch faults （induced faults） of grade Ⅲ respectively based on its developmental scale. The faults of grade Ⅰ and Ⅱwere deep, early and large while the faults of grade Ⅲwere shallow, late and small. The formation, evolution and distribution features played a significant role in controlling the migration of oil and gas in both horizontal and vertical directions. The fluid transfer in the fault system occurred in the process of faulting. The strike-slip and trunk faults moved actively forming predominant pathways for oil and gas migration. The branch faults, with weak activity, generally controlled the development of traps and were beneficial for the accumulation and preservation of oil and gas. The faults of grade Ⅰ and Ⅱ formed the major migration pathways for oil and gas, but their fault activity rates appeared to vary along their strikes. The zones with a relatively low fault activity rate might be favorable for oil and gas accumulation. When the activities of strike-slip, trunk, and branch faults came to a halt, the fault seal behavior had a vitally important effect on the accumulation of oil and gas. The controlling role of the fault over fluid distribution was further analyzed by calculating the fault activity quantitatively.
