In order to increase the understanding of the pyrolysis mechanism, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetry-mass spectrometric coupling technique (TG-MS) were used to study the pyrolysis be...In order to increase the understanding of the pyrolysis mechanism, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetry-mass spectrometric coupling technique (TG-MS) were used to study the pyrolysis behavior of furfural-acetone resin used for new carbon materials. The curing and carbonization mechanisms of furfural-acetone resin were mainly investigated; structural changes and volatile products evolved during pyrolysis were analyzed. The results indicate that, during pyrolysis of furfural-acetone resin adding 7% (mass fraction) phosphorous acid as curing agent, the rupture of C—O bond in the five-membered heterocycle firstly takes place to release oxygen atoms and then does the C—H bond, which enable the molecular chain to cross-link and condense, then lead to the formation of three dimensional networking structure. With the increase of pyrolyzing temperature, the scission of methyl and the opening of furan ring are generated. As a result, the recomposition of molecular chain structure is generated and a hexatomic fused ring containing double bonds is built. The main volatile products during pyrolysis of furfural- acetone resin are H2O, and a small mount of CO, CO2 and CH4. At elevated temperatures, dehydrogenation takes place and hydrogen gas is evolved.展开更多
Platinum group metals (PGM) include six elements, namely Pt, Pd, Rh, Ir, Os and Ru. PGM and their alloys are the important fundamental materials for modern industry and national defense construction, they have special...Platinum group metals (PGM) include six elements, namely Pt, Pd, Rh, Ir, Os and Ru. PGM and their alloys are the important fundamental materials for modern industry and national defense construction, they have special physical and chemical properties, widely used in metallurgy, chemical, electric, electronic, information, energy, environmental protection, aviation, aerospace, navigation and other high technology industry. Platinum group metals and their alloys, which have good plasticity and processability, can be processed to electrical contact materials, resistance materials, solder, electronic paste, temperature-measurement materials, elastic materials, magnetic materials and high temperature structural materials.展开更多
A new clay-cement composite grouting material (CCGM) for tunnelling in underwater karst area was developed through the excellent synergistic interactions among cement, clay, meta-aluminate and lignin. The probable for...A new clay-cement composite grouting material (CCGM) for tunnelling in underwater karst area was developed through the excellent synergistic interactions among cement, clay, meta-aluminate and lignin. The probable formation mechanism of the material was proposed based on a series of experimental tests. The results show that with an optimal mass ratio (2:1:1:0.024) for water, cement, clay and additives, the obtained CCGM displayed an excellent grouting performance for karst in an underwater condition. Compared with neat cement grouts and clay-cement grouts, CCGM has faster gel time, lower bleeding rate and bulk shrinkage rate, greater initial viscosity, and a strong resistance to water dispersion. A successful engineering application indicates that CCGM not only fulfils a better grouting performance for karst in underwater conditions but also reduces the engineering cost and environmental pollution.展开更多
基金Project(2006CB600902) supported by the Major State Basic Research and Development Program of China
文摘In order to increase the understanding of the pyrolysis mechanism, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetry-mass spectrometric coupling technique (TG-MS) were used to study the pyrolysis behavior of furfural-acetone resin used for new carbon materials. The curing and carbonization mechanisms of furfural-acetone resin were mainly investigated; structural changes and volatile products evolved during pyrolysis were analyzed. The results indicate that, during pyrolysis of furfural-acetone resin adding 7% (mass fraction) phosphorous acid as curing agent, the rupture of C—O bond in the five-membered heterocycle firstly takes place to release oxygen atoms and then does the C—H bond, which enable the molecular chain to cross-link and condense, then lead to the formation of three dimensional networking structure. With the increase of pyrolyzing temperature, the scission of methyl and the opening of furan ring are generated. As a result, the recomposition of molecular chain structure is generated and a hexatomic fused ring containing double bonds is built. The main volatile products during pyrolysis of furfural- acetone resin are H2O, and a small mount of CO, CO2 and CH4. At elevated temperatures, dehydrogenation takes place and hydrogen gas is evolved.
基金supported by the National Nature Science Foundation of China(No.u0837601)
文摘Platinum group metals (PGM) include six elements, namely Pt, Pd, Rh, Ir, Os and Ru. PGM and their alloys are the important fundamental materials for modern industry and national defense construction, they have special physical and chemical properties, widely used in metallurgy, chemical, electric, electronic, information, energy, environmental protection, aviation, aerospace, navigation and other high technology industry. Platinum group metals and their alloys, which have good plasticity and processability, can be processed to electrical contact materials, resistance materials, solder, electronic paste, temperature-measurement materials, elastic materials, magnetic materials and high temperature structural materials.
基金Project(51608539)supported by the National Natural Science Foundation of ChinaProjects(2016M592451,2017T100610)supported by the China Postdoctoral Science Foundation
文摘A new clay-cement composite grouting material (CCGM) for tunnelling in underwater karst area was developed through the excellent synergistic interactions among cement, clay, meta-aluminate and lignin. The probable formation mechanism of the material was proposed based on a series of experimental tests. The results show that with an optimal mass ratio (2:1:1:0.024) for water, cement, clay and additives, the obtained CCGM displayed an excellent grouting performance for karst in an underwater condition. Compared with neat cement grouts and clay-cement grouts, CCGM has faster gel time, lower bleeding rate and bulk shrinkage rate, greater initial viscosity, and a strong resistance to water dispersion. A successful engineering application indicates that CCGM not only fulfils a better grouting performance for karst in underwater conditions but also reduces the engineering cost and environmental pollution.
