The orientation effect of θʹ precipitates in stress-aged Al-Cu alloys has ambiguous interpretations. One view is that θʹ precipitates prefer to grow on the habit planes perpendicular to the applied compressive stres...The orientation effect of θʹ precipitates in stress-aged Al-Cu alloys has ambiguous interpretations. One view is that θʹ precipitates prefer to grow on the habit planes perpendicular to the applied compressive stress, while the other view suggests growth on habit planes parallel to the applied stress. In this study, stress-aged Al-4 wt.%Cu single crystal was sampled from three different <100>Al zone axes to observe the distribution of θʹ precipitates. A hybrid Monte-Carlo/ molecular dynamics simulations were used to investigate the orientation effect of θʹ precipitates. The simulation results are consistent with experimental observations and indicate that θʹ precipitates prefer to grow on the habit planes that are parallel to the direction of the applied compressive stress, not along the planes perpendicular to it. It is also found that 1/2<110> perfect dislocations are generated as θʹ precipitates plates grow thicker, and the reaction of 1/2<110> perfect dislocations decomposing into 1/6<112> Shockley dislocations lead to an increase in the length of θʹ precipitates. The former does not enhance the orientation effect, whereas the latter leads to a more significant orientation effect. Additionally, the degree of the orientation effect of θʹ precipitates is determined by the reduction of 1/2<110> dislocations with a positive correlation between them.展开更多
The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron m...The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron microscopy(TEM). The results indicate that with the increase of second-step aging time of two-step aging, the mechanical properties increase first and then decrease, while the SCC resistance increases. Compared with two-step aging, three-step aging treatment improves SCC resistance and the strength increases by about 5%. The effects of novel three-step aging on strength and SCC resistance are explained by the role of matrix precipitates and grain boundary precipitates, respectively.展开更多
In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process,a one month thermal aging test was carried out at70C with ...In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process,a one month thermal aging test was carried out at70C with pre-strain of 0%,3%,6%and 9%,respectively.The low-field1 H NMR and stress relaxation modulus tests were carried out for HTPB coating at different aging stages.The stress relaxation model considering the molecular chains was proposed according to the changes of crosslinking chain and dangling chain of HTPB coating during pre-strain aging.The results showed that with the increase of aging time,the decay rate of transverse relaxation curve became faster,the transverse relaxation time decreased,the value of combined parameter q Mrl increased,the proportion of crosslinking chain decreased,while the proportion of dangling chain increased.Moreover,the stress relaxation modulus increased,the crosslinking network structure of HTPB coating became denser and the degree of crosslinking increased.At the initial aging stage,the pre-strain will destroy the crosslinking network structure of HTPB coating to a certain extent.With the increase of aging time,the effect of pre-strain will gradually weaken and the influence of aging on materials will gradually increase.The correlations between the stress relaxation model considering the molecular chains and the test results were more than 0.9950,which can accurately describe the stress relaxation modulus of HTPB coating during the pre-strain thermal aging process.展开更多
The ratio of crack initiation stress to the uniaxial compressive strength(SCI,B/SUC,B) and the ratio of axial strain at the crack initiation stress to the axial strain at the uniaxial compressive strength(B,UCB,CI,A,A...The ratio of crack initiation stress to the uniaxial compressive strength(SCI,B/SUC,B) and the ratio of axial strain at the crack initiation stress to the axial strain at the uniaxial compressive strength(B,UCB,CI,A,A/SSSS) were studied by performing numerical stress analysis on blocks having multi flaws at close spacing's under uniaxial loading using PFC3 D. The following findings are obtained: SCI,B/SUC,B has an average value of about 0.5 with a variability of ± 0.1. This range agrees quite well with the values obtained by former research. For joint inclination angle, β=90°,B,UCB,CI,A,A/SSSS is found to be around 0.48 irrespective of the value of joint continuity factor, k. No particular relation is found betweenB,UCB,CI,A,A/SSSS and β; however, the average B,UCB,CI,A,A/SSSS seems to slightly decrease with increasing k. The variability ofB,UCB,CI,A,A/SSSS is found to increase with k.Based on the cases studied in this work,B,UCB,CI,A,A/SSSS ranges between 0.3 and 0.5. This range is quite close to the range of 0.4to 0.6 obtained for SCI,B/SUC,B. The highest variability of ± 0.12 forB,UCB,CI,A,A/SSSS is obtained for k=0.8. For the remaining k values the variability ofB,UCB,CI,A,A/SSSS can be expressed within ± 0.05. This finding is very similar to the finding obtained for the variability of SCI,B/SUC,B.展开更多
In this paper,the effect of cathodic polarization on corrosion behavior of AA7003 under three kinds of aging treatments(including peak aging(PA),double peak aging(DPA)and regression re-aging(RRA))was studied in 3.5 wt...In this paper,the effect of cathodic polarization on corrosion behavior of AA7003 under three kinds of aging treatments(including peak aging(PA),double peak aging(DPA)and regression re-aging(RRA))was studied in 3.5 wt%sodium chloride solution through slow strain rate testing(SSRT)and electrochemical testing.X-ray diffraction(XRD)and scanning electron microscopy(SEM)methods were also applied to investigating corrosion behavior and fracture morphology.The results showed that under open circuit,stress corrosion cracking(SCC)of AA7003 might by classified as anodic dissolution.In this case,the extent of SCC susceptibility(ISCC)of AA7003 alloy with different aging treatments was as follows:ISCC(PA)>ISCC(DPA)>ISCC(RRA).On the other hand,stress corrosion cracking(SCC)of AA7003 under cathodic polarization might be classified as hydrogen embrittlement(HE)which had been proved in this paper by presence of AlH3 diffraction peak in XRD patterns.In this case,for AA7003 with any of the three aging treatments,hydrogen embrittlement susceptibility(IHE)increases with negatively shifting of cathodic polarization.展开更多
Superior properties of maraging steels make them suitable for the fabrication of components used for military applications like missile covering, rocket motor casing and ship hulls. Welding is the main process for fab...Superior properties of maraging steels make them suitable for the fabrication of components used for military applications like missile covering, rocket motor casing and ship hulls. Welding is the main process for fabrication of these components, while the maraging steels can be fusion welded using gas tungsten arc welding(GTAW) process. All these fabricated components require longer storage life and a major problem in welds is susceptible to stress corrosion cracking(SCC). The present study is aimed at studying the SCC behaviour of MDN 250(18% Ni) steel and its welds with respect to microstructural changes. In the present study, 5.2 mm thick sheets made of MDN 250 steel in the solution annealed condition was welded using GTAW process. Post-weld heat treatments of direct ageing(480 C for 3 h), solutionizing(815 C for 1 h) followed by ageing and homogenizing(1150 C for 1 h) followed by ageing were carried out. A mixture of martensite and austenite was observed in the microstructure of the fusion zone of solutionized and direct aged welds and only martensite in as-welded condition. Homogenization and ageing treatment have eliminated reverted austenite and elemental segregation. Homogenized welds also exhibited a marginal improvement in the corrosion resistance compared to those in the as-welded, solutionized and aged condition. Constant load SCC test data clearly revealed that the failure time of homogenized weld is much longer compared to other post weld treatments, and the homogenization treatment is recommended to improve the SCC life of GTA welds of MDN 250 Maraging steel.展开更多
Due to the insufficient information regarding the aging phenomenon of cables caused by switching impulses, we aged 15 kV XLPE and EPR cable samples by 10 000 switching impulses in experiments and tested them. Plus in ...Due to the insufficient information regarding the aging phenomenon of cables caused by switching impulses, we aged 15 kV XLPE and EPR cable samples by 10 000 switching impulses in experiments and tested them. Plus in order to compare the aging phenome- non under multi-stress conditions, additional EPR cable samples were aged by rated AC voltage and current with switching impulses superimposed. We used measurements of partial discharge parameters to monitor the cables’ conditions during their aging process, and the AC breakdown voltages measurement to evaluate the cables after aging. Moreover, the Fourier transform infrared (FTIR) spectroscopy measurements revealed the changes of insulation materials after aging. The measurement results confirm that the accelerated aging of cable samples had taken place. The impacts of each individual aging factor are shown through the selected measurements and comparison. The study also helps to assess the reliability of the XLPE and EPR cables under similar condition while serving in power systems.展开更多
The effects of stress,ageing time and ageing temperature on creep behavior of poly(methyl methacrylate) were studied.After annealing above its glass transition temperature for a period of time to eliminate the stress ...The effects of stress,ageing time and ageing temperature on creep behavior of poly(methyl methacrylate) were studied.After annealing above its glass transition temperature for a period of time to eliminate the stress and thermal history,the specimens were quenched and aged at various ageing temperatures for different ageing time,and then the short-term creep tests under different stress levels were carried out at room temperature.The creep strains were modeled by means of time-ageing time equivalence and time-stress equivalence,and the master creep curves were constructed via ageing time shift factors and stress shift factors.The results indicate that the creep rate increases with stress,while decreases with ageing time,and the ageing temperature history obviously affects the creep rate.For linear viscoelastic material,the ageing shift rate is independent on imposed stress,while for nonlinear viscoelastic material,the ageing shift rate decreases with increasing stress.The unified master creep curve up to 540 d at reference state was constructed by shifting the creep curves horizontally along the logarithmic time axis to overlap each other.It is demonstrated that the time-stress equivalence,united with the time-ageing time equivalence,provides an effective accelerated characterization technique in the laboratory to evaluate the long-term creep behavior of physical ageing polymers.展开更多
Traditional ERP software system cannot efficiently su pport new management ideas such as BPR, DEM and virtual enterprise which emphasi zes that enterprise should be adjusted to market changes and business process ch a...Traditional ERP software system cannot efficiently su pport new management ideas such as BPR, DEM and virtual enterprise which emphasi zes that enterprise should be adjusted to market changes and business process ch ain and value chain should be integrated tightly. To solve these problems, this paper proposed the conception of Flexible ERP system. F-ERP is a self- adapti ve software system based on multi-agent technology. It developed the followin g kind of agents which are useful for F-ERP: business process agent, interf ace agent, data agent and decision and analysis agent. The F-ERP software syste m is an hierarchy system which is composed of data layer, system tools layer, bu siness application layer and business decision layer. It used component based de velopment mythology and complied with CORBA to development F-ERP. The F-ERP sy stem can support the new management ideas such as BPR, DEM and virtual enterpris e etc. By implementation of it, enterprise can improve its management and promot e its competence.展开更多
基金Project(2023YFB3710503) supported by the National Key R&D Program of ChinaProject(52305439) supported by the National Natural Science Foundation of China。
文摘The orientation effect of θʹ precipitates in stress-aged Al-Cu alloys has ambiguous interpretations. One view is that θʹ precipitates prefer to grow on the habit planes perpendicular to the applied compressive stress, while the other view suggests growth on habit planes parallel to the applied stress. In this study, stress-aged Al-4 wt.%Cu single crystal was sampled from three different <100>Al zone axes to observe the distribution of θʹ precipitates. A hybrid Monte-Carlo/ molecular dynamics simulations were used to investigate the orientation effect of θʹ precipitates. The simulation results are consistent with experimental observations and indicate that θʹ precipitates prefer to grow on the habit planes that are parallel to the direction of the applied compressive stress, not along the planes perpendicular to it. It is also found that 1/2<110> perfect dislocations are generated as θʹ precipitates plates grow thicker, and the reaction of 1/2<110> perfect dislocations decomposing into 1/6<112> Shockley dislocations lead to an increase in the length of θʹ precipitates. The former does not enhance the orientation effect, whereas the latter leads to a more significant orientation effect. Additionally, the degree of the orientation effect of θʹ precipitates is determined by the reduction of 1/2<110> dislocations with a positive correlation between them.
基金Project(2012CB619502)supported by the National Basic Research Program of ChinaProject(2016YFB0300800)supported by the National Key Research and Development Program of China+1 种基金Project(CALT201507)supported by the CALT Research Innovation Partnership Fund,ChinaProject(HPCM-201403)supported by the State Key Laboratory of High Performance Complex Manufacturing,China
文摘The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron microscopy(TEM). The results indicate that with the increase of second-step aging time of two-step aging, the mechanical properties increase first and then decrease, while the SCC resistance increases. Compared with two-step aging, three-step aging treatment improves SCC resistance and the strength increases by about 5%. The effects of novel three-step aging on strength and SCC resistance are explained by the role of matrix precipitates and grain boundary precipitates, respectively.
基金supported by the National Defense Pre-Research Projects[grant number ZS2015070132A12002]。
文摘In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process,a one month thermal aging test was carried out at70C with pre-strain of 0%,3%,6%and 9%,respectively.The low-field1 H NMR and stress relaxation modulus tests were carried out for HTPB coating at different aging stages.The stress relaxation model considering the molecular chains was proposed according to the changes of crosslinking chain and dangling chain of HTPB coating during pre-strain aging.The results showed that with the increase of aging time,the decay rate of transverse relaxation curve became faster,the transverse relaxation time decreased,the value of combined parameter q Mrl increased,the proportion of crosslinking chain decreased,while the proportion of dangling chain increased.Moreover,the stress relaxation modulus increased,the crosslinking network structure of HTPB coating became denser and the degree of crosslinking increased.At the initial aging stage,the pre-strain will destroy the crosslinking network structure of HTPB coating to a certain extent.With the increase of aging time,the effect of pre-strain will gradually weaken and the influence of aging on materials will gradually increase.The correlations between the stress relaxation model considering the molecular chains and the test results were more than 0.9950,which can accurately describe the stress relaxation modulus of HTPB coating during the pre-strain thermal aging process.
基金Project(11102224)supported by the National Natural Science Foundation of ChinaProject(201206370124)supported by the China Scholarship Council,China
文摘The ratio of crack initiation stress to the uniaxial compressive strength(SCI,B/SUC,B) and the ratio of axial strain at the crack initiation stress to the axial strain at the uniaxial compressive strength(B,UCB,CI,A,A/SSSS) were studied by performing numerical stress analysis on blocks having multi flaws at close spacing's under uniaxial loading using PFC3 D. The following findings are obtained: SCI,B/SUC,B has an average value of about 0.5 with a variability of ± 0.1. This range agrees quite well with the values obtained by former research. For joint inclination angle, β=90°,B,UCB,CI,A,A/SSSS is found to be around 0.48 irrespective of the value of joint continuity factor, k. No particular relation is found betweenB,UCB,CI,A,A/SSSS and β; however, the average B,UCB,CI,A,A/SSSS seems to slightly decrease with increasing k. The variability ofB,UCB,CI,A,A/SSSS is found to increase with k.Based on the cases studied in this work,B,UCB,CI,A,A/SSSS ranges between 0.3 and 0.5. This range is quite close to the range of 0.4to 0.6 obtained for SCI,B/SUC,B. The highest variability of ± 0.12 forB,UCB,CI,A,A/SSSS is obtained for k=0.8. For the remaining k values the variability ofB,UCB,CI,A,A/SSSS can be expressed within ± 0.05. This finding is very similar to the finding obtained for the variability of SCI,B/SUC,B.
基金Projects(51371039,51871031)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),China
文摘In this paper,the effect of cathodic polarization on corrosion behavior of AA7003 under three kinds of aging treatments(including peak aging(PA),double peak aging(DPA)and regression re-aging(RRA))was studied in 3.5 wt%sodium chloride solution through slow strain rate testing(SSRT)and electrochemical testing.X-ray diffraction(XRD)and scanning electron microscopy(SEM)methods were also applied to investigating corrosion behavior and fracture morphology.The results showed that under open circuit,stress corrosion cracking(SCC)of AA7003 might by classified as anodic dissolution.In this case,the extent of SCC susceptibility(ISCC)of AA7003 alloy with different aging treatments was as follows:ISCC(PA)>ISCC(DPA)>ISCC(RRA).On the other hand,stress corrosion cracking(SCC)of AA7003 under cathodic polarization might be classified as hydrogen embrittlement(HE)which had been proved in this paper by presence of AlH3 diffraction peak in XRD patterns.In this case,for AA7003 with any of the three aging treatments,hydrogen embrittlement susceptibility(IHE)increases with negatively shifting of cathodic polarization.
基金Financial assistance from Defence Research Development Organization (DRDO)
文摘Superior properties of maraging steels make them suitable for the fabrication of components used for military applications like missile covering, rocket motor casing and ship hulls. Welding is the main process for fabrication of these components, while the maraging steels can be fusion welded using gas tungsten arc welding(GTAW) process. All these fabricated components require longer storage life and a major problem in welds is susceptible to stress corrosion cracking(SCC). The present study is aimed at studying the SCC behaviour of MDN 250(18% Ni) steel and its welds with respect to microstructural changes. In the present study, 5.2 mm thick sheets made of MDN 250 steel in the solution annealed condition was welded using GTAW process. Post-weld heat treatments of direct ageing(480 C for 3 h), solutionizing(815 C for 1 h) followed by ageing and homogenizing(1150 C for 1 h) followed by ageing were carried out. A mixture of martensite and austenite was observed in the microstructure of the fusion zone of solutionized and direct aged welds and only martensite in as-welded condition. Homogenization and ageing treatment have eliminated reverted austenite and elemental segregation. Homogenized welds also exhibited a marginal improvement in the corrosion resistance compared to those in the as-welded, solutionized and aged condition. Constant load SCC test data clearly revealed that the failure time of homogenized weld is much longer compared to other post weld treatments, and the homogenization treatment is recommended to improve the SCC life of GTA welds of MDN 250 Maraging steel.
基金Electric Ship Research De- velopment and Consortium (ESRDC) for providing financial support for the research work
文摘Due to the insufficient information regarding the aging phenomenon of cables caused by switching impulses, we aged 15 kV XLPE and EPR cable samples by 10 000 switching impulses in experiments and tested them. Plus in order to compare the aging phenome- non under multi-stress conditions, additional EPR cable samples were aged by rated AC voltage and current with switching impulses superimposed. We used measurements of partial discharge parameters to monitor the cables’ conditions during their aging process, and the AC breakdown voltages measurement to evaluate the cables after aging. Moreover, the Fourier transform infrared (FTIR) spectroscopy measurements revealed the changes of insulation materials after aging. The measurement results confirm that the accelerated aging of cable samples had taken place. The impacts of each individual aging factor are shown through the selected measurements and comparison. The study also helps to assess the reliability of the XLPE and EPR cables under similar condition while serving in power systems.
基金Projects(10772156, 10672136) supported by the National Natural Science Foundation of ChinaProject(05C100) supported by the Scientific Research Fund of Education Department of Hunan Province,China
文摘The effects of stress,ageing time and ageing temperature on creep behavior of poly(methyl methacrylate) were studied.After annealing above its glass transition temperature for a period of time to eliminate the stress and thermal history,the specimens were quenched and aged at various ageing temperatures for different ageing time,and then the short-term creep tests under different stress levels were carried out at room temperature.The creep strains were modeled by means of time-ageing time equivalence and time-stress equivalence,and the master creep curves were constructed via ageing time shift factors and stress shift factors.The results indicate that the creep rate increases with stress,while decreases with ageing time,and the ageing temperature history obviously affects the creep rate.For linear viscoelastic material,the ageing shift rate is independent on imposed stress,while for nonlinear viscoelastic material,the ageing shift rate decreases with increasing stress.The unified master creep curve up to 540 d at reference state was constructed by shifting the creep curves horizontally along the logarithmic time axis to overlap each other.It is demonstrated that the time-stress equivalence,united with the time-ageing time equivalence,provides an effective accelerated characterization technique in the laboratory to evaluate the long-term creep behavior of physical ageing polymers.
文摘Traditional ERP software system cannot efficiently su pport new management ideas such as BPR, DEM and virtual enterprise which emphasi zes that enterprise should be adjusted to market changes and business process ch ain and value chain should be integrated tightly. To solve these problems, this paper proposed the conception of Flexible ERP system. F-ERP is a self- adapti ve software system based on multi-agent technology. It developed the followin g kind of agents which are useful for F-ERP: business process agent, interf ace agent, data agent and decision and analysis agent. The F-ERP software syste m is an hierarchy system which is composed of data layer, system tools layer, bu siness application layer and business decision layer. It used component based de velopment mythology and complied with CORBA to development F-ERP. The F-ERP sy stem can support the new management ideas such as BPR, DEM and virtual enterpris e etc. By implementation of it, enterprise can improve its management and promot e its competence.
