Metal phosphides have been studied as prospective anode materials for sodium-ion batteries(SIBs)due to their higher specific capacity compared to other anode materials.However,rapid capacity decay and limited cycle li...Metal phosphides have been studied as prospective anode materials for sodium-ion batteries(SIBs)due to their higher specific capacity compared to other anode materials.However,rapid capacity decay and limited cycle life caused by volume expansion and low electrical conductivity of phosphides in SIBs remain still unsolved.To address these issues,GeP_(3) was first prepared by high-energy ball milling,and then Ketjen black(KB)was introduced to synthesize composite GeP_(3)/KB anode materials under controlled milling speed and time by a secondary ball milling process.During the ball milling process,GeP_(3) and KB form strong chemical bonds,resulting in a closely bonded composite.Consequently,the GeP_(3)/KB anodes was demonstrated excellent sodium storage performance,achieving a high reversible capacity of 933.41 mAh·g^(–1) at a current density of 0.05 A·g^(–1) for a special formula of GeP_(3)/KB-600-40 sample prepared at ball milling speed of 600 r/min for 40 h.Even at a high current density of 2 A·g^(–1) over 200 cycles,the capacity remains 314.52 mAh·g^(–1) with a retention rate of 66.6%.In conclusion,this work successfully prepares GeP_(3)/KB anode-carbon composite for electrodes by high-energy ball milling,which can restrict electrode volume expansion,enhance capacity,and improve cycle stability of SIBs.展开更多
A three-dimensional finite element model was established for the milling of thin-walled parts. The physical model of the milling of the part was established using the AdvantEdge FEM software as the platform. The alumi...A three-dimensional finite element model was established for the milling of thin-walled parts. The physical model of the milling of the part was established using the AdvantEdge FEM software as the platform. The aluminum alloy impeller was designated as the object to be processed and the boundary conditions which met the actual machining were set. Through the solution, the physical quantities such as the three-way cutting force, the tool temperature, and the tool stress were obtained, and the calculation of the elastic deformation of the thin-walled blade of the free-form surface at the contact points between the tool and the workpiece was realized. The elastic deformation law of the thin-walled blade was then predicted. The results show that the maximum deviation between the predicted value and the actual measured machining value of the elastic deformation was 26.055 μm; the minimum deviation was 2.011 μm, with the average deviation being 10.154 μm. This shows that the prediction is in close agreement with the actual result.展开更多
AlTiN,AlTiN–Cu and AlTiN/AlTiN–Cu coatings were prepared on WC–6%Co substrates by cathode arc evaporation deposition technology.Two kinds of nitrogen pressures were used to deposit both AlTiN–Cu and AlTiN/AlTiN–C...AlTiN,AlTiN–Cu and AlTiN/AlTiN–Cu coatings were prepared on WC–6%Co substrates by cathode arc evaporation deposition technology.Two kinds of nitrogen pressures were used to deposit both AlTiN–Cu and AlTiN/AlTiN–Cu coatings.Surface and cross-sectional morphologies of films were observed by scanning electron microscopy(SEM).Crystal structure of films was analyzed by X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).Hardness and adhesion of films were measured by nano-indentation and nano-scratch tester.Cutting tests were performed under milling conditions during wet machining of TC4 alloy.The results show that with addition of Cu,more droplets occur on AlTiN coating surface,but the grain size of it is refined,and the hardness decreases but the toughness is improved.Under higher N2 pressure,the defects on the surface of AlTiN–Cu and AlTiN/AlTiN–Cu coatings diminish,and the hardness of them is enhanced,while the adhesion is reduced.Compared to AlTiN coated cemented carbide tool,the lifetimes of AlTiN–Cu and AlTiN/AlTiN–Cu coated tools under the same N2 pressure are improved by 11%and 24%,respectively.展开更多
Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energ...Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.展开更多
A high-aspect-ratio microchannel heat exchanger based on multi-tool milling process was developed. Several slotting cutters were stacked together for simultaneously machining several high-aspect-ratio microchannels wi...A high-aspect-ratio microchannel heat exchanger based on multi-tool milling process was developed. Several slotting cutters were stacked together for simultaneously machining several high-aspect-ratio microchannels with manifold structures. On the basis of multi-tool milling process, the structural design of the manifold side height, microchannel length, width, number, and interval were analyzed. The heat transfer performances of high-aspect-ratio microchannel heat exchangers with two different manifolds were investigated by experiments, and the influencing factors were analyzed. The results indicate that the magnitude of heat transfer area per unit volume dominates the heat transfer performances of plate-type micro heat exchanger, while the velocity distribution between microchannels has little effects on the heat transfer performances.展开更多
An experiment about rice milling was made to study on the relationship between the different moisture content of brown rice and the energy consumption, the broken rice rate, the crack rate and the head rice yield. It ...An experiment about rice milling was made to study on the relationship between the different moisture content of brown rice and the energy consumption, the broken rice rate, the crack rate and the head rice yield. It could be concluded that the head rice yield increased at first falls and then along with the raise of moisture content and it could reach the maximum 70.78% when moisture content was 15.5%; the energy consumption of rice milling decreased along with the increase of moisture contents; the broken rice rate fell at first and then increased along with the raise of moisture contents and it could reach the minimum 4.28% when the moisture content was 15.5%.展开更多
To avoid the machine problems of excessive axial force, complex process flow and frequent tool changing during robotic drilling holes, a new hole-making technology (i.e., helical milling hole) was introduced for desig...To avoid the machine problems of excessive axial force, complex process flow and frequent tool changing during robotic drilling holes, a new hole-making technology (i.e., helical milling hole) was introduced for designing a new robotic helical milling hole system, which could further improve robotic hole-making ability in airplane digital assembly. After analysis on the characteristics of helical milling hole, advantages and limitations of two typical robotic helical milling hole systems were summarized. Then, vector model of helical milling hole movement was built on vector analysis method. Finally, surface roughness calculation formula was deduced according to the movement principle of helical milling hole, then the influence of main technological parameters on surface roughness was analyzed. Analysis shows that theoretical surface roughness of hole becomes poor with the increase of tool speed ratio and revolution radius. Meanwhile, the roughness decreases according to the increase of tool teeth number. The research contributes greatly to the construction of roughness prediction model in helical milling hole.展开更多
Nanocrystalline/amorphous La Mg11Ni+x Ni(x=100%, 200%, mass fraction) composite hydrogen storage alloys were synthesized by ball milling technology. The effects of Ni content and milling time on the gaseous hydrogen s...Nanocrystalline/amorphous La Mg11Ni+x Ni(x=100%, 200%, mass fraction) composite hydrogen storage alloys were synthesized by ball milling technology. The effects of Ni content and milling time on the gaseous hydrogen storage thermodynamics and dynamics of the alloys were systematically investigated. The hydrogen desorption properties were studied by Sievert's apparatus and a differential scanning calorimeter(DSC) connected with a H2 detector. The thermodynamic parameters(ΔH and ΔS) for the hydrogen absorption and desorption of the alloys were calculated by Van't Hoff equation. The hydrogen desorption activation energy of the alloy hydride was estimated using Arrhenius and Kissinger methods. The results indicate that a variation in the Ni content has a slight effect on the thermodynamic properties of the alloys, but it significantly improves their absorption and desorption kinetics performances. Furthermore, varying milling time clearly affects the hydrogen storage properties of the alloys. All the as-milled alloys show so fast hydrogen absorption rate that the absorbed amount in 10 min reaches to at least more than 95% of the saturated hydrogen absorption capacity. Moreover, the improvement of the gaseous hydrogen storage kinetics of the alloys is found to be ascribed to a decrease in the hydrogen desorption activation energy caused by increasing Ni content and prolong milling time.展开更多
In order to choose the appropriate reference surface on the machined surface roughness of Si Cp/Al composites, the cutting experiments of Si Cp/Al composites were carried out, and the machined surface topography was m...In order to choose the appropriate reference surface on the machined surface roughness of Si Cp/Al composites, the cutting experiments of Si Cp/Al composites were carried out, and the machined surface topography was measured by OLS3000 Confocal laser scanning microscope. The 3D measured data of machined surface topography were analyzed by the area power spectrum density. The result shows that the texture of machined surface topography in milling of Si Cp/Al composites is almost isotropic. This is the reason that the values of Rq at different locations on the same machined surface are obviously different. Through the comparison of performance of different filtering methods, the robust least squares reference surface can be used to extract the surface roughness of SiC p/Al composites effectively.展开更多
A new technology of treating molybdenum residues by simultaneous ultrafine milling and alkali leaching was put forward to recover molybdenum from metallurgical residues. The effects of residue size, milling time, soli...A new technology of treating molybdenum residues by simultaneous ultrafine milling and alkali leaching was put forward to recover molybdenum from metallurgical residues. The effects of residue size, milling time, solid content, n (Na 2CO 3)/ n (Mo) and slurry pH value on molybdenum leaching rate were investigated. The results indicate that a simpler process, lower slurry temperature, 50% shorter treating time, 60% decrease of Na 2CO 3 content and 15% increase of molybdenum leaching rate can be obtained by the new technology compared with the traditional process. The leaching kinetic equation was determined, and calculation of active energy ( E =56.2 kJ/mol) shows that the leaching process of molybdenum residues by simultaneous ultrafine milling and alkali leaching is controlled by chemical reaction. Potential exists for the new process to form the basis for an economically viable, environmentally friendly process to recover valuable elements from residues.展开更多
In accordance with the relative movement between end-milling cutter and workpiece surface, a theoretical generation model for milled surface was established with the movement error of principal axle considered. Then t...In accordance with the relative movement between end-milling cutter and workpiece surface, a theoretical generation model for milled surface was established with the movement error of principal axle considered. Then the milled surfaces under various cutting condition were simulated, the results of which showed that end milled surfaces were of "vaulted profile", heights of surface irregularty at various points to be different with maximum value in the middle and smaller at both sides, the difference were determined by diameter of milling cutter, feeding speed, ratio between the diameter of milling cutter and teeth point curve radius and width of workpiece. The study results can be applied to quality prediction of milled surfaces for precision and/or super precision milling operation.展开更多
Ball-end mill is widely used in workpiece processi ng with free-form surfaces. Such models that can predict processing character istics precisely are very necessary to the aim of cost reducing, quality improvi ng and ...Ball-end mill is widely used in workpiece processi ng with free-form surfaces. Such models that can predict processing character istics precisely are very necessary to the aim of cost reducing, quality improvi ng and productivity progressing, the cutting force prediction is the most import ant among these models. To explore the physical essence of metal cutting, model researchers commonly simplify the geometric conditions in cutting process, and a ssume that the geometric parameters that are needed to solve the physical models have already been predefined, so it results in the separation between model res earch and practical application. In this paper, for the representative cutting f orce models of ball end milling, a new extraction method of geometric parameters is suggested, which makes it possible for physical model to actually serve for the practical manufacturing, and take in the inspection of real production.展开更多
Ti Beta 21S (Ti-15Mo-2.7Nb-3Al-0.2Si) was devel op ed by TIMET in 1989. It is a metastable beta titanium alloy that offers subs tantial weight reductions over other engineering materials. Compared with common beta Ti ...Ti Beta 21S (Ti-15Mo-2.7Nb-3Al-0.2Si) was devel op ed by TIMET in 1989. It is a metastable beta titanium alloy that offers subs tantial weight reductions over other engineering materials. Compared with common beta Ti alloys, it offers the high specific strength, good cold formability, im proved oxidation resistance, elevated temperature strength, creep resistance, an d thermal stability. Besides the common characters of titanium alloy, such as po or heat diffusivity, low elastic modulus, Ti Beta 21S has very high specific str ength and good plasticity. These make Ti Beta 21S a difficult-to-cut material. In this paper, the tool wear and cutting force in milling process were studied by experiment. The tool wear experiments were carried out in order to determine the opticmum cutting parameters and tool material, and the purpose of cutting fo rce measurement is to explain the cuting phenomenon and tool wear results in fur ther degree. The machinablity assessment of Ti Beta 21S with different cutting t ools was given out. As a difficult-to-cut material, Ti Beta 21S should be mill ed with sharp-edged tool at lower cutting parameters to avoid severe wear of th e tool. Coolant should be used to conduct cutting heat. Proper tool material sho uld be selected, for example, the cutting force by YS25 tool is 20 percent lower than that by YG8 at the milling speed of 80 m/min. The roughness of flank and r ake surface is another important factor that affects tool wear and cutting f orce, and Ra should be below 0.2 μm while milling Ti Beta 21S. These results wi ll be useful in the actual production process, and have thrown new light on the cutting of difficult-to-cut material.展开更多
High speed machining has received an important interest because it leads to an increase of productivity and a better workpiece surface quality. However, at high cutting speeds, the tool wear increases dramatically due...High speed machining has received an important interest because it leads to an increase of productivity and a better workpiece surface quality. However, at high cutting speeds, the tool wear increases dramatically due to the high temperature at the tool-workpiece interface. Tool wear impairs the surface finish and hence the tool life is reduced. That is why an important objective of metal cutting research has been the assessment of tool wear patterns and mechanisms. In this paper, wear performances of PCBN tool, ceramic tool, coated carbide tool and fine-grained carbide tool in high speed face milling were presented when cutting cast iron, 45# tempered carbon steel and 45# hardened carbon steel. Tool wear patterns were examined through a tool-making microscope. The research results showed that tool wear types differed in various matching of materials between cutting tool and workpiece. The dominant wear patterns observed were rake face wear, flank wear, chipping, fracture and breakage. The main wear mechanisms were mechanical friction, adhesion, diffusion and chemical wear promoted by cutting forces and high cutting temperature. Hence, the important considerations of high speed cutting tool materials are high heat-resistance and wear-resistance, chemical stability as well as resistance to failure of coatings. The research results will be great benefit to the design and the selection of tool materials and control of tool wear in high-speed machining processes.展开更多
Form milling cutter is built-for-purpose cutter which process the form surface, for example, usually process male and female circular arc face and form trench and so on. From the traditional concept, form milling cutt...Form milling cutter is built-for-purpose cutter which process the form surface, for example, usually process male and female circular arc face and form trench and so on. From the traditional concept, form milling cutter is divided into pointed tooth and relieving follow its structure. Relieving shaped cutter is more convenient than pointed tooth milling cutter, because only its rake face is needed to grind after it turn into blunting, so the current books which are used in college almost select relieving shaped cutter in order to introduce how to design the form milling cutter.The curve of the back of tooth of relieving cutter is the transversal which is formed by the rear face of tooth in the end cut plane of the milling cutter. In the past, because of the limit of the manufacturing technology, the curve of the back of tooth is often selected Archimedes’ curve, in order that the shovel-nose tool acquire the uniform motion when the cutter shovel the back, in other word, the rear face of the milling cutter rotate its axis by the new cutting lip, in the same time, it move uniformly to the axis in order to form the surface. Although this curve of the back of tooth meet the fixedness of the form of blade around grinding the cutter, the rear angle of the dot of the cutting lip don’t keep fixedness. With the development of the modern manufacturing technology, the unmanageable problem of many complex curves is already easily solved. So it is need to study the optimum profile of the curve of the back of tooth in theory, and study the design theory of the relieving shaped cutter under the condition of new manufacture, in order to ensure that the rear angle of the dot of the cutting lip keep fixedness after the relieving shaped cutter is grinded. The paper derive the curve profile of tooth of the form cutter and the modifier calculation formula of the profile of the cutter edge from the definition of the rear angle of the cutter, which establish the foundation for the precision design and manufacture of other form cutter.展开更多
The profit margin in the flour milling industry is quite narrow,so high-quality raw materials and efficiency of milling operations are crucial for every company. Many flour mills,especially those which import wheat fr...The profit margin in the flour milling industry is quite narrow,so high-quality raw materials and efficiency of milling operations are crucial for every company. Many flour mills,especially those which import wheat from other countries and have limited storage space for the different varieties or classes of wheat,can not afford to buy low quality wheat. Consequently,a mathematical model which can test the impact and interactions of raw materials,in technical point of view,would be a useful decision-making tool for the milling industry. A flour miller tests wheat for physical and chemical characteristics,cleanness and soundness. The miller also performs experimental milling,if available,to have some idea how the given wheat will behave during commercial milling. Based on these test results,the miller can only guess the commercial milling results such as flour yields and flour ash and protein contents. Thus,the objective of this study was to develop empirical equations to estimate commercial milling results,using the physical,chemical and experimental milling data of the given wheat blend and also,additionally,flour ash and protein specifications of the end-user. This was done by using the actual commercial milling procedures and their wheat physical,chemical,experimental milling data,and other vital data. Data were collected from a commercial mill located in East Asia that had four production lines and used wheat blend combinations from five different wheat classes,i.e. Hard Red Winter (HRW),Dark Northern Spring (DNS),Soft White (SW),Australian Soft (AS),and Australian Standard White (ASW) wheat to produce over 40 different products. The wheat physical and chemical characteristics included test weight,thousand kernel weight,ash and protein contents. The experimental milling data were straight-grade and patent flour yields,along with patent flour ash and protein contents from a Buhler experimental mill. The commercial milling results included the flour yields of patent,first clear,and second clear flours,as well as the ash and protein contents of commercial patent flours. Using multiple linear regression procedures,we have developed empirical equations to be able to estimate the commercial patent flour yields with R2 values above 0.90 for all four production lines,and commercial first clear flour yields with R2 values ranging 0.76 to 0.98,and the commercial patent flour protein contents with R2 values of 0.89 to 0.92. However,the yields of commercial second clear flours and the commercial patent flour ash contents were not able to be estimated with high coefficients of determination (R2 values). We recommend that the empirical equations for estimating commercial milling parameters should be derived using data from each individual flour milling company,for each production line of a given mill,and furthermore,tailored to specific products at a given ash and/or protein contents desired by end-users.展开更多
The effect of moisture conditioned for brown rice （moisture content of 1.45%） on milling characteristic was studied in this paper. Milling experiments were conducted for the brown rice, which were conditioned under ...The effect of moisture conditioned for brown rice （moisture content of 1.45%） on milling characteristic was studied in this paper. Milling experiments were conducted for the brown rice, which were conditioned under different amount of humidification and duration. Software SAS was used to analyze the effect of amount of humidification and duration on the head rice yield and energy consumption of milled brown rice. The reasonable parameters including amount of humidification of 1.45% and duration of 60-90 rain were obtained, which decreased energy consumption by 30% and increased head rice yield by 10%. Therefore, the method of moisture conditioned can improve milling quality of stored paddy due to the hardness and crisp of paddy reduced.展开更多
In order to control cutting force and its direction i n milling operation, a new milling head was developed. The head has two milling cutters, which are connected by a pair of gears and rotate in opposite direction re...In order to control cutting force and its direction i n milling operation, a new milling head was developed. The head has two milling cutters, which are connected by a pair of gears and rotate in opposite direction respectively. Both up-cut and down-cut can be carried out simultaneously by t hese milling cutters. The each depth of cut, the ratio of up/down cutting depth , by these cutters can be also selected. The cutting force characteristics were experimentally discussed by changing the ratio. The cutting force and its locus can be also changed by the selection of the ratio of up/down cutting depth. For practical usage of the head the analytical prediction method of the cutting forc e characteristics under selected cutting condition was proposed based on the ene rgy approach method proposed, in which both of cutting force characteristics of a single milling cutter and the combined milling cutter under a selected up/dow n cutting depth ratio were analytically estimated based on the two dimensional c utting data. It was experimentally shown that in NC milling machine the cutting force locus was controlled in pre-determined direction under various tool paths .展开更多
Boron has been considered a promising powdered metal fuel for enhancing composite propellants'energy output due to its high energy density.However,the high ignition temperature and low combustion efficiency limit ...Boron has been considered a promising powdered metal fuel for enhancing composite propellants'energy output due to its high energy density.However,the high ignition temperature and low combustion efficiency limit the application of boron powder due to the high boiling point of the boron oxide layer.Much research is ongoing to overcome these shortcomings,and one potential approach is to introduce a small quantity of metal oxide additives to promote the reaction of boron.This study prepared boron-rich fuels with 10 wt%of eight nano-metal oxide additives by mechanical ball milling.The effect of metal oxides on the thermo-oxidation,ignition,and combustion properties of boron powder was comprehensively studied by the thermogravimetric analysis(TG),the electrically heated filament setup(T-jump),and the laser-induced combustion experiments.TG experiments at 5 K/min found that Bi_(2)O_(3),MoO_(3),TiO_(2),Fe_(2)O_(3),and CuO can promote thermo-oxidation of boron.Compared to pure boron,Tonsetcan be reduced from 569℃to a minimum of 449℃(B/Bi_(2)O_(3)).Infrared temperature measurement in T-jump tests showed that when heated by an electric heating wire at rates from 1000 K/s to 25000 K/s,the ignition temperatures of B/Bi_(2)O_(3) are the lowest,even lower than the melting point of boron oxide.Ignition images and SEM for the products further showed that the high heating rate is beneficial to the rapid reaction of boron powder in the single-particle combustion state.Fuels(B/Bi_(2)O_(3),B/MoO_(3),and B/CuO)were mixed with the oxidant AP and ignited by laser to study the combustion performance.The results showed that B/CuO/AP has the largest flame area,the highest BO_(2) characteristic spectral intensity,and the largest burn rate for powder lines.To combine the advantages of CuO and Bi_(2)O_(3),binary metal oxide(CBO,mass ratio of 3:1)was prepared and the test results showed that CBO can very well improve both ignition and combustion properties of boron.Especially B/CBO/AP has the highest burn rate compared with all fuels containing other additives.It was found that multi-component metal-oxide additive can more synergistically improve the reaction characteristics of boron powder than unary additive.These findings contribute to the development of boron-rich fuels and their application in propellants.展开更多
基金National Natural Science Foundation of China Young Scientist Fund(22105120)Shaanxi Province Qin Chuangyuan“Scientist+Engineer”Team Construction Project(2024QCY-KXJ-127)。
文摘Metal phosphides have been studied as prospective anode materials for sodium-ion batteries(SIBs)due to their higher specific capacity compared to other anode materials.However,rapid capacity decay and limited cycle life caused by volume expansion and low electrical conductivity of phosphides in SIBs remain still unsolved.To address these issues,GeP_(3) was first prepared by high-energy ball milling,and then Ketjen black(KB)was introduced to synthesize composite GeP_(3)/KB anode materials under controlled milling speed and time by a secondary ball milling process.During the ball milling process,GeP_(3) and KB form strong chemical bonds,resulting in a closely bonded composite.Consequently,the GeP_(3)/KB anodes was demonstrated excellent sodium storage performance,achieving a high reversible capacity of 933.41 mAh·g^(–1) at a current density of 0.05 A·g^(–1) for a special formula of GeP_(3)/KB-600-40 sample prepared at ball milling speed of 600 r/min for 40 h.Even at a high current density of 2 A·g^(–1) over 200 cycles,the capacity remains 314.52 mAh·g^(–1) with a retention rate of 66.6%.In conclusion,this work successfully prepares GeP_(3)/KB anode-carbon composite for electrodes by high-energy ball milling,which can restrict electrode volume expansion,enhance capacity,and improve cycle stability of SIBs.
基金Project(U1530138)supported by the National Natural Science Foundation of ChinaProject(A1-8903-17-0103)supported by the Natural Science Foundation of Shanghai Municipal Education Commission,China
文摘A three-dimensional finite element model was established for the milling of thin-walled parts. The physical model of the milling of the part was established using the AdvantEdge FEM software as the platform. The aluminum alloy impeller was designated as the object to be processed and the boundary conditions which met the actual machining were set. Through the solution, the physical quantities such as the three-way cutting force, the tool temperature, and the tool stress were obtained, and the calculation of the elastic deformation of the thin-walled blade of the free-form surface at the contact points between the tool and the workpiece was realized. The elastic deformation law of the thin-walled blade was then predicted. The results show that the maximum deviation between the predicted value and the actual measured machining value of the elastic deformation was 26.055 μm; the minimum deviation was 2.011 μm, with the average deviation being 10.154 μm. This shows that the prediction is in close agreement with the actual result.
基金Project(2014ZX04012011)supported by Major National Science and Technology Projects,ChinaProject(51327902)supported by the National Natural Science Foundation of China
文摘AlTiN,AlTiN–Cu and AlTiN/AlTiN–Cu coatings were prepared on WC–6%Co substrates by cathode arc evaporation deposition technology.Two kinds of nitrogen pressures were used to deposit both AlTiN–Cu and AlTiN/AlTiN–Cu coatings.Surface and cross-sectional morphologies of films were observed by scanning electron microscopy(SEM).Crystal structure of films was analyzed by X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).Hardness and adhesion of films were measured by nano-indentation and nano-scratch tester.Cutting tests were performed under milling conditions during wet machining of TC4 alloy.The results show that with addition of Cu,more droplets occur on AlTiN coating surface,but the grain size of it is refined,and the hardness decreases but the toughness is improved.Under higher N2 pressure,the defects on the surface of AlTiN–Cu and AlTiN/AlTiN–Cu coatings diminish,and the hardness of them is enhanced,while the adhesion is reduced.Compared to AlTiN coated cemented carbide tool,the lifetimes of AlTiN–Cu and AlTiN/AlTiN–Cu coated tools under the same N2 pressure are improved by 11%and 24%,respectively.
基金Project(MSV-2013-09)supported by State Key Laboratory of Mechanical System and Vibration,China
文摘Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.
基金Projects(50675070 50805052) supported by the National Nature Science Foundation of China+1 种基金Projects(07118064 8451064101000320) supported by the Natural Science Foundation of Guangdong Province
文摘A high-aspect-ratio microchannel heat exchanger based on multi-tool milling process was developed. Several slotting cutters were stacked together for simultaneously machining several high-aspect-ratio microchannels with manifold structures. On the basis of multi-tool milling process, the structural design of the manifold side height, microchannel length, width, number, and interval were analyzed. The heat transfer performances of high-aspect-ratio microchannel heat exchangers with two different manifolds were investigated by experiments, and the influencing factors were analyzed. The results indicate that the magnitude of heat transfer area per unit volume dominates the heat transfer performances of plate-type micro heat exchanger, while the velocity distribution between microchannels has little effects on the heat transfer performances.
基金Tenth Five-year Plan of the Committee of the Science and Technology of Heilongjiang Province (GB02B4040-1)Item of Heilongjiang Education Bureau (10511012)
文摘An experiment about rice milling was made to study on the relationship between the different moisture content of brown rice and the energy consumption, the broken rice rate, the crack rate and the head rice yield. It could be concluded that the head rice yield increased at first falls and then along with the raise of moisture content and it could reach the maximum 70.78% when moisture content was 15.5%; the energy consumption of rice milling decreased along with the increase of moisture contents; the broken rice rate fell at first and then increased along with the raise of moisture contents and it could reach the minimum 4.28% when the moisture content was 15.5%.
基金Foundation item： Projects（50975141, 51005118） supported by the National Natural Science Foundation of China Projects（20091652018, 2010352005） supported by Aviation Science Fund of China Project（YKJ11-001） supported by Key Program of Nanjing College of Information Technology Institute, China
文摘To avoid the machine problems of excessive axial force, complex process flow and frequent tool changing during robotic drilling holes, a new hole-making technology (i.e., helical milling hole) was introduced for designing a new robotic helical milling hole system, which could further improve robotic hole-making ability in airplane digital assembly. After analysis on the characteristics of helical milling hole, advantages and limitations of two typical robotic helical milling hole systems were summarized. Then, vector model of helical milling hole movement was built on vector analysis method. Finally, surface roughness calculation formula was deduced according to the movement principle of helical milling hole, then the influence of main technological parameters on surface roughness was analyzed. Analysis shows that theoretical surface roughness of hole becomes poor with the increase of tool speed ratio and revolution radius. Meanwhile, the roughness decreases according to the increase of tool teeth number. The research contributes greatly to the construction of roughness prediction model in helical milling hole.
基金Projects(51161015,51371094,51471054)supported by the National Natural Science Foundation of China
文摘Nanocrystalline/amorphous La Mg11Ni+x Ni(x=100%, 200%, mass fraction) composite hydrogen storage alloys were synthesized by ball milling technology. The effects of Ni content and milling time on the gaseous hydrogen storage thermodynamics and dynamics of the alloys were systematically investigated. The hydrogen desorption properties were studied by Sievert's apparatus and a differential scanning calorimeter(DSC) connected with a H2 detector. The thermodynamic parameters(ΔH and ΔS) for the hydrogen absorption and desorption of the alloys were calculated by Van't Hoff equation. The hydrogen desorption activation energy of the alloy hydride was estimated using Arrhenius and Kissinger methods. The results indicate that a variation in the Ni content has a slight effect on the thermodynamic properties of the alloys, but it significantly improves their absorption and desorption kinetics performances. Furthermore, varying milling time clearly affects the hydrogen storage properties of the alloys. All the as-milled alloys show so fast hydrogen absorption rate that the absorbed amount in 10 min reaches to at least more than 95% of the saturated hydrogen absorption capacity. Moreover, the improvement of the gaseous hydrogen storage kinetics of the alloys is found to be ascribed to a decrease in the hydrogen desorption activation energy caused by increasing Ni content and prolong milling time.
基金Projects(51305284,61203208) supported by the National Natural Science Foundation of China
文摘In order to choose the appropriate reference surface on the machined surface roughness of Si Cp/Al composites, the cutting experiments of Si Cp/Al composites were carried out, and the machined surface topography was measured by OLS3000 Confocal laser scanning microscope. The 3D measured data of machined surface topography were analyzed by the area power spectrum density. The result shows that the texture of machined surface topography in milling of Si Cp/Al composites is almost isotropic. This is the reason that the values of Rq at different locations on the same machined surface are obviously different. Through the comparison of performance of different filtering methods, the robust least squares reference surface can be used to extract the surface roughness of SiC p/Al composites effectively.
文摘A new technology of treating molybdenum residues by simultaneous ultrafine milling and alkali leaching was put forward to recover molybdenum from metallurgical residues. The effects of residue size, milling time, solid content, n (Na 2CO 3)/ n (Mo) and slurry pH value on molybdenum leaching rate were investigated. The results indicate that a simpler process, lower slurry temperature, 50% shorter treating time, 60% decrease of Na 2CO 3 content and 15% increase of molybdenum leaching rate can be obtained by the new technology compared with the traditional process. The leaching kinetic equation was determined, and calculation of active energy ( E =56.2 kJ/mol) shows that the leaching process of molybdenum residues by simultaneous ultrafine milling and alkali leaching is controlled by chemical reaction. Potential exists for the new process to form the basis for an economically viable, environmentally friendly process to recover valuable elements from residues.
文摘In accordance with the relative movement between end-milling cutter and workpiece surface, a theoretical generation model for milled surface was established with the movement error of principal axle considered. Then the milled surfaces under various cutting condition were simulated, the results of which showed that end milled surfaces were of "vaulted profile", heights of surface irregularty at various points to be different with maximum value in the middle and smaller at both sides, the difference were determined by diameter of milling cutter, feeding speed, ratio between the diameter of milling cutter and teeth point curve radius and width of workpiece. The study results can be applied to quality prediction of milled surfaces for precision and/or super precision milling operation.
文摘Ball-end mill is widely used in workpiece processi ng with free-form surfaces. Such models that can predict processing character istics precisely are very necessary to the aim of cost reducing, quality improvi ng and productivity progressing, the cutting force prediction is the most import ant among these models. To explore the physical essence of metal cutting, model researchers commonly simplify the geometric conditions in cutting process, and a ssume that the geometric parameters that are needed to solve the physical models have already been predefined, so it results in the separation between model res earch and practical application. In this paper, for the representative cutting f orce models of ball end milling, a new extraction method of geometric parameters is suggested, which makes it possible for physical model to actually serve for the practical manufacturing, and take in the inspection of real production.
文摘Ti Beta 21S (Ti-15Mo-2.7Nb-3Al-0.2Si) was devel op ed by TIMET in 1989. It is a metastable beta titanium alloy that offers subs tantial weight reductions over other engineering materials. Compared with common beta Ti alloys, it offers the high specific strength, good cold formability, im proved oxidation resistance, elevated temperature strength, creep resistance, an d thermal stability. Besides the common characters of titanium alloy, such as po or heat diffusivity, low elastic modulus, Ti Beta 21S has very high specific str ength and good plasticity. These make Ti Beta 21S a difficult-to-cut material. In this paper, the tool wear and cutting force in milling process were studied by experiment. The tool wear experiments were carried out in order to determine the opticmum cutting parameters and tool material, and the purpose of cutting fo rce measurement is to explain the cuting phenomenon and tool wear results in fur ther degree. The machinablity assessment of Ti Beta 21S with different cutting t ools was given out. As a difficult-to-cut material, Ti Beta 21S should be mill ed with sharp-edged tool at lower cutting parameters to avoid severe wear of th e tool. Coolant should be used to conduct cutting heat. Proper tool material sho uld be selected, for example, the cutting force by YS25 tool is 20 percent lower than that by YG8 at the milling speed of 80 m/min. The roughness of flank and r ake surface is another important factor that affects tool wear and cutting f orce, and Ra should be below 0.2 μm while milling Ti Beta 21S. These results wi ll be useful in the actual production process, and have thrown new light on the cutting of difficult-to-cut material.
文摘High speed machining has received an important interest because it leads to an increase of productivity and a better workpiece surface quality. However, at high cutting speeds, the tool wear increases dramatically due to the high temperature at the tool-workpiece interface. Tool wear impairs the surface finish and hence the tool life is reduced. That is why an important objective of metal cutting research has been the assessment of tool wear patterns and mechanisms. In this paper, wear performances of PCBN tool, ceramic tool, coated carbide tool and fine-grained carbide tool in high speed face milling were presented when cutting cast iron, 45# tempered carbon steel and 45# hardened carbon steel. Tool wear patterns were examined through a tool-making microscope. The research results showed that tool wear types differed in various matching of materials between cutting tool and workpiece. The dominant wear patterns observed were rake face wear, flank wear, chipping, fracture and breakage. The main wear mechanisms were mechanical friction, adhesion, diffusion and chemical wear promoted by cutting forces and high cutting temperature. Hence, the important considerations of high speed cutting tool materials are high heat-resistance and wear-resistance, chemical stability as well as resistance to failure of coatings. The research results will be great benefit to the design and the selection of tool materials and control of tool wear in high-speed machining processes.
文摘Form milling cutter is built-for-purpose cutter which process the form surface, for example, usually process male and female circular arc face and form trench and so on. From the traditional concept, form milling cutter is divided into pointed tooth and relieving follow its structure. Relieving shaped cutter is more convenient than pointed tooth milling cutter, because only its rake face is needed to grind after it turn into blunting, so the current books which are used in college almost select relieving shaped cutter in order to introduce how to design the form milling cutter.The curve of the back of tooth of relieving cutter is the transversal which is formed by the rear face of tooth in the end cut plane of the milling cutter. In the past, because of the limit of the manufacturing technology, the curve of the back of tooth is often selected Archimedes’ curve, in order that the shovel-nose tool acquire the uniform motion when the cutter shovel the back, in other word, the rear face of the milling cutter rotate its axis by the new cutting lip, in the same time, it move uniformly to the axis in order to form the surface. Although this curve of the back of tooth meet the fixedness of the form of blade around grinding the cutter, the rear angle of the dot of the cutting lip don’t keep fixedness. With the development of the modern manufacturing technology, the unmanageable problem of many complex curves is already easily solved. So it is need to study the optimum profile of the curve of the back of tooth in theory, and study the design theory of the relieving shaped cutter under the condition of new manufacture, in order to ensure that the rear angle of the dot of the cutting lip keep fixedness after the relieving shaped cutter is grinded. The paper derive the curve profile of tooth of the form cutter and the modifier calculation formula of the profile of the cutter edge from the definition of the rear angle of the cutter, which establish the foundation for the precision design and manufacture of other form cutter.
文摘The profit margin in the flour milling industry is quite narrow,so high-quality raw materials and efficiency of milling operations are crucial for every company. Many flour mills,especially those which import wheat from other countries and have limited storage space for the different varieties or classes of wheat,can not afford to buy low quality wheat. Consequently,a mathematical model which can test the impact and interactions of raw materials,in technical point of view,would be a useful decision-making tool for the milling industry. A flour miller tests wheat for physical and chemical characteristics,cleanness and soundness. The miller also performs experimental milling,if available,to have some idea how the given wheat will behave during commercial milling. Based on these test results,the miller can only guess the commercial milling results such as flour yields and flour ash and protein contents. Thus,the objective of this study was to develop empirical equations to estimate commercial milling results,using the physical,chemical and experimental milling data of the given wheat blend and also,additionally,flour ash and protein specifications of the end-user. This was done by using the actual commercial milling procedures and their wheat physical,chemical,experimental milling data,and other vital data. Data were collected from a commercial mill located in East Asia that had four production lines and used wheat blend combinations from five different wheat classes,i.e. Hard Red Winter (HRW),Dark Northern Spring (DNS),Soft White (SW),Australian Soft (AS),and Australian Standard White (ASW) wheat to produce over 40 different products. The wheat physical and chemical characteristics included test weight,thousand kernel weight,ash and protein contents. The experimental milling data were straight-grade and patent flour yields,along with patent flour ash and protein contents from a Buhler experimental mill. The commercial milling results included the flour yields of patent,first clear,and second clear flours,as well as the ash and protein contents of commercial patent flours. Using multiple linear regression procedures,we have developed empirical equations to be able to estimate the commercial patent flour yields with R2 values above 0.90 for all four production lines,and commercial first clear flour yields with R2 values ranging 0.76 to 0.98,and the commercial patent flour protein contents with R2 values of 0.89 to 0.92. However,the yields of commercial second clear flours and the commercial patent flour ash contents were not able to be estimated with high coefficients of determination (R2 values). We recommend that the empirical equations for estimating commercial milling parameters should be derived using data from each individual flour milling company,for each production line of a given mill,and furthermore,tailored to specific products at a given ash and/or protein contents desired by end-users.
基金the Tenth Five-Year Plan of the Science and Technology of Heilongjiang Province (GB02B4040-1)Attack Item of Plan of the Science and Technology of Harbin (2005AA6CN178)
文摘The effect of moisture conditioned for brown rice （moisture content of 1.45%） on milling characteristic was studied in this paper. Milling experiments were conducted for the brown rice, which were conditioned under different amount of humidification and duration. Software SAS was used to analyze the effect of amount of humidification and duration on the head rice yield and energy consumption of milled brown rice. The reasonable parameters including amount of humidification of 1.45% and duration of 60-90 rain were obtained, which decreased energy consumption by 30% and increased head rice yield by 10%. Therefore, the method of moisture conditioned can improve milling quality of stored paddy due to the hardness and crisp of paddy reduced.
文摘In order to control cutting force and its direction i n milling operation, a new milling head was developed. The head has two milling cutters, which are connected by a pair of gears and rotate in opposite direction respectively. Both up-cut and down-cut can be carried out simultaneously by t hese milling cutters. The each depth of cut, the ratio of up/down cutting depth , by these cutters can be also selected. The cutting force characteristics were experimentally discussed by changing the ratio. The cutting force and its locus can be also changed by the selection of the ratio of up/down cutting depth. For practical usage of the head the analytical prediction method of the cutting forc e characteristics under selected cutting condition was proposed based on the ene rgy approach method proposed, in which both of cutting force characteristics of a single milling cutter and the combined milling cutter under a selected up/dow n cutting depth ratio were analytically estimated based on the two dimensional c utting data. It was experimentally shown that in NC milling machine the cutting force locus was controlled in pre-determined direction under various tool paths .
基金State Key Laboratory of Explosion Science and Safety Protection of China (Grant No.QNKT21-8)National Natural Science Foundation of China (Grant No.12302432)to provide financial support。
文摘Boron has been considered a promising powdered metal fuel for enhancing composite propellants'energy output due to its high energy density.However,the high ignition temperature and low combustion efficiency limit the application of boron powder due to the high boiling point of the boron oxide layer.Much research is ongoing to overcome these shortcomings,and one potential approach is to introduce a small quantity of metal oxide additives to promote the reaction of boron.This study prepared boron-rich fuels with 10 wt%of eight nano-metal oxide additives by mechanical ball milling.The effect of metal oxides on the thermo-oxidation,ignition,and combustion properties of boron powder was comprehensively studied by the thermogravimetric analysis(TG),the electrically heated filament setup(T-jump),and the laser-induced combustion experiments.TG experiments at 5 K/min found that Bi_(2)O_(3),MoO_(3),TiO_(2),Fe_(2)O_(3),and CuO can promote thermo-oxidation of boron.Compared to pure boron,Tonsetcan be reduced from 569℃to a minimum of 449℃(B/Bi_(2)O_(3)).Infrared temperature measurement in T-jump tests showed that when heated by an electric heating wire at rates from 1000 K/s to 25000 K/s,the ignition temperatures of B/Bi_(2)O_(3) are the lowest,even lower than the melting point of boron oxide.Ignition images and SEM for the products further showed that the high heating rate is beneficial to the rapid reaction of boron powder in the single-particle combustion state.Fuels(B/Bi_(2)O_(3),B/MoO_(3),and B/CuO)were mixed with the oxidant AP and ignited by laser to study the combustion performance.The results showed that B/CuO/AP has the largest flame area,the highest BO_(2) characteristic spectral intensity,and the largest burn rate for powder lines.To combine the advantages of CuO and Bi_(2)O_(3),binary metal oxide(CBO,mass ratio of 3:1)was prepared and the test results showed that CBO can very well improve both ignition and combustion properties of boron.Especially B/CBO/AP has the highest burn rate compared with all fuels containing other additives.It was found that multi-component metal-oxide additive can more synergistically improve the reaction characteristics of boron powder than unary additive.These findings contribute to the development of boron-rich fuels and their application in propellants.
