The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development...The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development of the construction strategies for achieving zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) micro/nanostructures from energetic molecules is introduced. Also, an overview of the unique properties induced by micro/nanostructures and size effects is provided. Special emphasis is focused on the size-dependent properties that are different from those of the conventional micro-sized energetic materials, such as thermal decomposition, sensitivity, combustion and detonation, and compaction behaviors. A conclusion and our view of the future development of micro/nano-energetic materials and devices are given.展开更多
Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two diffe...Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two different modes including filmwise (FWC) and dropwise (DWC) condensation.DWC occurring on hydrophobic and superhydrophobic surfaces has a much higher heat transfer capacity than FWC.Therefore,wide investigations have been done to produce DWC in recent years.Superhydrophobic surfaces have micro/nano structures with low surface energy.In this study,a two-step electrodeposition process is used to produce micro/nano structures on copper specimens.The surface energy of specimens is reduced by a self-assembled monolayer using ethanol and 1-octadecanethiol solution.The results show that there is an optimum condition for electrodeposition parameters.For example,a surface prepared by 2000 s step time has 5 times greater heat transfer than FWC while a surface with 4000 s step time has nearly the same heat transfer as FWC.The surfaces of the fabricated specimens are examined using XRD and SEM analyses.The SEM analyses of the surfaces show that there are some micro-structures on the surfaces and the surface porosities are reduced by increasing the second step electrodeposition time.展开更多
The Chamba\|Bharmaur syncline located in between Zanskar range in the north and Dhauladhar\|Pirpanjal range in the south , in the Chamba district of Western Himachal Pradesh. The rocks constituting Chamba\|Bharmaur sy...The Chamba\|Bharmaur syncline located in between Zanskar range in the north and Dhauladhar\|Pirpanjal range in the south , in the Chamba district of Western Himachal Pradesh. The rocks constituting Chamba\|Bharmaur syncline belong to Precambrian to Lr. Triassic (Rattan, 1973) and represent the southern extension of the Tethyan facies of the Zanskar Tethys Himalayan sequence (Thakur, 1998). The geological and structural mapping in the Chamba\|Bharmaur syncline reveal that the area comprises of various litho\|units which show imprint of various phases of deformation. Three main phases of deformation DF\-1, DF\-2 and DF\-3 have affected the rocks of the Chamba\|Bharmaur syncline. The earliest recognisable deformational structures of the area are tight isoclinal folds appressed with long drawn out limbs and thickened hinges have experienced buckle shortening of 80%. They have been rendered intrafolial folds in many places; only a few of them show disharmony. The folds initiated in the multilayered sequences are generally controlled in their distribution and wave\|length by more competent members of the sequence.展开更多
Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface ...Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface with interaction high speed wire electrode discharge machining (HS-WEDM). The other was the ramification of MCAS, named micro-column-array and sintered-copper compound structure (MSCS), which was fabricated with sintered method on micro-column array structure. Considering the wall superheat and critical heat flux (CHF), comparisons were made between them. The results show that both MCAS and MSCS can enhance the boiling heat transfer. It is also found that the enhanced boiling heat transfer ability of MSCS is changed obviously while the porosity of the sintered copper layer is changed.展开更多
The 3-D velocity tomography image of the central-eastern part of Qilianshan is obtained by the joint inversion of 3-D velocity structure and focal parameters based on the S-P data of micro-earthquakes recorded by the ...The 3-D velocity tomography image of the central-eastern part of Qilianshan is obtained by the joint inversion of 3-D velocity structure and focal parameters based on the S-P data of micro-earthquakes recorded by the digital seismic network set up for a Sino-French cooperation program since 1996. The inversed velocity structure does primarily reflect some important features of the deep structure in the region and provide the scientific background for the further study of active tectonic structure and the calculation of earthquake parameters.展开更多
The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2...The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.展开更多
基金Sponsored by National Natural Science Foundation of China (21231002,21276026,21271023,21173021,91022006,11202193,11172276,and 11072225)the 111 Project ( B07012)+1 种基金the Program of Cooperation of the Beijing Education Commission ( 20091739006)Specialized Research Fund for the Doctoral Program of Higher Education ( 20101101110031)
文摘The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development of the construction strategies for achieving zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) micro/nanostructures from energetic molecules is introduced. Also, an overview of the unique properties induced by micro/nanostructures and size effects is provided. Special emphasis is focused on the size-dependent properties that are different from those of the conventional micro-sized energetic materials, such as thermal decomposition, sensitivity, combustion and detonation, and compaction behaviors. A conclusion and our view of the future development of micro/nano-energetic materials and devices are given.
文摘Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two different modes including filmwise (FWC) and dropwise (DWC) condensation.DWC occurring on hydrophobic and superhydrophobic surfaces has a much higher heat transfer capacity than FWC.Therefore,wide investigations have been done to produce DWC in recent years.Superhydrophobic surfaces have micro/nano structures with low surface energy.In this study,a two-step electrodeposition process is used to produce micro/nano structures on copper specimens.The surface energy of specimens is reduced by a self-assembled monolayer using ethanol and 1-octadecanethiol solution.The results show that there is an optimum condition for electrodeposition parameters.For example,a surface prepared by 2000 s step time has 5 times greater heat transfer than FWC while a surface with 4000 s step time has nearly the same heat transfer as FWC.The surfaces of the fabricated specimens are examined using XRD and SEM analyses.The SEM analyses of the surfaces show that there are some micro-structures on the surfaces and the surface porosities are reduced by increasing the second step electrodeposition time.
文摘The Chamba\|Bharmaur syncline located in between Zanskar range in the north and Dhauladhar\|Pirpanjal range in the south , in the Chamba district of Western Himachal Pradesh. The rocks constituting Chamba\|Bharmaur syncline belong to Precambrian to Lr. Triassic (Rattan, 1973) and represent the southern extension of the Tethyan facies of the Zanskar Tethys Himalayan sequence (Thakur, 1998). The geological and structural mapping in the Chamba\|Bharmaur syncline reveal that the area comprises of various litho\|units which show imprint of various phases of deformation. Three main phases of deformation DF\-1, DF\-2 and DF\-3 have affected the rocks of the Chamba\|Bharmaur syncline. The earliest recognisable deformational structures of the area are tight isoclinal folds appressed with long drawn out limbs and thickened hinges have experienced buckle shortening of 80%. They have been rendered intrafolial folds in many places; only a few of them show disharmony. The folds initiated in the multilayered sequences are generally controlled in their distribution and wave\|length by more competent members of the sequence.
基金Projects(50605023 50436010) supported by the National Natural Science Foundation of China
文摘Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface with interaction high speed wire electrode discharge machining (HS-WEDM). The other was the ramification of MCAS, named micro-column-array and sintered-copper compound structure (MSCS), which was fabricated with sintered method on micro-column array structure. Considering the wall superheat and critical heat flux (CHF), comparisons were made between them. The results show that both MCAS and MSCS can enhance the boiling heat transfer. It is also found that the enhanced boiling heat transfer ability of MSCS is changed obviously while the porosity of the sintered copper layer is changed.
基金National Natural Science Foundation of China (40074010) and Natural Science Foundation of Gansu Province (ZS981-A25-011)
文摘The 3-D velocity tomography image of the central-eastern part of Qilianshan is obtained by the joint inversion of 3-D velocity structure and focal parameters based on the S-P data of micro-earthquakes recorded by the digital seismic network set up for a Sino-French cooperation program since 1996. The inversed velocity structure does primarily reflect some important features of the deep structure in the region and provide the scientific background for the further study of active tectonic structure and the calculation of earthquake parameters.
基金The Ministry of Science and Higher Education of the Russian Federation(Agreement with Zelinsky Institute of Organic Chemistry RAS No 075-15-2020-803).
文摘The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.
