Tributyl phosphate(TBP) was employed for the Bi(Ⅲ) extraction from hydrochloric acid medium.The effects of extraction time and material concentration were examined.The replacement mechanism between the anion(Cl^-) an...Tributyl phosphate(TBP) was employed for the Bi(Ⅲ) extraction from hydrochloric acid medium.The effects of extraction time and material concentration were examined.The replacement mechanism between the anion(Cl^-) and TBP was proposed for extraction.The results show the species extracted into the organic phase were found to be mainly BiCl_3·x TBP(x=2 or 3).Thermodynamic parameters of the extraction reaction were obtained from the thermodynamics analysis,which illustrates that higher temperatures show a negative effect on the extraction.Extraction isotherm was obtained with 2.16 mol/L TBP for a typical solution containing 0.1 mol/L of bismuth and 1.0 mol/L of hydrochloric acid.About 98.5 % of bismuth has been extracted from the leaching solution under the optimum condition.Moreover,oxalate was explored as a precipitation stripping agent for BiCl_3·x TBP(x=2 or 3) complexes,by which Bi(Ⅲ) was stripped in the form of Bi_2(C_2O_4)_3·7H_2O.A stripping efficiency of 99.3% was obtained in only one stage at the phase ratio of 1 and TBP also could be recycled.Therefore,the method is an efficient,effective and highly selective approach to extract Bi(Ⅲ) and to recover metal bismuth.展开更多
The mechanism of synergistic extraction of gold in HCl media was researched with tri n octyl amine(TOA) and tri n octyl phospine oxide(TOPO). It was determined that the composition of synergistic extract is (TOAHT...The mechanism of synergistic extraction of gold in HCl media was researched with tri n octyl amine(TOA) and tri n octyl phospine oxide(TOPO). It was determined that the composition of synergistic extract is (TOAHTOPO)AuCl 4; the constant of synergistic extracting equilibrium is 10 9.20 ; and the synergistic reaction is exothermic with -17.187 kJ/K·mol of Δ H 298 . The extraction mechanism was also studied by the IR spectra and UV spectra. It is found that the extraction mechanism belongs to ion association type.展开更多
The authors investigated the mechanism of crud formation in copper solvent extraction. It is indicated that pH value of solution and the phase ratio (O/A) are the main factors affecting crud formation in solvent extra...The authors investigated the mechanism of crud formation in copper solvent extraction. It is indicated that pH value of solution and the phase ratio (O/A) are the main factors affecting crud formation in solvent extraction. The amount of crud extraction increases with aqueous pH value increase, and reduces with the increase of the phase ratio. Fe 3+ , Mg 2+ , fine air bubble and suspended particulates in leaching solution contribute to crud formation. One case is that a series of reactions of hydrolization and polymerization occurs for Fe 3+ , while pH>2.5, polyhydric complex or Fe SO 4 complex are formed. Then the complex ions of FeOH 2+ , Fe 2(OH) 4+ 2 cause poly reaction, which is likely to lead emulsion. The study on Zeta potential indicates the repulsion between electriferous droplets in solvent extraction prevents phase coalescence, which is one of the major reasons for emulsion.展开更多
A novel cloud-point extraction （CPE） was successfully used in preconcentration of biphenol A （BPA） from aqueous solutions. Majority of BPA is extracted into the surfactant-rich phase. The parameters affecting the ...A novel cloud-point extraction （CPE） was successfully used in preconcentration of biphenol A （BPA） from aqueous solutions. Majority of BPA is extracted into the surfactant-rich phase. The parameters affecting the CPE such as concentration of surfactant and electrolyte, equilibration temperature and time and pH of sample solution were investigated. The samples were analyzed by high-performance liquid chromatography with ultraviolet detection. Under the optimized conditions, preconcentration of 10 mL sample gives a preconcentration factor of 11. The limit of detection （LOD） and limit of quantification （LOQ） are 0.1 μg/L and 0.33 μg/L, respectively. The linear range of the proposed method is 0.2-20 μg/L with correlation coefficients greater than 0.998 7 and the spiking recove6es are 97.96%-100.42%. The interference factor was tested and the extraction mechanism was also investigated. Thus, the developed CPE has proven to be an efficient, green, rapid and inexpensive approach for extraction and preconcentration of BPA from water samples.展开更多
By establishing the numerical model in the vertical plane and the similar model in the horizontal plane of gas flow in goaf, the influence of high drainage roadway or drilling on the gas seepage field was analyzed, an...By establishing the numerical model in the vertical plane and the similar model in the horizontal plane of gas flow in goaf, the influence of high drainage roadway or drilling on the gas seepage field was analyzed, and the extraction mechanism was clarified. On this basis, the academic thought of directional long drilling group instead of high drainage roadway was put forward. And then using complex function theory, the permeation mechanical model of drilling group with circle distribution in the mining-induced fracture zone was established to explore the coupling relationship between the drilling quantity, extraction volume and the equivalent extraction rate of single drilling. Finally, combined with the concrete geological production conditions, the main parameters of directional long drilling group were determined. The distance between the drilling group center and the air-return roadway is 24 m, the height is 18 m, and the three drillings are in an approximate equilateral triangle distribution with a space of 8 m. The equivalent extraction square is 4.15 m2. It is shown that the effect of directional long drilling group is evident. The gas content in the upper comer is controlled below 0.95%, the content in the tail roadway is kept below the alarm value, and the content is over 50% in the drill, realizing the secure and effective extraction of coal and gas.展开更多
基金Project(2011AA061002)supported by the High-Tech Research and Development Program of ChinaProject(2010SK2010)supported by the Key Program of Science and Technology of Hunan Province,ChinaProject supported by the Hunan Nonferrous Metals Fund,China
文摘Tributyl phosphate(TBP) was employed for the Bi(Ⅲ) extraction from hydrochloric acid medium.The effects of extraction time and material concentration were examined.The replacement mechanism between the anion(Cl^-) and TBP was proposed for extraction.The results show the species extracted into the organic phase were found to be mainly BiCl_3·x TBP(x=2 or 3).Thermodynamic parameters of the extraction reaction were obtained from the thermodynamics analysis,which illustrates that higher temperatures show a negative effect on the extraction.Extraction isotherm was obtained with 2.16 mol/L TBP for a typical solution containing 0.1 mol/L of bismuth and 1.0 mol/L of hydrochloric acid.About 98.5 % of bismuth has been extracted from the leaching solution under the optimum condition.Moreover,oxalate was explored as a precipitation stripping agent for BiCl_3·x TBP(x=2 or 3) complexes,by which Bi(Ⅲ) was stripped in the form of Bi_2(C_2O_4)_3·7H_2O.A stripping efficiency of 99.3% was obtained in only one stage at the phase ratio of 1 and TBP also could be recycled.Therefore,the method is an efficient,effective and highly selective approach to extract Bi(Ⅲ) and to recover metal bismuth.
文摘The mechanism of synergistic extraction of gold in HCl media was researched with tri n octyl amine(TOA) and tri n octyl phospine oxide(TOPO). It was determined that the composition of synergistic extract is (TOAHTOPO)AuCl 4; the constant of synergistic extracting equilibrium is 10 9.20 ; and the synergistic reaction is exothermic with -17.187 kJ/K·mol of Δ H 298 . The extraction mechanism was also studied by the IR spectra and UV spectra. It is found that the extraction mechanism belongs to ion association type.
文摘The authors investigated the mechanism of crud formation in copper solvent extraction. It is indicated that pH value of solution and the phase ratio (O/A) are the main factors affecting crud formation in solvent extraction. The amount of crud extraction increases with aqueous pH value increase, and reduces with the increase of the phase ratio. Fe 3+ , Mg 2+ , fine air bubble and suspended particulates in leaching solution contribute to crud formation. One case is that a series of reactions of hydrolization and polymerization occurs for Fe 3+ , while pH>2.5, polyhydric complex or Fe SO 4 complex are formed. Then the complex ions of FeOH 2+ , Fe 2(OH) 4+ 2 cause poly reaction, which is likely to lead emulsion. The study on Zeta potential indicates the repulsion between electriferous droplets in solvent extraction prevents phase coalescence, which is one of the major reasons for emulsion.
基金Project(20956001) supported by the National Natural Science Foundation of ChinaProject(CX2011B083) supported by Hunan Provincial Innovation Foundation for Postgraduate, ChinaProject(K1104026-11) supported by Project of Changsha Science and Technology Bureau, China
文摘A novel cloud-point extraction （CPE） was successfully used in preconcentration of biphenol A （BPA） from aqueous solutions. Majority of BPA is extracted into the surfactant-rich phase. The parameters affecting the CPE such as concentration of surfactant and electrolyte, equilibration temperature and time and pH of sample solution were investigated. The samples were analyzed by high-performance liquid chromatography with ultraviolet detection. Under the optimized conditions, preconcentration of 10 mL sample gives a preconcentration factor of 11. The limit of detection （LOD） and limit of quantification （LOQ） are 0.1 μg/L and 0.33 μg/L, respectively. The linear range of the proposed method is 0.2-20 μg/L with correlation coefficients greater than 0.998 7 and the spiking recove6es are 97.96%-100.42%. The interference factor was tested and the extraction mechanism was also investigated. Thus, the developed CPE has proven to be an efficient, green, rapid and inexpensive approach for extraction and preconcentration of BPA from water samples.
基金Project(50834005) supported by the National Natural Science Foundation of ChinaProject(2010QZ06) supported by the Fundamental Research Funds for the Central Universities of China
文摘By establishing the numerical model in the vertical plane and the similar model in the horizontal plane of gas flow in goaf, the influence of high drainage roadway or drilling on the gas seepage field was analyzed, and the extraction mechanism was clarified. On this basis, the academic thought of directional long drilling group instead of high drainage roadway was put forward. And then using complex function theory, the permeation mechanical model of drilling group with circle distribution in the mining-induced fracture zone was established to explore the coupling relationship between the drilling quantity, extraction volume and the equivalent extraction rate of single drilling. Finally, combined with the concrete geological production conditions, the main parameters of directional long drilling group were determined. The distance between the drilling group center and the air-return roadway is 24 m, the height is 18 m, and the three drillings are in an approximate equilateral triangle distribution with a space of 8 m. The equivalent extraction square is 4.15 m2. It is shown that the effect of directional long drilling group is evident. The gas content in the upper comer is controlled below 0.95%, the content in the tail roadway is kept below the alarm value, and the content is over 50% in the drill, realizing the secure and effective extraction of coal and gas.
