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Disturbance observer based time-varying sliding mode control for uncertain mechanical system 被引量:12
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作者 Binglong Cong Xiangdong Liu Zhen Chen 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2012年第1期108-118,共11页
It is now well known that the time-varying sliding mode control (TVSMC) is characterized by its global robustness against matched model uncertainties and disturbances. The accurate tracking problem of the mechanical... It is now well known that the time-varying sliding mode control (TVSMC) is characterized by its global robustness against matched model uncertainties and disturbances. The accurate tracking problem of the mechanical system in the presence of the parametric uncertainty and external disturbance is addressed in the TVSMC framework. Firstly, an exponential TVSMC algorithm is designed and the main features are analyzed. Especially, the control parameter is obtained by solving an optimal problem. Subsequently, the global chattering problem in TVSMC is considered. To reduce the static error resulting from the continuous TVSMC algorithm, a disturbance observer based time-varying sliding mode control (DOTVSMC) algorithm is presented. The detailed design principle and the stability of the closed-loop system under the composite controller are provided. Simulation results verify the effectiveness of the proposed algorithm. 展开更多
关键词 mechanical system time-varying sliding mode control (TVSMC) global sliding phase global chattering disturbance observer.
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Reinforcement learning based adaptive control for uncertain mechanical systems with asymptotic tracking 被引量:1
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作者 Xiang-long Liang Zhi-kai Yao +1 位作者 Yao-wen Ge Jian-yong Yao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期19-28,共10页
This paper mainly focuses on the development of a learning-based controller for a class of uncertain mechanical systems modeled by the Euler-Lagrange formulation.The considered system can depict the behavior of a larg... This paper mainly focuses on the development of a learning-based controller for a class of uncertain mechanical systems modeled by the Euler-Lagrange formulation.The considered system can depict the behavior of a large class of engineering systems,such as vehicular systems,robot manipulators and satellites.All these systems are often characterized by highly nonlinear characteristics,heavy modeling uncertainties and unknown perturbations,therefore,accurate-model-based nonlinear control approaches become unavailable.Motivated by the challenge,a reinforcement learning(RL)adaptive control methodology based on the actor-critic framework is investigated to compensate the uncertain mechanical dynamics.The approximation inaccuracies caused by RL and the exogenous unknown disturbances are circumvented via a continuous robust integral of the sign of the error(RISE)control approach.Different from a classical RISE control law,a tanh(·)function is utilized instead of a sign(·)function to acquire a more smooth control signal.The developed controller requires very little prior knowledge of the dynamic model,is robust to unknown dynamics and exogenous disturbances,and can achieve asymptotic output tracking.Eventually,co-simulations through ADAMS and MATLAB/Simulink on a three degrees-of-freedom(3-DOF)manipulator and experiments on a real-time electromechanical servo system are performed to verify the performance of the proposed approach. 展开更多
关键词 Adaptive control Reinforcement learning Uncertain mechanical systems Asymptotic tracking
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Robust stabilization and disturbance attenuation for a class of underactuated mechanical systems 被引量:1
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作者 赖旭芝 潘昌忠 +2 位作者 吴敏 佘锦华 Simon X.YANG 《Journal of Central South University》 SCIE EI CAS 2012年第9期2488-2495,共8页
The robust control problem for a class of underactuated mechanical systems called acrobots is addressed. The goal is to drive the acrobots away from the straight-down position and balance them at the straight-up unsta... The robust control problem for a class of underactuated mechanical systems called acrobots is addressed. The goal is to drive the acrobots away from the straight-down position and balance them at the straight-up unstable equilibrium position in the presence of parametric uncertainties and external disturbance. First, in the swing-up area, it is shown that the time derivative of energy is independent of the parameter uncertainties, but exogenous disturbance may destroy the characteristic of increase in mechanical energy. So, a swing-up controller with compensator is designed to suppress the influence of the disturbance. Then, in the attractive area, the control problem is formulated into a H~ control framework by introducing a proper error signal, and a sufficient condition of the existence of Hoo state feedback control law based on linear matrix inequality (LMI) is proposed to guarantee the quadratic stability of the control system. Finally, the simulation results show that the proposed control approach can simultaneously handle a maximum ±10% parameter perturbation and a big disturbance simultaneously. 展开更多
关键词 underactuated mechanical systems robust stabilization disturbance attenuation H∞ linear matrix inequality (LMI)
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Research on and Design of Mechanical System with Optimal Cutting Movement Trajectory of Energy-Saving Stone-Sawing Machine
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作者 WANG Ji-rong 1, LI Lan-ji 1, LI Jun 1,3, LI Hua 2, ZHONG Yun-qing 3 (1.Qingdao University, Qingdao 266071, China 2.Wendeng Foreign Economic and Trade Corp, Wendeng 264400, China 3.Qingdao University of Science and Technology, Qingdao 266042, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期140-141,共2页
The technique of cutting slabstone with stone-sawi ng machine is analyzed completely. A new kind of cutting movement trajectory is gi ven whose actual cutting efficiency is near to 100%. It can reduce the energy w ear... The technique of cutting slabstone with stone-sawi ng machine is analyzed completely. A new kind of cutting movement trajectory is gi ven whose actual cutting efficiency is near to 100%. It can reduce the energy w earing greatly, and the surface quality of the product is improved to the utmost extent. The design mechanism of the optimal cutting movement trajectory system structure is analyzed incisively. At the same time, the principle of the complex movement of horizontal movement and swing is researched. The optimal design scheme of th e cutting movement trajectory system structure is set up. The choice method to g et the superior value of the movement system structure is found. The mathematics function formula is established which exhibits the relationship between the par ameter of the complex movement structure and that of the system movement structu re. By the formula, the precision value of the offset can be figured out. The r ule is adapted to different types of energy-saving stone-sawing machines. The complex movement structure of horizontal movement and swing is designed to f ulfill the cutting movement. It can make the saw frame move up with the hanging pod deviating from the vertical direction. At the same time, the saw frame have a down-movement. Then the sum of the two movements is near to zero, and the saw blade and the stone can keep in touch during the whole horizontal cutting. The result is that the actual cutting efficiency is 100%. Also, when the hanging pod moves to the limited position, the saw frame can keep the original inertia, and continue to swing up. It makes the back-cutting have high energy-storing. The optimal design of the eccentricity balance wheel is done. The mathematics fo rmula for expressing the movement system structure is deduced. The calculation m ethod and formula is set up which is used to get the value of important componen ts such as offset. The choice method and formula of elasticity distortion coeffi cient is set up when the saw frame moves smoothly. It is concluded that the offs et is the key dimension to actualize the optimal cutting movement trajectory. The resolving of the technical problems discussed above offers a theoretic and technical basis for optimal design of energy-saving stone-sawing machines. 展开更多
关键词 DESIGN Research on and Design of mechanical system with Optimal Cutting Movement Trajectory of Energy-Saving Stone-Sawing Machine
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MOTION CONTROL OF A CLASS OF UNDERACTUATED MECHANICAL SYSTEMS: THE ACROBOT EXAMPLE
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作者 Lai Xuzhi Cai Zixing (College of Information Engineering, Central South University of Technology, Changsha 410083, China) She Jinhua (Mechatronics Department, Tokyo University of Engineering,Tokyo, 192 8580, Japan) 《Journal of Central South University》 SCIE EI CAS 1999年第2期134-137,共4页
Presents a control strategy for underactuated mechanical system: the acrobot example, which combines fuzzy control and linear quadratic control. The fuzzy controller designed for the upswing ensures that the energy of... Presents a control strategy for underactuated mechanical system: the acrobot example, which combines fuzzy control and linear quadratic control. The fuzzy controller designed for the upswing ensures that the energy of the acrobot increases with each swing. After the acrobot enters a neighborhood of the unstable straight up equilibrium position, a linear quadratic regulator is designed to balance it. 展开更多
关键词 ACROBOT UNDERACTUATED mechanical systems fuzzy control linear QUADRATIC REGULATOR
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Shear mechanical properties and debonding failure mechanisms of bolt-resin-rock anchoring system with anisotropic interfaces
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作者 NIE Xin-xin YIN Qian +7 位作者 TAO Zhi-gang GUO Long-ji RIABOKON Evgenii ZHU De-fu XIE Liang-fu ZHA Wen-hua WANG Lin-feng REN Ya-jun 《Journal of Central South University》 2025年第7期2535-2552,共18页
This study investigates the shear mechanical responses and debonding failure mechanisms of anchoring systems comprising three anisotropic media and two anisotropic interfaces under controlled boundary conditions of co... This study investigates the shear mechanical responses and debonding failure mechanisms of anchoring systems comprising three anisotropic media and two anisotropic interfaces under controlled boundary conditions of constant normal load(F_(s)),constant normal stiffness(K),and shear rate(v).A systematic analysis of shear mechanical properties,the evolution of maximum principal strain field,and damage characteristics along shear failure surface is presented.Results from direct shear tests demonstrate that initial shear slip diminishes with increasing F_(s)and K,attributed to the normal constraint strengthening effect,while an increase in v enhances initial shear slip due to attenuated deformation coordination and stress transfer.As F_(s)increases from 7.5 to 120 kN,K from 0 to 12 MPa/mm,and v from 0.1 to 2 mm/min,the peak shear load increases by 210.32%and 80.16%with rising F_(s)and K,respectively,while decreases by 38.57%with increasing v.Correspondingly,the shear modulus exhibits,respectively,a 135.29%and 177.06%increase with rising F_(s)and K,and a 37.03%decrease with larger v.Initial shear dilation is identified as marking the formation of shear failure surface along anisotropic interfaces,resulting from the combined shear actions at the resin bolt interface,where resin undergoes shear by bolt surface protrusions,and the resin-rock interface,where mutual shear occurs between resin and rock.With increasing F_(s)and K and decreasing v,the location of the shear failure surface shifts from the resin-rock interface to the resin-bolt interface,accompanied by a transition in failure mode from tensile rupture of resin to shear off at the resin surface. 展开更多
关键词 anchoring system anisotropic interfaces shear mechanical properties strain field evolution debonding failure
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DYNAMICAL OPTIMUM DESIGN OF THE MECHANICAL OSCILLATION SYSTEM IN FLUIDIC GENERATOR
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作者 李福松 陈建军 《兵工学报》 EI CAS CSCD 北大核心 2000年第1期-,共4页
文中通过对射流发电机工作原理、结构特点及作用荷载的分析,建立了射流发电机机械振动系统的动力优化设计数学模型,以结构尺寸为设计变量,使结构重量极小化,满足动力位移、应力响应、基频以及尺寸限等约束条件,利用振型迭加法和复... 文中通过对射流发电机工作原理、结构特点及作用荷载的分析,建立了射流发电机机械振动系统的动力优化设计数学模型,以结构尺寸为设计变量,使结构重量极小化,满足动力位移、应力响应、基频以及尺寸限等约束条件,利用振型迭加法和复合形法求解。优化和试验结果表明:经优化后,既减轻结构重量,又显著地提高了射流发电机的输出功率。 展开更多
关键词 引信 射流技术 电源 有限元法 动力响应 动力优化 DYNAMICAL OPTIMUM DESIGN OF THE mechanical
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Structure and mechanical properties of ZrO_2-mullite nano-ceramics in SiO_2-Al_2O_3-ZrO_2 system 被引量:4
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作者 梁叔全 谭小平 +1 位作者 李少强 唐艳 《Journal of Central South University of Technology》 EI 2007年第1期1-6,共6页
ZrO2-mullite nano-ceramics were fabricated by in-situ controlled crystallizing from SiO2-Al2O3-ZrO2 amorphous bulk. The thermal transformation sequences of the SiO2-Al2O3-ZrO2 amorphous bulk were investigated by X-ray... ZrO2-mullite nano-ceramics were fabricated by in-situ controlled crystallizing from SiO2-Al2O3-ZrO2 amorphous bulk. The thermal transformation sequences of the SiO2-Al2O3-ZrO2 amorphous bulk were investigated by X-ray diffraction, infrared spectrum, scanning electron microscope and differential scanning calorimetric. And the mechanical properties of the nano-ceramics were studied. The results show that the bulks are still in amorphous state at 900 ℃ and the t-ZrO2 forms at about 950 ℃ with a faint spinel-like phase which changes into mullite on further heating. ZrO2 and mullite become major phases at 1 100 ℃ and an amount of m-ZrO2 occur at the same time. The sample heated at 950 ℃ for 2 h and then at 1 100 ℃ for 1 h shows very dense and homogenous microstructure with ball-like grains in size of 20-50 nm. With the increase of crystallization temperature up to 1 350 ℃, the grains grow quickly and some grow into lath-shaped grains with major diameter of 5 μm. After two-step treatment the highest micro-hardness, flexural strength and fracture toughness of the samples are 13.72 GPa, 520 MPa and 5.13 MPa·m1/2, respectively. 展开更多
关键词 SiO2-Al2O3-ZrO2 system amorphous bulk heat treatment structural change mechanical properties
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Undrained mechanical behavior of unsaturated completely weathered granite:Experimental investigation and constitutive modeling 被引量:1
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作者 DU Shao-hua MA Jin-yin +2 位作者 RUAN Bo WU Gen-shui ZHANG Rui-chao 《Journal of Central South University》 2025年第6期2307-2327,共21页
The undrained mechanical behavior of unsaturated completely weathered granite(CWG)is highly susceptible to alterations in the hydraulic environment,particularly under uniaxial loading conditions,due to the unique natu... The undrained mechanical behavior of unsaturated completely weathered granite(CWG)is highly susceptible to alterations in the hydraulic environment,particularly under uniaxial loading conditions,due to the unique nature of this soil type.In this study,a series of unconfined compression tests were carried out on unsaturated CWG soil in an underground engineering site,and the effects of varying the environmental variables on the main undrained mechanical properties were analyzed.Based on the experimental results,a novel constitutive model was then established using the damage mechanics theory and the undetermined coefficient method.The results demonstrate that the curves of remolded CWG specimens with different moisture contents and dry densities exhibited diverse characteristics,including brittleness,significant softening,and ductility.As a typical indicator,the unconfined compression strength of soil specimens initially increased with an increase in moisture content and then decreased.Meanwhile,an optimal moisture content of approximately 10.5%could be observed,while a critical moisture content value of 13.0%was identified,beyond which the strength of the specimen decreases sharply.Moreover,the deformation and fracture of CWG specimens were predominantly caused by shear failure,and the ultimate failure modes were primarily influenced by moisture content rather than dry density.Furthermore,by comparing several similar models and the experimental data,the proposed model could accurately replicate the undrained mechanical characteristics of unsaturated CWG soil,and quantitatively describe the key mechanical indexes.These findings offer a valuable reference point for understanding the underlying mechanisms,anticipating potential risks,and implementing effective control measures in similar underground engineering projects. 展开更多
关键词 completely weathered granite undrained mechanical behavior environmental variable unconfined compression test constitutive model
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Syntheses,crystal structures,and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ)metal-organic frameworks
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作者 CHEN Yukun FENG Kexin +2 位作者 ZHANG Bolun SONG Wentao ZHANG Jianjun 《无机化学学报》 北大核心 2025年第6期1227-1234,共8页
The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and... The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2. 展开更多
关键词 metal-organic framework crystal structure mechanical chromic luminescence resistance mechanical chromic luminescence weak interaction
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Geomechanical implications of joints and veins
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作者 JI Shaocheng 《地质力学学报》 北大核心 2025年第5期769-792,共24页
[Objective]Traditional structural geology textbooks often provide outdated treatments of joints and veins,failing to reflect the significant advances made in the past three decades.This review seeks to address part of... [Objective]Traditional structural geology textbooks often provide outdated treatments of joints and veins,failing to reflect the significant advances made in the past three decades.This review seeks to address part of this gap by highlighting the significance of barren joints and veins in reconstructing both the directions and magnitudes of geological paleostresses.[Conclusion]Conjugate shear joints not only indicate the orientation of the three effective principal stresses but also imply differential stresses at least four times greater than the tensile strength of the brittle host rock.Exfoliation joints form under stress states ofσ_(1)≈σ_(2)>0>σ_(3),whereas polygonal columnar joints in sedimentary rocks reflectσ_(1)^(*)>>σ_(2)^(*)=σ_(3)^(*),allowing the tensile strength of rocks to be estimated.Tensile joints in brittle strong beds interlayered with ductile soft layers are primarily driven by tensile stresses transferred from interfacial shear stresses between the hard and soft layers,with joint saturation mainly controlled by tectonic strain.Under natural strain-rate conditions,the Weibull modulus and tensile strength of the strong layers,as well as the shear-flow strength of the ductile layers,can be inferred from the nonlinear relationship between joint spacing and bed thickness.Ladder-like orthogonal joints,which form under a stress state ofσ_(1)^(*)>>σ_(2)^(*)>σ_(3)^(*),divide strata into blocky units and,after weathering and erosion,give rise to characteristic castle-and tower-like landforms.Veins,as mineral-filled joints,provide spacing and thickness data that allow estimates of layer strain.Moreover,the nonlinear relationship between vein spacing and bed thickness permits quantification of the extent to which mineral precipitation restores the tensile strength of rock beds.The absence of ladder-like orthogonal veins is attributed to this strength recovery.[Significance]Collectively,these observations demonstrate the critical role of joints and veins in constraining both the magnitudes and orientations of geological paleostress fields. 展开更多
关键词 JOINTS VEINS PALEOSTRESS brittle deformation mechanical properties
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Effects of Warm Rolling on the Microstructure and Mechanical Properties of Low-Cr FeCrAl Alloys at Room and Elevated Temperatures
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作者 CHEN Gangming WANG Hui HUANG Xuefei 《材料导报》 北大核心 2025年第9期178-188,共11页
The effects of different warm rolling(WR)reductions on the microstructure and mechanical properties of low-Cr FeCrAl alloys at both room and elevated temperatures were investigated.The study revealed that when the WR ... The effects of different warm rolling(WR)reductions on the microstructure and mechanical properties of low-Cr FeCrAl alloys at both room and elevated temperatures were investigated.The study revealed that when the WR reduction is small,it effectively refines the grains and forms a large number of subgrains in the matrix,while also inducing the dissolution of the Laves phase.This enhances the mechanical properties of FeCrAl alloys primarily through grain refinement and solid solution strengthening.Conversely,with larger WR reductions,the grain refinement effect diminishes,but a significant number of Laves phases form in the matrix,strengthening the alloys primarily through precipitation strengthening.WR exhibited a remarkable enhancing effect on the comprehensive mechanical properties at both room and high temperatures,with a signi-ficant enhancement in ductility at high temperatures.Notably,a 10%WR reduction resulted in the optimal overall mechanical properties at both room and elevated temperatures. 展开更多
关键词 FeCrAl alloy low-Cr warm rolling Laves phases mechanical property
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Defect Dipole Thermal-stability to the Electro-mechanical Properties of Fe Doped PZT Ceramics
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作者 SUN Yuxuan WANG Zheng +5 位作者 SHI Xue SHI Ying DU Wentong MAN Zhenyong ZHENG Liaoying LI Guorong 《无机材料学报》 北大核心 2025年第5期545-551,I0009-I0010,共9页
The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy beco... The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy becomes defect dipole,which prevents the domain rotation.In this field,a serious problem is that generally,Qm decreases as the temperature(T)increases,since the oxygen vacancies are decoupled from the defect dipoles.In this work,Q_(m) of Pb_(0.95)Sr_(0.05)(Zr_(0.53)Ti_(0.47))O_(3)(PSZT)ceramics doped by 0.40%Fe_(2)O_(3)(in mole)abnormally increases as T increases,of which the Qm and piezoelectric coefficient(d_(33))at room temperature and Curie temperature(TC)are 507,292 pC/N,and 345℃,respectively.The maximum Qm of 824 was achieved in the range of 120–160℃,which is 62.52%higher than that at room temperature,while the dynamic piezoelectric constant(d_(31))was just slightly decreased by 3.85%.X-ray diffraction(XRD)and piezoresponse force microscopy results show that the interplanar spacing and the fine domains form as temperature increases,and the thermally stimulated depolarization current shows that the defect dipoles are stable even the temperature up to 240℃.It can be deduced that the aggregation of oxygen vacancies near the fine domains and defect dipole can be stable up to 240℃,which pins domain rotation,resulting in the enhanced Q_(m) with the increasing temperature.These results give a potential path to design high Q_(m) at high temperature. 展开更多
关键词 defect dipole temperature characteristic oxygen vacancy electro-mechanical property mechanical quality factor hardening doping
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Simulation and Experimental Analysis of Mechanical Properties of a Bidirectional Adjustable Magnetorheological Fluid Damper
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作者 YANG Zhi−rong YE Zhong−min +2 位作者 LIU Jin−liang RAO Zhu−shi XIAO Wang−qiang 《船舶力学》 北大核心 2025年第6期1000-1012,共13页
The aim of this study is to address the issues associated with traditional magnetorheological fluid(MRF)dampers,such as insufficient damping force after power failure and susceptibility to settlement.In order to achie... The aim of this study is to address the issues associated with traditional magnetorheological fluid(MRF)dampers,such as insufficient damping force after power failure and susceptibility to settlement.In order to achieve this,a bidirectional adjustable MRF damper was designed and developed.Magnetic field simulation analysis was conducted on the damper,along with simulation analysis on its dynamic characteristics.The dynamic characteristics were ultimately validated through experimental testing on the material testing machine,thereby corroborating the theoretical simulation results.Concurrently,this process generated valuable test data for subsequent implementation of the semi-active vibration control system.The simulation and test results demonstrate that the integrated permanent magnet effectively accomplishes bidirectional regulation.The magnetic induction intensity of the damping channel is 0.2 T in the absence of current,increases to 0.5 T when a maximum forward current of 4 A is applied,and becomes 0 T when a maximum reverse current of 3.8 A is applied.When the excitation amplitude is 8 mm and the frequency is 2 Hz,with the applied currents varying,the maximum damping force reaches 8 kN,while the minimum damping force measures at 511 N.Additionally,at zero current,the damping force stands at 2 kN,which aligns closely with simulation results.The present paper can serve as a valuable reference for the design and research of semi-active MRF dampers. 展开更多
关键词 magnetorheological fluid(MRF) DAMPER permanent magnet finite element analysis test of mechanical properties
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Research on structural design and mechanical properties of precision electroplating machinery for automobiles based on finite element analysis
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作者 Wang Jie Jiang Xiaobei 《电镀与精饰》 北大核心 2025年第11期10-21,共12页
Design a precision electroplating mechanical structure for automobiles based on finite element analysis method and analyze its mechanical properties.Taking the automobile steering knuckle as the research object,ABAQUS... Design a precision electroplating mechanical structure for automobiles based on finite element analysis method and analyze its mechanical properties.Taking the automobile steering knuckle as the research object,ABAQUS parametric modeling technology is used to construct its three-dimensional geometric model,and geometric simplification is carried out.Two surface treatment processes,HK-35 zinc nickel alloy electroplating and pure zinc electroplating,were designed,and the influence of different coatings on the mechanical properties of steering knuckles was compared and analyzed through numerical simulation.At the same time,standard specimens were prepared for salt spray corrosion testing and scratch method combined strength testing to verify the numerical simulation results.The results showed that under emergency braking and composite working conditions,the peak Von Mises stress of the zinc nickel alloy coating was 119.85 MPa,which was lower than that of the pure zinc coating and the alkaline electroplated zinc layer.Its equivalent strain value was 652×10^(-6),which was lower than that of the pure zinc coating and the alkaline electroplated zinc layer.Experimental data confirms that zinc nickel alloy coatings exhibit significant advantages in stress distribution uniformity,strain performance,and load-bearing capacity in high stress zones.The salt spray corrosion test further indicates that the coating has superior corrosion resistance and coating substrate interface bonding strength,which can significantly improve the mechanical stability and long-term reliability of automotive precision electroplating mechanical structures. 展开更多
关键词 finite element analysis electroplating machinery structure mechanical properties electroplating process salt spray corrosion bonding strength
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The synthesis of alcohol ether esters through the catalytic hydrogenation of diethyl oxalate in the Cu-Al systems induced by Al_(2)O_(3) properties
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作者 Peng Wu Lina Ma +3 位作者 Yu Zheng Li Luo Lihong Su Juntian Li 《日用化学工业(中英文)》 北大核心 2025年第9期1100-1111,共12页
The structure-performance relationship of Cu/Al_(2)O_(3) catalysts in the hydrogenation of diethyl oxalate(DEO)for the synthesis of alcohol ether esters has been investigated by various characterization techniques inc... The structure-performance relationship of Cu/Al_(2)O_(3) catalysts in the hydrogenation of diethyl oxalate(DEO)for the synthesis of alcohol ether esters has been investigated by various characterization techniques including XRD,XPS,N2O titration,and 27Al MAS-NMR.The results showed that when the crystal configurations of Al_(2)O_(3) were the same,increasing the specific surface area could effectively refine the size of copper nanoparticles(Cu NPs),and ultimately improve the conversion of DEO.Meanwhile,the smaller size ofγ-Al_(2)O_(3)(HSAl and SBAl)loaded Cu NPs promotes the reaction towards the deep hydrogenation to produce ethanol(EtOH)and ethylene glycol(EG).Besides,the larger size of Cu NPs on the surface of amorphous Al_(2)O_(3)(HTAl and SolAl)resulted in a lower conversion rate,where ethyl glycolate(Egly)is the main product.Despite there are differences in Al^(3+)ionic coordination in Al_(2)O_(3) with different crystal structures,the experimental data showed that the differences in Al^(3+)ionic coordination did not significantly affect the catalytic performance in the hydrogenation reaction.The formation of alcohol-ether ester chemicals is critically dependent on the interactions between Cu sites and acidic sites.Among them,EG and EtOH were dehydrated to form 2-ethoxyethanol via the SN2 mechanism,while Egly and EtOH were reacted to form ethyl ethoxyacetate(EEA)via the SN2 mechanism.This study provides a theoretical basis for the optimization of the coal-based glycol processes to achieve a diversified product portfolio. 展开更多
关键词 oxalate hydrogenation alcohol ether esters Cu-Al catalyst SN2 mechanism
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Innovative dispersion techniques of graphene nanoplatelets(GNPs)through mechanical stirring and ultrasonication:Impact on morphological,mechanical,and thermal properties of epoxy nanocomposites
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作者 Vasi Uddin Siddiqui S.M.Sapuan Mohd Roshdi Hassan 《Defence Technology(防务技术)》 2025年第1期13-25,共13页
Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding capabilities.This study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological beh... Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding capabilities.This study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological behavior of GNP/epoxy nanocomposites.This study aims to understand how the dispersion of GNPs affects the properties of epoxy nanocomposite and to identify the best dispersion approach for improving mechanical performance.A solvent mixing technique that includes mechanical stirring and ultrasonication was used for producing the nanocomposites.Fourier transform infrared spectroscopy was used to investigate the interaction between GNPs and the epoxy matrix.The measurements of density and moisture content were used to confirm that GNPs were successfully incorporated into the nanocomposite.The findings showed that GNPs are successfully dispersed in the epoxy matrix by combining mechanical stirring and ultrasonication in a single step,producing well-dispersed nanocomposites with improved mechanical properties.Particularly,the nanocomposites at a low GNP loading of 0.1 wt%,demonstrate superior mechanical strength,as shown by increased tensile properties,including improved Young's modulus(1.86 GPa),strength(57.31 MPa),and elongation at break(4.98).The nanocomposite with 0.25 wt%GNP loading performs better,according to the viscoelastic analysis and flexural properties(113.18 MPa).Except for the nanocomposite with a 0.5 wt%GNP loading,which has a higher thermal breakdown temperature,the thermal characteristics do not significantly alter.The effective dispersion of GNPs in the epoxy matrix and low agglomeration is confirmed by the morphological characterization.The findings help with filler selection and identifying the best dispersion approach,which improves mechanical performance.The effective integration of GNPs and their interaction with the epoxy matrix provides the doorway for additional investigation and the development of sophisticated nanocomposites.In fields like aerospace,automotive,and electronics where higher mechanical performance and functionality are required,GNPs'improved mechanical properties and successful dispersion present exciting potential. 展开更多
关键词 Graphene nanoplatelets Epoxy Nanocomposites mechanical properties Thermal properties mechanical stirrer Sonication
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Promotion effect of mechanical activation on the role of pyrite in chalcopyrite bioleaching
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作者 LIAO Rui YU Shi-chao +4 位作者 YANG Bao-jun SUN Xin WANG Chen-xu QIU Guan-zhou WANG Jun 《Journal of Central South University》 2025年第9期3574-3590,共17页
Mechanical activation (MA) is a significant pretreatment technique for enhancing the dissolution of mineral;however, its promotion effect on the role of pyrite during chalcopyrite bioleaching has not been elucidated u... Mechanical activation (MA) is a significant pretreatment technique for enhancing the dissolution of mineral;however, its promotion effect on the role of pyrite during chalcopyrite bioleaching has not been elucidated up to now. In this study, the effect of MA on the role of pyrite on chalcopyrite bioleaching mediated by Acidithiobacillus ferroxidans was investigated by X-ray diffraction, scanning electron microscopy, particle size distribution analysis, and electrochemical measurement. The results showed MA could significantly reduce the minerals particle size, and increase the specific surface area and surface energy of minerals. For example, the d50 of chalcopyrite reduced from 13.40 to 0.31 μm after MA. The copper extraction of mixed MA-chalcopyrite and MA-pyrite system was 63.4%, which exhibited a 51.8% enhancement compared to the non-activated mixed system. Electrochemical experiments identified that the strengthening effect of pyrite on chalcopyrite dissolution was negligible before MA. After MA, the dissolution mechanism of chalcopyrite was not changed, and pyrite could not only provide additional oxidants (acids and iron) but also act as the cathode in the galvanic couple. In this case, the bioleaching of chalcopyrite was accelerated. Therefore, a model of the promotion effect of mechanical activation on the role of pyrite on chalcopyrite bioleaching was proposed. 展开更多
关键词 CHALCOPYRITE BIOLEACHING acidophilic microorganisms mechanical activation electrochemical dissolution
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Prospects of energy release and mechanical behavior of reactive highentropy alloys
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作者 Shanghao Wu Zezhou Li +4 位作者 Jianye He Fan Zhang Lin Wang Lei Zhang Xingwang Cheng 《Defence Technology(防务技术)》 2025年第8期236-253,共18页
High-entropy alloys(HEAs)with multi-component elements have attracted significant interest since they exhibit numerous superior properties compared to traditional ones.These properties include significant energy relea... High-entropy alloys(HEAs)with multi-component elements have attracted significant interest since they exhibit numerous superior properties compared to traditional ones.These properties include significant energy release,remarkable fracture toughness,and high strength,making them promising candidates as energetic structural materials(ESMs).This paper summarizes the energy release mechanisms under dynamic impact and the mechanical behavior of TiZr-based HEAs,TiNb-based HEAs,andWbased HEA,including velocity threshold for energy release,chamber quasi-static pressure curve,energy release efficiency,interface reactions,and"self-sharpening".In addition,we propose future research directions for their energy release and mechanical behavior. 展开更多
关键词 High-entropy alloys Energetic structural materials Energy release mechanism mechanical properties
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Microstructure and mechanical properties of welds of AZ31B magnesium alloy produced by different gas tungsten arc welding variants
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作者 S.Srinivasan R.Ravi Bharath +1 位作者 A.Atrens P.Bala Srinivasan 《Defence Technology(防务技术)》 2025年第2期98-110,共13页
This work aimed to(i)understand conventional and pulse gas tungsten arc welding(GTAW)of AZ31B,and(ii)explore high frequency welding(100 Hz-1500 Hz).GTA welding with alternating current(AC)and direct current electrode ... This work aimed to(i)understand conventional and pulse gas tungsten arc welding(GTAW)of AZ31B,and(ii)explore high frequency welding(100 Hz-1500 Hz).GTA welding with alternating current(AC)and direct current electrode positive(DCEP)polarities yielded crack-free partial penetration welds for6 mm thick AZ31B alloy sheet.Welding under direct current electrode negative(DCEN)polarity with identical parameters as that for AC and DCEP resulted in full penetration welds that had microcracks.Defect-free full-penetration welds could be accomplished with pulse GTA welding using DCEN polarity at a pulse frequency of 1 Hz with a pulse duration ratio of 1:1.The resultant DCEN P 1:1 weld metal had a microstructure finer than the conventional DCEN weld.Welds produced with pulse duration ratios of 1:2and 1:4 lacked penetration but had a much finer microstructures because of the lower heat input.The arc constriction by the high frequency pulsing in the Activ Arc■-High frequency(AA-HF)mode welding was responsible for deeper penetration.Welds produced under DCEN pulsing and AA-HF conditions had hardness higher than conventional DCEN,DCEP and AC GTA welds,attributed to the finer microstructure.AA-HF GTA welding produced defect free deeper penetration welds with good microstructural features/mechanical properties and also gave an advantage of 50%enhanced productivity when welded at1500 Hz. 展开更多
关键词 AZ31B alloy Pulse GTAW High frequency Microstructure mechanical properties PRODUCTIVITY
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