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A data selection method for matrix effects and uncertainty reduction for laser-induced breakdown spectroscopy 被引量:1
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作者 龙杰 宋惟然 +1 位作者 侯宗余 王哲 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第7期82-89,共8页
Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superp... Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superposition of both matrix effects and signal uncertainty directly affects plasma parameters and further influences spectral intensity and LIBS quantification performance,a data selection method based on plasma temperature matching(DSPTM)was proposed to reduce both matrix effects and signal uncertainty.By selecting spectra with smaller plasma temperature differences for all samples,the proposed method was able to build up the quantification model to rely more on spectra with smaller matrix effects and signal uncertainty,therefore improving final quantification performance.When applied to quantitative analysis of the zinc content in brass alloys,it was found that both accuracy and precision were improved using either a univariate model or multiple linear regression(MLR).More specifically,for the univariate model,the root-mean-square error of prediction(RMSEP),the determination coefficients(R^(2))and relative standard derivation(RSD)were improved from 3.30%,0.864 and 18.8%to 1.06%,0.986 and 13.5%,respectively;while for MLR,RMSEP,R^(2)and RSD were improved from 3.22%,0.871 and 26.2%to 1.07%,0.986 and 17.4%,respectively.These results prove that DSPTM can be used as an effective method to reduce matrix effects and improve repeatability by selecting reliable data. 展开更多
关键词 laser-induced breakdown spectroscopy(LIBS) quantification UNCERTAINTY univariate/multivariate analysis matrix effects temperature matching
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Matrix effect suppressing in the element analysis of soils by laser-induced breakdown spectroscopy with acoustic correction
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作者 何智权 刘莉 +6 位作者 郝中骐 徐智帅 王奇 卢颖 赵梓屹 史久林 何兴道 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第12期97-104,共8页
Laser-induced breakdown spectroscopy(LIBS)has been used for soil analysis,but its measurement accuracy is often influenced by matrix effects of different kinds of soils.In this work,a method for matrix effect suppress... Laser-induced breakdown spectroscopy(LIBS)has been used for soil analysis,but its measurement accuracy is often influenced by matrix effects of different kinds of soils.In this work,a method for matrix effect suppressing was developed using laser-induced plasma acoustic signals to correct the original spectrum,thereby improving the analysis accuracy of the soil elements.A good linear relationship was investigated firstly between the original spectral intensity and the acoustic signals.The relative standard deviations(RSDs)of Mg,Ca,Sr,and Ba elements were then calculated for both the original spectrum and the spectrum with the acoustic correction,and the RSDs were significantly reduced with the acoustic correction.Finally,calibration curves of MgⅠ285.213 nm,CaⅠ422.673 nm,SrⅠ460.733 nm and BaⅡ455.403 nm were established to assess the analytical performance of the proposed acoustic correction method.The values of the determination coefficient(R~2)of the calibration curves for Mg,Ca,Sr,and Ba elements,corrected by the acoustic amplitude,are improved from 0.9845,0.9588,0.6165,and 0.6490 to 0.9876,0.9677,0.8768,and 0.8209,respectively.The values of R~2 of the calibration curves corrected by the acoustic energy are further improved to 0.9917,0.9827,0.8835,and 0.8694,respectively.These results suggest that the matrix effect of LIBS on soils can be clearly improved by using acoustic correction,and acoustic energy correction works more efficiently than acoustic amplitude correction.This work provides a simple and efficient method for correcting matrix effects in the element analysis of soils by acoustic signals. 展开更多
关键词 laser-induced breakdown spectroscopy acoustic correction matrix effect calibration curve relative standard deviation
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Neural network-based matrix effect correction in EDXRF analysis 被引量:4
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作者 TUO Xianguo CHENG Bo MU Keliang LI Zhe 《Nuclear Science and Techniques》 SCIE CAS CSCD 2008年第5期278-281,共4页
In this paper we discuss neural network-based matrix effect correction in energy dispersive X-ray fluorescence (EDXRF) analysis,with detailed algorithm to classify the samples.The method can correct the matrix effect ... In this paper we discuss neural network-based matrix effect correction in energy dispersive X-ray fluorescence (EDXRF) analysis,with detailed algorithm to classify the samples.The method can correct the matrix effect effectively through classifying the samples automatically,and influence of X-ray absorption and enhancement by major elements of the samples is reduced.Experiments for the complex matrix effect correction in EDXRF analysis of samples in Pangang showed improved accuracy of the elemental analysis result. 展开更多
关键词 能量耗散X射线荧光分析 神经网络 聚类分析 基体效应 烧结矿物
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Effect of parameter setting and spectral normalization approach on study of matrix effect by laser induced breakdown spectroscopy of Ag–Zn binary composites 被引量:1
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作者 Harse SATTAR Liying SUN +3 位作者 Muhammad IMRAN Ran HAI Ding WU Hongbin DING 《Plasma Science and Technology》 SCIE EI CAS CSCD 2019年第3期155-166,共12页
The complex nature of laser-material interaction causes non-stoichiometric ablation of alloy samples.This is attributed to matrix effect, which reduces analyzing capability. To address this issue, the analytical perfo... The complex nature of laser-material interaction causes non-stoichiometric ablation of alloy samples.This is attributed to matrix effect, which reduces analyzing capability. To address this issue, the analytical performance of three different normalization methods, namely normalization with background, internal normalization and three point smoothing techniques at different parameter settings is studied for quantification of Ag and Zn by Laser induced breakdown spectroscopy(LIBS).The LIBS spectra of five known concentration of silver zinc binary composites have been investigated at various laser irradiances(LIs). Calibration curves for both Ag(I) line(4d^(10)5s^2S_(1/2)→4d^(10)5p^2P_(1/2) at 338.28 nm) and Zn(I) line(4s5s^3S_1→4s4p^3P_2 at 481.053 nm) have been determined at LI of 5.86?×?10^(10)W cm^(-2). Slopes of these calibration curves provide the valuation of matrix effect in the Ag–Zn composites. With careful sample preparation and normalization after smoothing at optimum parameter setting(OPS), the minimization of sample matrix effect has been successfully achieved. A good linearity has been obtained in Ag and Zn calibration curve at OPS when normalized the whole area of spectrum after smoothing and the obtained coefficients of determination values were R^2?=?0.995 and 0.998 closer to 1. The results of matrix effect have been further verified by analysis of plasma parameters. Both plasma parameters showed no change with varying concentration at OPS. However, at high concentration of Ag, the observed significant changes in both plasma parameters at common parameter setting PS-1 and PS-2 were the gesture of matrix effect. In our case, the better analytical results were obtained at smoothing function with optimized parameter setting that indicates it is more efficient than normalization with background and internal normalization method. 展开更多
关键词 Ag–Zn COMPOSITES laser induced BREAKDOWN spectroscopy optimum parameter setting SELF-ABSORPTION matrix effect
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Effect of matrix thermal properties on laser-induced plasma
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作者 Yuheng Shan An Li +4 位作者 Xinyu Zhang Wen Yi Ying Zhang Xiaodong Liu Ruibin Liu 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期331-336,共6页
The matrix thermal properties have an important impact on laser-induced plasma,as the thermal effect dominates the interaction between ns-pulsed laser and matter,especially in metals.We used a series of pure metals an... The matrix thermal properties have an important impact on laser-induced plasma,as the thermal effect dominates the interaction between ns-pulsed laser and matter,especially in metals.We used a series of pure metals and aluminum alloys to measure plasma temperature and electron density through laser-induced breakdown spectroscopy,in order to investigate the effect of matrix thermal properties on laser-induced plasma.In pure metals,a significant negative linear correlation was observed between the matrix thermal storage coefficient and plasma temperature,while a weak correlation was observed with electron density.The results indicate that metals with low thermal conductivity or specific heat capacity require less laser energy for thermal diffusion or melting and evaporation,resulting in higher ablation rates and higher plasma temperatures.However,considering ionization energy,thermal effects may be a secondary factor affecting electron density.The experiment of aluminum alloy further confirms the influence of thermal conductivity on plasma temperature and its mechanism explanation. 展开更多
关键词 laser-induced plasma thermal properties matrix effect thermal storage coefficient plasma temperature
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Thermal resistance matrix representation of thermal effects and thermal design of microwave power HBTs with two-dimensional array layout 被引量:2
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作者 Rui Chen Dong-Yue Jin +5 位作者 Wan-Rong Zhang Li-Fan Wang Bin Guo Hu Chen Ling-Han Yin Xiao-Xue Jia 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第9期373-380,共8页
Based on the thermal network of the two-dimensional heterojunction bipolar transistors(HBTs) array, the thermal resistance matrix is presented, including the self-heating thermal resistance and thermal coupling resist... Based on the thermal network of the two-dimensional heterojunction bipolar transistors(HBTs) array, the thermal resistance matrix is presented, including the self-heating thermal resistance and thermal coupling resistance to describe the self-heating and thermal coupling effects, respectively.For HBT cells along the emitter length direction, the thermal coupling resistance is far smaller than the self-heating thermal resistance, and the peak junction temperature is mainly determined by the self-heating thermal resistance.However, the thermal coupling resistance is in the same order with the self-heating thermal resistance for HBT cells along the emitter width direction.Furthermore, the dependence of the thermal resistance matrix on cell spacing along the emitter length direction and cell spacing along the emitter width direction is also investigated, respectively.It is shown that the moderate increase of cell spacings along the emitter length direction and the emitter width direction could effectively lower the self-heating thermal resistance and thermal coupling resistance,and hence the peak junction temperature is decreased, which sheds light on adopting a two-dimensional non-uniform cell spacing layout to improve the uneven temperature distribution.By taking a 2 × 6 HBTs array for example, a twodimensional non-uniform cell spacing layout is designed, which can effectively lower the peak junction temperature and reduce the non-uniformity of the dissipated power.For the HBTs array with optimized layout, the high power-handling capability and thermal dissipation capability are kept when the bias voltage increases. 展开更多
关键词 HETEROJUNCTION BIPOLAR transistors(HBTs) array THERMAL effects THERMAL resistance matrix THERMAL design
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Effects of Solid Matrix and Porosity of Porous Medium on Heat Transfer of Marangoni Boundary Layer Flow Saturated with Power-Law Nanofluids
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作者 陈晖 肖天丽 +1 位作者 陈嘉阳 沈明 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第10期80-84,共5页
The effect of the solid matrix and porosity of the porous medium are first introduced to the study of power-law nanofluids, and the Marangoni boundary layer flow with heat generation is investigated. Two cases of soli... The effect of the solid matrix and porosity of the porous medium are first introduced to the study of power-law nanofluids, and the Marangoni boundary layer flow with heat generation is investigated. Two cases of solid matrix of porous medium including glass balls and aluminum foam are considered. The governing partial differential equations are simplified by dimensionless variables and similarity transformations, and are solved numerically by using a shooting method with the fourth-fifth-order Runge-Kutta integration technique. It is indicated that the increase of the porosity leads to the enhancement of heat transfer in the surface of the Marangoni boundary layer flow. 展开更多
关键词 of is as effects of Solid matrix and Porosity of Porous Medium on Heat Transfer of Marangoni Boundary Layer Flow Saturated with Power-Law Nanofluids in with on
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样品基质对吸附管采样-热脱附-气相色谱-质谱法测定挥发性有机化合物的影响
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作者 董翊 姜阳 +3 位作者 于瑞祥 高艳秋 任逸尘 魏王慧 《理化检验(化学分册)》 北大核心 2025年第2期143-148,共6页
用氮气稀释含有丙酮、异丙醇、正己烷、乙酸乙酯、苯等5种挥发性有机化合物(VOCs)的混合标准气体制备标准吸附管系列,采用热脱附-气相色谱-质谱法测定并绘制工作曲线,以考察空气、二氧化碳、甲醇基质对低、中、高含量上述5种VOCs测定的... 用氮气稀释含有丙酮、异丙醇、正己烷、乙酸乙酯、苯等5种挥发性有机化合物(VOCs)的混合标准气体制备标准吸附管系列,采用热脱附-气相色谱-质谱法测定并绘制工作曲线,以考察空气、二氧化碳、甲醇基质对低、中、高含量上述5种VOCs测定的影响。结果显示:5种VOCs的质量在不同范围内和对应的定量离子的峰面积呈线性关系,检出限(3S/N)为0.0300~1.00 ng,测定值的相对标准偏差(n=7)为2.1%~5.7%;除甲醇基质中低含量丙酮和异丙醇的回收率大于200%外,3种基质中不同含量的5种VOCs的回收率均在90.0%~110%内,推测残留在检测器中的甲醇影响了与甲醇保留时间接近的丙酮和异丙醇的电离,导致离子强度增大,回收率增加。 展开更多
关键词 吸附管采样 热脱附 气相色谱-质谱法 挥发性有机化合物 基质影响 甲醇
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细菌素协同物理技术对食源性致病菌和腐败微生物防控的研究进展
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作者 王明珠 田子豪 +8 位作者 谭中美 任洁 武高云 郭进琪 姚玉昌 尹园 李柏良 马佳歌 于微 《食品工业科技》 北大核心 2025年第3期425-435,共11页
由食源性致病菌和腐败微生物引发的食品安全问题已成为全球公共卫生的挑战之一。细菌素是一类抗菌肽,通常在某些细菌的核糖体内合成,被广泛用作生物防腐剂和食品添加剂。然而,单独使用细菌素存在一些局限性,比如抑菌谱窄、易被酶降解等... 由食源性致病菌和腐败微生物引发的食品安全问题已成为全球公共卫生的挑战之一。细菌素是一类抗菌肽,通常在某些细菌的核糖体内合成,被广泛用作生物防腐剂和食品添加剂。然而,单独使用细菌素存在一些局限性,比如抑菌谱窄、易被酶降解等。研究表明,将细菌素与物理技术结合可能会产生协同效应,可以扩大抑菌范围、增强抑菌效果并延长食品货架期,从而保障食品安全和人类健康。本文综述了细菌素与超声波处理、高压处理、热处理、脉冲电场以及纳米技术等物理技术协同的抑菌策略和机制,阐述了该策略对食品风味和品质的影响,并展望了其未来发展趋势和应用前景。旨在为细菌素与物理技术协同抑制食源性致病菌和腐败微生物的工业应用提供理论支持和参考依据。 展开更多
关键词 细菌素 物理技术 协同作用 抑菌机制 食品基质
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食品农药残留的高效液相色谱-质谱联用检测方法优化策略
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作者 黄芳 羊超菠 +1 位作者 韦雪飞 厉畅达 《食品安全导刊》 2025年第1期169-171,共3页
本研究分析了食品农药残留检测中高效液相色谱-质谱联用技术面临的主要挑战,包括检测灵敏度不足、定量准确性受限及复杂基质干扰等问题。通过优化样品前处理方法、改进色谱分离条件、创新质谱检测参数等策略,提出了基质固相分散萃取与... 本研究分析了食品农药残留检测中高效液相色谱-质谱联用技术面临的主要挑战,包括检测灵敏度不足、定量准确性受限及复杂基质干扰等问题。通过优化样品前处理方法、改进色谱分离条件、创新质谱检测参数等策略,提出了基质固相分散萃取与同位素内标法相结合的分析方案,有助于提高农药残留检测的灵敏度和准确度。 展开更多
关键词 液相色谱-质谱联用 农药残留 基质效应
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QuEChERS结合GC-MS/MS法测定蕹菜中41种农药残留
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作者 李南 韦盈 +3 位作者 王丹 吴含秀 陈思明 智丽 《现代食品》 2025年第1期183-188,195,共7页
建立测定蕹菜中41种农药残留量的QuEChERS-气相色谱-串联质谱(Gas Chromatography-Tandem Mass Spectrometry,GC-MS/MS)检测方法。蕹菜样品经乙腈提取后,采用QuEChERS方法前处理,以N-丙基乙二胺(N-Propyl Ethylenediamine,PSA)、石墨化... 建立测定蕹菜中41种农药残留量的QuEChERS-气相色谱-串联质谱(Gas Chromatography-Tandem Mass Spectrometry,GC-MS/MS)检测方法。蕹菜样品经乙腈提取后,采用QuEChERS方法前处理,以N-丙基乙二胺(N-Propyl Ethylenediamine,PSA)、石墨化炭黑(Graphitized Carbon Black,GCB)吸附提取液中的干扰组分,提取液经GC-MS/MS多反应监测模式分析测定,匹配基质标准曲线内标法定量。结果表明,采用本研究建立的方法测定41种农药,线性范围为10~500 ng·mL^(-1),相关系数(R^(2))在0.9938~0.9998,线性关系良好,定量限均为0.01 mg·kg^(-1)。在0.010、0.025、0.250 mg·kg^(-1)3个加标水平下的平均加标回收率为62.1%~117.2%,相对标准偏差在0.2%~14.3%(n=6)。所建方法的准确度、精密度均能满足蕹菜中41种农药残留基本定量要求,操作简单、效率高,可用于蕹菜中实际农药残留的检测。 展开更多
关键词 QUECHERS 气相色谱-三重四极杆串联质谱 基质效应
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QuEChERS-超高效液相色谱-串联三重四极杆质谱法同时测定猪肉中24种兽药残留
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作者 李红丽 贺超 +5 位作者 苏敏 吴彦蕾 蔡小钦 吴晓琴 黄大亮 吴雨消 《食品安全质量检测学报》 2025年第4期86-96,共11页
目的建立QuEChERS技术结合超高效液相色谱-串联三重四极杆质谱法(ultra performance liquid chromatography-tandem triple quadrupole mass spectrometry,UPLC-MS/MS)同时测定猪肉中24种兽药残留快速检测方法。方法样品经0.1%甲酸乙腈... 目的建立QuEChERS技术结合超高效液相色谱-串联三重四极杆质谱法(ultra performance liquid chromatography-tandem triple quadrupole mass spectrometry,UPLC-MS/MS)同时测定猪肉中24种兽药残留快速检测方法。方法样品经0.1%甲酸乙腈溶液提取,3 g无水MgSO4和2 g C18 E净化,Thermo-Fisher Hypersil GOLD aQ色谱柱(50 mm×2.1 mm,1.9μm)分离,乙腈和0.1%甲酸水溶液梯度洗脱,在电喷雾正离子扫描的模式下进行定性和定量的检测。结果24种兽药线性关系良好,相关系数均达0.9910以上,检出限范围为0.2~10.0μg/kg,方法回收率范围为70.2%~110.3%,相对标准偏差为1.2%~13.8%。结论该方法简便、快速、准确、实用性强,适用于猪肉中兽药残留的检测。 展开更多
关键词 QUECHERS 前处理技术 超高效液相色谱-串联三重四极杆质谱法 基质效应 多兽药残留
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混合基质气体分离膜渗透性能模型的研究进展
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作者 赵娟 艾宏儒 《化工新型材料》 北大核心 2025年第1期54-61,共8页
混合基质膜(MMMs)通过结合无机填料的优异选择性和聚合物基质的卓越渗透性,展现出超越传统聚合物膜的气体分离性能。针对目前流行的用于预测混合基质膜的有效介质(EMA)渗透模型,讨论了其基本假设和局限性。通过对渗透模型预测值与实验... 混合基质膜(MMMs)通过结合无机填料的优异选择性和聚合物基质的卓越渗透性,展现出超越传统聚合物膜的气体分离性能。针对目前流行的用于预测混合基质膜的有效介质(EMA)渗透模型,讨论了其基本假设和局限性。通过对渗透模型预测值与实验数据的比较分析,揭示了这些模型在预测MMMs渗透性能时的应用范围。在此基础上,提出了未来模型发展的方向,旨在为高性能气体分离膜材料的设计和优化提供理论基础和指导。 展开更多
关键词 混合基质膜 气体分离 数学模型 有效介质法 渗透性能
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Analytic solution for a circular nano-inhomogeneity in a finite matrix 被引量:1
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作者 Shuang Wang Zengtao Chen Cunfa Gao 《Nano Materials Science》 CAS 2019年第2期116-120,共5页
The Gurtin-Murdoch model has found wide applications in analyzing the mechanical behaviors of nanocomposites with surface/interface effect. In the existing literature, the matrix is usually assumed to be infinite and ... The Gurtin-Murdoch model has found wide applications in analyzing the mechanical behaviors of nanocomposites with surface/interface effect. In the existing literature, the matrix is usually assumed to be infinite and the surface/interface effect is considered only at the inhomogeneity-matrix interface. This assumption is indeed valid as the matrix is usually at macroscale rather than nanoscale. However, if the size of the matrix decreases to the nanoscale too, the surface/interface effect will have to be considered at the outer boundary of the matrix. In this paper, the plane deformation of a circular nano-inhomogeneity embedded inside a finite circular matrix (which implies the matrix is also at nanoscale) is investigated. The stress boundary conditions are given at the inhomogeneity-matrix interface and the outer boundary of the matrix by the G-M model. The analytic solution for the stress field is finally obtained through the complex variable method. The results show that the stress field inside the inhomogeneity is still uniform (size-dependent) when the surface/interface effect is considered. In addition, the stress field inside the bulk (including the inhomogeneity and the matrix) can be influenced not only by the size and elastic constant of the inhomogeneity, but also by those of the matrix. 展开更多
关键词 PLANE problem NANOSCALE INHOMOGENEITY FINITE matrix Surface/interface effect Complex variable methods
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MATRIX ABSORPTION CORRECTION OF MEDIUM THICK TARGETS IN XRF
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作者 张元勋 汪学朋 +2 位作者 秦俊法 汪勇先 吴士明 《Nuclear Science and Techniques》 SCIE CAS CSCD 1993年第2期120-124,共5页
This paper deals with the matrix absorption and enhancement effects of thick targets in energy dispersive X-ray fluorescence analysis. Two kinds of absorption correction methods are studied especially for medium thick... This paper deals with the matrix absorption and enhancement effects of thick targets in energy dispersive X-ray fluorescence analysis. Two kinds of absorption correction methods are studied especially for medium thick targets (5-10 mg/cm2). For analysis of hair samples, both the measurement of absorption correction coefficients and the determination of sensitivity factors using an addition method are introduced. Quantitative analysis of medial thick samples is established. The relative deviation between different methods for most of the elements is found to be less than 5 %. 展开更多
关键词 X-RAY FLUORESCENCE matrix effect NUCLEAR analysis
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Integrated petrophysical log characterization for tight carbonate reservoir effectiveness: A case study from the Longgang area, Sichuan Basin, China 被引量:3
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作者 Deng Shaogui Wang Yang +2 位作者 Hu Yunyun Ge Xinmin He Xuquan 《Petroleum Science》 SCIE CAS CSCD 2013年第3期336-346,共11页
Ultra-low porosity and permeability, inhomogeneous fracture distribution, and complex storage space together make the effectiveness evaluation of tight carbonate reservoirs difficult. Aiming at the carbonate reservoir... Ultra-low porosity and permeability, inhomogeneous fracture distribution, and complex storage space together make the effectiveness evaluation of tight carbonate reservoirs difficult. Aiming at the carbonate reservoirs of the Da'anzhai Formation in the Longgang area of the Sichuan Basin, based on petrophysical experiments and logging response characteristics, we investigated the storage properties of matrix pores and the characteristics of fracture development to establish a method for the characterization of effectiveness of tight reservoirs. Mercury injection and nuclear magnetic resonance (NMR) experiments show that the conventional relationship between porosity and permeability cannot fully reflect the fluid flow behavior in tight matrix pores. Under reservoir conditions, the tight reservoirs still possess certain storage space and permeability, which are controlled by the characteristic structures of the matrix porosity. The degree of fracture development is crucial to the productivity and quality of tight reservoirs. By combining the fracture development similarity of the same type of reservoirs and the fracture development heterogeneity in the same block, a three-level classification method of fracture development was established on the basis of fracture porosity distribution and its cumulative features. According to the actual production data, based on the effectiveness analysis of the matrix pores and fast inversion of fracture parameters from dual laterolog data, we divided the effective reservoirs into three classes: Class I with developed fractures and pores, and high-intermediate productivity; Class II with moderately developed fractures and pores or of fractured type, and intermediate-low productivity; Class III with poorly developed fractures and matrix pores, and extremely low productivity. Accordingly log classification standards were set up. Production data shows that the classification of effective reservoirs is highly consistent with the reservoir productivity level, providing a new approach for the effectiveness evaluation of tight reservoirs. 展开更多
关键词 matrix porosity fracture porosity reservoir effectiveness reservoir classification petrophysical log characterization
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高效液相色谱-质谱法测定淡水鱼中地西泮 被引量:1
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作者 林涛 蔡苇 +5 位作者 王志飞 普家云 李金峰 陈兴连 刘宏程 刘振环 《化学分析计量》 CAS 2024年第9期28-32,共5页
建立高效液相色谱-质谱法测定淡水鱼中地西泮。样品用乙腈提取,采用Florisil填料和氨基填料净化,当Florisil填料和氨基填料的质量比为2∶3时,能够有效地吸附淡水鱼基质中的脂肪、脂质和蛋白质等杂质,降低基质效应,提高质谱响应的信噪比... 建立高效液相色谱-质谱法测定淡水鱼中地西泮。样品用乙腈提取,采用Florisil填料和氨基填料净化,当Florisil填料和氨基填料的质量比为2∶3时,能够有效地吸附淡水鱼基质中的脂肪、脂质和蛋白质等杂质,降低基质效应,提高质谱响应的信噪比。地西泮的质量浓度在0.05~20 ng/mL范围内与色谱峰面积线性关系良好,相关系数为0.9996,检出限为0.15μg/kg,定量限为0.5μg/kg。空白样品加标回收率为84.2%~95.5%,测定结果的相对标准偏差为5.25%~6.83%(n=6)。该方法快速准确,基质效应小,能够满足水产品中地西泮的测定要求。 展开更多
关键词 高效液相色谱-质谱法 淡水鱼 地西泮 基质效应
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X射线荧光光谱在国内航空金属材料分析中的应用
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作者 李辉 张重远 《分析测试学报》 CAS CSCD 北大核心 2024年第9期1310-1316,共7页
该文介绍了X射线荧光光谱分析(XRF)的基本原理及其进行定性分析、半定量分析、定量分析的理论基础。对检测涉及的基体效应、光谱重叠等影响因素及数学校正方法进行了简单说明。总结了航空用金属材料中铝合金、镁合金、钛合金、钢铁、高... 该文介绍了X射线荧光光谱分析(XRF)的基本原理及其进行定性分析、半定量分析、定量分析的理论基础。对检测涉及的基体效应、光谱重叠等影响因素及数学校正方法进行了简单说明。总结了航空用金属材料中铝合金、镁合金、钛合金、钢铁、高温合金、陶瓷、金属基复合材料、镀层分析以及手持荧光定性、半定量快速分析近年来在航空金属材料分析中的应用情况,梳理了XRF分析的技术要点并对XRF技术的发展进行了展望。 展开更多
关键词 航空 金属材料 基体效应 定性分析 定量分析 合金
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An effective reflectance method for designing broadband antireflection films coupled with solar cells
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作者 詹锋 贺继方 +4 位作者 尚向军 李密锋 倪海桥 徐应强 牛智川 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第3期458-462,共5页
The solar spectrum covers a broad wavelength range, which requires that antireflection coating (ARC) is effective over a relatively wide wavelength range for more incident light coming into the cell. In this paper, ... The solar spectrum covers a broad wavelength range, which requires that antireflection coating (ARC) is effective over a relatively wide wavelength range for more incident light coming into the cell. In this paper, we present two methods to measure the composite reflection of SiO2/ZnS double-layer ARC in the wavelength ranges of 300-870 nm (duaI- junction) and 300-1850 nm (triple-junction), under the solar spectrum AM0. In order to give sufficient consideration to the ARC coupled with the window layer and the dispersion effect of the refractive index of each layer, we use multidimensional matrix data for reliable simulation. A comparison between the results obtained from the weighted-average reflectance (WAR) method commonly used and that from the effective-average reflectance (EAR) method introduced here shows that the optimized ARC through minimizing the effective-average reflectance is convenient and available. 展开更多
关键词 weighted-average reflectance effective-average reflectance transfer matrix
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色谱法测定农药残留量的基质效应的研究进展 被引量:4
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作者 王家瑶 朱杰丽 +2 位作者 柴振林 甘美娇 杨柳 《理化检验(化学分册)》 CAS CSCD 北大核心 2024年第6期635-642,共8页
从基质效应的主要影响因素(农药的结构和种类、农药的浓度水平、基质的种类、基质的浓度水平、前处理方法和色谱条件)和应用性研究(改进前处理方法、优化色谱条件、选择标准品保护剂、选择匹配基质、改进定量方法)两方面综述了色谱法测... 从基质效应的主要影响因素(农药的结构和种类、农药的浓度水平、基质的种类、基质的浓度水平、前处理方法和色谱条件)和应用性研究(改进前处理方法、优化色谱条件、选择标准品保护剂、选择匹配基质、改进定量方法)两方面综述了色谱法测定农药残留量的基质效应研究进展,并对今后的研究方向进行了展望(引用文献79篇)。 展开更多
关键词 色谱法 测定 农药残留 基质效应 研究进展
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