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Elasto-plastic Analysis of Circular Tunnels in Jointed Rock Masses Satisfy the Hoek-Brown Failure Criterion 被引量:11
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作者 SUN Jin-shan LU Wen-bo ZHU Qi-hu CHEN Ming 《Journal of China University of Mining and Technology》 EI 2007年第3期393-398,共6页
The relationship between the Hoek-Brown parameters and the mechanical response of circular tunnels is il-lustrated. Closed-form and approximate solutions are given for the extent of the plastic zone and the stress and... The relationship between the Hoek-Brown parameters and the mechanical response of circular tunnels is il-lustrated. Closed-form and approximate solutions are given for the extent of the plastic zone and the stress and dis-placement fields under axisymmetrical and asymmetric stress conditions. For the same rock masses and under axisym-metrical stress conditions,the radius of the plastic zone in terms of Hoek-Brown criterion is generally an approximation of the radius in terms of the Mohr-Coulomb criterion. The radius in terms of the Hoek-Brown criterion is larger under low stress conditions. For poor quality rock masses (GSI<25),measures (such as grouting,setting rock bolts,etc.) that improve the GSI of rock masses are effective in improving the stability of tunnels. It is not advisable to improve the sta-bility of the tunnels by providing a small support resistance p through shotcrete,except for very poor quality jointed rock masses. Without reference to the quality of the rock mass,the disturbance factor D should not less than 0.5. Meas-ures which disturb rock masses during tunnel construction should be taken carefully when the tunnel depth increases. 展开更多
关键词 jointed rock masses circular tunnel general Hoek-Brown failure criterion elasto-plastic analysis con-struction measures
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Analytical and Experimental Study of Free Vibration of Beams Carrying Multiple Masses and Springs 被引量:1
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作者 Zhuang Wang Ming Hong +1 位作者 Junchen Xu Hongyu Cui 《Journal of Marine Science and Application》 2014年第1期32-40,共9页
The structures in engineering can be simplified into elastic beams with concentrated masses and elastic spring supports. Studying the law of vibration of the beams can be a help in guiding its design and avoiding reso... The structures in engineering can be simplified into elastic beams with concentrated masses and elastic spring supports. Studying the law of vibration of the beams can be a help in guiding its design and avoiding resonance. Based on the Laplace transform method, the mode shape functions and the frequency equations of the beams in the typical boundary conditions are derived. A cantilever beam with a lumped mass and a spring is selected to obtain its natural frequencies and mode shape functions. An experiment was conducted in order to get the modal parameters of the beam based on the NExT-ERA method. By comparing the analytical and experimental results, the effects of the locations of the mass and spring on the modal parameter are discussed. The variation of the natural frequencies was obtained with the changing stiffness coefficient and mass coefficient, respectively. The findings provide a reference for the vibration analysis methods and the lumped parameters layout design of elastic beams used in engineering. 展开更多
关键词 ELASTIC BEAMS concentrated masses SPRINGS naturalfrequencies mode shape functions free vibration NExT-ERA MODAL identification
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Design and Evaluation of a Differential Accelerometer for Drop-Tower Equivalence Principle Test with Rotating Masses
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作者 Feng-Tian Han Tian-Yi Liu +1 位作者 Xiao-Xia He Qiu-Ping Wu 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第10期13-17,共5页
A differential accelerometer comprising of two rotating masses made of the same material is proposed for drop tower-based free-fall testing of the spin-spin force between the rotating mass and the Earth. The measureme... A differential accelerometer comprising of two rotating masses made of the same material is proposed for drop tower-based free-fall testing of the spin-spin force between the rotating mass and the Earth. The measurement is performed by placing the two concentric masses of very different momenta in a vacuum drop capsule which is falling freely in the Earth's gravitational field. A nonzero output of the differential aeeelerometer is an indication of possible violation of new equivalence principle (NEP). We present the conceptual design of a modified free-fall NEP experiment which can be performed at the Belting drop tower. Design and evaluation of the differential accelerometer with a hybrid electrostatic/magnetic suspension system are presented to accommodate for operation on ground and drop-tower tests. Details specific to the measurement uncertainty are discussed to yield an NEP test accuracy of 7.2×10^-9. 展开更多
关键词 TM Design and Evaluation of a Differential Accelerometer for Drop-Tower Equivalence Principle Test with Rotating masses NEP
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First-principles investigation of electronic structure,effective carrier masses, and optical properties of ferromagnetic semiconductor CdCr_2S_4 被引量:1
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作者 朱旭辉 陈向荣 刘邦贵 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第5期346-351,共6页
The electronic structures, the effective masses, and optical properties of spinel CdCr_2S_4 are studied by using the fullpotential linearized augmented planewave method and a modified Becke–Johnson exchange functiona... The electronic structures, the effective masses, and optical properties of spinel CdCr_2S_4 are studied by using the fullpotential linearized augmented planewave method and a modified Becke–Johnson exchange functional within the densityfunctional theory. Most importantly, the effects of the spin–orbit coupling(SOC) on the electronic structures and carrier effective masses are investigated. The calculated band structure shows a direct band gap. The electronic effective mass and the hole effective mass are analytically determined by reproducing the calculated band structures near the BZ center.SOC substantially changes the valence band top and the hole effective masses. In addition, we calculated the corresponding optical properties of the spinel structure CdCr_2S_4. These should be useful to deeply understand spinel CdCr_2S_4 as a ferromagnetic semiconductor for possible semiconductor spintronic applications. 展开更多
关键词 CdCr2S4 semiconductor effective mass optical properties density functional theory
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Feasibility study on the suitability of dielectric barrier discharge plasma treatment of desert sand for concrete production purposes
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作者 Yorick FENNER Martin BELLMANN +1 位作者 Andreas TUMMEL Christoph GERHARD 《Plasma Science and Technology》 2025年第1期111-117,共7页
Due to the continuously increasing building and construction industry,sand has become one of the most questioned raw materials worldwide.However,the available amount of sand suitable for concrete production is orders ... Due to the continuously increasing building and construction industry,sand has become one of the most questioned raw materials worldwide.However,the available amount of sand suitable for concrete production is orders of magnitude lower that the demand and consumption.Even though desert sand is sufficiently available,it is not usable for realizing stable concrete due to its surface shape.Against this background,the suitability of energy-efficient‘cold'dielectric barrier discharge plasma operated at atmospheric pressure for improving the properties of concrete produced from desert sand was investigated in this contribution.It is shown that such plasma treatment allows for a certain roughening and re-shaping of sand grains.As a result,the mass flow of treated sand is decreased due to an improved wedging of sand grains.This leads to a certain increase in compressive strength of concrete samples.Even though this increase is marginal,the suitability of the applied type of plasma for modification of the geometry and surface chemistry of sand grains was proven,showing its basic potential for the treatment and preconditioning of sand used for concrete,mortar or plastering. 展开更多
关键词 plasma treatment atmospheric pressure plasma SAND CONCRETE surface roughening mass flow compressive strength
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Properties of the drip-line nucleus and mass relation of mirror nuclei
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作者 Meng-Ting Wan Li Ou +1 位作者 Min Liu Ning Wang 《Nuclear Science and Techniques》 2025年第2期112-122,共11页
The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb e... The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb energy heightened by an aug-mented charge could not be mitigated completely by symmetry energy because of isospin asymmetry saturation but is resisted complementally by strong nuclear deformation.The positions of saltation for the difference in proton numbers between two neighboring nuclei at the neutron drip line,and the isospin asymmetry of the neutron drip-line nucleus as a function of the neutron number distinctly correspond to the known magic numbers,which can serve as a reference to verify the undeter-mined neutron magic number.Through fitting of the binding energy difference between mirror nuclei(BEDbMN),a set of Coulomb energy coefficients with greater accuracy is obtained.A high-precision description of the BEDbMN is useful for accurately determining the experimentally unknown mass of the nucleus close to the proton drip line if the mass of its mirror nucleus is measured experimentally. 展开更多
关键词 Nuclear mass formula Drip-line nucleus Magic number Mirror nuclei Coulomb energy
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A two-sample Mendelian randomization study on the relationship of body weight,body mass index,and waist circumference with cardiac arrest
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作者 Tingting Xu Shaokun Wang +2 位作者 Liqiang Zhao Jiawen Wang Jihong Xing 《World Journal of Emergency Medicine》 2025年第2期129-135,共7页
BACKGROUND:This study aims to explore the causal relationship of body weight,body mass index(BMI),and waist circumference (WC) with the risk of cardiac arrest (CA) using two-sample Mendelian randomization (MR).METHODS... BACKGROUND:This study aims to explore the causal relationship of body weight,body mass index(BMI),and waist circumference (WC) with the risk of cardiac arrest (CA) using two-sample Mendelian randomization (MR).METHODS:Data were summarized using genome-wide association studies (GWAS).Twosample MR analyses were performed using the inverse variance weighting (IVW) method,the weighted median method,and the MR-Egger analysis.Heterogeneity test and sensitivity analysis were performed using Cochran’s Q test and the leave-one-out method,respectively.The Steiger test was used to detect reverse causality.Bayesian model-averaged MR was used to identify the most influential risk factors.RESULTS:A total of 13 GWAS data were collected for BMI,body weight and WC.IVW analyses showed a positive correlation of body weight,BMI,and WC with CA (all OR>1 and P<0.05),with MR-Egger and weighted median methods confirming the IVW findings.No horizontal pleiotropy or heterogeneity was observed.Sensitivity analysis indicated that no single nucleotide polymorphism(SNP) caused significant changes in overall causality.Bayesian model-averaged MR was also used to rank causality based on marginal inclusion probability (MIP),and the corresponding modelaveraged causal estimate (MACE) were confirmed,which indicated that WC (GWAS ID:ukb-b-9405)was the highest-ranked risk factor (MIP=0.119,MACE=0.011);its posterior probability was 0.057.A total of 14 sex-specific GWAS data on weight,BMI,and WC were analyzed in relationship with CA,and the MR results showed no significant effects of sex-specific factors.CONCLUSION:Body weight,BMI,and WC are causally associated with an increased risk of CA,with WC identified as the most important risk factor. 展开更多
关键词 Body weight Body mass index Waist circumference Cardiac arrest Mendelian randomization
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Isospin splitting of the Dirac mass probed using the relativistic Brueckner-Hartree-Fock theory
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作者 Pianpian Qin Qiang Zhao +2 位作者 Hui Tong Chencan Wang Sibo Wang 《Nuclear Science and Techniques》 2025年第2期123-130,共8页
The isospin splitting of the Dirac mass obtained using the relativistic Brueckner-Hartree-Fock(RBHF)theory was thor-oughly investigated.From the perspective in the full Dirac space,the long-standing controversy betwee... The isospin splitting of the Dirac mass obtained using the relativistic Brueckner-Hartree-Fock(RBHF)theory was thor-oughly investigated.From the perspective in the full Dirac space,the long-standing controversy between the momentum-independent approximation(MIA)method and the projection method on the isospin splitting of the Dirac mass in asymmetric nuclear matter was analyzed in detail.We found that the assumption procedure of the MIA method,which assumes that single-particle potentials are momentum independent,is not a sufficient condition that directly leads to the opposite sign of the isospin splitting of the Dirac mass,whereas the extraction procedure of the MIA method,which extracts single-particle potentials from single-particle potential energy,changes the sign.A formal expression of the Dirac mass was obtained by approximately solving a set of equations involved in the extraction procedure.The opposite isospin splitting of the Dirac mass was mainly caused by the extraction procedure,which forcibly assumed that the momentum dependence of the single-particle potential energy was in a quadratic form,in which the strength was solely determined by a constant scalar potential.Improved understanding of the isospin splitting of the Dirac mass from ab initio calculations could enhance our knowledge of neutron-rich systems,such as exotic nuclei and neutron stars. 展开更多
关键词 Dirac mass Relativistic Brueckner-Hartree-Fock theory Single-particle potential Momentum dependence
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Geostatistics-block-based characterization of the relationship between rock mass quality and powder factor and its application on open-pit limit optimization
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作者 Jinduo Li Tianhong Yang +6 位作者 Feiyue Liu Shigui Du Wenxue Deng Yong Zhao Honglei Liu Leilei Niu Zhiqiang Xu 《International Journal of Mining Science and Technology》 2025年第1期135-147,共13页
Accurately predicting the powder factor during blasting is essential for sustainable production planning in low-grade mines.This research presents a method for predicting powder factor based on the heterogeneity of ro... Accurately predicting the powder factor during blasting is essential for sustainable production planning in low-grade mines.This research presents a method for predicting powder factor based on the heterogeneity of rock mass rating(RMR).Considering a low-grade metal mine as an example,this study exploited geostatistical methods to obtain independent RMR for each block unit.A three-dimensional spatial distribution model for the powder factor was developed on the basis of the relationships between the RMR and the powder factor.Subsequently,models for blasting cost and mining value were built and employed to optimize the open-pit limit.The multi-variable model based on the RMR performed well in predicting the powder factor,achieving a correlation coefficient of 0.88(root mean square error of 4.3)and considerably outperforming the uniaxial compressive strength model.After model optimization,the mean size and standard deviation of the fragments in the blast pile decreased by 8.5%and 35.1%,respectively,whereas the boulder yield and its standard deviation decreased by 33.3%and 58.8%,respectively.Additionally,optimizing the open-pit limit using this method reduced the amount of rock,increased the amount of ore,and lowered blasting costs,thereby enhancing the economic efficiency of the mine.This study provides valuable insights for blasting design and mining decisions,demonstrating the advantages and potential applications of powder factor prediction based on the heterogeneity of rock mass quality. 展开更多
关键词 Geostatistics method Powder factor Open-pit limit optimization Blasting cost Rock mass quality
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The application and perspective of NMR and MS based strategies for functional compounds mining in medicinal and dietary plants
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作者 Bodou Zhang Sheng Li +6 位作者 Zhenzhen Liang Yinling Wei Jing Dong Hongyan Wen Lingli Guo Xiaojiang Hao Yu Zhang 《Food Science and Human Wellness》 2025年第1期50-63,共14页
Medicinal and dietary plants provide numerous nutritional and functional compounds and also have various potential health benefits to humanity.The specific and efficient techniques for accurate identification of nutri... Medicinal and dietary plants provide numerous nutritional and functional compounds and also have various potential health benefits to humanity.The specific and efficient techniques for accurate identification of nutritional compounds and functional metabolites is crucial for the development of functional foods from medicinal and dietary plants.Nuclear magnetic resonance(NMR)and mass spectrometry(MS)are indispensable and essential technologies that provide an unsurpassed wealth of untargeted identification,quantitative and qualitative analysis,and structural information in the study of food and plant products.In the past decade,the rapid development of modern analytical technology has led to the emergence of new approaches and strategies for natural products discovery.Especially the application of novel NMRand MS-based identification and dereplication strategies aided by artificial intelligence and machine learning algorithms have brought about a significant shift in the natural products discovery process.These developments and changes in the natural products filed have given us insights into how to accurately target and mining nutritional,functional,and bioactive compounds.Thus,we have summarized recent research on novel NMR and MS based strategies and methods focusing on functional compounds,accurate identification and efficient discovery mainly in medicinal and dietary plants.This review could provide a comprehensive perspective for a better understanding of novel strategies and methods based on NMR and MS technologies,which could provide valuable insights and ideas for functional compounds mining. 展开更多
关键词 Nuclear magnetic resonance(NMR) Mass spectrometry(MS) New strategies Functional compounds MINING
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Sulfur atom occupying surface oxygen vacancy to boost the charge transfer and stability for aqueous Bi_(2)O_(3)electrode
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作者 Guangmin Yang Jianyan Lin +3 位作者 Guanwu Li Tian Li Dong Wang Weitao Zheng 《Journal of Energy Chemistry》 2025年第2期751-759,I0016,共10页
Oxygen vacancies(Ov)within metal oxide electrodes can enhance mass/charge transfer dynamics in energy storage systems.However,construction of surface Ovoften leads to instability in electrode structure and irreversibl... Oxygen vacancies(Ov)within metal oxide electrodes can enhance mass/charge transfer dynamics in energy storage systems.However,construction of surface Ovoften leads to instability in electrode structure and irreversible electrochemical reactions,posing a significant challenge.To overcome these challenges,atomic heterostructures are employed to address the structural instability and enhance the mass/charge transfer dynamics associated with phase conversion mechanism in aqueous electrodes,Herein,we introduce an atomic S-Bi_(2)O_(3)heterostructure(sulfur(S)anchoring on the surface Ovof Bi_(2)O_(3)).The integration of S within Bi_(2)O_(3)lattice matrix triggers a charge imbala nce at the heterointerfaces,ultimately resulting in the creation of a built-in electric field(BEF).Thus,the BEF attracts OH-ions to be adsorbed onto Bi within the regions of high electron cloud overlap in S-Bi_(2)O_(3),facilitating highly efficient charge transfer.Furthermore,the anchored S plays a pivotal role in preserving structural integrity,thus effectively stabilizing the phase conversion reaction of Bi_(2)O_(3).As a result,the S-Bi_(2)O_(3)electrode achieves72.3 mA h g^(-1)at 10 A g^(-1)as well as high-capacity retention of 81.9%after 1600 cycles.Our innovative SBi_(2)O_(3)design presents a groundbreaking approach for fabricating electrodes that exhibit efficient and stable mass and charge transfer capabilities.Furthermore,it enhances our understanding of the underlying reaction mechanism within energy storage electrodes. 展开更多
关键词 Oxygen vavancy Atomic heterostructure Structural integrity Charge/mass transfer Anchoring effect
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Energy and Buildings
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《建筑节能(中英文)》 2025年第3期10-10,共1页
The present study develops a data-based compact model for the prediction of the fluid temperature evolution in district heating-and-cooling pipeline networks.This model is based on an existing“reduced-order model”by... The present study develops a data-based compact model for the prediction of the fluid temperature evolution in district heating-and-cooling pipeline networks.This model is based on an existing“reduced-order model”by the authors obtained from reduction of the“full-order model”describing the spatio-temporal energy balance for each pipe segment to a semi-analytical input-output relation between the pipe outlet temperature and the pipe inlet and ground temperatures.The proposed model(denoted XROM)expands on the original reduced-order model by incorporating variable mass flux as an additional input and thus greatly increases its practical relevance.The XROM represents variable mass flux by step-wise switching between mass-flux levels and thereby induces a prediction error relative to the true full-order model evolution after each switching.Theoretical analysis rigorously demonstrates that this error always decays and the XROM invariably converges on the full-order model evolution and,consequently,affords the same prediction accuracy.Performance analyses reveal that prediction errors are restricted to short“convergence intervals”after each mass-flux switching and the XROM therefore can handle substantially faster operating schemes than the current ones based on hourly monitoring and control.Convergence intervals of O(minutes)are namely typically sufficient-and thus switching frequencies up to O(minutes 1)permissible during dynamic operation and control actions-for reliable predictions.Quantification of these convergence intervals by an easy-to-use empirical relation furthermore enables a priori determination of the conditions for reliable predictions.Moreover,the XROM can capture the full 3D system dynamics(provided incompressible flow and heat-transfer mechanisms depending linearly on temperature)versus the essentially 1D approximation of current compact pipe models yet at similar computational cost.These attributes advance(parts of)district heating and cooling networks demanding prediction accuracies beyond 1D as its primary application area.This makes the XROM complementary to said pipe models and thereby expands the modelling capabilities for handling the growing complexity of(next-generation)networks. 展开更多
关键词 District heating network Reduced-order model Variable mass flux Linear time-variant system Input-output relation
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Precision storage lifetime measurements of highly charged heavy ions in the CSRe storage ring using a Schottky resonator
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作者 Qian Wang Xin-Liang Yan +13 位作者 Guang-Yu Zhu Shahab Sanjari Li-Jun Mao He Zhao Yuri ALitvinov Rui-Jiu Chen Meng Wang Yu-Hu Zhang You-Jin Yuan Jun-Xia Wu Hong-Yang Jiao Yue Yu Zu-Yi Chen Yin-Fang Luo 《Nuclear Science and Techniques》 2025年第1期150-160,共11页
Schottky mass spectrometry utilizing heavy-ion storage rings is a powerful technique for the precise mass and decay half-life measurements of highly charged ions.Owing to the nondestructive ion detection features of S... Schottky mass spectrometry utilizing heavy-ion storage rings is a powerful technique for the precise mass and decay half-life measurements of highly charged ions.Owing to the nondestructive ion detection features of Schottky noise detectors,the number of stored ions in the ring is determined by the peak area in the measured revolution frequency spectrum.Because of their intrinsic amplitude-frequency characteristic(AFC),Schottky detector systems exhibit varying sensitivities at different frequencies.Using low-energy electron-cooled stored ions,a new method is developed to calibrate the AFC curve of the Schottky detector system of the Experimental Cooler Storage Ring(CSRe)storage ring located in Lanzhou,China.Using the amplitude-calibrated frequency spectrum,a notable refinement was observed in the precision of both the peak position and peak area.As a result,the storage lifetimes of the electron-cooled fully ionized^(56)Fe^(26+)ions were determined with high precision at beam energies of 13.7 and 116.4 MeV/u,despite of frequency drifts during the experiment.When electron cooling was turned off,the effective vacuum condition experienced by the 116.4 MeV/u^(56)Fe^(26+)ions was determined using amplitude-calibrated spectra,revealing a value of 2×10^(−10)mbar,which is consistent with vacuum gauge readings along the CSRe ring.The method reported herein will be adapted for the next-generation storage ring of the HIAF facility under construction in Huizhou,China.It can also be adapted to other storage ring facilities worldwide to improve precision and enhance lifetime measurements using many ions in the ring. 展开更多
关键词 Lifetime measurement Schottky mass spectrometry Sensitivity response Highly charged heavy ion RESONATOR UH vacuum Nondestructive diagnostics
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A new search for the variation of fundamental constants using the rovibrational levels and isotope effects of the magnesium fluoride molecule
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作者 Di Wu Jin Wei +3 位作者 Taojing Dong Chenyu Zu Yong Xia Jianping Yin 《Chinese Physics B》 2025年第2期215-221,共7页
The recently demonstrated methods for cooling and trapping diatomic molecules offer new possibilities for precision searches in fundamental physical theories.Here,we propose to study the variations of the fine-structu... The recently demonstrated methods for cooling and trapping diatomic molecules offer new possibilities for precision searches in fundamental physical theories.Here,we propose to study the variations of the fine-structure constant(α=e^(2)/(hc)) and the proton-to-electron mass ratio(μ=m_(p)/m_(e)) with time by taking advantage of the nearly degenerate rovibrational levels in the electronic states of the magnesium fluoride(MgF) molecule.Specifically,due to the cancellation between the fine-structure splitting and the rovibrational intervals in the different MgF natural isotopes,a degeneracy occurs for A^(2)П_(3/2)(v'=0,J'=18.5,-) and A^(2)П_(1/2)(v "=0,J" =20.5,-).We find that using the nearly degenerate energy level of such states can be 104 times more sensitive than using a pure rotational transition to measure the variations of α and μ.To quantify the small gap between A^(2)П_(3/2)(v'=0,J'=18.5,-) and A^(2)П_(1/2)(v "=0,J" =20.5,-),special transitions of choice are feasible:X^(2)Σ_(1/2)~+(v=0,J=19.5,+) to A^(2)П_(3/2)(v'=0,J'=18.5,-) and X^(2)Σ_(1/2)~+(v=0.J=19.5,+)to A^(2)П_(1/2)(v "=0,J" =20.5,-).In addition,we estimate the frequency uncertainties caused by the narrow linewidth,Zeeman shift,Stark shift,Doppler broadening and blackbody radiation. 展开更多
关键词 cold molecule proton-to-electron mass ratio precision measurement
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Pulsed dynamic electrolysis enhanced PEMWE hydrogen production:Revealing the effects of pulsed electric fields on protons mass transport and hydrogen bubble escape
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作者 Xuewei Zhang Wei Zhou +13 位作者 Yuming Huang Liang Xie Tonghui Li Huimin Kang Lijie Wang Yang Yu Yani Ding Junfeng Li Jiaxiang Chen Miaoting Sun Shuo Cheng Xiaoxiao Meng Jihui Gao Guangbo Zhao 《Journal of Energy Chemistry》 2025年第1期201-214,共14页
The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for... The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for hydrogen production.Despite remarkable advancements in this field,confronting the sluggish electrochemical kinetics and inherent high-energy consumption arising from deteriorated mass transport within PEMWE systems remains a formidable obstacle.This impediment stems primarily from the hindered protons mass transfer and the untimely hydrogen bubbles detachment.To address these challenges,we harness the inherent variability of electrical energy and introduce an innovative pulsed dynamic water electrolysis system.Compared to constant voltage electrolysis(hydrogen production rate:51.6 m L h^(-1),energy consumption:5.37 kWh Nm-^(3)H_(2)),this strategy(hydrogen production rate:66 m L h^(-1),energy consumption:3.83 kWh Nm-^(3)H_(2))increases the hydrogen production rate by approximately 27%and reduces the energy consumption by about 28%.Furthermore,we demonstrate the practicality of this system by integrating it with an off-grid photovoltaic(PV)system designed for outdoor operation,successfully driving a hydrogen production current of up to 500 mA under an average voltage of approximately 2 V.The combined results of in-situ characterization and finite element analysis reveal the performance enhancement mechanism:pulsed dynamic electrolysis(PDE)dramatically accelerates the enrichment of protons at the electrode/solution interface and facilitates the release of bubbles on the electrode surface.As such,PDE-enhanced PEMWE represents a synergistic advancement,concurrently enhancing both the hydrogen generation reaction and associated transport processes.This promising technology not only redefines the landscape of electrolysis-based hydrogen production but also holds immense potential for broadening its application across a diverse spectrum of electrocatalytic endeavors. 展开更多
关键词 Water electrolysis Hydrogen production Pulsed dynamic electrolysis Proton exchange membrane water electrolysis Mass transport
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海上自主水面船舶运输法律责任研究 被引量:1
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作者 李桢 周翔宇 +1 位作者 章文俊 张继军 《世界海运》 2024年第2期48-52,共5页
海上自主水面船舶(MASS)的飞速发展引发了国际社会对其安全性和监管问题的广泛关注。MASS在技术上的发展必然要求明确损害的民事救济以管控风险,亟待解决MASS运输法律责任中的责任主体、归责原则、免责事项等核心关切问题。结合MASS议... 海上自主水面船舶(MASS)的飞速发展引发了国际社会对其安全性和监管问题的广泛关注。MASS在技术上的发展必然要求明确损害的民事救济以管控风险,亟待解决MASS运输法律责任中的责任主体、归责原则、免责事项等核心关切问题。结合MASS议题在国际海事组织的审议进程及其他国家在立法方面的探索,提出MASS从事运输所致损害的可能的责任分配方案。 展开更多
关键词 MASS MASS船长 远程操作中心 远程操作员 MASS生产厂商
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Stepped-up development of accelerator mass spectrometry method for the detection of ^(60)Fe with the HI-13 tandem accelerator 被引量:2
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作者 Yang Zhang Sheng-Quan Yan +36 位作者 Ming He Qing-Zhang Zhao Wen-Hui Zhang Chao-Xin Kan Jian-Ming Zhou Kang-Ning Li Xiao-Fei Wang Jian-Cheng Liu Zhao-Hua Peng Zhuo Liang Ai-Ling Li Jian Zheng Qi-Wen Fan Yun-Ju Li You-Bao Wang Zhi-Hong Li Yang-Ping Shen Ding Nan Wei Nan Yu-Qiang Zhang Jia-Ying-Hao Li Jun-Wen Tian Jiang-Lin Hou Chang-Xin Guo Zhi-Cheng Zhang Ming-Hao Zhu Yu-Wen Chen Yu-Chen Jiang Tao Tian Jin-Long Ma Yi-Hui Liu Jing-Yu Dong Run-Long Liu Mei-Yue-Nan Ma Yong-Shou Chen Wei-Ping Liu Bing Guo 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第4期136-143,共8页
The Moon provides a unique environment for investigating nearby astrophysical events such as supernovae.Lunar samples retain valuable information from these events,via detectable long-lived“fingerprint”radionuclides... The Moon provides a unique environment for investigating nearby astrophysical events such as supernovae.Lunar samples retain valuable information from these events,via detectable long-lived“fingerprint”radionuclides such as^(60)Fe.In this work,we stepped up the development of an accelerator mass spectrometry(AMS)method for detecting^(60)Fe using the HI-13tandem accelerator at the China Institute of Atomic Energy(CIAE).Since interferences could not be sufficiently removed solely with the existing magnetic systems of the tandem accelerator and the following Q3D magnetic spectrograph,a Wien filter with a maximum voltage of±60 kV and a maximum magnetic field of 0.3 T was installed after the accelerator magnetic systems to lower the detection background for the low abundance nuclide^(60)Fe.A 1μm thick Si_(3)N_(4) foil was installed in front of the Q3D as an energy degrader.For particle detection,a multi-anode gas ionization chamber was mounted at the center of the focal plane of the spectrograph.Finally,an^(60)Fe sample with an abundance of 1.125×10^(-10)was used to test the new AMS system.These results indicate that^(60)Fe can be clearly distinguished from the isobar^(60)Ni.The sensitivity was assessed to be better than 4.3×10^(-14)based on blank sample measurements lasting 5.8 h,and the sensitivity could,in principle,be expected to be approximately 2.5×10^(-15)when the data were accumulated for 100 h,which is feasible for future lunar sample measurements because the main contaminants were sufficiently separated. 展开更多
关键词 Accelerator mass spectrometry Wien filter Isobar separation SUPERNOVAE Chang'e-5 lunar samples
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Calcium-chelating peptides from rabbit bone collagen:characterization,identification and mechanism elucidation 被引量:2
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作者 Fuhuan Yuan Yu Fu +8 位作者 Liang Ma Hankun Zhu Yong Yu Xin Feng Yi Sun Hongjie Dai Xin Liu Zhengfang Liu Yuhao Zhang 《Food Science and Human Wellness》 SCIE CSCD 2024年第3期1485-1493,共9页
This study aimed to characterize and identify calcium-chelating peptides from rabbit bone collagen and explore the underlying chelating mechanism.Collagen peptides and calcium were extracted from rabbit bone by instan... This study aimed to characterize and identify calcium-chelating peptides from rabbit bone collagen and explore the underlying chelating mechanism.Collagen peptides and calcium were extracted from rabbit bone by instant ejection steam explosion(ICSE)combined with enzymatic hydrolysis,followed by chelation reaction to prepare rabbit bone peptide-calcium chelate(RBCP-Ca).The chelating sites were further analyzed by liquid chromatography-tandem mass(LC-MS/MS)spectrometry while the chelating mechanism and binding modes were investigated.The structural characterization revealed that RBCP successfully chelated with calcium ions.Furthermore,LC-MS/MS analysis indicated that the binding sites included both acidic amino acids(Asp and Glu)and basic amino acids(Lys and Arg),Interestingly,three binding modes,namely Inter-Linking,Loop-Linking and Mono-Linking were for the first time found,while Inter-Linking mode accounted for the highest proportion(75.1%),suggesting that chelation of calcium ions frequently occurred between two peptides.Overall,this study provides a theoretical basis for the elucidation of chelation mechanism of calcium-chelating peptides. 展开更多
关键词 Rabbit bone Collagen peptide Peptide-calcium chelate Chelation mechanism Liquid chromatography-tandem mass(LC-MS/MS)
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Rock mass quality prediction on tunnel faces with incomplete multi-source dataset via tree-augmented naive Bayesian network 被引量:1
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作者 Hongwei Huang Chen Wu +3 位作者 Mingliang Zhou Jiayao Chen Tianze Han Le Zhang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第3期323-337,共15页
Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantita... Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantitative parameters.However,due to the harsh on-site construction conditions,it is rather difficult to obtain some of the evaluation parameters which are essential for the rock mass quality prediction.In this study,a novel improved Swin Transformer is proposed to detect,segment,and quantify rock mass characteristic parameters such as water leakage,fractures,weak interlayers.The site experiment results demonstrate that the improved Swin Transformer achieves optimal segmentation results and achieving accuracies of 92%,81%,and 86%for water leakage,fractures,and weak interlayers,respectively.A multisource rock tunnel face characteristic(RTFC)dataset includes 11 parameters for predicting rock mass quality is established.Considering the limitations in predictive performance of incomplete evaluation parameters exist in this dataset,a novel tree-augmented naive Bayesian network(BN)is proposed to address the challenge of the incomplete dataset and achieved a prediction accuracy of 88%.In comparison with other commonly used Machine Learning models the proposed BN-based approach proved an improved performance on predicting the rock mass quality with the incomplete dataset.By utilizing the established BN,a further sensitivity analysis is conducted to quantitatively evaluate the importance of the various parameters,results indicate that the rock strength and fractures parameter exert the most significant influence on rock mass quality. 展开更多
关键词 Rock mass quality Tunnel faces Incomplete multi-source dataset Improved Swin Transformer Bayesian networks
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Improved isochronous mass spectrometry with tune measurement
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作者 Han-Yu Deng Yuan-Ming Xing +5 位作者 Xu Zhou Yu-Hu Zhang Xin-Liang Yan Jin-Yang Shi Ting Liao Meng Wang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第11期174-181,共8页
In conventional isochronous mass spectrometry(IMS)performed on a storage ring,the precision of mass measurements for short-lived nuclei depends on the accurate determination of the revolution times(T)of stored ions.Ho... In conventional isochronous mass spectrometry(IMS)performed on a storage ring,the precision of mass measurements for short-lived nuclei depends on the accurate determination of the revolution times(T)of stored ions.However,the resolution of T inevitably deteriorates due to the magnetic rigidity spread of the ions,limiting the mass-resolving power.In this study,we used the betatron tunes Q(the number of betatron oscillations per revolution)of the ions and established a correlation between T and Q.From this correlation,T was transformed to correspond to a fixed Q with higher resolution.Using these transformed T values,the masses of ^(63)Ge,^(65)As,^(67)Se,and ^(71)Kr agreed well with the mass values measured using the newly developed IMS(Bρ-IMS).We also studied the systematics of Coulomb displacement energies(CDEs)and found that anomalous staggering in CDEs was eliminated using new mass values.This method of T transformation is highly effective for conventional IMS equipped with a single time-of-flight detector. 展开更多
关键词 Isochronous Mass Spectrometry Storage ring TUNE Natural chromaticity Nuclear mass measurement
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