Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic...Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.展开更多
A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,el...A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,elemental analysis,IR,and magnetic properties.X-ray diffraction analysis shows that the complex exists as mononuclear molecules and Co(Ⅱ)ion is four-coordinated with two radicals and two PNB-ligands.The magnetic susceptibility study indicates the complex exhibits weak ferromagnetic interactions between cobalt(Ⅱ)and im4-py radical.The magnetic property is explained by the magnetic and structure exchange mechanism.CCDC:976028.展开更多
This paper explores the recovery of block sparse signals in frame-based settings using the l_(2)/l_(q)-synthesis technique(0<q≤1).We propose a new null space property,referred to as block D-NSP_(q),which is based ...This paper explores the recovery of block sparse signals in frame-based settings using the l_(2)/l_(q)-synthesis technique(0<q≤1).We propose a new null space property,referred to as block D-NSP_(q),which is based on the dictionary D.We establish that matrices adhering to the block D-NSP_(q)condition are both necessary and sufficient for the exact recovery of block sparse signals via l_(2)/l_(q)-synthesis.Additionally,this condition is essential for the stable recovery of signals that are block-compressible with respect to D.This D-NSP_(q)property is identified as the first complete condition for successful signal recovery using l_(2)/l_(q)-synthesis.Furthermore,we assess the theoretical efficacy of the l2/lq-synthesis method under conditions of measurement noise.展开更多
This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materi...This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications.展开更多
Sc_(2)O_(3),as a host for solid-state laser gain materials,has advantage of high thermal conductivity and easy matching with activating ions,which is promising in high-power laser applications.Currently,Yb-doped Sc_(2...Sc_(2)O_(3),as a host for solid-state laser gain materials,has advantage of high thermal conductivity and easy matching with activating ions,which is promising in high-power laser applications.Currently,Yb-doped Sc_(2)O_(3) ceramics have been fabricated at very high sintering temperatures,but their optical quality and sintering process still need further improvement.In this work,5%Yb:Sc_(2)O_(3)(in mass)nano-powders were obtained by co-precipitation,and then transparent ceramics were fabricated by vacuum pre-sintering and hot isostatic pressing(HIP)post-treatment.The cubic Yb:Sc_(2)O_(3) nano-powders with good dispersity and an average crystallite of 29 nm were obtained.Influence of pre-sintering temperatures(1500-1700℃)on densification process,microstructure changes,and optical transmittance of Yb:Sc_(2)O_(3) ceramics was detected.Experimental data revealed that all samples have a uniform microstructure,while the average grain sizes increase with the increase of the sintering temperatures.Impressively,the optimum in-line transmittance of Yb:Sc_(2)O_(3) ceramics,pre-sintered at 1550℃after HIP post-treatment,reaches 78.1%(theoretical value of 80%)at 1100 nm.Spectroscopic properties of the Yb:Sc_(2)O_(3) ceramics reveal that the minimum population inversion parameterβ2 and the luminescence decay time of 5%Yb:Sc_(2)O_(3) ceramics are 0.041 and 0.49 ms,respectively,which demonstrate that the optical quality of the Yb:Sc_(2)O_(3) has been improved.Meanwhile,their best vacuum sintering temperature can be controlled down to a lower temperature(1550℃).In conclusion,Yb:Sc_(2)O_(3) nano-powders are successfully synthesized by co-precipitation method,and good optical quality transparent ceramics are fabricated by vacuum pre-sintering at 1550℃and HIP post-treatment.展开更多
Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments.Oil contents(mass fraction) of 4%,8%,12%,16% and 20% were selected to represent different contamina...Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments.Oil contents(mass fraction) of 4%,8%,12%,16% and 20% were selected to represent different contamination degrees,and the soil specimens were manually prepared through mixing and static compaction method.Initial water content and dry density of the test kaolin clay were controlled at 10% and 1.58 g/cm^3,respectively.Test results indicate that since part of the diesel oil will be released from soil by evaporation,the real water content should be derived through calibration of the quasi water content obtained by traditional test method.As contamination degree of the kaolin clay increases,both liquid limit and plastic limit decrease,but there's only a slight increase for plasticity index.Swelling pressure of contaminated kaolin clay under confined condition will be lowered when oil-content gets higher.Unconfined compressive strength(UCS) of the oil-contaminated kaolin clay is influenced by not only oil content but also curing period.Increase of contamination degree will continually lower UCS of the kaolin clay specimen.In addition,electrical resistivity of the contaminated kaolin clay with given water content decreases with the increase of oil content.However,soil resistivity is in good relationship with oil content and UCS.Finally,oil content of 8% is found to be a critical value for engineering property of kaolin clay to transit from water-dominated towards oil-dominated characteristics.展开更多
Topological method is applied firstly to calculate the group connectivity indexes of some flotation reagents for sulfide minerals and oxide minerals. The study reveals that some properties of flotation reagents, such ...Topological method is applied firstly to calculate the group connectivity indexes of some flotation reagents for sulfide minerals and oxide minerals. The study reveals that some properties of flotation reagents, such as group electronegativity, energy criterion, solubility product of chemicals and maximum wavelength of ultraviolet absorbency, have linear correlation with the first order group connectivity index (GCI) of polar group, and the related coefficients are all larger than 0.900. The GCI can be used to characterize the structure of groups, and is a sort of new effective structural parameter to study the quantitative structure activity relationship of flotation reagents.展开更多
The Poyang lake is currently the largest freshwater lake in China. Hydrologic properties of this lake, including precipitation, runoff, flood, sediment transport and so on have been analyzed on basis of large amount o...The Poyang lake is currently the largest freshwater lake in China. Hydrologic properties of this lake, including precipitation, runoff, flood, sediment transport and so on have been analyzed on basis of large amount of measurements. Variation of these properties within a year and among years and the regional distribution are explored. The encounter probability of the outflow from Poyang Lake with that from Changjiang River is computed and the detention volume of Poyang Lake is analyzed. In accordance with water balance theory, the detention storage volume of Poyang Lake and Changjiang River corresponding to the annual maximum 60-day flood volumes in 9 typical heavy flood years of 1968, 1969, 1973, 1980, 1983, 1996 and 1998 have been calculated. The detention storage capacity of both the Lake and the River ranges from 5.6 billion to 16.5 billion m\+3, 11.5 billion m\+3 at average. Among which, the detention storage capacity of Poyang Lake is 9.5 billion m\+3, accounting for 82.6%. Poyang Lake has played a very important role in detaining floods from the five rivers of the Lake system as well as floods on the river section from Changjiang to Bali. There would have more frequent and more serious flooding on the middle and lower Changjiang River, especially in the region around Hukou if there were no Poyang Lake to detain and store the floodwater.展开更多
Selective laser melting(SLM)technology is the prevailing method of manufacturing components with complex geometries.However,the cost of the additive manufacturing(AM)fine powder is relatively high,which significantly ...Selective laser melting(SLM)technology is the prevailing method of manufacturing components with complex geometries.However,the cost of the additive manufacturing(AM)fine powder is relatively high,which significantly limits the development of the SLM.In this study,the 316L fine powder and coarse powder with a mass ratio of 80:20,70:30 and 60:40 were mixed using a ball milling and the samples with a relative density greater than 97%were prepared by SLM.The results show that the intricate temperature gradients and surface tension gradients in SLM will produce Marangoni flow,forming a typical molten pool morphology,cellular and strip subgrain structures.And as the proportion of coarse powder increases,the scanning track morphology changes from smooth to undulating;the morphology of the molten pool and subgrain structure are weakened.Meanwhile,the unmelted particles appear on the surface of the SLM sample.On the premise of an introducing appropriate amount of large particle size powder(20%),the SLM samples still have good mechanical properties(662 MPa,47%).展开更多
The research and development of high-level radioactive waste(HLW)repository is a long-term systematic engineering project.Normally,it involves such stages as foundation study,site selection and assessment,underground ...The research and development of high-level radioactive waste(HLW)repository is a long-term systematic engineering project.Normally,it involves such stages as foundation study,site selection and assessment,underground research laboratory testing, and the design,construction,operation,and close of the repository.The key issue in repository design展开更多
Interactions between the dissolved mineral species and other mineralsurface were investigated using solution chemistry calculation, -potential measurement, AES analysis and flotation tests. It has been indicated that ...Interactions between the dissolved mineral species and other mineralsurface were investigated using solution chemistry calculation, -potential measurement, AES analysis and flotation tests. It has been indicated that there canbe precipitation of scheelite over fluorite in scheelite supernatant at PH> 4.The conversion of fluorite into scheellte was detected by AES. Fluorite in the supernatant of scheelite exhibits nearly identical electrokinetic property andflotation behavior with those of scheelite. The selective flotatlon separation of fluorite from scheelite or vice vasa may be achieved by using selective amphoteric collector for fluorite at PH<4 to avoid surface conversion.展开更多
The results of pot and pond trials are as follows.On equal amount of nitrogen(N)applied,the wheat nitrate reduction activity(NRA)and photosynthesis strength and other phy-siological properties are stronger and yields ...The results of pot and pond trials are as follows.On equal amount of nitrogen(N)applied,the wheat nitrate reduction activity(NRA)and photosynthesis strength and other phy-siological properties are stronger and yields are higher at normal soil moisture than those atdrought.At the same soil moisture,in a certain range of N applied,these properties of wheat in-crease with the increasing of N applied,but they descend when the amount of N applied exceedsa certain range.展开更多
gradient aluminum alloy was prepared by semi-continuous casting using double-stream-pouring technique. The microstructures of the as-cast, pressed and heat-treated alloys were analyzed by scanning electron microscope ...gradient aluminum alloy was prepared by semi-continuous casting using double-stream-pouring technique. The microstructures of the as-cast, pressed and heat-treated alloys were analyzed by scanning electron microscope and transmission electron microscope. And the mechanical properties of the alloy in pressed and heat-treated states were studied. The results show that the ingots with diameter of 65 mm and external thickness （about） 5.5 mm are obtained when the temperatures of the melt in the internal and external ladles are 1 023 and 1 003 K, respectively, and the nozzle diameter is 2.0 mm. The microstructures of the as-cast alloy consist of α（Al）+（θ（CuAl2））+S（Al2CuMg） in the internal region and （α（Al）+MnAl6） in the external region. The phases found in the internal and external layers coexist in the transition zone. The transition layer is maintained after plastic deformation and heat treatment of the alloy. The tensile strength, yield strength and elongation of the alloy are 300 MPa, 132 MPa and 16.0%, respectively, after T6 treatment. The tensile and yield strength are increased by 150.0% and （94.1%,） respectively, compared with that of 3003 aluminum alloy. The maximum hardness in the internal region of 2024/3003 gradient aluminum alloy can be increased from HRF 55 in the pressed state to HRF 70 in the heat-treated state.展开更多
Based on the working principles of particle bed comminution, particles produced by high-pressure grinding rolls （HPGR） have surface properties different from particles produced by other grinding patterns, which exer...Based on the working principles of particle bed comminution, particles produced by high-pressure grinding rolls （HPGR） have surface properties different from particles produced by other grinding patterns, which exert great influence on mineral flotation. Flotation performances of calcite particles under different grinding patterns involving the use of HPGR, a jaw crusher, a dry ball mill, a wet ball mill, and a wet rod mill were studied using single mineral flotation tests. The surface properties of the particles under different grinding patterns were characterized to determine the flotation performance variation in terms of specific surface area, particle size distribution, AFM, XPS, and zeta potential. The results show that particles ground by HPGR exhibited improved flotation performance within the lower range of grinding fineness in both NaOL and dodecyl amine flotation systems compared to the particles prepared using other grinding patterns. Specific surface area, particle size distribution, surface roughness, Fe（III） contamination, binding energy, and zeta potential are greatly influenced by grinding patterns, which is the main cause of the flotation performance variation.展开更多
Pre-heat treatment is a vital step before cold ring rolling and it has significant effect on the microstructure and mechanical properties of rolled rings.The 100Cr6 steel rings were subjected to pre-heat treatment and...Pre-heat treatment is a vital step before cold ring rolling and it has significant effect on the microstructure and mechanical properties of rolled rings.The 100Cr6 steel rings were subjected to pre-heat treatment and subsequent cold rolling process.Scanning electron microscopy and tensile tests were applied to investigate microstructure characteristic and mechanical property variations of 100Cr6 steel rings undergoing different pre-heat treatings.The results indicate that the average diameter of carbide particles,the tensile strength and hardness increase,while the elongation decreases with the decrease of cooling rate.The cooling rate has minor effect on the yield strength of sample.After cold ring rolling,the ferrite matrix shows a clear direction along the rolling direction.The distribution of cementite is more homogeneous and the cementite particles are finer.Meanwhile,the hardness of the rolled ring is higher than that before rolling.展开更多
Calcined ginger nuts admixed by fly ash and quartz sand(CGN-(F+S))has been validated to be basically compatible to earthen sites as an anchor grout.Accelerated ageing tests including water stability test,temperature a...Calcined ginger nuts admixed by fly ash and quartz sand(CGN-(F+S))has been validated to be basically compatible to earthen sites as an anchor grout.Accelerated ageing tests including water stability test,temperature and humidity cycling test,soundness test and alkali resistance test are conducted with the objective to further research the property changes of CGN-(F+S)grout.Density,surface hardness,water penetration capacity,water permeability capacity,soluble salt,scanning electron microscopy(SEM)images and energy dispersive spectrometry(EDS)spectrum of these samples have been tested after accelerated ageing tests.The results show that densities of samples decrease,surface hardness,water penetration capacity and water permeability capacity of samples increase generally.Besides,soluble salt analysis,SEM and EDS results well corroborate the changes.Based on the results it can be concluded that property changes are most serious after temperature and humidity cycling test,followed by water stability,soundness and alkali resistance test in sequence.But in general,CGN-(F+S)still has good durability.展开更多
The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the ...The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the alterable mechanical property under hydrostatic stress and radially inner surface pressure of the lining.The alterable mechanical properties of the surrounding rock and the lining are embodied by the changing of their elasticity modulus with service time and radial direction of the tunnel,respectively.The proposed mechanical model is successfully validated by comparison with the existing theoretical models and the numerical simulation,respectively.The influences of the main parameters of the proposed mechanical model,such as the radial power-law indexes and the time-varying coefficients of the surrounding rock and the lining,as well as the radially inner surface pressure of the lining,on the interface displacement and pressure between surrounding rock and lining are investigated.The research results can provide some valuable references for timely diagnosis and correct evaluation of the long-term behaviours of a tunnel in service.展开更多
A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, ...A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, one cooled by water, the other cooled by oil–water emulsion. The results of wet/dry cyclic accelerated corrosion test showed that the anti-rust property of rebar cooled by oil–water emulsion was better than that by water obviously. The results of OM, SEM and EPMA analysis indicated that these two scales contained three layers: an outer Fe_3O_4 layer, an intermediate Fe O layer with island-shaped pro-eutectoid Fe_3O_4, an inner eutectoid Fe_3O_4 layer. For the water cooled rebar, all three layers of oxide scale were relatively thin. Moreover, the scale had plenty of defects such as porosity, and crack. However, for the oil–water emulsion cooled rebar, all three layers of oxide scale were relatively thick and compact, which played an important role in protecting the rebar from atmospheric rust.展开更多
文摘Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.
文摘A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,elemental analysis,IR,and magnetic properties.X-ray diffraction analysis shows that the complex exists as mononuclear molecules and Co(Ⅱ)ion is four-coordinated with two radicals and two PNB-ligands.The magnetic susceptibility study indicates the complex exhibits weak ferromagnetic interactions between cobalt(Ⅱ)and im4-py radical.The magnetic property is explained by the magnetic and structure exchange mechanism.CCDC:976028.
基金Supported by The Featured Innovation Projects of the General University of Guangdong Province(2023KTSCX096)The Special Projects in Key Areas of Guangdong Province(ZDZX1088)Research Team Project of Guangdong University of Education(2024KYCXTD018)。
文摘This paper explores the recovery of block sparse signals in frame-based settings using the l_(2)/l_(q)-synthesis technique(0<q≤1).We propose a new null space property,referred to as block D-NSP_(q),which is based on the dictionary D.We establish that matrices adhering to the block D-NSP_(q)condition are both necessary and sufficient for the exact recovery of block sparse signals via l_(2)/l_(q)-synthesis.Additionally,this condition is essential for the stable recovery of signals that are block-compressible with respect to D.This D-NSP_(q)property is identified as the first complete condition for successful signal recovery using l_(2)/l_(q)-synthesis.Furthermore,we assess the theoretical efficacy of the l2/lq-synthesis method under conditions of measurement noise.
文摘This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications.
基金National Key R&D Program of China(2023YFE3812005)International Partnership Program of Chinese Academy of Sciences(121631KYSB20200039)+1 种基金National Center for Research and Development(WPC2/1/SCAPOL/2021)Chinese Academy of Sciences President’s International Fellowship Initiative(2024VEA0005,2024VEA0014)。
文摘Sc_(2)O_(3),as a host for solid-state laser gain materials,has advantage of high thermal conductivity and easy matching with activating ions,which is promising in high-power laser applications.Currently,Yb-doped Sc_(2)O_(3) ceramics have been fabricated at very high sintering temperatures,but their optical quality and sintering process still need further improvement.In this work,5%Yb:Sc_(2)O_(3)(in mass)nano-powders were obtained by co-precipitation,and then transparent ceramics were fabricated by vacuum pre-sintering and hot isostatic pressing(HIP)post-treatment.The cubic Yb:Sc_(2)O_(3) nano-powders with good dispersity and an average crystallite of 29 nm were obtained.Influence of pre-sintering temperatures(1500-1700℃)on densification process,microstructure changes,and optical transmittance of Yb:Sc_(2)O_(3) ceramics was detected.Experimental data revealed that all samples have a uniform microstructure,while the average grain sizes increase with the increase of the sintering temperatures.Impressively,the optimum in-line transmittance of Yb:Sc_(2)O_(3) ceramics,pre-sintered at 1550℃after HIP post-treatment,reaches 78.1%(theoretical value of 80%)at 1100 nm.Spectroscopic properties of the Yb:Sc_(2)O_(3) ceramics reveal that the minimum population inversion parameterβ2 and the luminescence decay time of 5%Yb:Sc_(2)O_(3) ceramics are 0.041 and 0.49 ms,respectively,which demonstrate that the optical quality of the Yb:Sc_(2)O_(3) has been improved.Meanwhile,their best vacuum sintering temperature can be controlled down to a lower temperature(1550℃).In conclusion,Yb:Sc_(2)O_(3) nano-powders are successfully synthesized by co-precipitation method,and good optical quality transparent ceramics are fabricated by vacuum pre-sintering at 1550℃and HIP post-treatment.
基金Projects(41330641,41272311,41202192)supported by the National Natural Science Foundation of ChinaProject(BK2010060)supported by the Key Project of Natural Science Foundation of Jiangsu Province,China
文摘Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments.Oil contents(mass fraction) of 4%,8%,12%,16% and 20% were selected to represent different contamination degrees,and the soil specimens were manually prepared through mixing and static compaction method.Initial water content and dry density of the test kaolin clay were controlled at 10% and 1.58 g/cm^3,respectively.Test results indicate that since part of the diesel oil will be released from soil by evaporation,the real water content should be derived through calibration of the quasi water content obtained by traditional test method.As contamination degree of the kaolin clay increases,both liquid limit and plastic limit decrease,but there's only a slight increase for plasticity index.Swelling pressure of contaminated kaolin clay under confined condition will be lowered when oil-content gets higher.Unconfined compressive strength(UCS) of the oil-contaminated kaolin clay is influenced by not only oil content but also curing period.Increase of contamination degree will continually lower UCS of the kaolin clay specimen.In addition,electrical resistivity of the contaminated kaolin clay with given water content decreases with the increase of oil content.However,soil resistivity is in good relationship with oil content and UCS.Finally,oil content of 8% is found to be a critical value for engineering property of kaolin clay to transit from water-dominated towards oil-dominated characteristics.
文摘Topological method is applied firstly to calculate the group connectivity indexes of some flotation reagents for sulfide minerals and oxide minerals. The study reveals that some properties of flotation reagents, such as group electronegativity, energy criterion, solubility product of chemicals and maximum wavelength of ultraviolet absorbency, have linear correlation with the first order group connectivity index (GCI) of polar group, and the related coefficients are all larger than 0.900. The GCI can be used to characterize the structure of groups, and is a sort of new effective structural parameter to study the quantitative structure activity relationship of flotation reagents.
文摘The Poyang lake is currently the largest freshwater lake in China. Hydrologic properties of this lake, including precipitation, runoff, flood, sediment transport and so on have been analyzed on basis of large amount of measurements. Variation of these properties within a year and among years and the regional distribution are explored. The encounter probability of the outflow from Poyang Lake with that from Changjiang River is computed and the detention volume of Poyang Lake is analyzed. In accordance with water balance theory, the detention storage volume of Poyang Lake and Changjiang River corresponding to the annual maximum 60-day flood volumes in 9 typical heavy flood years of 1968, 1969, 1973, 1980, 1983, 1996 and 1998 have been calculated. The detention storage capacity of both the Lake and the River ranges from 5.6 billion to 16.5 billion m\+3, 11.5 billion m\+3 at average. Among which, the detention storage capacity of Poyang Lake is 9.5 billion m\+3, accounting for 82.6%. Poyang Lake has played a very important role in detaining floods from the five rivers of the Lake system as well as floods on the river section from Changjiang to Bali. There would have more frequent and more serious flooding on the middle and lower Changjiang River, especially in the region around Hukou if there were no Poyang Lake to detain and store the floodwater.
基金Projects(51671152,51304153,51504191,51874225)supported by the National Natural Science Foundation of ChinaProject(14JK512)supported by the Natural Science Foundation of Shaanxi Educational Committee,China+1 种基金Project(18JC019)supported by Shaanxi Provincial Department of Education Industrialization Project,ChinaProject(14JK1512)supported by Shaanxi Provincial Department of Education Natural Science Special Project,China
文摘Selective laser melting(SLM)technology is the prevailing method of manufacturing components with complex geometries.However,the cost of the additive manufacturing(AM)fine powder is relatively high,which significantly limits the development of the SLM.In this study,the 316L fine powder and coarse powder with a mass ratio of 80:20,70:30 and 60:40 were mixed using a ball milling and the samples with a relative density greater than 97%were prepared by SLM.The results show that the intricate temperature gradients and surface tension gradients in SLM will produce Marangoni flow,forming a typical molten pool morphology,cellular and strip subgrain structures.And as the proportion of coarse powder increases,the scanning track morphology changes from smooth to undulating;the morphology of the molten pool and subgrain structure are weakened.Meanwhile,the unmelted particles appear on the surface of the SLM sample.On the premise of an introducing appropriate amount of large particle size powder(20%),the SLM samples still have good mechanical properties(662 MPa,47%).
文摘The research and development of high-level radioactive waste(HLW)repository is a long-term systematic engineering project.Normally,it involves such stages as foundation study,site selection and assessment,underground research laboratory testing, and the design,construction,operation,and close of the repository.The key issue in repository design
文摘Interactions between the dissolved mineral species and other mineralsurface were investigated using solution chemistry calculation, -potential measurement, AES analysis and flotation tests. It has been indicated that there canbe precipitation of scheelite over fluorite in scheelite supernatant at PH> 4.The conversion of fluorite into scheellte was detected by AES. Fluorite in the supernatant of scheelite exhibits nearly identical electrokinetic property andflotation behavior with those of scheelite. The selective flotatlon separation of fluorite from scheelite or vice vasa may be achieved by using selective amphoteric collector for fluorite at PH<4 to avoid surface conversion.
文摘The results of pot and pond trials are as follows.On equal amount of nitrogen(N)applied,the wheat nitrate reduction activity(NRA)and photosynthesis strength and other phy-siological properties are stronger and yields are higher at normal soil moisture than those atdrought.At the same soil moisture,in a certain range of N applied,these properties of wheat in-crease with the increasing of N applied,but they descend when the amount of N applied exceedsa certain range.
文摘gradient aluminum alloy was prepared by semi-continuous casting using double-stream-pouring technique. The microstructures of the as-cast, pressed and heat-treated alloys were analyzed by scanning electron microscope and transmission electron microscope. And the mechanical properties of the alloy in pressed and heat-treated states were studied. The results show that the ingots with diameter of 65 mm and external thickness （about） 5.5 mm are obtained when the temperatures of the melt in the internal and external ladles are 1 023 and 1 003 K, respectively, and the nozzle diameter is 2.0 mm. The microstructures of the as-cast alloy consist of α（Al）+（θ（CuAl2））+S（Al2CuMg） in the internal region and （α（Al）+MnAl6） in the external region. The phases found in the internal and external layers coexist in the transition zone. The transition layer is maintained after plastic deformation and heat treatment of the alloy. The tensile strength, yield strength and elongation of the alloy are 300 MPa, 132 MPa and 16.0%, respectively, after T6 treatment. The tensile and yield strength are increased by 150.0% and （94.1%,） respectively, compared with that of 3003 aluminum alloy. The maximum hardness in the internal region of 2024/3003 gradient aluminum alloy can be increased from HRF 55 in the pressed state to HRF 70 in the heat-treated state.
基金Project(2013EG132088)supported by Special Program for Research Institutes of the Ministry of Science and Technology,ChinaProject(12010402c187)supported by Key Science and Technology Program of Anhui Province,ChinaProject(GJKJ-14-89)supported by Science and Technology Program of Nanchang Institute of Science and Technology,China
文摘Based on the working principles of particle bed comminution, particles produced by high-pressure grinding rolls （HPGR） have surface properties different from particles produced by other grinding patterns, which exert great influence on mineral flotation. Flotation performances of calcite particles under different grinding patterns involving the use of HPGR, a jaw crusher, a dry ball mill, a wet ball mill, and a wet rod mill were studied using single mineral flotation tests. The surface properties of the particles under different grinding patterns were characterized to determine the flotation performance variation in terms of specific surface area, particle size distribution, AFM, XPS, and zeta potential. The results show that particles ground by HPGR exhibited improved flotation performance within the lower range of grinding fineness in both NaOL and dodecyl amine flotation systems compared to the particles prepared using other grinding patterns. Specific surface area, particle size distribution, surface roughness, Fe（III） contamination, binding energy, and zeta potential are greatly influenced by grinding patterns, which is the main cause of the flotation performance variation.
基金Project(2011CB706605)supported by the National Basic Research Program of ChinaProject(2011CDA12)supported by the Innovative Research Groups of the Natural Science Foundation of Hubei Province,ChinaProjects(2012-Ia-017,2013-IV-014)supported by the Fundamental Research Funds for the Central Universities,China
文摘Pre-heat treatment is a vital step before cold ring rolling and it has significant effect on the microstructure and mechanical properties of rolled rings.The 100Cr6 steel rings were subjected to pre-heat treatment and subsequent cold rolling process.Scanning electron microscopy and tensile tests were applied to investigate microstructure characteristic and mechanical property variations of 100Cr6 steel rings undergoing different pre-heat treatings.The results indicate that the average diameter of carbide particles,the tensile strength and hardness increase,while the elongation decreases with the decrease of cooling rate.The cooling rate has minor effect on the yield strength of sample.After cold ring rolling,the ferrite matrix shows a clear direction along the rolling direction.The distribution of cementite is more homogeneous and the cementite particles are finer.Meanwhile,the hardness of the rolled ring is higher than that before rolling.
基金Project(51578272)supported by the National Natural Science Foundation of China
文摘Calcined ginger nuts admixed by fly ash and quartz sand(CGN-(F+S))has been validated to be basically compatible to earthen sites as an anchor grout.Accelerated ageing tests including water stability test,temperature and humidity cycling test,soundness test and alkali resistance test are conducted with the objective to further research the property changes of CGN-(F+S)grout.Density,surface hardness,water penetration capacity,water permeability capacity,soluble salt,scanning electron microscopy(SEM)images and energy dispersive spectrometry(EDS)spectrum of these samples have been tested after accelerated ageing tests.The results show that densities of samples decrease,surface hardness,water penetration capacity and water permeability capacity of samples increase generally.Besides,soluble salt analysis,SEM and EDS results well corroborate the changes.Based on the results it can be concluded that property changes are most serious after temperature and humidity cycling test,followed by water stability,soundness and alkali resistance test in sequence.But in general,CGN-(F+S)still has good durability.
基金Project(U1934210) supported by the Key Project of High-speed Rail Joint Fund of National Natural Science Foundation of ChinaProject(8202037) supported by the Natural Science Foundation of Beijing,China。
文摘The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the alterable mechanical property under hydrostatic stress and radially inner surface pressure of the lining.The alterable mechanical properties of the surrounding rock and the lining are embodied by the changing of their elasticity modulus with service time and radial direction of the tunnel,respectively.The proposed mechanical model is successfully validated by comparison with the existing theoretical models and the numerical simulation,respectively.The influences of the main parameters of the proposed mechanical model,such as the radial power-law indexes and the time-varying coefficients of the surrounding rock and the lining,as well as the radially inner surface pressure of the lining,on the interface displacement and pressure between surrounding rock and lining are investigated.The research results can provide some valuable references for timely diagnosis and correct evaluation of the long-term behaviours of a tunnel in service.
基金Project(51374069) supported by the National Natural Science Foundation of China
文摘A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, one cooled by water, the other cooled by oil–water emulsion. The results of wet/dry cyclic accelerated corrosion test showed that the anti-rust property of rebar cooled by oil–water emulsion was better than that by water obviously. The results of OM, SEM and EPMA analysis indicated that these two scales contained three layers: an outer Fe_3O_4 layer, an intermediate Fe O layer with island-shaped pro-eutectoid Fe_3O_4, an inner eutectoid Fe_3O_4 layer. For the water cooled rebar, all three layers of oxide scale were relatively thin. Moreover, the scale had plenty of defects such as porosity, and crack. However, for the oil–water emulsion cooled rebar, all three layers of oxide scale were relatively thick and compact, which played an important role in protecting the rebar from atmospheric rust.
