The infrared absorption spectra of different superconducting phase of high Tc super conductor Bi-Sb-Sr-Ca-Cu-O have been measured . The results show that only in the range of 400cm-1 -700cm-1,there is a group of peaks...The infrared absorption spectra of different superconducting phase of high Tc super conductor Bi-Sb-Sr-Ca-Cu-O have been measured . The results show that only in the range of 400cm-1 -700cm-1,there is a group of peaks which changes with different superconducting phases.According to group theory and infrared spectra of CuO, this group of peaks could be assigned to be the [CuO6]octahedron, the [CuO5] pyramid and the [CuO4]plane quadrilateral,but not CU-O plane or CU-O chain. Furthermore, the quasi-three dimensional Cu-O layers consisting of [CuO5] pyramids and proper coupling between them are essential factor for high Tc. It seems that the weaker compling of layers, the higher Tc展开更多
Silver nanoparticle thin films with different average particle diameters are grown on silicon substrates. Boron nitride thin films are then deposited on the silver nanoparticle interlayers by radio frequency （RF） ma...Silver nanoparticle thin films with different average particle diameters are grown on silicon substrates. Boron nitride thin films are then deposited on the silver nanoparticle interlayers by radio frequency （RF） magnetron sputtering. The boron nitride thin films are characterized by Fourier transform infrared spectra. The average particle diameters of silver nanoparticle thin films are 126.6, 78.4, and 178.8 nm. The results show that the sizes of the silver nanoparticles have effects on the intensities of infrared spectra of boron nitride thin films. An enhanced infrared absorption is detected for boron nitride thin film grown on silver nanoparticle thin film. This result is helpful to study the growth mechanism of boron nitride thin film.展开更多
Theoretical and experimental investigations on the dependence of the intensity of infrared （IR） absorption of poly- crystalline cubic boron nitride thin films under the residual compressive stress conditions have be...Theoretical and experimental investigations on the dependence of the intensity of infrared （IR） absorption of poly- crystalline cubic boron nitride thin films under the residual compressive stress conditions have been performed. Our results indicate that the intensity of the IR absorption is proportional to the total degree of freedom of all the ions in the ordered regions. The reduction of interstitial Ar atom concentration, which causes the increase in the ordered regions of cubic boron nitride （cBN） crystallites, could be one cause for the increase in the intensity of IR absorption after residual compressive stress relaxation. Theoretical derivation is in good agreement with the experimental results concerning the IR absorption intensity and the Ar interstitial atom concentration in cubic boron nitride films measured by energy dispersion X-ray spec- troscopy. Our results also suggest that the interstitial Ar is the origin of residual compressive stress accumulation in plasma enhanced cBN film deposition.展开更多
Advanced textiles for thermal management give rise to many functional applications and unveil a new frontier for the study of human thermal comfort.Manipulating the coated quasi-particles between the composite compone...Advanced textiles for thermal management give rise to many functional applications and unveil a new frontier for the study of human thermal comfort.Manipulating the coated quasi-particles between the composite components offers a platform to study the advanced thermoregulatory textiles.Here,we propose that coating the hyperbolic polariton can be an effective tool to tune infrared absorption in hexagonal boron nitride-coated silk composite.Remarkably,we achieve significant tuning of the infrared absorption efficiency of silk fibrils through the designed hexagonal boron nitride film.The underlying mechanism is related to resonance coupling between hyperbolic phonon polaritons.We find a notably high infrared absorption efficiency,nearly 3 orders larger than that without hBN coating,which can be achieved in our composite system.Our results indicate the promising future of advanced polariton-coated textiles and open a pathway to guide the artificial-intelligence design of advanced functional textiles.展开更多
An enhancement of mid-wavelength infrared absorbance is achieved via a cost-effectively chemical method to bend the flakes by grafting two types of alkane octane(C_(8)H_(18))and dodecane(C_(12)H_(26))onto the surface ...An enhancement of mid-wavelength infrared absorbance is achieved via a cost-effectively chemical method to bend the flakes by grafting two types of alkane octane(C_(8)H_(18))and dodecane(C_(12)H_(26))onto the surface terminals respectively.The chain-length of alkane exceeds the bond-length of surface functionalities T(x=O,-OH,-F)so as to introduce intra-flake and inter-flake strains into Ti_(3)C_(2)T_(x)MXene.The electronic microscopy(TEM/AFM)shows obvious edge-fold and tensile/compressive deformation of flake.The alkane termination increases the intrinsic absorbance of Ti_(3)C_(2)T_(x)MXene from no more than 50%up to more than 99%in the mid-wavelength in⁃frared region from 2.5μm to 4.5μm.Such an absorption enhancement attributes to the reduce of infrared reflec⁃tance of Ti_(3)C_(2)T_(x)MXene.The C-H bond skeleton vibration covers the aforementioned region and partially reduces the surface reflectance.Meanwhile,the flake deformation owing to edge-fold and tensile/compression increases the specific surface area so as to increase the absorption as well.These results have applicable value in the area of mid-infrared camouflage.展开更多
Plasmonic nanoantennas provide unique opportunities for precise control of light–matter coupling in surface-enhanced infrared absorption(SEIRA)spectroscopy,but most of the resonant systems realized so far suffer from...Plasmonic nanoantennas provide unique opportunities for precise control of light–matter coupling in surface-enhanced infrared absorption(SEIRA)spectroscopy,but most of the resonant systems realized so far suffer from the obstacles of low sensitivity,narrow bandwidth,and asymmetric Fano resonance perturbations.Here,we demonstrated an overcoupled resonator with a high plasmon-molecule coupling coefficient(μ)(OC-Hμresonator)by precisely controlling the radiation loss channel,the resonator-oscillator coupling channel,and the frequency detuning channel.We observed a strong dependence of the sensing performance on the coupling state,and demonstrated that OC-Hμresonator has excellent sensing properties of ultra-sensitive(7.25%nm^(−1)),ultra-broadband(3–10μm),and immune asymmetric Fano lineshapes.These characteristics represent a breakthrough in SEIRA technology and lay the foundation for specific recognition of biomolecules,trace detection,and protein secondary structure analysis using a single array(array size is 100×100μm^(2)).In addition,with the assistance of machine learning,mixture classification,concentration prediction and spectral reconstruction were achieved with the highest accuracy of 100%.Finally,we demonstrated the potential of OC-Hμresonator for SARS-CoV-2 detection.These findings will promote the wider application of SEIRA technology,while providing new ideas for other enhanced spectroscopy technologies,quantum photonics and studying light–matter interactions.展开更多
Light absorption and radiation are fundamental processes in optical science and engineering.Materials with perfect absorption properties play an important role in numerous optical applications.Following the meteoric r...Light absorption and radiation are fundamental processes in optical science and engineering.Materials with perfect absorption properties play an important role in numerous optical applications.Following the meteoric rise of MoS_(2)material,global opportunities and challenges coexist due to its extremely weak light-matter interaction capability beyond its energy band.In this work,we designed a kind of sandwich resonance structure and investigated MoS_(2)as a perfect absorber in the infrared spectrum that should be transparent according to the optical band theory.The infrared absorption properties of W or Au/MoS_(2)/Au models at 800 nm-2400 nm were systematic simulated.By optimizing the structural parameters,the resonant wavelength of perfect absorption can be modulated from 830 nm to 1700 nm with angle insensitivity and polar independence.Moreover,we discovered that the bandwidth of absorption exceeding 50%of the W-top model reaches500 nm,while that of the Au-top model is less than 100 nm,indicating that the top metal material has a great influence on the resonance absorption spectrum.Our work provides a practical route for enhancing and manipulating the light-matter interactions of low-dimensional materials beyond their own band gaps,which will be critical in the future design and implementation of optoelectronic devices and systems.展开更多
Diamond-like carbon (DLC) films are deposited on quartz substrate using pure CH4 in the surface wave plasma equipment. A direct current negative bias up to -90 V is applied to the substrate to investigate the bias eff...Diamond-like carbon (DLC) films are deposited on quartz substrate using pure CH4 in the surface wave plasma equipment. A direct current negative bias up to -90 V is applied to the substrate to investigate the bias effect on the film characteristics. Deposited films are characterized by Raman spectroscopy, infrared (IR) and ultraviolet-visible absorption techniques. There are two broad Raman peaks around 1340 cm-1 and 1600 cm-1 and the first one has a greater sp3 component with an increased bias. Infrared spectroscopy has three sp3 C-H modes at 2852 cm-1, 2926 cm-1 and 2962 cm-1, respectively and also shows an intensity increase with the negative bias. Optical band gap is calculated from the ultraviolet-visible absorption spectroscopy and the increased values with negative bias and deposition time are obtained. After a thermal anneal at about 500℃ for an hour to the film deposited under the bias of-90 V, we get an almost unchanged Raman spectrum and a peak intensity-reduced IR signal, which indicates a reduced H-content in the film. Meanwhile the optical band gap changed from 0.85 eV to 1.5 eV.展开更多
The absorption of one to six ammonia molecules by the （H2O）50 cluster is studied by the molecular dynamics method under near-atmospheric conditions. The capture of NH 3 molecules by a water cluster produces an incre...The absorption of one to six ammonia molecules by the （H2O）50 cluster is studied by the molecular dynamics method under near-atmospheric conditions. The capture of NH 3 molecules by a water cluster produces an increase in the integrated intensity of IR absorbance, substantially decreases emission power in the frequency range of 0≤ω≤3500cm-1,and transforms a continuous reflectance spectrum into a banded one. Adsorption of ammonia molecules by water clusters greatly diminishes the number of electrons that are active with respect to electromagnetic radiation. The present results are also compared with the experimental findings wherever available.展开更多
Infrared absorption local vibration mode（LVM） spectroscopy is used to study hydrogen related defects in n-type ZnO single crystal grown by a closed chemical vapor transport（CVT） method under Zn-rich growth conditi...Infrared absorption local vibration mode（LVM） spectroscopy is used to study hydrogen related defects in n-type ZnO single crystal grown by a closed chemical vapor transport（CVT） method under Zn-rich growth conditions, in which carbon is used as a transport agent. Two C-H complex related absorption peaks at 2850 cm-1and 2919 cm-1 are detected in the sample. The formation of the C-H complex implies an effect of carbon donor passivation and formation suppression of H donor in ZnO. The influence of the complex defects on the electrical property of the CVT-ZnO is discussed based on Hall measurement results and residual impurity analysis.展开更多
The hydrated-proton structure is critical for understanding the proton transport in water.However,whether the hydrated proton adopts Zundel or Eigen structure in solution has been highly debated in the past several de...The hydrated-proton structure is critical for understanding the proton transport in water.However,whether the hydrated proton adopts Zundel or Eigen structure in solution has been highly debated in the past several decades.Current experimental techniques cannot directly visualize the dynamic structures in situ,while the available theoretical results on the infrared(IR)spectrum derived from current configurational models cannot fully reproduce the experimental results and thus are unable to provide their precise structures.In this work,using H5O2^+ as a model,we performed first-principles calculations to demonstrate that both the structural feature and the IR frequency of proton stretching,characteristics to discern the Zundel or Eigen structures,evolve discontinuously with the change of the O–O distance.A simple formula was introduced to discriminate the Zundel,Zundel-like,and Eigen-like structures.This work arouses new perspectives to understand the proton hydration in water.展开更多
A quantum cascade laser（QCL） based system for simultaneous detection of CO and CO_2 is developed.The QCL can scan over two neighboring CO（2055.40 cm^（-1）） and CO_2（2055.16 cm^（-1）） lines with a single curren...A quantum cascade laser（QCL） based system for simultaneous detection of CO and CO_2 is developed.The QCL can scan over two neighboring CO（2055.40 cm^（-1）） and CO_2（2055.16 cm^（-1）） lines with a single current scan.The wavelength modulation spectroscopy（ f = 20 k Hz） is utilized to enhance the signal-to-noise ratio.A white cell with an effective optical path length of 74 m is used.The calibration of the sensor is performed and minimum detection limits of 1.3 ppb（1 × 10^（-9））for CO and 0.44 ppm（1 × 10^（-6）） for CO_2 are achieved.展开更多
文摘The infrared absorption spectra of different superconducting phase of high Tc super conductor Bi-Sb-Sr-Ca-Cu-O have been measured . The results show that only in the range of 400cm-1 -700cm-1,there is a group of peaks which changes with different superconducting phases.According to group theory and infrared spectra of CuO, this group of peaks could be assigned to be the [CuO6]octahedron, the [CuO5] pyramid and the [CuO4]plane quadrilateral,but not CU-O plane or CU-O chain. Furthermore, the quasi-three dimensional Cu-O layers consisting of [CuO5] pyramids and proper coupling between them are essential factor for high Tc. It seems that the weaker compling of layers, the higher Tc
基金Project supported by the Natural Science Foundation of Beijing,China(Grant No.4072007)the National Natural Science Foundation of China(Grant Nos.60876006 and 60376007)
文摘Silver nanoparticle thin films with different average particle diameters are grown on silicon substrates. Boron nitride thin films are then deposited on the silver nanoparticle interlayers by radio frequency （RF） magnetron sputtering. The boron nitride thin films are characterized by Fourier transform infrared spectra. The average particle diameters of silver nanoparticle thin films are 126.6, 78.4, and 178.8 nm. The results show that the sizes of the silver nanoparticles have effects on the intensities of infrared spectra of boron nitride thin films. An enhanced infrared absorption is detected for boron nitride thin film grown on silver nanoparticle thin film. This result is helpful to study the growth mechanism of boron nitride thin film.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.50772096 and 61176051)
文摘Theoretical and experimental investigations on the dependence of the intensity of infrared （IR） absorption of poly- crystalline cubic boron nitride thin films under the residual compressive stress conditions have been performed. Our results indicate that the intensity of the IR absorption is proportional to the total degree of freedom of all the ions in the ordered regions. The reduction of interstitial Ar atom concentration, which causes the increase in the ordered regions of cubic boron nitride （cBN） crystallites, could be one cause for the increase in the intensity of IR absorption after residual compressive stress relaxation. Theoretical derivation is in good agreement with the experimental results concerning the IR absorption intensity and the Ar interstitial atom concentration in cubic boron nitride films measured by energy dispersion X-ray spec- troscopy. Our results also suggest that the interstitial Ar is the origin of residual compressive stress accumulation in plasma enhanced cBN film deposition.
文摘Advanced textiles for thermal management give rise to many functional applications and unveil a new frontier for the study of human thermal comfort.Manipulating the coated quasi-particles between the composite components offers a platform to study the advanced thermoregulatory textiles.Here,we propose that coating the hyperbolic polariton can be an effective tool to tune infrared absorption in hexagonal boron nitride-coated silk composite.Remarkably,we achieve significant tuning of the infrared absorption efficiency of silk fibrils through the designed hexagonal boron nitride film.The underlying mechanism is related to resonance coupling between hyperbolic phonon polaritons.We find a notably high infrared absorption efficiency,nearly 3 orders larger than that without hBN coating,which can be achieved in our composite system.Our results indicate the promising future of advanced polariton-coated textiles and open a pathway to guide the artificial-intelligence design of advanced functional textiles.
文摘An enhancement of mid-wavelength infrared absorbance is achieved via a cost-effectively chemical method to bend the flakes by grafting two types of alkane octane(C_(8)H_(18))and dodecane(C_(12)H_(26))onto the surface terminals respectively.The chain-length of alkane exceeds the bond-length of surface functionalities T(x=O,-OH,-F)so as to introduce intra-flake and inter-flake strains into Ti_(3)C_(2)T_(x)MXene.The electronic microscopy(TEM/AFM)shows obvious edge-fold and tensile/compressive deformation of flake.The alkane termination increases the intrinsic absorbance of Ti_(3)C_(2)T_(x)MXene from no more than 50%up to more than 99%in the mid-wavelength in⁃frared region from 2.5μm to 4.5μm.Such an absorption enhancement attributes to the reduce of infrared reflec⁃tance of Ti_(3)C_(2)T_(x)MXene.The C-H bond skeleton vibration covers the aforementioned region and partially reduces the surface reflectance.Meanwhile,the flake deformation owing to edge-fold and tensile/compression increases the specific surface area so as to increase the absorption as well.These results have applicable value in the area of mid-infrared camouflage.
基金supported by A*STAR under the“Nanosystems at the Edge”program(Grant No.A18A4b0055)Ministry of Education(MOE)under the research grant of R-263-000-F18-112/A-0009520-01-00+1 种基金National Research Foundation Singapore grant CRP28-2022-0038the Reimagine Re-search Scheme(RRSC)Project(Grant A-0009037-02-00&A0009037-03-00)at National University of Singapore.
文摘Plasmonic nanoantennas provide unique opportunities for precise control of light–matter coupling in surface-enhanced infrared absorption(SEIRA)spectroscopy,but most of the resonant systems realized so far suffer from the obstacles of low sensitivity,narrow bandwidth,and asymmetric Fano resonance perturbations.Here,we demonstrated an overcoupled resonator with a high plasmon-molecule coupling coefficient(μ)(OC-Hμresonator)by precisely controlling the radiation loss channel,the resonator-oscillator coupling channel,and the frequency detuning channel.We observed a strong dependence of the sensing performance on the coupling state,and demonstrated that OC-Hμresonator has excellent sensing properties of ultra-sensitive(7.25%nm^(−1)),ultra-broadband(3–10μm),and immune asymmetric Fano lineshapes.These characteristics represent a breakthrough in SEIRA technology and lay the foundation for specific recognition of biomolecules,trace detection,and protein secondary structure analysis using a single array(array size is 100×100μm^(2)).In addition,with the assistance of machine learning,mixture classification,concentration prediction and spectral reconstruction were achieved with the highest accuracy of 100%.Finally,we demonstrated the potential of OC-Hμresonator for SARS-CoV-2 detection.These findings will promote the wider application of SEIRA technology,while providing new ideas for other enhanced spectroscopy technologies,quantum photonics and studying light–matter interactions.
基金Project supported by the National Natural Science Foundation of China(Grant No.62105169)Natural Science Foundation of Ningbo(Grant No.2021J078)Special fund for Talents Project of Ningbo University(Grant No.432094940)。
文摘Light absorption and radiation are fundamental processes in optical science and engineering.Materials with perfect absorption properties play an important role in numerous optical applications.Following the meteoric rise of MoS_(2)material,global opportunities and challenges coexist due to its extremely weak light-matter interaction capability beyond its energy band.In this work,we designed a kind of sandwich resonance structure and investigated MoS_(2)as a perfect absorber in the infrared spectrum that should be transparent according to the optical band theory.The infrared absorption properties of W or Au/MoS_(2)/Au models at 800 nm-2400 nm were systematic simulated.By optimizing the structural parameters,the resonant wavelength of perfect absorption can be modulated from 830 nm to 1700 nm with angle insensitivity and polar independence.Moreover,we discovered that the bandwidth of absorption exceeding 50%of the W-top model reaches500 nm,while that of the Au-top model is less than 100 nm,indicating that the top metal material has a great influence on the resonance absorption spectrum.Our work provides a practical route for enhancing and manipulating the light-matter interactions of low-dimensional materials beyond their own band gaps,which will be critical in the future design and implementation of optoelectronic devices and systems.
基金The project supported by the National Natural Science Foundation of China (No. 19835030 and 19875053)
文摘Diamond-like carbon (DLC) films are deposited on quartz substrate using pure CH4 in the surface wave plasma equipment. A direct current negative bias up to -90 V is applied to the substrate to investigate the bias effect on the film characteristics. Deposited films are characterized by Raman spectroscopy, infrared (IR) and ultraviolet-visible absorption techniques. There are two broad Raman peaks around 1340 cm-1 and 1600 cm-1 and the first one has a greater sp3 component with an increased bias. Infrared spectroscopy has three sp3 C-H modes at 2852 cm-1, 2926 cm-1 and 2962 cm-1, respectively and also shows an intensity increase with the negative bias. Optical band gap is calculated from the ultraviolet-visible absorption spectroscopy and the increased values with negative bias and deposition time are obtained. After a thermal anneal at about 500℃ for an hour to the film deposited under the bias of-90 V, we get an almost unchanged Raman spectrum and a peak intensity-reduced IR signal, which indicates a reduced H-content in the film. Meanwhile the optical band gap changed from 0.85 eV to 1.5 eV.
文摘The absorption of one to six ammonia molecules by the （H2O）50 cluster is studied by the molecular dynamics method under near-atmospheric conditions. The capture of NH 3 molecules by a water cluster produces an increase in the integrated intensity of IR absorbance, substantially decreases emission power in the frequency range of 0≤ω≤3500cm-1,and transforms a continuous reflectance spectrum into a banded one. Adsorption of ammonia molecules by water clusters greatly diminishes the number of electrons that are active with respect to electromagnetic radiation. The present results are also compared with the experimental findings wherever available.
基金Project supported by the National Natural Science Foundation of China(Grant No.61474104)
文摘Infrared absorption local vibration mode（LVM） spectroscopy is used to study hydrogen related defects in n-type ZnO single crystal grown by a closed chemical vapor transport（CVT） method under Zn-rich growth conditions, in which carbon is used as a transport agent. Two C-H complex related absorption peaks at 2850 cm-1and 2919 cm-1 are detected in the sample. The formation of the C-H complex implies an effect of carbon donor passivation and formation suppression of H donor in ZnO. The influence of the complex defects on the electrical property of the CVT-ZnO is discussed based on Hall measurement results and residual impurity analysis.
基金the National Natural Science Foundation of China(Grant No.21773287).
文摘The hydrated-proton structure is critical for understanding the proton transport in water.However,whether the hydrated proton adopts Zundel or Eigen structure in solution has been highly debated in the past several decades.Current experimental techniques cannot directly visualize the dynamic structures in situ,while the available theoretical results on the infrared(IR)spectrum derived from current configurational models cannot fully reproduce the experimental results and thus are unable to provide their precise structures.In this work,using H5O2^+ as a model,we performed first-principles calculations to demonstrate that both the structural feature and the IR frequency of proton stretching,characteristics to discern the Zundel or Eigen structures,evolve discontinuously with the change of the O–O distance.A simple formula was introduced to discriminate the Zundel,Zundel-like,and Eigen-like structures.This work arouses new perspectives to understand the proton hydration in water.
基金Project supported by the National Key Scientific Instrument and Equipment Development Project of China(Grnat No.2014YQ060537)the National Basic Research Program of China(Grant No.2013CB632803)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA05040102)the National Natural Science Foundation of China(Grant No.41405134)
文摘A quantum cascade laser（QCL） based system for simultaneous detection of CO and CO_2 is developed.The QCL can scan over two neighboring CO（2055.40 cm^（-1）） and CO_2（2055.16 cm^（-1）） lines with a single current scan.The wavelength modulation spectroscopy（ f = 20 k Hz） is utilized to enhance the signal-to-noise ratio.A white cell with an effective optical path length of 74 m is used.The calibration of the sensor is performed and minimum detection limits of 1.3 ppb（1 × 10^（-9））for CO and 0.44 ppm（1 × 10^（-6）） for CO_2 are achieved.
