期刊文献+
共找到33,427篇文章
< 1 2 250 >
每页显示 20 50 100
Risk identification and safety assessment of human-computer interaction in integrated avionics based on STAMP
1
作者 ZHAO Changxiao LI Hao +2 位作者 ZHANG Wei DAI Jun DONG Lei 《Journal of Systems Engineering and Electronics》 SCIE CSCD 2024年第3期689-706,共18页
To solve the problem of risk identification and quantitative assessment for human-computer interaction(HCI)in complex avionics systems,an HCI safety analysis framework based on system-theoretical process analysis(STPA... To solve the problem of risk identification and quantitative assessment for human-computer interaction(HCI)in complex avionics systems,an HCI safety analysis framework based on system-theoretical process analysis(STPA)and cognitive reliability and error analysis method(CREAM)is proposed.STPACREAM can identify unsafe control actions and find the causal path during the interaction of avionics systems and pilot with the help of formal verification tools automatically.The common performance conditions(CPC)of avionics systems in the aviation environment is established and a quantitative analysis of human failure is carried out.Taking the head-up display(HUD)system interaction process as an example,a case analysis is carried out,the layered safety control structure and formal model of the HUD interaction process are established.For the interactive behavior“Pilots approaching with HUD”,four unsafe control actions and35 causal scenarios are identified and the impact of common performance conditions at different levels on the pilot decision model are analyzed.The results show that HUD's HCI level gradually improves as the scores of CPC increase,and the quality of crew member cooperation and time sufficiency of the task is the key to its HCI.Through case analysis,it is shown that STPACREAM can quantitatively assess the hazards in HCI and identify the key factors that impact safety. 展开更多
关键词 AVIONICS human-computer interaction(HCI) safety assessment system-theoretic accident model and process human reliability analysis
在线阅读 下载PDF
Design Method for Optimizing the Interactive Interface of Live Broadcasting Platform for the Elderly Users 被引量:1
2
作者 WEI Bi-ze FAN Wei DUAN Ying-ke 《印刷与数字媒体技术研究》 CAS 北大核心 2024年第4期167-178,共12页
In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interact... In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interaction design mode used is still mainly based on the interaction mode for young groups,and is not designed for elderly users.Therefore,a design method for optimizing the interaction interface of live broadcasting platform for elderly users was proposed in this study.Firstly,the case study method and Delphi expert survey method were used to determine the design needs of elderly users and the design mode was analysed.Secondly,the orthogonal design principle was used to design a test sample of the interactive interface of live broadcasting platform applicable for the elderly users,and then a user evaluation system was established to calculate the weights of the design elements using hierarchical analysis,and then the predictive relationship between the design mode of the interactive interface of live broadcasting platform and the elderly users was established by Quantitative Theory I.Finally,Genetic Algorithm was applied to generate the optimized design scheme.The results showed that the design method based on the Genetic Algorithm and the combination of Quantitative Theory can scientifically and effectively optimize the design of the interactive interface of the live broadcasting platform for the elderly users,and improve the experience of the elderly users. 展开更多
关键词 Live broadcasting platform interaction design Elderly users Genetic Algorithm Quantitative Theory I
在线阅读 下载PDF
Strong electronic metal-support interactions for enhanced hydroformylation activity and stability over Rh single-atom catalysts through phosphorus doping
3
作者 Boyang Fu Ping Ma +11 位作者 Xiaoyang Ding Kaifu Cai Limin Sun Yujin Zhu Qiwei Yin Yihao Sun Tianle Liu Yuzhen Li Yuxing Xu Jian Gu Haowen Ma Junling Lu 《中国科学技术大学学报》 北大核心 2025年第3期2-10,1,I0001,共11页
By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts d... By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts developed thus far still suffer from the issues of much lower activity and metal leaching,which severely hinder their practical application.Here,we demonstrate that incorporating phosphorus(P)atoms into graphitic carbon nitride(PCN)supports facilitates charge transfer from Rh to the PCN support,thus largely enhancing electronic metal-support interactions(EMSIs).In the styrene hydroformylation reaction,the activity of Rh_(1)/PCN single-atom catalysts(SACs)with varying P contents exhibited a volcano-shaped relationship with P doping,where the Rh_(1)/PCN SAC with optimal P doping showed exceptional activity,approximately 5.8-and 3.3-fold greater than that of the Rh_(1)/g-C_(3)N_(4)SAC without P doping and the industrial homogeneous catalyst HRh(CO)(PPh_(3))_(3),respectively.In addition,the optimal Rh_(1)/PCN SAC catalyst also demonstrated largely enhanced multicycle stability without any visible metal aggregation owing to the increased EMSIs,which sharply differed from the severe metal aggregation of large nanoparticles on the Rh_(1)/g-C_(3)N_(4)SAC.Mechan-istic studies revealed that the enhanced catalytic performance could be attributed to electron-deficient Rh species,which reduced CO adsorption while simultaneously promoting alkene adsorption through increased EMSIs.These findings suggest that tuning EMSIs is an effective way to achieve SACs with high activity and durability. 展开更多
关键词 heterogeneous hydroformylation Rh single-atom catalysts electronic metal-support interactions phosphorus doping
在线阅读 下载PDF
Numerical Modeling of Ship-Ice-Water Interaction for Freerunning Ships in Pack Ice
4
作者 ZOU Ming ZOU Zao−jian +1 位作者 ZOU Lu ZHU Sheng−tao 《船舶力学》 北大核心 2025年第6期878-887,共10页
Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dyn... Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dynamic Fluid-Body Interaction)method are employed in this paper to enable the free-running motion of the ship in modeling.A numerical model capable of simulating a ship navigating through pack ice area is proposed,which uses Computational Fluid Dynamics(CFD)method to solve the flow field and applies the Discrete Element Method(DEM)to simulate ship-ice and ice-ice interactions.Besides,the proposed high-precision method for generating pack ice area can be used in conjunction with the proposed numerical model.By comparing the numerical results with the available model test data and experimental observations,the effectiveness of the numerical model is validated,demonstrating its strong capability of predicting resistance and simulating ship navigation in pack ice,as well as its significant potential and applicability for further studies. 展开更多
关键词 pack ice ship-ice-water interaction CFD-DEM dynamic overset grid technology ship resistance
在线阅读 下载PDF
Design of commonly-resonated extended interaction circuits for submillimeter-wave phase-locked oscillators
5
作者 BI Liang-Jie LI Hai-Long +2 位作者 WANG Bin MENG Lin YIN Yong 《红外与毫米波学报》 北大核心 2025年第4期553-561,共9页
In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-... In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-band.Two separate EIOs are coupled through a specific single-gap coupling field supported by a designed gap waveguide with length Lg,which form the phase-locked EIOs based on the commonly-resonated system.As a whole system,the system has been focused on with mode analysis based on different single-gap coupling fields,mode hopping,which present the variation of phase difference between the two-beam-wave interactions when changing Lg.To demonstrate the effectiveness of the proposed circuit system in producing the phase locking,we conducted particle-in-cell(PIC)simulations to show that the interesting mode hopping occurs with the phase difference of O and r between the output signals from two output ports,corresponding to the excitation of the TMn mode with different n.Simulation results show that 1)the oscillator can deliver two times of the output power obtained from one single oscillator at 220 GHz,2)the two EIOs can still deliver output signals with phase difference of O and when the currents of the two beams are different or the fabrication errors of the two EIO cavities are taken into account.The proposed scheme is promising in extending to phase locking between multiple EIOs,and generating higher power at millimeter-wave and higher frequencies. 展开更多
关键词 electron physics phase-locked extended interaction oscillator(EIO) PIC simulations distributed beam high order mode
在线阅读 下载PDF
Research progress on metal-support interactions over Ni-based catalysts for CH_(4)-CO_(2)reforming reaction
6
作者 SUN Kai JIANG Jianfei +4 位作者 LIU Zixuan GENG Shiqi LIU Zhenmin YANG Jiaqian LI Shasha 《燃料化学学报(中英文)》 北大核心 2025年第4期434-451,共18页
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni... With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies. 展开更多
关键词 CO_(2)utilization CH_(4)-CO_(2)reforming Ni-based catalysts metal-support interactions supports
在线阅读 下载PDF
基于多头自注意力机制与MLP-Interactor的多模态情感分析
7
作者 林宜山 左景 卢树华 《浙江大学学报(工学版)》 北大核心 2025年第8期1653-1661,1679,共10页
针对多模态情感分析中单模态特征质量较差及多模态特征交互不够充分的问题,提出基于多头自注意力机制和MLP-Interactor的多模态情感分析方法.通过基于多头自注意力机制的模态内特征交互模块,实现单模态内的特征交互,提高单模态特征的质... 针对多模态情感分析中单模态特征质量较差及多模态特征交互不够充分的问题,提出基于多头自注意力机制和MLP-Interactor的多模态情感分析方法.通过基于多头自注意力机制的模态内特征交互模块,实现单模态内的特征交互,提高单模态特征的质量.通过MLP-Interactor机制实现多模态特征之间的充分交互,学习不同模态之间的一致性信息.利用提出方法,在CMU-MOSI和CMU-MOSEI 2个公开数据集上进行大量的实验验证与测试.结果表明,提出方法超越了当前诸多的先进方法,可以有效地提升多模态情感分析的准确性. 展开更多
关键词 多模态情感分析 MLP-interactor 多头自注意力机制 特征交互
在线阅读 下载PDF
A comprehensive review on elucidating the host disease resistance mechanism from the perspective of the interaction between cotton and Verticillium dahliae
8
作者 ZHANG Yalin ZHAO Lihong +8 位作者 LI Dongpo LI Ziming FENG Hongjie FENG Zili WEI Feng ZHOU Jinglong MA Zhiying YANG Jun ZHU Heqin 《Journal of Cotton Research》 2025年第1期129-142,共14页
Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interacti... Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interaction dynamics between the cotton plant host and V.dahliae pathogen pose a crucial predicament for effectively managing cotton Verticillium wilt.Nevertheless,the most cost-effective approach to controlling this disease involves breeding and cul-tivating resistant cotton varieties,demanding a meticulous analysis of the mechanisms underlying cotton’s resistance to Verticillium wilt and the identification of pivotal genes.These aspects constitute focal points in disease-resistance breeding programs.In this review,we comprehensively discuss genetic inheritance associated with Verticillium wilt resistance in cotton,the advancements in molecular markers for disease resistance,the functional investiga-tion of resistance genes in cotton,the analysis of pathogenicity genes in V.dahliae,as well as the intricate interplay between cotton and this fungus.Moreover,we delve into the future prospects of cutting-edge research on cotton Verticillium wilt,aiming to proffer valuable insights for the effective management of this devastating fungus. 展开更多
关键词 Cotton Verticillium wilt Verticillium dahliae Resistance inheritance Disease resistance mechanism interaction mechanism
在线阅读 下载PDF
Analytic method of skin friction for plum blossom pile foundations considering pile-soil interaction under vertical load
9
作者 LI Long JIANG Quan DENG You-sheng 《Journal of Central South University》 2025年第9期3336-3347,共12页
Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blo... Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blossom piles, it is important to investigate the skin friction behavior of plum blossom pile foundations precluding any straightforward constitutive model. In this work, an analytic method dependent on the cross-sectional geometry and the vertical shearing effects is proposed by means of equilibrium analysis to calculate the effective vertical stress in the surrounding soil, the skin friction/negative skin friction, and the axial force/dragload of a plum blossom pile. Additionally, the curves of skin friction of piles are investigated with the same conditions. The results show that the curves of skin friction of piles deduced according to the developed analytic method agree well with the FEM results and related literature solution, which validates the solution. The axial force of the pile decreases with the increase of the shear action coefficient in the buried depth direction under the vertical concentrated load when considering the vertical shearing effects on the pile-soil interfaces. 展开更多
关键词 plum blossom pile skin friction pile-soil interaction vertical shearing effects negative skin friction
在线阅读 下载PDF
Seismic pseudo-static stability analysis of bedding jointed rock slope stability under the interaction of the upper dangerous rock mass and lower stepped slope mass based on acceleration assessment
10
作者 LI De-jian XIAO Yu +3 位作者 YANG Yan-song YU Peng-cheng ZHANG Ying-bin ZHAO Lian-heng 《Journal of Central South University》 2025年第7期2619-2637,共19页
In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefo... In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks. 展开更多
关键词 bedding jointed rock slope upper dangerous rock mass stepped sliding interaction mechanism stability analysis
在线阅读 下载PDF
Interactive early warning technique based on SVDD 被引量:6
11
作者 Lin Jian~(1,2) Peng Minjing~(1,2) 1.School of Business Administration,South China Univ.of Technology,Guangzhou 510641,F.R.China 2.Systems Science & Technology Inst,Wuyi Univ.,Jiangmen 529020,P.R.China 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2007年第3期527-533,共7页
After reviewing current researches on early warning, it is found that “bad”data of some systems is not easy to obtain, which makes methods proposed by these researches unsuitable for monitored systems. An interactiv... After reviewing current researches on early warning, it is found that “bad”data of some systems is not easy to obtain, which makes methods proposed by these researches unsuitable for monitored systems. An interactive early warning technique based on SVDD (support vector data description) is proposed to adopt “good” data as samples to overcome the difficulty in obtaining the “bad” data. The process consists of two parts: (1) A hypersphere is fitted on “good” data using SVDD. If the data object are outside the hypersphere, it would be taken as “suspicious”; (2) A group of experts would decide whether the suspicious data is “bad” or “good”, early warning messages would be issued according to the decisions. And the detailed process of implementation is proposed. At last, an experiment based on data of a macroeconomic system is conducted to verify the proposed technique. 展开更多
关键词 interactive data mining early warning support vector data description group decision making.
在线阅读 下载PDF
Interactive group decision making procedure based on uncertain multiplicative linguistic preference relations 被引量:10
12
作者 Zeshui Xu1,2,1.College of Economics and Management,Southeast University,Nanjing 210096,P.R.China 2.Institute of Sciences,University of Science and Technology of the PLA,Nanjing 210007,P.R.China 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2010年第3期408-415,共8页
Group decision making problems are investigated with uncertain multiplicative linguistic preference relations.An unbalanced multiplicative linguistic label set is introduced,which can be used by the experts to express... Group decision making problems are investigated with uncertain multiplicative linguistic preference relations.An unbalanced multiplicative linguistic label set is introduced,which can be used by the experts to express their linguistic preference information over alternatives.The uncertain linguistic weighted geometric mean operator is utilized to aggregate all the individual uncertain multiplicative linguistic preference relations into a collective one,and then a simple approach is developed to determine the experts' weights by utilizing the consensus degrees among the individual uncertain multiplicative linguistic preference relations and the collective uncertain multiplicative linguistic preference relations.Furthermore,a practical interactive procedure for group decision making is proposed based on uncertain multiplicative linguistic preference relations,in which a possibility degree formula and a complementary matrix are used to rank the given alternatives.Finally,the proposed procedure is applied to solve the group decision making problem of a manufacturing company searching the best global supplier for one of its most critical parts used in assembling process. 展开更多
关键词 group decision making uncertain multiplicative linguistic preference relations unbalanced multiplicative linguistic label set consensus degree interaction.
在线阅读 下载PDF
Improved particle filtering techniques based on generalized interactive genetic algorithm 被引量:4
13
作者 Yan Zhang Shafei Wang Jicheng Li 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第1期242-250,共9页
This paper improves the resampling step of particle filtering(PF) based on a broad interactive genetic algorithm to resolve particle degeneration and particle shortage.For target tracking in image processing,this pa... This paper improves the resampling step of particle filtering(PF) based on a broad interactive genetic algorithm to resolve particle degeneration and particle shortage.For target tracking in image processing,this paper uses the information coming from the particles of the previous fame image and new observation data to self-adaptively determine the selecting range of particles in current fame image.The improved selecting operator with jam gene is used to ensure the diversity of particles in mathematics,and the absolute arithmetical crossing operator whose feasible solution space being close about crossing operation,and non-uniform mutation operator is used to capture all kinds of mutation in this paper.The result of simulating experiment shows that the algorithm of this paper has better iterative estimating capability than extended Kalman filtering(EKF),PF,regularized partide filtering(RPF),and genetic algorithm(GA)-PF. 展开更多
关键词 particle filtering(PF) particle degeneration particle shortage broad interactive genetic algorithm
在线阅读 下载PDF
Fast interactive segmentation algorithm of image sequences based on relative fuzzy connectedness 被引量:1
14
作者 Tian Chunna Gao Xinbo 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2005年第4期750-755,共6页
A fast interactive segmentation algorithm of image-sequences based on relative fuzzy connectedness is presented. In comparison with the original algorithm, the proposed one, with the same accuracy, accelerates the seg... A fast interactive segmentation algorithm of image-sequences based on relative fuzzy connectedness is presented. In comparison with the original algorithm, the proposed one, with the same accuracy, accelerates the segmentation speed by three times for single image. Meanwhile, this fast segmentation algorithm is extended from single object to multiple objects and from single-image to image-sequences. Thus the segmentation of multiple objects from complex hackground and batch segmentation of image-sequences can be achieved. In addition, a post-processing scheme is incorporated in this algorithm, which extracts smooth edge with one-pixel-width for each segmented object. The experimental results illustrate that the proposed algorithm can obtain the object regions of interest from medical image or image-sequences as well as man-made images quickly and reliably with only a little interaction. 展开更多
关键词 fuzzy connectedness interactive image segmentation image-sequences segmentation multiple objects segmentation fast algorithm.
在线阅读 下载PDF
Instability Mechanism of a Rotating Disc Subjected to Various Transverse Interactive Forces
15
作者 XIONG Guo-liang, CHEN Hui, YI Jun-min (School of Mechanical Engineering, East China Jiaotong University, Nanc hang 330013, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期130-131,共2页
In the past three decades, numerous papers have bee n publishedon the dynamics of rotating discs. most of them have focused on the ma thematical modeling and solution for a specific interactive force, such as a n elas... In the past three decades, numerous papers have bee n publishedon the dynamics of rotating discs. most of them have focused on the ma thematical modeling and solution for a specific interactive force, such as a n elastic force produced by a stationary spring or a damping force from a statio nary viscous damper. Few of them have looked into the instability mechanisms. This study has established a generalized approach to investigate the instability mechanisms that are involved in the interaction between a rotating and an arbit rary interactive force. An energy flux equation has been developed, which leads to the following conclusions: (1) The possibility of the occurrence of instability due to any interactive forc es may be identified based on the energy flux analysis, even without solving equ ations. (2) Instabilities will occur if the interactive forces are in phase with the vel ocity measured at the interactive point from the coordinates rotating with the d isc. (3) Instability cannot occur when a rotating disc is subjected to a stationary c onstant lateral force, but a stationary harmonic lateral force, a moving constan t lateral force or a moving harmonic lateral force may cause instability. (4) Conservative forces may only cause coupling instability associated with two modes, and non-conservative forces usually cause terminal instability where onl y one mode is involved. 展开更多
关键词 rotating disk instability mechanism transverse interactive forces
在线阅读 下载PDF
Approaches to Affective Computing and Learning towards Interactive Decision Making in Process Control Engineering 被引量:8
16
作者 宿翀 李宏光 《自动化学报》 EI CSCD 北大核心 2013年第5期617-625,共9页
关键词 多目标决策问题 过程控制工程 情感计算 学习策略 PID参数整定 制作 法向 收敛性分析
在线阅读 下载PDF
Interactive Multi-label Image Segmentation With Multi-layer Tumors Automata 被引量:1
17
作者 Sixian Chan Xiaolong Zhou +1 位作者 Zhuo Zhang Shengyong Chen 《自动化学报》 EI CSCD 北大核心 2017年第10期1829-1840,共12页
关键词 图像分割算法 元胞自动机 交互式 标记 肿瘤 像素级 图像处理 自动分割
在线阅读 下载PDF
A Correlational Study between Teachers' Emotional Factors and Class Interactive Teaching Efficacy
18
作者 Xie Yan 《学术界》 CSSCI 北大核心 2015年第7期310-316,共7页
The author brought forward two suppositions in this thesis:The students' achievements have the direct proportion with the degree of the appreciation to their teachers.Aiming at the supposition,the author developed... The author brought forward two suppositions in this thesis:The students' achievements have the direct proportion with the degree of the appreciation to their teachers.Aiming at the supposition,the author developed a set of statistics modeling and simulation study,which focused on the teachers' characters,the students' appreciations and students' exam scores in order to reveal the influence of teachers' affective variables on students' achievements.Therefore,according to the series of the suppositions,the author suggested that teachers should pay full attention to the students' emotional needs and decrease the negative effects on students.Meanwhile,the students should encourage the teachers to be absorbed in their instruction by cooperating with their teachers actively in order to acquire abundant knowledge in the limited time. 展开更多
关键词 情感因素 互动教学 教师 学生成绩 课堂 统计建模 考试成绩 作者
在线阅读 下载PDF
Remote electron effects and π-π interactions of α-diimine nickel complexes
19
作者 Yizhan Wang Hailong He Dan Peng 《中国科学技术大学学报》 CAS CSCD 北大核心 2024年第9期17-22,68,共7页
The seminal report ofα-diimine palladium and nickel catalysts in 1995 represented a major breakthrough in the preparation of functionalized polyolefin materials.Owing to the high abundance and low cost of nickel,nick... The seminal report ofα-diimine palladium and nickel catalysts in 1995 represented a major breakthrough in the preparation of functionalized polyolefin materials.Owing to the high abundance and low cost of nickel,nickel-based catalysts have great application prospects in the industrialization process of olefin coordination polymerization.In this work,various N-aryl substituents with different electronic effects were synthesized and introduced intoα-diimine ligands.The aspreparedα-diimine nickel catalysts showed high polymerization activity(0.9×10^(7)–3.0×10^(7)g·mol^(−1)·h^(−1))in ethylene polymerization,generating polyethylene products with adjustable molecular weights(Mn values:7.4×10^(4)–146.9×10^(4)g·mol^(−1))and branching densities(31/1000 C–68/1000 C).The resulting polyethylene products showed excellent mechanical properties,with high tensile strength(up to 25.0 MPa)and high strain at break values(up to 3890%).The copolymerization of ethylene and polar monomers can also be achieved by these nicekel complexes,ultimately preparing functionalized polyolefins. 展开更多
关键词 α-diimine nickel catalyst ethylene polymerization π-πinteraction effect electronic effect polar monomer
在线阅读 下载PDF
Electrochemical-Method-Induced Strong Metal-Support Interaction in Pt-CNT@SnO_(2) for CO-Tolerant Hydrogen Oxidation Reaction
20
作者 Shen-Zhou Li Zi-Jie Lin +2 位作者 Qi-An Chen Zhao Cai Qing Li 《电化学(中英文)》 北大核心 2024年第12期28-38,共11页
Inducing the classic strong metal-support interaction(SMSI)is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles(NPs)with supports.Conventional therm... Inducing the classic strong metal-support interaction(SMSI)is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles(NPs)with supports.Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs.In this study,a mild electrochemical method has been developed as a new approach to induce SMSI,using the cable structured core@shell CNT@SnO_(2) loaded Pt NPs as a proof of concept.The induced SnO_(x) encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in hydrogen oxidation reaction(HOR),and the HOR current density could still maintain 85% for 2000 s with 10,000 ppm CO in H_(2),while the commercial Pt/C is completely inactivated.In addition,the electrons transfer from SnO_(x) to Pt NPs improved the HOR activity of the E-Pt-CNT@SnO_(2),achieving the excellent exchange current density of 1.55 A·mgPt^(-1).In situ Raman spectra and theoretical calculations show that the key to the electrochemical-method-induced SMSI is the formation of defects and the migration of SnO_(x) caused by the electrochemical redox operation,and the weakening the SneO bond strength by Pt NPs. 展开更多
关键词 Strong metal-support interaction Pt Supported metal catalyst Hydrogen oxidation reaction CO tolerance
在线阅读 下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部