High temperature air combustion (HTAC) is an attractive technology of saving energy and controlling environment. The mathematical models of turbulent jet flame under the highly preheated air combustion condition are c...High temperature air combustion (HTAC) is an attractive technology of saving energy and controlling environment. The mathematical models of turbulent jet flame under the highly preheated air combustion condition are conducted in the paper. The mixture fraction/probability density function model is employed. The results show that the maximum flame temperature is decreased, the temperature in the HTAC furnace is more uniform than that in the conventional furnace, and the NO x emission is low. The numerical results are partially validated by some experimental measurements.展开更多
为了认识稠油开发过程中低温氧化与高温氧化阶段原油变化规律,利用静态氧化釜开展稠油的高低温氧化实验,借助傅里叶变换离子回旋共振质谱分析技术对高低温氧化前后的原油分子量及O、N、S杂原子化合物特征开展研究,结果表明:原油低温氧...为了认识稠油开发过程中低温氧化与高温氧化阶段原油变化规律,利用静态氧化釜开展稠油的高低温氧化实验,借助傅里叶变换离子回旋共振质谱分析技术对高低温氧化前后的原油分子量及O、N、S杂原子化合物特征开展研究,结果表明:原油低温氧化阶段分子量分布特征与原样相似,相对分子量分布范围在200~750,整体呈平缓状单峰型分布,高温氧化阶段分子量分布范围前移,呈明显的前峰单峰型分布;杂原子化合物中的O元素在低温氧化阶段主要以无环的饱和二元酸形式存在,在高温氧化阶段受环化、芳构化及脱甲基作用的影响,伴随着侧链烷基及杂原子基团的断裂和芳构化过程,造成原油中杂原子化合物向着碳数更小、双键当量(double bond equivalents,DBE)值更低的方向演化。该研究探索了温度与原油结构及化学组成之间的关系,对于指导稠油开发现场具有重要意义。展开更多
文摘High temperature air combustion (HTAC) is an attractive technology of saving energy and controlling environment. The mathematical models of turbulent jet flame under the highly preheated air combustion condition are conducted in the paper. The mixture fraction/probability density function model is employed. The results show that the maximum flame temperature is decreased, the temperature in the HTAC furnace is more uniform than that in the conventional furnace, and the NO x emission is low. The numerical results are partially validated by some experimental measurements.
文摘为了认识稠油开发过程中低温氧化与高温氧化阶段原油变化规律,利用静态氧化釜开展稠油的高低温氧化实验,借助傅里叶变换离子回旋共振质谱分析技术对高低温氧化前后的原油分子量及O、N、S杂原子化合物特征开展研究,结果表明:原油低温氧化阶段分子量分布特征与原样相似,相对分子量分布范围在200~750,整体呈平缓状单峰型分布,高温氧化阶段分子量分布范围前移,呈明显的前峰单峰型分布;杂原子化合物中的O元素在低温氧化阶段主要以无环的饱和二元酸形式存在,在高温氧化阶段受环化、芳构化及脱甲基作用的影响,伴随着侧链烷基及杂原子基团的断裂和芳构化过程,造成原油中杂原子化合物向着碳数更小、双键当量(double bond equivalents,DBE)值更低的方向演化。该研究探索了温度与原油结构及化学组成之间的关系,对于指导稠油开发现场具有重要意义。
