Oxygen-free copper and pre-metalized graphite were brazed using CuNiSnP braze alloy by high frequency induction heating method. Interracial microstructures and reaction phases were analyzed by scanning electron micros...Oxygen-free copper and pre-metalized graphite were brazed using CuNiSnP braze alloy by high frequency induction heating method. Interracial microstructures and reaction phases were analyzed by scanning electron microscopy （SEM） and energy dispersive X-ray spectroscopy （EDS）. The strength and resistance of the joints were tested. It is found that when the brazing parameters are optimized, the structures of the joints are graphite/（Cu,Ni）/Ni（s.s）＋NixPy/Cu3P＋Cu（s.s） （including Sn）＋eutectic structures （Cu3P＋Ni3P＋Cu（s.s）/Cu （s.s）/Cu）. When the temperature increases to 750℃ or the holding time prolongs to 300 s, the eutectie structures disappear and the amount of Cu3P increases. The maximum shear strength of the joints is 5.2 MPa, which fracture at the interface of graphite and metallization. The resistance of the joints is no more than 5 mΩ.展开更多
基金Project(50705022) supported by the National Natural Science Foundation of ChinaProject supported by the Program for New Century Excellent Talents in University
文摘Oxygen-free copper and pre-metalized graphite were brazed using CuNiSnP braze alloy by high frequency induction heating method. Interracial microstructures and reaction phases were analyzed by scanning electron microscopy （SEM） and energy dispersive X-ray spectroscopy （EDS）. The strength and resistance of the joints were tested. It is found that when the brazing parameters are optimized, the structures of the joints are graphite/（Cu,Ni）/Ni（s.s）＋NixPy/Cu3P＋Cu（s.s） （including Sn）＋eutectic structures （Cu3P＋Ni3P＋Cu（s.s）/Cu （s.s）/Cu）. When the temperature increases to 750℃ or the holding time prolongs to 300 s, the eutectie structures disappear and the amount of Cu3P increases. The maximum shear strength of the joints is 5.2 MPa, which fracture at the interface of graphite and metallization. The resistance of the joints is no more than 5 mΩ.
