Dual-ion batteries(DIBs)usually use carbon-based materials as electrodes,showing advantages in high operating volt-age,potential low cost,and environmental friendliness.Different from conventional“rocking chair”type...Dual-ion batteries(DIBs)usually use carbon-based materials as electrodes,showing advantages in high operating volt-age,potential low cost,and environmental friendliness.Different from conventional“rocking chair”type secondary batter-ies,DIBs perform a unique working mechanism,which employ both cation and anion taking part in capacity contribution at an anode and a cathode,respectively,during electrochemical reactions.Graphite has been identified as a suitable cathode material for anion intercalation at high voltages(>4.8 V)with fast reaction kinetics.However,the development of DIBs is being hindered by dynamic mismatch between a cathode and an anode due to sluggish Li+diffusion at a high rate.Herein,we prepared phyllostachys edulis derived carbon(PEC)through microstructure regulation strategy and investigated the carbonized temperature effect,which effectively tailored the rich short-range ordered graphite microdomains and disor-dered amorphous regions,as well as a unique nano-pore hierarchical structure.The pore size distribution of nano-pores was concentrated in 0.5-5 nm,providing suitable channels for rapid Li+transportation.It was found that PEC-500(carbon-ized at 500℃)achieved a high capacity of 436 mAh·g^(-1)at 300 mA·g^(-1)and excellent rate performance(maintaining a high capacity of 231 mAh·g^(-1)at 3 A·g^(-1)).The assembled dual-carbon PEC-500||graphite full battery delivered 114 mAh·g^(-1)at 10 C with 96%capacity retention after 3000 cycles and outstanding rate capability,providing 74 mAh·g^(-1)at 50 C.展开更多
Recent advances in additive manufacturing have enabled the construction of metallic lattice structures with tailored mechanical and functional properties.One potential application of metallic lattice struc-tures is in...Recent advances in additive manufacturing have enabled the construction of metallic lattice structures with tailored mechanical and functional properties.One potential application of metallic lattice struc-tures is in the impact load mitigation where an external kinetic energy is absorbed by the deformation/crushing of lattice cells.This has motivated a growing number of experimental and numerical studies,recently,on the crushing behavior of additively produced lattice structures.The present study overviews the dynamic and quasi-static crushing behavior of additively produced Ti64,316L,and AlSiMg alloy lattice structures.The first part of the study summarizes the main features of two most commonly used additive processing techniques for lattice structures,namely selective-laser-melt(SLM)and electro-beam-melt(EBM),along with a description of commonly observed process induced defects.In the second part,the deformation and strain rate sensitivities of the selected alloy lattices are outlined together with the most widely used dynamic test methods,followed by a part on the observed micro-structures of the SLM and EBM-processed Ti64,316L and AlSiMg alloys.Finally,the experimental and numerical studies on the quasi-static and dynamic compression behavior of the additively processed Ti64,316L,and AlSiMg alloy lattices are reviewed.The results of the experimental and numerical studies of the dynamic properties of various types of lattices,including graded,non-uniform strut size,hollow,non-uniform cell size,and bio-inspired,were tabulated together with the used dynamic testing methods.The dynamic tests have been noted to be mostly conducted in compression Split Hopkinson Pressure Bar(SHPB)or Taylor-and direct-impact tests using the SHPB set-up,in all of which relatively small-size test specimens were tested.The test specimen size effect on the compression behavior of the lattices was further emphasized.It has also been shown that the lattices of Ti64 and AlSiMg alloys are relatively brittle as compared with the lattices of 316L alloy.Finally,the challenges associated with modelling lattice structures were explained and the micro tension tests and multi-scale modeling techniques combining microstructural characteristics with macroscopic lattice dynamics were recommended to improve the accuracy of the numerical simulations of the dynamic compression deformations of metallic lattice structures.展开更多
Modern warfare demands weapons capable of penetrating substantial structures,which presents sig-nificant challenges to the reliability of the electronic devices that are crucial to the weapon's perfor-mance.Due to...Modern warfare demands weapons capable of penetrating substantial structures,which presents sig-nificant challenges to the reliability of the electronic devices that are crucial to the weapon's perfor-mance.Due to miniaturization of electronic components,it is challenging to directly measure or numerically predict the mechanical response of small-sized critical interconnections in board-level packaging structures to ensure the mechanical reliability of electronic devices in projectiles under harsh working conditions.To address this issue,an indirect measurement method using the Bayesian regularization-based load identification was proposed in this study based on finite element(FE)pre-dictions to estimate the load applied on critical interconnections of board-level packaging structures during the process of projectile penetration.For predicting the high-strain-rate penetration process,an FE model was established with elasto-plastic constitutive models of the representative packaging ma-terials(that is,solder material and epoxy molding compound)in which material constitutive parameters were calibrated against the experimental results by using the split-Hopkinson pressure bar.As the impact-induced dynamic bending of the printed circuit board resulted in an alternating tensile-compressive loading on the solder joints during penetration,the corner solder joints in the edge re-gions experience the highest S11 and strain,making them more prone to failure.Based on FE predictions at different structural scales,an improved Bayesian method based on augmented Tikhonov regulariza-tion was theoretically proposed to address the issues of ill-posed matrix inversion and noise sensitivity in the load identification at the critical solder joints.By incorporating a wavelet thresholding technique,the method resolves the problem of poor load identification accuracy at high noise levels.The proposed method achieves satisfactorily small relative errors and high correlation coefficients in identifying the mechanical response of local interconnections in board-level packaging structures,while significantly balancing the smoothness of response curves with the accuracy of peak identification.At medium and low noise levels,the relative error is less than 6%,while it is less than 10%at high noise levels.The proposed method provides an effective indirect approach for the boundary conditions of localized solder joints during the projectile penetration process,and its philosophy can be readily extended to other scenarios of multiscale analysis for highly nonlinear materials and structures under extreme loading conditions.展开更多
The structure and properties of high chromium white cast iron in different treatment states were studied. Using X ray diffraction method, observing their metallograph and measuring their microhardness, the phases inv...The structure and properties of high chromium white cast iron in different treatment states were studied. Using X ray diffraction method, observing their metallograph and measuring their microhardness, the phases involved in the iron were determined. The notch toughness, macrohardness and the fractograph of the samples are compared and their performance was determined, which mainly depends on the matrix structure. Relatively good comprehensive properties can be obtained in the tempering state. Improvements have been made on the commonly used tempering standard. Tempering for a short period at low temperature can improve the materials′ service performance obviously.展开更多
Reduction of Cr(VI)using zero-valent iron(ZVI)could not only decrease the amounts of chemicals used for reduction,but also decrease the discharge of sludge.In order to find a desirable ZVI material,reduction of Cr(VI)...Reduction of Cr(VI)using zero-valent iron(ZVI)could not only decrease the amounts of chemicals used for reduction,but also decrease the discharge of sludge.In order to find a desirable ZVI material,reduction of Cr(VI)with a relative high concentration using different kinds of ZVI powders(mainly carbon differences)including reduced Fe,grey cast iron,pig iron,nodular pig iron was carried out.Parameters such as ZVI dosage,type and size affecting on Cr(VI)reduction were firstly examined and grey cast iron was selected as a preferable reducing material,followed by pig iron.Additionally,it was found that the parameters had significant influences on experimental kinetics.Then,morphology and composition of the sample before and after reaction were characterized by SEM,EPMA and XPS analyses to disclose carbon effect on the reducibility.In order to further interpret reaction mechanism,different reaction models were constructed.It was revealed that not only the carbon content could affect the Cr(VI)reduction,but also the carbon structure had an important effect on its reduction.展开更多
The slow wave structure(SWS)of higher-order depressed magnetically insulated transmission line oscillator(HDMILO)is analyzed rigorously,and the electromagnetic field distribution is derived.High-frequency analysis res...The slow wave structure(SWS)of higher-order depressed magnetically insulated transmission line oscillator(HDMILO)is analyzed rigorously,and the electromagnetic field distribution is derived.High-frequency analysis results reveal that the degeneracy of two degenerate HEM!1 modes is removed by the slot in swS plate and the two degenerate modes split into two modes which polarize perpendicularly.Adjusting the azi-muthal position of the slots destroys longitudinal oscillation condition of higher-order modes.展开更多
Boiling structures on evaporation surface of red copper sheet with a diameter （D） of 10 mm and a wall thickness （h） of 1 mm were processed by the ploughing-extrusion （P-E） processing method, which is one part of...Boiling structures on evaporation surface of red copper sheet with a diameter （D） of 10 mm and a wall thickness （h） of 1 mm were processed by the ploughing-extrusion （P-E） processing method, which is one part of the phase-change heat sink for high power （HP） light emitting diode （LED）. The experimental results show that two different structures of rectangular- and triangular-shaped micro-grooves are formed in P-E process. When P-E depth （ap）, interval of helical grooves （dp） and rotation speed （n） are 0.12 ram, 0.2 mm and 100 r/min, respectively, the boiling structures of triangular-shaped grooves with the fin height of 0.15 mm that has good evaporation performance are obtained. The shapes of the boiling structures are restricted by dp and ap, and dp is determined by n and amount of feed （f）. The ploughing speed has an important influence on the formation of groove structure in P-E process.展开更多
Carbon materials with adjustable porosity,controllable het-eroatom doping and low-cost have been received considerable attention as supercapacitor electrodes.However,using carbon materials with abundant micropores,a h...Carbon materials with adjustable porosity,controllable het-eroatom doping and low-cost have been received considerable attention as supercapacitor electrodes.However,using carbon materials with abundant micropores,a high surface area and a high-dopant content for an aqueous su-percapacitor with a high energy output still remains a challenge.We report the easy synthesis of interconnected carbon spheres by a polymerization re-action between p-benzaldehyde and 2,6-diaminopyridine.The synthesis in-volves adjusting the mass ratio of the copolymer and KOH activator to achieve increased charge storage ability and high energy output,which are attributed to the high ion-accessible area provided by the large number of micropores,high N/O contents and rapid ion diffusion channels in the porous structure.At a PMEC∶KOH mass ratio of 1∶1,the high electrolyte ion-adsorption area(2599.76 m^(2) g^(−1))and the N/O dopant atoms of the conductive framework of a typical carbon electrode produce a superior specific capacity(303.2 F g^(−1)@0.5 A g^(−1))giving an assembled symmetric capacitor a high energy delivery of 11.3 Wh kg^(−1)@250 W kg^(−1).This study presents a simple strategy for synthesizing microporous carbon and highlights its potential use in KOH-based supercapacitors.展开更多
To investigate the problem of ethylene jet mixing and combustion in the scramjet at high Mach number(Ma = 8), numerical simulations were carried out for different equivalent ratios at cold and combustion conditions, i...To investigate the problem of ethylene jet mixing and combustion in the scramjet at high Mach number(Ma = 8), numerical simulations were carried out for different equivalent ratios at cold and combustion conditions, in which three-dimensional steady compressible RANS and k-ω SST turbulence model were adopted. It demonstrates that as the equivalence ratio increases from 0.42 to 1.08, the combustion becomes more intensified, and the higher backpressure pushes flame to propagate upstream. The supersonic combustion region in the combustor decreases from 92% to 85% with the increase of equivalence ratio from 0.42 to 1.08, resulting in the transition of the combustor from scram-mode to dual-mode. Both mixing and combustion efficiencies decrease by 35% and 16% respectively when the equivalence ratio increases from 0.42 to 1.08, indicating that the high equivalence ratio is unfavorable to the mixing and combustion processes. Combustion mode analysis reveals that the flame in the cavity under the high Mach number is dominated by non-premixed flames, i.e., more than 95% behaves as non-premixed mode, and the heat release is also mainly contributed by non-premixed flame. Increasing the equivalence ratio is beneficial to the thrust performance. Although the viscous force hardly changes with equivalence ratio, the percentage of pressure force used to balance the viscous force increases gradually,which limits the engine performance.展开更多
In the structural design of the high pier,in order to analyze the strength and structure stability,the pier was often considered a thin-walled structure.Elastoplastic incremental theory was used to establish the model...In the structural design of the high pier,in order to analyze the strength and structure stability,the pier was often considered a thin-walled structure.Elastoplastic incremental theory was used to establish the model of elastoplastic stability of high pier.By considering the combined action of pile,soil and pier together,the destabilization bearing capacity was calculated by using 3-D finite element method(3-D FEM) for piers with different pile and section height.Meanwhile,the equivalent stress in different sections of pier was computed and the processor of destabilization was discussed.When the pier is lower,the bearing capacity under mutual effect of pile,soil and pier is less than the situation when mutual effect is not considered;when the pier is higher,their differences are not conspicuous.Along with the increase of the cross-sectional height,the direction of destabilization bearing capacity is varied and the ultimate capacity is buildup.The results of a stability analysis example are almost identical with the practice.展开更多
Expansive soil is sensitive to dry and wet environment change. And the volume deformation and inflation pressure of expansive soil may induce to cause the deformation failure of roadbed or many other adverse effects. ...Expansive soil is sensitive to dry and wet environment change. And the volume deformation and inflation pressure of expansive soil may induce to cause the deformation failure of roadbed or many other adverse effects. Aimed at a high-speed railway engineering practice in the newly built Yun-Gui high-speed railway expansive soil section in China, indoor vibration test on a full-scaled new cutting subgrade model is carried out. Based on the established track-subgrade-foundation of expansive soil system dynamic model test platform, dynamic behavior of new cutting subgrade structure under train loads coupling with extreme service environment(dry, raining, and groundwater level rising) is analyzed comparatively. The results show that the subgrade dynamic response is significantly influenced by service conditions and the dynamic response of subgrade gradually becomes stable with the increasing vibration times under various service environment conditions. The vertical dynamic soil stress is related with the depth in an approximate exponential function, and the curves of vertical dynamic soil stress present a "Z" shape distribution along transverse distance. The peak value of dynamic soil stress appears below the rail, and it increases more obviously near the roadbed surface. However, the peak value of dynamic soil stress is little affected outside 5.0 m of center line. The vibration velocity and acceleration are in a quadratic curve with an increase in depth, and the raining and groundwater level rising increase both the vibration velocity and the acceleration. The vertical deformations at different depths are differently affected by service environment in roadbed. The deformation of roadbed increases sharply when the water gets in the foundation of expansive soil, and more than 60% of the total deformation of roadbed occurs in expansive soil foundation. The laid waterproofing and drainage structure layer, which weakens the dynamic stress and improves the track regularity, presents a positive effect on the control deformation of roadbed surface. An improved empirical formula is then proposed to predict the dynamic stress of ballasted tracks subgrade of expansive soil.展开更多
Inverse synthetic aperture radar (ISAR) image can be represented and reconstructed by sparse recovery (SR) approaches. However, the existing SR algorithms, which are used for ISAR imaging, have suffered from high comp...Inverse synthetic aperture radar (ISAR) image can be represented and reconstructed by sparse recovery (SR) approaches. However, the existing SR algorithms, which are used for ISAR imaging, have suffered from high computational cost and poor imaging quality under a low signal to noise ratio (SNR) condition. This paper proposes a fast decoupled ISAR imaging method by exploiting the inherent structural sparse information of the targets. Firstly, the ISAR imaging problem is decoupled into two sub-problems. One is range direction imaging and the other is azimuth direction focusing. Secondly, an efficient two-stage SR method is proposed to obtain higher resolution range profiles by using jointly sparse information. Finally, the residual linear Bregman iteration via fast Fourier transforms (RLBI-FFT) is proposed to perform the azimuth focusing on low SNR efficiently. Theoretical analysis and simulation results show that the proposed method has better performence to efficiently implement higher-resolution ISAR imaging under the low SNR condition.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.52272208,22309057)the Natural Science Foundation of Hubei Province(Grant No.2023AFB355)the Fundamental Research Funds for the Central Universities of China(Grant No.2662022LXQD001).
文摘Dual-ion batteries(DIBs)usually use carbon-based materials as electrodes,showing advantages in high operating volt-age,potential low cost,and environmental friendliness.Different from conventional“rocking chair”type secondary batter-ies,DIBs perform a unique working mechanism,which employ both cation and anion taking part in capacity contribution at an anode and a cathode,respectively,during electrochemical reactions.Graphite has been identified as a suitable cathode material for anion intercalation at high voltages(>4.8 V)with fast reaction kinetics.However,the development of DIBs is being hindered by dynamic mismatch between a cathode and an anode due to sluggish Li+diffusion at a high rate.Herein,we prepared phyllostachys edulis derived carbon(PEC)through microstructure regulation strategy and investigated the carbonized temperature effect,which effectively tailored the rich short-range ordered graphite microdomains and disor-dered amorphous regions,as well as a unique nano-pore hierarchical structure.The pore size distribution of nano-pores was concentrated in 0.5-5 nm,providing suitable channels for rapid Li+transportation.It was found that PEC-500(carbon-ized at 500℃)achieved a high capacity of 436 mAh·g^(-1)at 300 mA·g^(-1)and excellent rate performance(maintaining a high capacity of 231 mAh·g^(-1)at 3 A·g^(-1)).The assembled dual-carbon PEC-500||graphite full battery delivered 114 mAh·g^(-1)at 10 C with 96%capacity retention after 3000 cycles and outstanding rate capability,providing 74 mAh·g^(-1)at 50 C.
基金the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 101034425 for the project titled A2M2TECHThe Scientific and Technological Research Council of Türkiye (TUBITAK) with grant No 120C158 for the same A2M2TECH project under the TUBITAK's 2236/B program
文摘Recent advances in additive manufacturing have enabled the construction of metallic lattice structures with tailored mechanical and functional properties.One potential application of metallic lattice struc-tures is in the impact load mitigation where an external kinetic energy is absorbed by the deformation/crushing of lattice cells.This has motivated a growing number of experimental and numerical studies,recently,on the crushing behavior of additively produced lattice structures.The present study overviews the dynamic and quasi-static crushing behavior of additively produced Ti64,316L,and AlSiMg alloy lattice structures.The first part of the study summarizes the main features of two most commonly used additive processing techniques for lattice structures,namely selective-laser-melt(SLM)and electro-beam-melt(EBM),along with a description of commonly observed process induced defects.In the second part,the deformation and strain rate sensitivities of the selected alloy lattices are outlined together with the most widely used dynamic test methods,followed by a part on the observed micro-structures of the SLM and EBM-processed Ti64,316L and AlSiMg alloys.Finally,the experimental and numerical studies on the quasi-static and dynamic compression behavior of the additively processed Ti64,316L,and AlSiMg alloy lattices are reviewed.The results of the experimental and numerical studies of the dynamic properties of various types of lattices,including graded,non-uniform strut size,hollow,non-uniform cell size,and bio-inspired,were tabulated together with the used dynamic testing methods.The dynamic tests have been noted to be mostly conducted in compression Split Hopkinson Pressure Bar(SHPB)or Taylor-and direct-impact tests using the SHPB set-up,in all of which relatively small-size test specimens were tested.The test specimen size effect on the compression behavior of the lattices was further emphasized.It has also been shown that the lattices of Ti64 and AlSiMg alloys are relatively brittle as compared with the lattices of 316L alloy.Finally,the challenges associated with modelling lattice structures were explained and the micro tension tests and multi-scale modeling techniques combining microstructural characteristics with macroscopic lattice dynamics were recommended to improve the accuracy of the numerical simulations of the dynamic compression deformations of metallic lattice structures.
基金supported by the National Natural Science Foundation of China(Grant Nos.52475166,52175148)the Regional Collaboration Project of Shanxi Province(Grant No.202204041101044).
文摘Modern warfare demands weapons capable of penetrating substantial structures,which presents sig-nificant challenges to the reliability of the electronic devices that are crucial to the weapon's perfor-mance.Due to miniaturization of electronic components,it is challenging to directly measure or numerically predict the mechanical response of small-sized critical interconnections in board-level packaging structures to ensure the mechanical reliability of electronic devices in projectiles under harsh working conditions.To address this issue,an indirect measurement method using the Bayesian regularization-based load identification was proposed in this study based on finite element(FE)pre-dictions to estimate the load applied on critical interconnections of board-level packaging structures during the process of projectile penetration.For predicting the high-strain-rate penetration process,an FE model was established with elasto-plastic constitutive models of the representative packaging ma-terials(that is,solder material and epoxy molding compound)in which material constitutive parameters were calibrated against the experimental results by using the split-Hopkinson pressure bar.As the impact-induced dynamic bending of the printed circuit board resulted in an alternating tensile-compressive loading on the solder joints during penetration,the corner solder joints in the edge re-gions experience the highest S11 and strain,making them more prone to failure.Based on FE predictions at different structural scales,an improved Bayesian method based on augmented Tikhonov regulariza-tion was theoretically proposed to address the issues of ill-posed matrix inversion and noise sensitivity in the load identification at the critical solder joints.By incorporating a wavelet thresholding technique,the method resolves the problem of poor load identification accuracy at high noise levels.The proposed method achieves satisfactorily small relative errors and high correlation coefficients in identifying the mechanical response of local interconnections in board-level packaging structures,while significantly balancing the smoothness of response curves with the accuracy of peak identification.At medium and low noise levels,the relative error is less than 6%,while it is less than 10%at high noise levels.The proposed method provides an effective indirect approach for the boundary conditions of localized solder joints during the projectile penetration process,and its philosophy can be readily extended to other scenarios of multiscale analysis for highly nonlinear materials and structures under extreme loading conditions.
文摘The structure and properties of high chromium white cast iron in different treatment states were studied. Using X ray diffraction method, observing their metallograph and measuring their microhardness, the phases involved in the iron were determined. The notch toughness, macrohardness and the fractograph of the samples are compared and their performance was determined, which mainly depends on the matrix structure. Relatively good comprehensive properties can be obtained in the tempering state. Improvements have been made on the commonly used tempering standard. Tempering for a short period at low temperature can improve the materials′ service performance obviously.
基金Project(51604131)supported by the National Natural Science Foundation of ChinaProject(2017FB084)supported by the Yunnan Province Applied Basic Research,China+1 种基金Project(KKSY201563041)supported by the Talent&Training Program of Yunnan Province,ChinaProjects(2017T20090159,2018T20150055)supported by the Testing and Analyzing Funds of Kunming University of Science and Technology,China
文摘Reduction of Cr(VI)using zero-valent iron(ZVI)could not only decrease the amounts of chemicals used for reduction,but also decrease the discharge of sludge.In order to find a desirable ZVI material,reduction of Cr(VI)with a relative high concentration using different kinds of ZVI powders(mainly carbon differences)including reduced Fe,grey cast iron,pig iron,nodular pig iron was carried out.Parameters such as ZVI dosage,type and size affecting on Cr(VI)reduction were firstly examined and grey cast iron was selected as a preferable reducing material,followed by pig iron.Additionally,it was found that the parameters had significant influences on experimental kinetics.Then,morphology and composition of the sample before and after reaction were characterized by SEM,EPMA and XPS analyses to disclose carbon effect on the reducibility.In order to further interpret reaction mechanism,different reaction models were constructed.It was revealed that not only the carbon content could affect the Cr(VI)reduction,but also the carbon structure had an important effect on its reduction.
文摘The slow wave structure(SWS)of higher-order depressed magnetically insulated transmission line oscillator(HDMILO)is analyzed rigorously,and the electromagnetic field distribution is derived.High-frequency analysis results reveal that the degeneracy of two degenerate HEM!1 modes is removed by the slot in swS plate and the two degenerate modes split into two modes which polarize perpendicularly.Adjusting the azi-muthal position of the slots destroys longitudinal oscillation condition of higher-order modes.
基金Projects(50436010, 50675070) supported by the National Natural Science Foundation of China Project(07118064) supported by the Natural Science Foundation of Guangdong Province, China+1 种基金 Project(U0834002) supported by the Joint Fund of NSFC-Guangdong of ChinaProjects(SY200806300289A, JSA200903190981A) supported by Shenzhen Scientific Program, China
文摘Boiling structures on evaporation surface of red copper sheet with a diameter （D） of 10 mm and a wall thickness （h） of 1 mm were processed by the ploughing-extrusion （P-E） processing method, which is one part of the phase-change heat sink for high power （HP） light emitting diode （LED）. The experimental results show that two different structures of rectangular- and triangular-shaped micro-grooves are formed in P-E process. When P-E depth （ap）, interval of helical grooves （dp） and rotation speed （n） are 0.12 ram, 0.2 mm and 100 r/min, respectively, the boiling structures of triangular-shaped grooves with the fin height of 0.15 mm that has good evaporation performance are obtained. The shapes of the boiling structures are restricted by dp and ap, and dp is determined by n and amount of feed （f）. The ploughing speed has an important influence on the formation of groove structure in P-E process.
基金financially supported by University-level key projects of Anhui University of Science and Technology(QNZD2021-04,QNZD2021-07)Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology(2021yjrc22,13210572)+2 种基金Huainan Science and Technology Bureau Plan Project(2023A3111)Open Research Fund Program of Engineering Technology Research Center of Coal Resources Comprehensive Utilization(MTYJZX202204)Natural Science Research Project of Anhui Educational Committee(2023AH051184,2023AH051210)。
文摘Carbon materials with adjustable porosity,controllable het-eroatom doping and low-cost have been received considerable attention as supercapacitor electrodes.However,using carbon materials with abundant micropores,a high surface area and a high-dopant content for an aqueous su-percapacitor with a high energy output still remains a challenge.We report the easy synthesis of interconnected carbon spheres by a polymerization re-action between p-benzaldehyde and 2,6-diaminopyridine.The synthesis in-volves adjusting the mass ratio of the copolymer and KOH activator to achieve increased charge storage ability and high energy output,which are attributed to the high ion-accessible area provided by the large number of micropores,high N/O contents and rapid ion diffusion channels in the porous structure.At a PMEC∶KOH mass ratio of 1∶1,the high electrolyte ion-adsorption area(2599.76 m^(2) g^(−1))and the N/O dopant atoms of the conductive framework of a typical carbon electrode produce a superior specific capacity(303.2 F g^(−1)@0.5 A g^(−1))giving an assembled symmetric capacitor a high energy delivery of 11.3 Wh kg^(−1)@250 W kg^(−1).This study presents a simple strategy for synthesizing microporous carbon and highlights its potential use in KOH-based supercapacitors.
文摘To investigate the problem of ethylene jet mixing and combustion in the scramjet at high Mach number(Ma = 8), numerical simulations were carried out for different equivalent ratios at cold and combustion conditions, in which three-dimensional steady compressible RANS and k-ω SST turbulence model were adopted. It demonstrates that as the equivalence ratio increases from 0.42 to 1.08, the combustion becomes more intensified, and the higher backpressure pushes flame to propagate upstream. The supersonic combustion region in the combustor decreases from 92% to 85% with the increase of equivalence ratio from 0.42 to 1.08, resulting in the transition of the combustor from scram-mode to dual-mode. Both mixing and combustion efficiencies decrease by 35% and 16% respectively when the equivalence ratio increases from 0.42 to 1.08, indicating that the high equivalence ratio is unfavorable to the mixing and combustion processes. Combustion mode analysis reveals that the flame in the cavity under the high Mach number is dominated by non-premixed flames, i.e., more than 95% behaves as non-premixed mode, and the heat release is also mainly contributed by non-premixed flame. Increasing the equivalence ratio is beneficial to the thrust performance. Although the viscous force hardly changes with equivalence ratio, the percentage of pressure force used to balance the viscous force increases gradually,which limits the engine performance.
基金Project(06JJ5080) supported by the Hunan Natural Science Foundation of ChinaProject(05026B) supported by the Young Science Foundation of Central South University of Forestry and Technology
文摘In the structural design of the high pier,in order to analyze the strength and structure stability,the pier was often considered a thin-walled structure.Elastoplastic incremental theory was used to establish the model of elastoplastic stability of high pier.By considering the combined action of pile,soil and pier together,the destabilization bearing capacity was calculated by using 3-D finite element method(3-D FEM) for piers with different pile and section height.Meanwhile,the equivalent stress in different sections of pier was computed and the processor of destabilization was discussed.When the pier is lower,the bearing capacity under mutual effect of pile,soil and pier is less than the situation when mutual effect is not considered;when the pier is higher,their differences are not conspicuous.Along with the increase of the cross-sectional height,the direction of destabilization bearing capacity is varied and the ultimate capacity is buildup.The results of a stability analysis example are almost identical with the practice.
基金Projects(51478484,51308551,51678571)supported by the National Natural Science Foundation of ChinaProject(2016zzts063)supported by Fundamental Research Funds for the Central Universities,China
文摘Expansive soil is sensitive to dry and wet environment change. And the volume deformation and inflation pressure of expansive soil may induce to cause the deformation failure of roadbed or many other adverse effects. Aimed at a high-speed railway engineering practice in the newly built Yun-Gui high-speed railway expansive soil section in China, indoor vibration test on a full-scaled new cutting subgrade model is carried out. Based on the established track-subgrade-foundation of expansive soil system dynamic model test platform, dynamic behavior of new cutting subgrade structure under train loads coupling with extreme service environment(dry, raining, and groundwater level rising) is analyzed comparatively. The results show that the subgrade dynamic response is significantly influenced by service conditions and the dynamic response of subgrade gradually becomes stable with the increasing vibration times under various service environment conditions. The vertical dynamic soil stress is related with the depth in an approximate exponential function, and the curves of vertical dynamic soil stress present a "Z" shape distribution along transverse distance. The peak value of dynamic soil stress appears below the rail, and it increases more obviously near the roadbed surface. However, the peak value of dynamic soil stress is little affected outside 5.0 m of center line. The vibration velocity and acceleration are in a quadratic curve with an increase in depth, and the raining and groundwater level rising increase both the vibration velocity and the acceleration. The vertical deformations at different depths are differently affected by service environment in roadbed. The deformation of roadbed increases sharply when the water gets in the foundation of expansive soil, and more than 60% of the total deformation of roadbed occurs in expansive soil foundation. The laid waterproofing and drainage structure layer, which weakens the dynamic stress and improves the track regularity, presents a positive effect on the control deformation of roadbed surface. An improved empirical formula is then proposed to predict the dynamic stress of ballasted tracks subgrade of expansive soil.
基金supported by the National Natural Science Foundation of China(61671469)
文摘Inverse synthetic aperture radar (ISAR) image can be represented and reconstructed by sparse recovery (SR) approaches. However, the existing SR algorithms, which are used for ISAR imaging, have suffered from high computational cost and poor imaging quality under a low signal to noise ratio (SNR) condition. This paper proposes a fast decoupled ISAR imaging method by exploiting the inherent structural sparse information of the targets. Firstly, the ISAR imaging problem is decoupled into two sub-problems. One is range direction imaging and the other is azimuth direction focusing. Secondly, an efficient two-stage SR method is proposed to obtain higher resolution range profiles by using jointly sparse information. Finally, the residual linear Bregman iteration via fast Fourier transforms (RLBI-FFT) is proposed to perform the azimuth focusing on low SNR efficiently. Theoretical analysis and simulation results show that the proposed method has better performence to efficiently implement higher-resolution ISAR imaging under the low SNR condition.
