The solid electrolyte interphase(SEI)layer,formed on the electrode through electrolyte decomposition,has garnered significant attention over the past several decades.Numerous characterization studies have shown that t...The solid electrolyte interphase(SEI)layer,formed on the electrode through electrolyte decomposition,has garnered significant attention over the past several decades.Numerous characterization studies have shown that the SEI enhances the stability of both the electrolyte and electrode,particularly by mitigating the well-known cation-solvent co-intercalation in graphite electrodes in lithium-ion batteries.However,recent electrolyte exchange experiments have revealed that variations in electrolyte solvation structure and the resulting desolvation behaviors play a more dominant role than the SEI in influencing electrolyte and electrode stability,which in turn critically impacts battery performance.In addition to contributing to the ongoing debate,electrolyte exchange experiments have proven to be a valuable tool for analyzing failures in electrolytes,electrodes,and batteries.This review highlights the application of electrolyte exchange experiments across various metal-ion batteries,incorporating diverse combinations of electrolytes and electrodes.It examines the influence of electrolyte solvation structures and desolvation behaviors on the stability of both electrolytes and electrodes.The aim is to enhance the methodology of electrolyte exchange experiments to deepen the understanding of the molecular interactions among metal ions,anions,and solvents within the electrolyte.This approach complements existing insights into SEI effects,providing a more thorough and accurate framework for battery failure analysis.展开更多
Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical cha...Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel.展开更多
A half-size prototype of the multi wire drift chamber for the cooling storage ring external-target experiment(CEE)was assembled and tested in the 350 MeV/u Kr+Fe reactions at the heavy-ion research facility in Lanzhou...A half-size prototype of the multi wire drift chamber for the cooling storage ring external-target experiment(CEE)was assembled and tested in the 350 MeV/u Kr+Fe reactions at the heavy-ion research facility in Lanzhou.The prototype consists of six sense layers,where the sense wires are stretched in three directions X,U,and V;meeting 0?,30?,and-30?,respectively,with respect to the vertical axis.The sensitive area of the prototype is 76 cm×76 cm.The amplified and shaped signals from the anode wires were digitized in a serial capacity array.When operating at a high voltage of 1500 V on the anode wires,the efficiency for each layer is greater than 95%.The tracking residual is approximately 301±2μm.This performance satisfies the requirements of CEE.展开更多
Sandy braided river deposits are widely preserved in ancient stratigraphic records and act as a significant type of hydrocarbon reservoir.Due to the frequent and rapid migration of channels within the riverbed,the sed...Sandy braided river deposits are widely preserved in ancient stratigraphic records and act as a significant type of hydrocarbon reservoir.Due to the frequent and rapid migration of channels within the riverbed,the sedimentary architecture is highly complex.In this paper,a flume experiment was conducted to reveal the detailed depositional process and establish a fine sedimentary architecture model for sandy braided rivers.The result showed that(1)Three types of braid channels,including the lateral migration channel,the confluence channel,and the deep incised channel,were recognized based on geometry,scale,distribution,and spatial patterns;they are interconnected,forming a complex channel network.(2)Braid channels were characterized by lateral migration,abandonment,filling,and chute cutoff.Lateral migration of channels shaped the braid bars and dominated the formation,growth,and reworking of braid bars.(3)Controlled by the fast and frequent variations of the braid channel network,braid bars were continuously formed,reworked,reshaped,and composited of multiple accretions with different types,orientations,scales,and preservation degrees.Symmetrical and asymmetrical braid bars pre-sented significantly different composition patterns.(4)Dominated by the continuous reworking of braid channels,temporary deposits were limited preserved,braid channel deposits account for 54.3 percent of the eventually preserved braided river deposits,and four types of amalgamate patterns were recognized.Braid bars were cut and limited preserved,only accounting for 45.7 percent of the eventually preserved braided river deposits.(5)During the experiment,only 28 percent of near-surface temporary deposits were eventually preserved in fragmented forms with the final experimental braided river;the shape,spatial patterns,and most of the deposits observed during the depositional process were largely reworked and poorly preserved.(6)The scale of eventually preserved braid bars and braid channels is significantly smaller than the temporary deposits from geomorphic observations.The aspect ratio of the eventually preserved braid bars and the width-to-depth ratio of the eventually preserved braid channel are also significantly different from that of the temporary ones measured from topography data.展开更多
Lead(Pb)plays a significant role in the nuclear industry and is extensively used in radiation shielding,radiation protection,neutron moderation,radiation measurements,and various other critical functions.Consequently,...Lead(Pb)plays a significant role in the nuclear industry and is extensively used in radiation shielding,radiation protection,neutron moderation,radiation measurements,and various other critical functions.Consequently,the measurement and evaluation of Pb nuclear data are highly regarded in nuclear scientific research,emphasizing its crucial role in the field.Using the time-of-flight(ToF)method,the neutron leakage spectra from three^(nat)Pb samples were measured at 60°and 120°based on the neutronics integral experimental facility at the China Institute of Atomic Energy(CIAE).The^(nat)Pb sample sizes were30 cm×30 cm×5 cm,30 cm×30 cm×10 cm,and 30 cm×30 cm×15 cm.Neutron sources were generated by the Cockcroft-Walton accelerator,producing approximately 14.5 MeV and 3.5 MeV neutrons through the T(d,n)^(4)He and D(d,n)^(3)He reactions,respectively.Leakage neutron spectra were also calculated by employing the Monte Carlo code of MCNP-4C,and the nuclear data of Pb isotopes from four libraries:CENDL-3.2,JEFF-3.3,JENDL-5,and ENDF/B-Ⅷ.0 were used individually.By comparing the simulation and experimental results,improvements and deficiencies in the evaluated nuclear data of the Pb isotopes were analyzed.Most of the calculated results were consistent with the experimental results;however,a few areas did not fit well.In the(n,el)energy range,the simulated results from CENDL-3.2 were significantly overestimated;in the(n,inl)D and the(n,inl)C energy regions,the results from CENDL-3.2 and ENDF/B-Ⅷ.0 were significantly overestimated at 120°,and the results from JENDL-5 and JEFF-3.3 are underestimated at 60°in the(n,inl)D energy region.The calculated spectra were analyzed by comparing them with the experimental spectra in terms of the neutron spectrum shape and C/E values.The results indicate that the theoretical simulations,using different data libraries,overestimated or underestimated the measured values in certain energy ranges.Secondary neutron energies and angular distributions in the data files have been presented to explain these discrepancies.展开更多
The exploration of Mars would heavily rely on Martian rocks mechanics and engineering technology.As the mechanical property of Martian rocks is uncertain,it is of utmost importance to predict the probability distribut...The exploration of Mars would heavily rely on Martian rocks mechanics and engineering technology.As the mechanical property of Martian rocks is uncertain,it is of utmost importance to predict the probability distribution of Martian rocks mechanical property for the success of Mars exploration.In this paper,a fast and accurate probability distribution method for predicting the macroscale elastic modulus of Martian rocks was proposed by integrating the microscale rock mechanical experiments(micro-RME),accurate grain-based modeling(AGBM)and upscaling methods based on reliability principles.Firstly,the microstructure of NWA12564 Martian sample and elastic modulus of each mineral were obtained by micro-RME with TESCAN integrated mineral analyzer(TIMA)and nanoindentation.The best probability distribution function of the minerals was determined by Kolmogorov-Smirnov(K-S)test.Secondly,based on best distribution function of each mineral,the Monte Carlo simulations(MCS)and upscaling methods were implemented to obtain the probability distribution of upscaled elastic modulus.Thirdly,the correlation between the upscaled elastic modulus and macroscale elastic modulus obtained by AGBM was established.The accurate probability distribution of the macroscale elastic modulus was obtained by this correlation relationship.The proposed method can predict the probability distribution of Martian rocks mechanical property with any size and shape samples.展开更多
In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional t...In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and dopants.These changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical performance.We unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles calculations.This holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for SIBs.We also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT computations.Our review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.展开更多
Photocatalysis,a critical strategy for harvesting sunlight to address energy demand and environmental concerns,is underpinned by the discovery of high-performance photocatalysts,thereby how to design photocatalysts is...Photocatalysis,a critical strategy for harvesting sunlight to address energy demand and environmental concerns,is underpinned by the discovery of high-performance photocatalysts,thereby how to design photocatalysts is now generating widespread interest in boosting the conversion effi-ciency of solar energy.In the past decade,computational technologies and theoretical simulations have led to a major leap in the development of high-throughput computational screening strategies for novel high-efficiency photocatalysts.In this viewpoint,we started with introducing the challenges of photocatalysis from the view of experimental practice,especially the inefficiency of the traditional“trial and error”method.Sub-sequently,a cross-sectional comparison between experimental and high-throughput computational screening for photocatalysis is presented and discussed in detail.On the basis of the current experimental progress in photocatalysis,we also exemplified the various challenges associated with high-throughput computational screening strategies.Finally,we offered a preferred high-throughput computational screening procedure for pho-tocatalysts from an experimental practice perspective(model construction and screening,standardized experiments,assessment and revision),with the aim of a better correlation of high-throughput simulations and experimental practices,motivating to search for better descriptors.展开更多
The Large Hadron Collider(LHC), the world's largest and most powerful particle accelerator, has been a pivotal tool in advancing our understanding of fundamental physics. By colliding heavy ions, such as lead ions...The Large Hadron Collider(LHC), the world's largest and most powerful particle accelerator, has been a pivotal tool in advancing our understanding of fundamental physics. By colliding heavy ions, such as lead ions, the LHC recreates conditions similar to those just after the Big Bang. This allows scientists to study the quark-gluon plasma(QGP), a state of matter in which quarks and gluons are not confned within protons and neutrons. These studies provide valuable insights into the strong force and the behavior of the early universe. In this paper, we present a comprehensive overview of recent signifcant fndings from A Large Ion Collider Experiment(ALICE) at the LHC. The topics covered include measurements related to the properties of the QGP, particle production, fow and correlations, dileptons, quarkonia, and electromagnetic probes, heavy favor, and jets. Additionally, we introduce future plans for detector upgrades in the ALICE experiment.展开更多
Bottom water coning is the main reason to reduce the recovery of horizontal bottom water reservoir. By water coning, we mean the oil-water interface changes from a horizontal state to a mound-shaped cone and breaks th...Bottom water coning is the main reason to reduce the recovery of horizontal bottom water reservoir. By water coning, we mean the oil-water interface changes from a horizontal state to a mound-shaped cone and breaks through to the wellbore. Autonomous inflow control device(AICD) is an important instrument maintain normal production after bottom water coning, however, the resistance increasing ability of the swirl type AICD is insufficient at present, which seriously affects the water control effect. Aiming this problem, this paper designs a multi-stage resistance-increasing and composite type AICD. The separation mechanism of oil-water two phases in this structure, the resistance form of oil-water single phase and the resistance-increasing principle of water phase are analyzed. Establishing the dual-phase multi-stage separation and resistance-increasing model, and verified by measuring the throttling pressure drop and oil-water volume fraction of the AICD, it is found that the composite type AICD has the effect of ICD and AICD at the same time, which can balance the production rate of each well section at the initial stage of production, delay the occurrence of bottom water coning. In the middle and later stages of production, water-blocking can be effectively increased to achieve water control and stable production.After structural sensitivity analysis, the influence law of various structural parameters on the water control performance of composite AICD was obtained. The simulation calculation results show that,compared with the existing swirl type AICD, composite AICD has higher sensitivity to moisture content,the water phase throttling pressure drop is increased by 4.5 times on average. The composite AICD is suitable for the entire stage of horizontal well production.展开更多
Corrosion leakages often occur in the air cooler of a hydrocracking unit,with the failure sites mainly located in the entrance area of the tubes.An analysis of the macroscopic morphology and corrosion products confirm...Corrosion leakages often occur in the air cooler of a hydrocracking unit,with the failure sites mainly located in the entrance area of the tubes.An analysis of the macroscopic morphology and corrosion products confirmed that the damage was caused by erosion-corrosion(E-C).Numerical and experimental methods were applied to investigate the E-C mechanism in the air cooler.Computational fluid dynamics(CFD)was used to calculate the hydrodynamic parameters of the air cooler.The results showed that there was a biased flow in the air cooler,which led to a significant increase in velocity,turbulent kinetic energy and wall shear within 0.2 m of the tube entrance.A visualization experiment was then performed to determine the principles of migration and transformation of multiphase flow in the air cooler tubes.Various flow patterns(pure droplet flow,mist flow,and annular flow)and their evolutionary processes were clearly depicted experimentally.The initiation mechanism and processes leading to the development of E-C in the air cooler were also determined.This study provided a comprehensive explanation for the E-C failures that occur in air coolers during operation.展开更多
A manipulator-type docking hardware-in-the-loop(HIL)simulation system is proposed in this paper,with further development of the space docking technology and corresponding requirements of the engineering project.First,...A manipulator-type docking hardware-in-the-loop(HIL)simulation system is proposed in this paper,with further development of the space docking technology and corresponding requirements of the engineering project.First,the structure of the manipulator-type HIL simulation system is explained.The mass and the flexibility of the manipulator has an important influence on the stability of the HIL system,which is the premise of accurately simulating actual space docking.Thus,the docking HIL simulation models of rigid,flexible and flexible-light space manipulators are established.The characteristics of the three HIL systems are studied from three important aspects:the system parameter configuration relation,the system stability condition and the dynamics frequency simulation ability.The key conclusions obtained were that the system satisfies stability or reproduction accuracy.Meanwhile,the influence of different manipulators on the system stability is further analyzed.The accuracy of the calculated results is verified experimentally.展开更多
The DarkSHINE experiment proposes a novel approach to single-electron-on-fixed-target exploration that focuses on the search for dark photons through their invisible decay into dark matter particles.Central to this in...The DarkSHINE experiment proposes a novel approach to single-electron-on-fixed-target exploration that focuses on the search for dark photons through their invisible decay into dark matter particles.Central to this initiative is an advanced tracking detector designed to achieve exceptional sensitivity in the detection of light dark matter candidates.This study evaluates the performance of several prototype AC-coupled low-gain avalanche diode(AC-LGAD)strip sensors specifically developed for the DarkSHINE tracking detector.The electrical properties of the sensors from two batches of wafers with different n^(+)doses are thoroughly evaluated.Spatial and temporal resolutions are measured using an infrared laser source.The spatial resolutions range from 6.5 to 8.2μm and from 8.8 to 12.3μm for the sensors from two distinct dose batches,each with a 100μm pitch size.Furthermore,the sensors demonstrate time resolutions of 8.3 and 11.4 ps,underscoring the potential of AC-LGAD technology in enhancing the performance of the DarkSHINE tracking detector.展开更多
The order-of-addition experiments are widely used in many fields,including food and industrial production,but the relative research under prior constraints is limited.The purpose of this paper is to select an optimal ...The order-of-addition experiments are widely used in many fields,including food and industrial production,but the relative research under prior constraints is limited.The purpose of this paper is to select an optimal sequence under the restriction that component i is added before component j,while it is unachievable to compare all sequences when the number of components m is large.To achieve this,a constrained PWO model is first provided,and then the D-optimal designs for order-of addition experiments with minimal-points via the modified threshold accepting algorithm is established.The effectiveness of the proposed method is demonstrated through a job scheduling problem with a prior constraint for teaching cases.展开更多
This study presents the ballistic limit velocity of small caliber projectiles against SS400 steel plate derived from live-fire ballistic experiments. Four different small caliber projectiles were tested against SS400 ...This study presents the ballistic limit velocity of small caliber projectiles against SS400 steel plate derived from live-fire ballistic experiments. Four different small caliber projectiles were tested against SS400 steel plates of 9 mm, 10 mm, and 12 mm thicknesses. The ballistic limit velocity was calculated using two standard methods, MIL-STD-662F and NIJ-STD-0101.06, and additionally using a support vector machine algorithm. The results show a linear relationship between the plate thickness and ballistic limit velocity. Further, the relative penetration performance among five different small caliber projectiles was analyzed using the Penetration Performance Ratio(PPR) introduced in this study, which suggests the potential of PPR to predict the ballistic limit velocity of other untested materials and/or different projectiles.展开更多
This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing...This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing,logging calculation,and seismic inversion technology,we obtained the current insitu stress characteristics of a single well and rock mechanical parameters.Simultaneously,significant controlling factors of rock mechanical properties were analyzed.Subsequently,by coupling hydraulic fracturing physical experiments with finite element numerical simulation,three different fracturing models were configured:single-cluster,double-cluster,and triple-cluster perforations.Combined with acoustic emission technology,the fracture initiation mode and evolution characteristics during the loading process were determined.The results indicate the following findings:(1)The extension direction and length of the fracture are significantly controlled by the direction of the maximum horizontal principal stress.(2)Areas with poor cementation and compactness exhibit complex fracture morphology,prone to generating network fractures.(3)The interlayer development of fracturing fractures is controlled by the strata occurrence.(4)Increasing the displacement of fracturing fluid enlarges the fracturing fracture length and height.This research provides theoretical support and effective guidance for hydraulic fracturing design in tight oil and gas reservoirs.展开更多
We report on the theoretical and experimental investigations of the transition of a typical quantum system with mixed regular-integrable classical dynamics to one with violated time-reversal(T)invariance.The measureme...We report on the theoretical and experimental investigations of the transition of a typical quantum system with mixed regular-integrable classical dynamics to one with violated time-reversal(T)invariance.The measurements are performed with a flat superconducting microwave resonator with circular shape in which chaoticity is induced by using either long antennas or inserting two circular disks into the cavity,and by magnetizing a ferrite disk placed at its center,which leads to violation of T invariance.We propose an extension of the Rosenzweig-Porter(RP)model,which interpolates between mixed regular-chaotic instead of integrable dynamics and fully chaotic dynamics with violated T-invariance,and derive a Wigner-surmise like analytical expression for the corresponding nearest-neighbor spacing distribution.We propose a procedure involving this result and those for the RP model to determine the size of T-invariance violation and chaoticity and validate it employing the experimental eigenfrequency spectra.展开更多
Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Slidi...Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Sliding Mode Controller(MPA-SMC)are proposed for such sloshing experiments.The simulator consists of a Stewart platform and a steel framework.The Stewart platform is located at the column's center of gravity(CoG)and supported by the steel framework.The platform's hydraulic servo system is controlled by a sliding mode controller with parameters optimized by MPA to improve robustness and precision.A numerical sloshing experiment is conducted using the proposed device and controller.The results show that the novel motion simulator has lower torque during the column sloshes,and the proposed controller performs better than a well-tuned PID controller in terms of target tracking precision and anti-interference capability.展开更多
The Chinese Academy of Engineering Physics Terahertz Free Electron Laser Facility(CAEP THz FEL,CTFEL)is the only high-average power free electron laser terahertz source based on superconducting accelerators in China.T...The Chinese Academy of Engineering Physics Terahertz Free Electron Laser Facility(CAEP THz FEL,CTFEL)is the only high-average power free electron laser terahertz source based on superconducting accelerators in China.The update of the CTFEL is now undergoing and will expand the frequency range from 0.1–4.2 THz to 0.1–125 THz.Two experimental stations for material spectroscopy and biomedicine will be built.A high harmonic generation(HHG)lightsource based beamline at the material spectroscopy experimental station for time-resolved angle-resolved photoemission spectroscopy(ARPES)research will be constructed and the optical design is presented.The HHG lightsource covers the extreme ultraviolet(XUV)photon energy range of 20–50 eV.A Czerny–Turner monochromator with two plane gratings worked in conical diffraction configuration is employed to maintain the transmission efficiency and preserve the pulse time duration.The calculated beamline transmission efficiency is better than 5%in the whole photon energy range.To our knowledge,this is the first time in China to combine THz-infrared FEL with HHG light source,and this experimental station will be a powerful and effective instrument that will give new research opportunities in the future for users doing research on the dynamic evolution of the excited electron band structure of a material’s surface.展开更多
Although many studies based on naturally deformed samples have been carried out to investigate the pore-crack characteristics of shales,studies based on high temperature(T)and high pressure(P)deformation experiments,w...Although many studies based on naturally deformed samples have been carried out to investigate the pore-crack characteristics of shales,studies based on high temperature(T)and high pressure(P)deformation experiments,which can exclude sample heterogeneity factors,simulate deep T-P conditions,and generate a continuous deformation sequence,are still rare.In this study,shales with different deformation levels are generated by triaxial compression experiments,and methods including scanning electron microscopy,mercury injection,and gas sorption are utilized to characterize their influence factors and pore-crack characteristics.Results indicate that T is the primary factor influencing shale deformation when P is low,while P is dominant under high P conditions.At T<90℃ and P<60 MPa,shales undergo brittle deformation and their macropores decrease due to the compaction of primary pores,while mesopores increase because of the interconnection of micropores.At 90℃<T<200℃ and 60 MPa<P<110 MPa,shales experience brittle-ductile transitional deformation,and their macro-and micropores increase because of the extension of open cracks and the plastic deformation of clay flakes respectively,while mesopores decrease dramatically.At T>200℃ and P>110 MPa,shales are subjected to ductile deformation,and their micro-and mesopores drop significantly due to the intense compaction in the matrix while macropores continuously increase with crack expansion.The permeability of shale increases with the degree of deformation and ductile material contents are predicted to be a key factor determining whether open microcracks can be preserved after ductile deformation.To account for these experimental results,an ideal model of micro pore-crack system evolution in deformed shales is further proposed,which can provide guidance for the exploration of shale gas resources in the deep or structurally complex zones.展开更多
基金supported by the Jilin Provincial Scientific and Technological Development Program(YDZJ202401572ZYTS)the Overseas Expertise Introduction Project for Discipline Innovation of China(D18012)+1 种基金Education Department of Jilin Province(JJKH20240678KJ)the National Natural Science Foundation of China(22122904,22109155,22379136)。
文摘The solid electrolyte interphase(SEI)layer,formed on the electrode through electrolyte decomposition,has garnered significant attention over the past several decades.Numerous characterization studies have shown that the SEI enhances the stability of both the electrolyte and electrode,particularly by mitigating the well-known cation-solvent co-intercalation in graphite electrodes in lithium-ion batteries.However,recent electrolyte exchange experiments have revealed that variations in electrolyte solvation structure and the resulting desolvation behaviors play a more dominant role than the SEI in influencing electrolyte and electrode stability,which in turn critically impacts battery performance.In addition to contributing to the ongoing debate,electrolyte exchange experiments have proven to be a valuable tool for analyzing failures in electrolytes,electrodes,and batteries.This review highlights the application of electrolyte exchange experiments across various metal-ion batteries,incorporating diverse combinations of electrolytes and electrodes.It examines the influence of electrolyte solvation structures and desolvation behaviors on the stability of both electrolytes and electrodes.The aim is to enhance the methodology of electrolyte exchange experiments to deepen the understanding of the molecular interactions among metal ions,anions,and solvents within the electrolyte.This approach complements existing insights into SEI effects,providing a more thorough and accurate framework for battery failure analysis.
文摘Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel.
基金supported by the National Natural Science Foundation of China(Nos.11927901,11875301,11875302,U1867214,U1832105,U1832167)the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB34000000)+2 种基金the National Key R&D Program of China(No.2018YFE0205200)the CAS"Light of West China"Programthe Tsinghua University Initiative Scientific Research Program。
文摘A half-size prototype of the multi wire drift chamber for the cooling storage ring external-target experiment(CEE)was assembled and tested in the 350 MeV/u Kr+Fe reactions at the heavy-ion research facility in Lanzhou.The prototype consists of six sense layers,where the sense wires are stretched in three directions X,U,and V;meeting 0?,30?,and-30?,respectively,with respect to the vertical axis.The sensitive area of the prototype is 76 cm×76 cm.The amplified and shaped signals from the anode wires were digitized in a serial capacity array.When operating at a high voltage of 1500 V on the anode wires,the efficiency for each layer is greater than 95%.The tracking residual is approximately 301±2μm.This performance satisfies the requirements of CEE.
基金funded by two projects of the National Natural Science Foundation of China(No.41802123,42130813).
文摘Sandy braided river deposits are widely preserved in ancient stratigraphic records and act as a significant type of hydrocarbon reservoir.Due to the frequent and rapid migration of channels within the riverbed,the sedimentary architecture is highly complex.In this paper,a flume experiment was conducted to reveal the detailed depositional process and establish a fine sedimentary architecture model for sandy braided rivers.The result showed that(1)Three types of braid channels,including the lateral migration channel,the confluence channel,and the deep incised channel,were recognized based on geometry,scale,distribution,and spatial patterns;they are interconnected,forming a complex channel network.(2)Braid channels were characterized by lateral migration,abandonment,filling,and chute cutoff.Lateral migration of channels shaped the braid bars and dominated the formation,growth,and reworking of braid bars.(3)Controlled by the fast and frequent variations of the braid channel network,braid bars were continuously formed,reworked,reshaped,and composited of multiple accretions with different types,orientations,scales,and preservation degrees.Symmetrical and asymmetrical braid bars pre-sented significantly different composition patterns.(4)Dominated by the continuous reworking of braid channels,temporary deposits were limited preserved,braid channel deposits account for 54.3 percent of the eventually preserved braided river deposits,and four types of amalgamate patterns were recognized.Braid bars were cut and limited preserved,only accounting for 45.7 percent of the eventually preserved braided river deposits.(5)During the experiment,only 28 percent of near-surface temporary deposits were eventually preserved in fragmented forms with the final experimental braided river;the shape,spatial patterns,and most of the deposits observed during the depositional process were largely reworked and poorly preserved.(6)The scale of eventually preserved braid bars and braid channels is significantly smaller than the temporary deposits from geomorphic observations.The aspect ratio of the eventually preserved braid bars and the width-to-depth ratio of the eventually preserved braid channel are also significantly different from that of the temporary ones measured from topography data.
基金supported by the National Natural Science Foundation of China(Nos.11775311 and U2067205)the Stable Support Basic Research Program Grant(BJ010261223282)the Research and Development Project of China National Nuclear Corporation。
文摘Lead(Pb)plays a significant role in the nuclear industry and is extensively used in radiation shielding,radiation protection,neutron moderation,radiation measurements,and various other critical functions.Consequently,the measurement and evaluation of Pb nuclear data are highly regarded in nuclear scientific research,emphasizing its crucial role in the field.Using the time-of-flight(ToF)method,the neutron leakage spectra from three^(nat)Pb samples were measured at 60°and 120°based on the neutronics integral experimental facility at the China Institute of Atomic Energy(CIAE).The^(nat)Pb sample sizes were30 cm×30 cm×5 cm,30 cm×30 cm×10 cm,and 30 cm×30 cm×15 cm.Neutron sources were generated by the Cockcroft-Walton accelerator,producing approximately 14.5 MeV and 3.5 MeV neutrons through the T(d,n)^(4)He and D(d,n)^(3)He reactions,respectively.Leakage neutron spectra were also calculated by employing the Monte Carlo code of MCNP-4C,and the nuclear data of Pb isotopes from four libraries:CENDL-3.2,JEFF-3.3,JENDL-5,and ENDF/B-Ⅷ.0 were used individually.By comparing the simulation and experimental results,improvements and deficiencies in the evaluated nuclear data of the Pb isotopes were analyzed.Most of the calculated results were consistent with the experimental results;however,a few areas did not fit well.In the(n,el)energy range,the simulated results from CENDL-3.2 were significantly overestimated;in the(n,inl)D and the(n,inl)C energy regions,the results from CENDL-3.2 and ENDF/B-Ⅷ.0 were significantly overestimated at 120°,and the results from JENDL-5 and JEFF-3.3 are underestimated at 60°in the(n,inl)D energy region.The calculated spectra were analyzed by comparing them with the experimental spectra in terms of the neutron spectrum shape and C/E values.The results indicate that the theoretical simulations,using different data libraries,overestimated or underestimated the measured values in certain energy ranges.Secondary neutron energies and angular distributions in the data files have been presented to explain these discrepancies.
文摘The exploration of Mars would heavily rely on Martian rocks mechanics and engineering technology.As the mechanical property of Martian rocks is uncertain,it is of utmost importance to predict the probability distribution of Martian rocks mechanical property for the success of Mars exploration.In this paper,a fast and accurate probability distribution method for predicting the macroscale elastic modulus of Martian rocks was proposed by integrating the microscale rock mechanical experiments(micro-RME),accurate grain-based modeling(AGBM)and upscaling methods based on reliability principles.Firstly,the microstructure of NWA12564 Martian sample and elastic modulus of each mineral were obtained by micro-RME with TESCAN integrated mineral analyzer(TIMA)and nanoindentation.The best probability distribution function of the minerals was determined by Kolmogorov-Smirnov(K-S)test.Secondly,based on best distribution function of each mineral,the Monte Carlo simulations(MCS)and upscaling methods were implemented to obtain the probability distribution of upscaled elastic modulus.Thirdly,the correlation between the upscaled elastic modulus and macroscale elastic modulus obtained by AGBM was established.The accurate probability distribution of the macroscale elastic modulus was obtained by this correlation relationship.The proposed method can predict the probability distribution of Martian rocks mechanical property with any size and shape samples.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(NRF-2022R1C1C1011058)。
文摘In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and dopants.These changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical performance.We unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles calculations.This holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for SIBs.We also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT computations.Our review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.
基金The authors are grateful for financial support from the National Key Projects for Fundamental Research and Development of China(2021YFA1500803)the National Natural Science Foundation of China(51825205,52120105002,22102202,22088102,U22A20391)+1 种基金the DNL Cooperation Fund,CAS(DNL202016)the CAS Project for Young Scientists in Basic Research(YSBR-004).
文摘Photocatalysis,a critical strategy for harvesting sunlight to address energy demand and environmental concerns,is underpinned by the discovery of high-performance photocatalysts,thereby how to design photocatalysts is now generating widespread interest in boosting the conversion effi-ciency of solar energy.In the past decade,computational technologies and theoretical simulations have led to a major leap in the development of high-throughput computational screening strategies for novel high-efficiency photocatalysts.In this viewpoint,we started with introducing the challenges of photocatalysis from the view of experimental practice,especially the inefficiency of the traditional“trial and error”method.Sub-sequently,a cross-sectional comparison between experimental and high-throughput computational screening for photocatalysis is presented and discussed in detail.On the basis of the current experimental progress in photocatalysis,we also exemplified the various challenges associated with high-throughput computational screening strategies.Finally,we offered a preferred high-throughput computational screening procedure for pho-tocatalysts from an experimental practice perspective(model construction and screening,standardized experiments,assessment and revision),with the aim of a better correlation of high-throughput simulations and experimental practices,motivating to search for better descriptors.
基金National Key Research and Development Program of China (Nos. 2018YFE0104600, 2018YFE0104700, 2018YFE0104800, and 2018YFE0104900)National Natural Science Foundation of China (Nos. 12061141008, 12147101, and 12322508)+1 种基金Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB34000000)Science and Technology Commission of Shanghai Municipality (23590780100)。
文摘The Large Hadron Collider(LHC), the world's largest and most powerful particle accelerator, has been a pivotal tool in advancing our understanding of fundamental physics. By colliding heavy ions, such as lead ions, the LHC recreates conditions similar to those just after the Big Bang. This allows scientists to study the quark-gluon plasma(QGP), a state of matter in which quarks and gluons are not confned within protons and neutrons. These studies provide valuable insights into the strong force and the behavior of the early universe. In this paper, we present a comprehensive overview of recent signifcant fndings from A Large Ion Collider Experiment(ALICE) at the LHC. The topics covered include measurements related to the properties of the QGP, particle production, fow and correlations, dileptons, quarkonia, and electromagnetic probes, heavy favor, and jets. Additionally, we introduce future plans for detector upgrades in the ALICE experiment.
基金supported by National Natural Science Foundation(52204050)Sichuan Science and Technology Program(2021ZHCG0013,22ZDYF3009)。
文摘Bottom water coning is the main reason to reduce the recovery of horizontal bottom water reservoir. By water coning, we mean the oil-water interface changes from a horizontal state to a mound-shaped cone and breaks through to the wellbore. Autonomous inflow control device(AICD) is an important instrument maintain normal production after bottom water coning, however, the resistance increasing ability of the swirl type AICD is insufficient at present, which seriously affects the water control effect. Aiming this problem, this paper designs a multi-stage resistance-increasing and composite type AICD. The separation mechanism of oil-water two phases in this structure, the resistance form of oil-water single phase and the resistance-increasing principle of water phase are analyzed. Establishing the dual-phase multi-stage separation and resistance-increasing model, and verified by measuring the throttling pressure drop and oil-water volume fraction of the AICD, it is found that the composite type AICD has the effect of ICD and AICD at the same time, which can balance the production rate of each well section at the initial stage of production, delay the occurrence of bottom water coning. In the middle and later stages of production, water-blocking can be effectively increased to achieve water control and stable production.After structural sensitivity analysis, the influence law of various structural parameters on the water control performance of composite AICD was obtained. The simulation calculation results show that,compared with the existing swirl type AICD, composite AICD has higher sensitivity to moisture content,the water phase throttling pressure drop is increased by 4.5 times on average. The composite AICD is suitable for the entire stage of horizontal well production.
基金supported by the National Key R&D Program of China(2021YFB3301100)Beijing University of Chemical Technology Interdisciplinary Program(XK2023-07).
文摘Corrosion leakages often occur in the air cooler of a hydrocracking unit,with the failure sites mainly located in the entrance area of the tubes.An analysis of the macroscopic morphology and corrosion products confirmed that the damage was caused by erosion-corrosion(E-C).Numerical and experimental methods were applied to investigate the E-C mechanism in the air cooler.Computational fluid dynamics(CFD)was used to calculate the hydrodynamic parameters of the air cooler.The results showed that there was a biased flow in the air cooler,which led to a significant increase in velocity,turbulent kinetic energy and wall shear within 0.2 m of the tube entrance.A visualization experiment was then performed to determine the principles of migration and transformation of multiphase flow in the air cooler tubes.Various flow patterns(pure droplet flow,mist flow,and annular flow)and their evolutionary processes were clearly depicted experimentally.The initiation mechanism and processes leading to the development of E-C in the air cooler were also determined.This study provided a comprehensive explanation for the E-C failures that occur in air coolers during operation.
基金Supported by the National Natural Science Foundation of China(51475116)。
文摘A manipulator-type docking hardware-in-the-loop(HIL)simulation system is proposed in this paper,with further development of the space docking technology and corresponding requirements of the engineering project.First,the structure of the manipulator-type HIL simulation system is explained.The mass and the flexibility of the manipulator has an important influence on the stability of the HIL system,which is the premise of accurately simulating actual space docking.Thus,the docking HIL simulation models of rigid,flexible and flexible-light space manipulators are established.The characteristics of the three HIL systems are studied from three important aspects:the system parameter configuration relation,the system stability condition and the dynamics frequency simulation ability.The key conclusions obtained were that the system satisfies stability or reproduction accuracy.Meanwhile,the influence of different manipulators on the system stability is further analyzed.The accuracy of the calculated results is verified experimentally.
基金supported by the National Natural Science Foundation of China(No.12150006)Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(No.21TQ1400209)the Young Talents of National Talent Support Programs(No.24Z130300579).
文摘The DarkSHINE experiment proposes a novel approach to single-electron-on-fixed-target exploration that focuses on the search for dark photons through their invisible decay into dark matter particles.Central to this initiative is an advanced tracking detector designed to achieve exceptional sensitivity in the detection of light dark matter candidates.This study evaluates the performance of several prototype AC-coupled low-gain avalanche diode(AC-LGAD)strip sensors specifically developed for the DarkSHINE tracking detector.The electrical properties of the sensors from two batches of wafers with different n^(+)doses are thoroughly evaluated.Spatial and temporal resolutions are measured using an infrared laser source.The spatial resolutions range from 6.5 to 8.2μm and from 8.8 to 12.3μm for the sensors from two distinct dose batches,each with a 100μm pitch size.Furthermore,the sensors demonstrate time resolutions of 8.3 and 11.4 ps,underscoring the potential of AC-LGAD technology in enhancing the performance of the DarkSHINE tracking detector.
基金supported by National Natural Science Foundation of China(Grant Nos.11971204,12271270)Natural Science Foundation of Jiangsu Province of China(Grant No.BK20200108)the Zhongwu Youth Innovative Talent Program of Jiangsu University of Technology and the Third Level Training Object of the Sixth“333 Project”in Jiangsu Province。
文摘The order-of-addition experiments are widely used in many fields,including food and industrial production,but the relative research under prior constraints is limited.The purpose of this paper is to select an optimal sequence under the restriction that component i is added before component j,while it is unachievable to compare all sequences when the number of components m is large.To achieve this,a constrained PWO model is first provided,and then the D-optimal designs for order-of addition experiments with minimal-points via the modified threshold accepting algorithm is established.The effectiveness of the proposed method is demonstrated through a job scheduling problem with a prior constraint for teaching cases.
文摘This study presents the ballistic limit velocity of small caliber projectiles against SS400 steel plate derived from live-fire ballistic experiments. Four different small caliber projectiles were tested against SS400 steel plates of 9 mm, 10 mm, and 12 mm thicknesses. The ballistic limit velocity was calculated using two standard methods, MIL-STD-662F and NIJ-STD-0101.06, and additionally using a support vector machine algorithm. The results show a linear relationship between the plate thickness and ballistic limit velocity. Further, the relative penetration performance among five different small caliber projectiles was analyzed using the Penetration Performance Ratio(PPR) introduced in this study, which suggests the potential of PPR to predict the ballistic limit velocity of other untested materials and/or different projectiles.
基金supported by the Major Scientific and Technological Projects of CNPC under grant ZD2019-183-006the National Science and Technology Major Project of China(2016ZX05014002-006)the National Natural Science Foundation of China(42072234)。
文摘This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing,logging calculation,and seismic inversion technology,we obtained the current insitu stress characteristics of a single well and rock mechanical parameters.Simultaneously,significant controlling factors of rock mechanical properties were analyzed.Subsequently,by coupling hydraulic fracturing physical experiments with finite element numerical simulation,three different fracturing models were configured:single-cluster,double-cluster,and triple-cluster perforations.Combined with acoustic emission technology,the fracture initiation mode and evolution characteristics during the loading process were determined.The results indicate the following findings:(1)The extension direction and length of the fracture are significantly controlled by the direction of the maximum horizontal principal stress.(2)Areas with poor cementation and compactness exhibit complex fracture morphology,prone to generating network fractures.(3)The interlayer development of fracturing fractures is controlled by the strata occurrence.(4)Increasing the displacement of fracturing fluid enlarges the fracturing fracture length and height.This research provides theoretical support and effective guidance for hydraulic fracturing design in tight oil and gas reservoirs.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11775100,12247101,and 11961131009)the financial support from the China Scholarship Council(Grant No.CSC202306180087)the financial support from the Institute for Basic Science in Korea(Grant No.IBS-R024-D1)。
文摘We report on the theoretical and experimental investigations of the transition of a typical quantum system with mixed regular-integrable classical dynamics to one with violated time-reversal(T)invariance.The measurements are performed with a flat superconducting microwave resonator with circular shape in which chaoticity is induced by using either long antennas or inserting two circular disks into the cavity,and by magnetizing a ferrite disk placed at its center,which leads to violation of T invariance.We propose an extension of the Rosenzweig-Porter(RP)model,which interpolates between mixed regular-chaotic instead of integrable dynamics and fully chaotic dynamics with violated T-invariance,and derive a Wigner-surmise like analytical expression for the corresponding nearest-neighbor spacing distribution.We propose a procedure involving this result and those for the RP model to determine the size of T-invariance violation and chaoticity and validate it employing the experimental eigenfrequency spectra.
文摘Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Sliding Mode Controller(MPA-SMC)are proposed for such sloshing experiments.The simulator consists of a Stewart platform and a steel framework.The Stewart platform is located at the column's center of gravity(CoG)and supported by the steel framework.The platform's hydraulic servo system is controlled by a sliding mode controller with parameters optimized by MPA to improve robustness and precision.A numerical sloshing experiment is conducted using the proposed device and controller.The results show that the novel motion simulator has lower torque during the column sloshes,and the proposed controller performs better than a well-tuned PID controller in terms of target tracking precision and anti-interference capability.
基金supported by Major Instrument Projects of Sichuan Province.
文摘The Chinese Academy of Engineering Physics Terahertz Free Electron Laser Facility(CAEP THz FEL,CTFEL)is the only high-average power free electron laser terahertz source based on superconducting accelerators in China.The update of the CTFEL is now undergoing and will expand the frequency range from 0.1–4.2 THz to 0.1–125 THz.Two experimental stations for material spectroscopy and biomedicine will be built.A high harmonic generation(HHG)lightsource based beamline at the material spectroscopy experimental station for time-resolved angle-resolved photoemission spectroscopy(ARPES)research will be constructed and the optical design is presented.The HHG lightsource covers the extreme ultraviolet(XUV)photon energy range of 20–50 eV.A Czerny–Turner monochromator with two plane gratings worked in conical diffraction configuration is employed to maintain the transmission efficiency and preserve the pulse time duration.The calculated beamline transmission efficiency is better than 5%in the whole photon energy range.To our knowledge,this is the first time in China to combine THz-infrared FEL with HHG light source,and this experimental station will be a powerful and effective instrument that will give new research opportunities in the future for users doing research on the dynamic evolution of the excited electron band structure of a material’s surface.
基金supported by the National Natural Science Foundation of China(Grant Nos.42372153,41530315)the National Key Research and Development Program of China(Grant No.2023YFF0804300)+1 种基金the National Science and Technology Major Project of China(Grant Nos.2016ZX05066,2017ZX05064)the“Climate Change:Carbon Budget and Related Issues”Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA05030100)。
文摘Although many studies based on naturally deformed samples have been carried out to investigate the pore-crack characteristics of shales,studies based on high temperature(T)and high pressure(P)deformation experiments,which can exclude sample heterogeneity factors,simulate deep T-P conditions,and generate a continuous deformation sequence,are still rare.In this study,shales with different deformation levels are generated by triaxial compression experiments,and methods including scanning electron microscopy,mercury injection,and gas sorption are utilized to characterize their influence factors and pore-crack characteristics.Results indicate that T is the primary factor influencing shale deformation when P is low,while P is dominant under high P conditions.At T<90℃ and P<60 MPa,shales undergo brittle deformation and their macropores decrease due to the compaction of primary pores,while mesopores increase because of the interconnection of micropores.At 90℃<T<200℃ and 60 MPa<P<110 MPa,shales experience brittle-ductile transitional deformation,and their macro-and micropores increase because of the extension of open cracks and the plastic deformation of clay flakes respectively,while mesopores decrease dramatically.At T>200℃ and P>110 MPa,shales are subjected to ductile deformation,and their micro-and mesopores drop significantly due to the intense compaction in the matrix while macropores continuously increase with crack expansion.The permeability of shale increases with the degree of deformation and ductile material contents are predicted to be a key factor determining whether open microcracks can be preserved after ductile deformation.To account for these experimental results,an ideal model of micro pore-crack system evolution in deformed shales is further proposed,which can provide guidance for the exploration of shale gas resources in the deep or structurally complex zones.
