Sodium chlorate is a no coloured,no smell and no poisonous transparent crystal with the formula of NaClO 3.Its structure belongs to the cubic( T 23)class and exhibits optical activity.The space group is P 2 13 and the...Sodium chlorate is a no coloured,no smell and no poisonous transparent crystal with the formula of NaClO 3.Its structure belongs to the cubic( T 23)class and exhibits optical activity.The space group is P 2 13 and there are four molecules per cubic unit cell with a =0.6570nm.We chose the crystal as a research system based on two reasons:(1)since the crystal structure belongs to the cubic class,the crystal faces,such as(100),(010),(001)are possessed of homogeneity,it is the suitable system for studying kinetics of crystal growth;(2)since the solubility of the NaClO 3 is higher in the H 2O and the crystal could be grown from low temperature solution,this is a suitable system for studying a influence of gravity on the boundary layer characteristics of the crystal growth under the microgravity condition.展开更多
Process of crystal growth can be controlled by both surface kinetics and by volume transport as well.Although the complicated relation between the surface kinetics and volume transport exsits,generally,they are studie...Process of crystal growth can be controlled by both surface kinetics and by volume transport as well.Although the complicated relation between the surface kinetics and volume transport exsits,generally,they are studied seprately.Due to the mathematical complexity of heat and mass transport equations,the in depth studies of heat and mass transport process become difficult.Most of the studies on the transport were performed for the growth from melt.Most of the work on Surface kinetics has been done for crystal growth from aqueous solution because the in situ observation of crystal growth is easily carried out.In recent years,the surface kinetics studies on the nanometer scale,even atomic scale,are demonstrated by using AFM.展开更多
文摘Sodium chlorate is a no coloured,no smell and no poisonous transparent crystal with the formula of NaClO 3.Its structure belongs to the cubic( T 23)class and exhibits optical activity.The space group is P 2 13 and there are four molecules per cubic unit cell with a =0.6570nm.We chose the crystal as a research system based on two reasons:(1)since the crystal structure belongs to the cubic class,the crystal faces,such as(100),(010),(001)are possessed of homogeneity,it is the suitable system for studying kinetics of crystal growth;(2)since the solubility of the NaClO 3 is higher in the H 2O and the crystal could be grown from low temperature solution,this is a suitable system for studying a influence of gravity on the boundary layer characteristics of the crystal growth under the microgravity condition.
文摘Process of crystal growth can be controlled by both surface kinetics and by volume transport as well.Although the complicated relation between the surface kinetics and volume transport exsits,generally,they are studied seprately.Due to the mathematical complexity of heat and mass transport equations,the in depth studies of heat and mass transport process become difficult.Most of the studies on the transport were performed for the growth from melt.Most of the work on Surface kinetics has been done for crystal growth from aqueous solution because the in situ observation of crystal growth is easily carried out.In recent years,the surface kinetics studies on the nanometer scale,even atomic scale,are demonstrated by using AFM.
