The effects of different yaw angles on the aerodynamic performance of city electric multiple units(EMUs)were investigated in a wind tunnel using a 1:16.8 scaled model.Pressure scanning valve and six-component box-type...The effects of different yaw angles on the aerodynamic performance of city electric multiple units(EMUs)were investigated in a wind tunnel using a 1:16.8 scaled model.Pressure scanning valve and six-component box-type aerodynamic balance were used to test the pressure distribution and aerodynamic force of the head car respectively from the 1.5-and 3-coach grouping city EMU models.Meanwhile,the effects of the yaw angles on the pressure distribution of the streamlined head as well as the aerodynamic forces of the train were analyzed.The experimental results showed that the pressure coefficient was the smallest at the maximum slope of the main shape-line.The side force coefficient and pressure coefficient along the head car cross-section were most affected by crosswind when the yaw angle was 55°,and replacing a 3-coach grouping with a 1.5-coach grouping had obvious advantages for wind tunnel testing when the yaw angle was within 24.2°.In addition,the relative errors of lift coefficient C_(L),roll moment coefficient C_(Mx),side force coefficient C_(S),and drag coefficient C_(D)between the 1.5-and 3-coach cases were below 5.95%,which all met the requirements of the experimental accuracy.展开更多
A novel synthetic aperture radar(SAR)image de-noising method based on the local pixel grouping(LPG)principal component analysis(PCA)and guided filter is proposed.This method contains two steps.In the first step,we pro...A novel synthetic aperture radar(SAR)image de-noising method based on the local pixel grouping(LPG)principal component analysis(PCA)and guided filter is proposed.This method contains two steps.In the first step,we process the noisy image by coarse filters,which can suppress the speckle effectively.The original SAR image is transformed into the additive noise model by logarithmic transform with deviation correction.Then,we use the pixel and its nearest neighbors as a vector to select training samples from the local window by LPG based on the block similar matching.The LPG method ensures that only the similar sample patches are used in the local statistical calculation of PCA transform estimation,so that the local features of the image can be well preserved after coefficients shrinkage in the PCA domain.In the second step,we do the guided filtering which can effectively eliminate small artifacts left over from the coarse filtering.Experimental results of simulated and real SAR images show that the proposed method outstrips the state-of-the-art image de-noising methods in the peak signalto-noise ratio(PSNR),the structural similarity(SSIM)index and the equivalent number of looks(ENLs),and is of perceived image quality.展开更多
For swarm robots moving in a harsh or uncharted outdoor environment without GPS guidance and global communication,algorithms that rely on global-based information are infeasible.Typically,traditional gene regulatory n...For swarm robots moving in a harsh or uncharted outdoor environment without GPS guidance and global communication,algorithms that rely on global-based information are infeasible.Typically,traditional gene regulatory networks(GRNs)that achieve superior performance in forming trapping pattern towards targets require accurate global positional information to guide swarm robots.This article presents a gene regulatory network with Self-organized grouping and entrapping method for swarms(SUNDER-GRN)to achieve adequate trapping performance with a large-scale swarm in a confined multitarget environment with access to only local information.A hierarchical self-organized grouping method(HSG)is proposed to structure subswarms in a distributed way.In addition,a modified distributed controller,with a relative coordinate system that is established to relieve the need for global information,is leveraged to facilitate subswarms entrapment toward different targets,thus improving the global multi-target entrapping performance.The results demonstrate the superiority of SUNDERGRN in the performance of structuring subswarms and entrapping 10 targets with 200 robots in an environment confined by obstacles and with only local information accessible.展开更多
Mobile CrowdSensing(MCS)is a promising sensing paradigm that recruits users to cooperatively perform sensing tasks.Recently,unmanned aerial vehicles(UAVs)as the powerful sensing devices are used to replace user partic...Mobile CrowdSensing(MCS)is a promising sensing paradigm that recruits users to cooperatively perform sensing tasks.Recently,unmanned aerial vehicles(UAVs)as the powerful sensing devices are used to replace user participation and carry out some special tasks,such as epidemic monitoring and earthquakes rescue.In this paper,we focus on scheduling UAVs to sense the task Point-of-Interests(PoIs)with different frequency coverage requirements.To accomplish the sensing task,the scheduling strategy needs to consider the coverage requirement,geographic fairness and energy charging simultaneously.We consider the complex interaction among UAVs and propose a grouping multi-agent deep reinforcement learning approach(G-MADDPG)to schedule UAVs distributively.G-MADDPG groups all UAVs into some teams by a distance-based clustering algorithm(DCA),then it regards each team as an agent.In this way,G-MADDPG solves the problem that the training time of traditional MADDPG is too long to converge when the number of UAVs is large,and the trade-off between training time and result accuracy could be controlled flexibly by adjusting the number of teams.Extensive simulation results show that our scheduling strategy has better performance compared with three baselines and is flexible in balancing training time and result accuracy.展开更多
The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems（LSAS）. The former researches have confirmed...The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems（LSAS）. The former researches have confirmed that the cells groupings time-shift pilots scheme is effective to reduce inter-cell interference, especially pilot contamination, which results from the pilot reuse in adjacent cells. However, they have not specified reasonable cells groupings factor, which plays a critical role in the general performance of the LSAS. Therefore, this problem is researched in details. The time for reverse-link data transmission will be compressed, when the groupings factor surpasses a certain range. Thus it is not always beneficial to increase the cells groupings factor without limitation. Furthermore,a reasonable cells groupings factor is deduced from the perspective of optimization to enhance the system performance. Simulations verify the proposed cell grouping factor.展开更多
A stochastic epidemic model with two age groups is established in this study,in which the susceptible(S),the exposed(E),the infected(I),the hospitalized(H)and the recovered(R)are involved within the total population,t...A stochastic epidemic model with two age groups is established in this study,in which the susceptible(S),the exposed(E),the infected(I),the hospitalized(H)and the recovered(R)are involved within the total population,the aging rates between two age groups are set to be constant.The existence-and-uniqueness of global positive solution is firstly showed.Then,by constructing several appropriate Lyapunov functions and using the high-dimensional Itô’s formula,the sufficient conditions for the stochastic extinction and stochastic persistence of the exposed individuals and the infected individuals are obtained.The stochastic extinction indicator and the stochastic persistence indicator are less-valued expressions compared with the basic reproduction number.Meanwhile,the main results of this study are modified into multi-age groups.Furthermore,by using the surveillance data for Fujian Provincial Center for Disease Control and Prevention,Fuzhou COVID-19 epidemic is chosen to carry out the numerical simulations,which show that the age group of the population plays the vital role when studying infectious diseases.展开更多
Lithium-ion capacitors(LICs)combine the high power dens-ity of electrical double-layer capacitors with the high energy density of lithium-ion batteries.However,they face practical limitations due to the narrow operati...Lithium-ion capacitors(LICs)combine the high power dens-ity of electrical double-layer capacitors with the high energy density of lithium-ion batteries.However,they face practical limitations due to the narrow operating voltage window of their activated carbon(AC)cathodes.We report a scalable thermal treatment strategy to develop high-voltage-tolerant AC cathodes.Through controlled thermal treatment of commer-cial activated carbon(Raw-AC)under a H_(2)/Ar atmosphere at 400-800℃,the targeted reduction of degradation-prone functional groups can be achieved while preserving the critical pore structure and increasing graph-itic microcrystalline ordering.The AC treated at 400℃(HAC-400)had a significant increase in specific capacity(96.0 vs.75.1 mAh/g at 0.05 A/g)and better rate capability(61.1 vs.36.1 mAh/g at 5 A/g)in half-cell LICs,along with an 83.5%capacity retention over 7400 cycles within an extended voltage range of 2.0-4.2 V in full-cell LICs.Scalability was demonstrated by a 120 g batch production,enabling fabrication of pouch-type LICs with commercial hard carbon anodes that delivered a higher energy density of 28.3 Wh/kg at 1 C,and a peak power density of 12.1 kW/kg compared to devices using raw AC.This simple,industry-compatible approach may be used for producing ad-vanced cathode materials for practical high-performance LICs.展开更多
This study constructs a function-private inner-product predicate encryption(FP-IPPE)and achieves standard enhanced function privacy.The enhanced function privacy guarantees that a predicate secret key skf reveals noth...This study constructs a function-private inner-product predicate encryption(FP-IPPE)and achieves standard enhanced function privacy.The enhanced function privacy guarantees that a predicate secret key skf reveals nothing about the predicate f,as long as f is drawn from an evasive distribution with sufficient entropy.The proposed scheme extends the group-based public-key function-private predicate encryption(FP-PE)for“small superset predicates”proposed by Bartusek et al.(Asiacrypt 19),to the setting of inner-product predicates.This is the first construction of public-key FP-PE with enhanced function privacy security beyond the equality predicates,which is previously proposed by Boneh et al.(CRYPTO 13).The proposed construction relies on bilinear groups,and the security is proved in the generic bilinear group model.展开更多
Herein the use of rare-earth compounds in catalytic reduction systems for the end-group functionalization of carboxyl-terminated low-molecularweight fluoropolymers was explored.Leveraging the high catalytic activity a...Herein the use of rare-earth compounds in catalytic reduction systems for the end-group functionalization of carboxyl-terminated low-molecularweight fluoropolymers was explored.Leveraging the high catalytic activity and selectivity of rare-earth compounds along with no residual impact on polymer product's performance,highly efficient catalytic reduction systems containing sodium borohydride(NaBH_(4))and rare-earth chloride(RECl_(3))were specifically designed for a telechelic carboxyl-terminated liquid fluoroeslastomer,aiming to facilitate the conversion of chainend carboxyl groups into hydroxyl groups and improvement in end-group reactivity.To achieve this,lanthanum chloride(LaCl_(3)),cerium chloride(CeCl_(3)),and neodymium chloride(NdCl_(3))were used separately to form catalytic reduction systems with NaBH_(4).The effects of solvent dosage,reaction temperature,reaction time length,and reductant dosage on carboxylic conversion were investigated,and the molecular chain structure,molecular weight,and functional group content of the raw materials and the products were analyzed and characterized by means of infrared spectroscopy(FTIR),proton nuclear magnetic resonance(^(1)H-NMR),fluorine-19 nuclear magnetic resonance(^(19)F-NMR),gel permeation chromatography(GPC),and chemical titration.Moreover,the catalytic activity and selectivity of the rare-earth chlorides,as well as the corresponding underlying interactions were discussed.Results indicated that the rare-earth-containing catalytic reduction systems studied in this work could efficiently convert the chain-end carboxyl groups into highly active hydroxyl groups,with a highest conversion up to 87.0%and differing catalytic reduction activities ranked as NaBH_(4)/CeCl_(3)>NaBH_(4)/LaCl_(3)>NaBH_(4)/NdCl_(3).Compared with the conventional lithium aluminum hydride(LiAIH_(4))reduction system,the NaBH_(4)/RECl_(3)systems provide multiple advantages such as mild reaction conditions,high conversion ratio with good selectivity,and environmental innocuity,and are potentially applicable as new reduction-catalysis combinations for the synthesis and functionalization of polymer materials.展开更多
Reaction of the non-substituted/substituted unsymmetric pinene-derived complex[Pt(N^C^N')Cl]with the aryl isocyanide 2,6-dimethylphenyl isocyanide(CNXyl)afforded a mixture of two isomeric species:the ionic complex...Reaction of the non-substituted/substituted unsymmetric pinene-derived complex[Pt(N^C^N')Cl]with the aryl isocyanide 2,6-dimethylphenyl isocyanide(CNXyl)afforded a mixture of two isomeric species:the ionic complex[Pt(κ^(3)-N^C^N')(CNXyl)]Cl([A]Cl)and the molecular complex[Pt(κ^(2)-N^C^N')(CNXyl)Cl](B).Isomer B was almost the dominating product.The structures of the isomer B derivatives bearing-CF_(3)and-Cl substituents on the pyridine ring of the pinene moiety(5B and 7B,respectively)have been confirmed by single-crystal X-ray diffraction,revealing a slightly distorted square planar geometry with trans-N_(N^C^N'),CNR configuration(The terminal N atom of theκ^(2)-N^C^N'ligand is trans to the isocyanide ligand CNXyl.).Isomer B is thermodynamically more stable,as confirmed by theoretical calculations.CCDC:2416415,5B;2416414,7B.展开更多
Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involv...Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.展开更多
To solve the problem of providing the best initial situation for terminal guidance when multiple missiles intercept multiple targets,a group cooperative midcourse guidance law(GCMGL)considering time-to-go is proposed....To solve the problem of providing the best initial situation for terminal guidance when multiple missiles intercept multiple targets,a group cooperative midcourse guidance law(GCMGL)considering time-to-go is proposed.Firstly,a threedimensional(3D)guidance model is established and a cooperative trajectory shaping guidance law is given.Secondly,for estimating the unknown target maneuvering acceleration,an adaptive disturbance observer(ADO)is designed,combining finitetime theory with a radial basis function(RBF)neural network,and the convergence of the estimation error is proven using Lyapunov stability theory.Then,to ensure time-to-go cooperation among missiles within the same group and across different groups,the group consensus protocols of virtual collision point mean and the inter-group cooperative consensus protocol are designed respectively.Based on the group consensus protocols,the virtual collision point cooperative guidance law is given,and the finite-time convergence is proved by Lyapunov stability theory.Simultaneously,combined with trajectory shaping guidance law,virtual collision point cooperative guidance law and the intergroup cooperative consensus protocol,the design of GCMGL considering time-to-go is given.Finally,numerical simulation results show the effectiveness and the superiority of the proposed GCMGL.展开更多
The seedlings of Vernicia montana derived from seeds soaking with water (the first group)or 300 mg5L -1 mixed nitric_acid rare earth solution (the second group) were treated with various concentrations of mixed nitric...The seedlings of Vernicia montana derived from seeds soaking with water (the first group)or 300 mg5L -1 mixed nitric_acid rare earth solution (the second group) were treated with various concentrations of mixed nitric_acid rare earth solution by foliage spraying. The results showed that the seedling heights sprayed with 100 和 1 000 mg·L -1 of the first group and with 50 和 100 mg·L -1 of the second group were significantly higher than the controls, and the diameter at ground level sprayed with 300 mg·L -1 of the second group was significantly greater than the control, being 26.92% more than the latter; except for spraying with 0 mg5L -1 and 700～1 500 mg5L -1 of the second group, the seedling dry weight above ground of others was 29.13%～73.91% greater than the control, whereas the seedling dry weight under ground of others was 20.78%～116.88% greater than the control; the contents of chlorophyll a and chlorophyll b for all spraying seedling were 91.67%～191.67% and 87.5%～306.25% greater than the control, respectively, and soluble proteins and soluble sugars were 16.00%～179.78% and 10.73%～105.65% greater than the control, respectively. Compared with the control, the activity of SOD tended to increase, whereas the contents of MDA decreased. These indicated that spraying leaves with optimum concentration of mixed nitric_acid rare earth solution could markedly promote the growth of seedlings and improve resistance ability of V. montana seedlings to bad environment. On the whole, the effects of spraying the leaves of seedling with 50～500 mg5L -1 mixed nitric_acid rare earth solution, which were derived from seeds soaking with 300 mg·L -1 mixed nitric_acid rare earth solution, were good.展开更多
N-salicylidene-benzylamineato M(Ⅱ) complexes (ZnL2, CuL2 and CdL2) were synthesized, characterized and valued for antimicrobial activities against bacterial strands using the agar diffusion method. The crystal of ZnL...N-salicylidene-benzylamineato M(Ⅱ) complexes (ZnL2, CuL2 and CdL2) were synthesized, characterized and valued for antimicrobial activities against bacterial strands using the agar diffusion method. The crystal of ZnL2 was determined by X-ray diffraction. It crystallizes in the Monoclinic system, space group C2/c with a=2.269 1(3), b=0.918 2(1), c=1.239 5(2) nm, β=117.89(2), Z=4, R1=0.049 4, wR2=0.138 2. The complexes were found to be active against Staphylococcus aureus and Eschierichia Coli. CCDC: 249474.展开更多
A novel coordination polymer of [Co( p-CPOA)(2,2′-bipy)(H2O)]n ( p-CPOA2-=4-carboxylphenoxyacetate dianion, 2,2′-bipy=2,2′-bipyridine) was synthesized and characterized by elemental analysis, IR and X-ray single cr...A novel coordination polymer of [Co( p-CPOA)(2,2′-bipy)(H2O)]n ( p-CPOA2-=4-carboxylphenoxyacetate dianion, 2,2′-bipy=2,2′-bipyridine) was synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction. The title complex crystallizes in monoclinic space group C2/c, with a=1.424 4(3) nm, b=1.316 6(3) nm, c=1.947 7(4) nm, β=104.56(3)°. V=3.535 3(14) nm3, Z=8, R=0.028 5, wR=0.089 1. The cobalt(Ⅱ) ion displays a distorted octahedral coordination geometry, defined by three carboxyl oxygen atoms from different p-CPOA2- groups, two nitrogen atoms from 2,2′-bipyridine ligand and one water molecule. The cobalt atoms are bridged by p-CPOA2- groups, forming a one-dimensional chain structure along a axis. The adjacent Co...Co atoms distance is 0.996 8 nm. A layer supramolecular network is contrsucted by the hydrogen bonds and π-π stacking interactions. CCDC: 220039.展开更多
new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the c...new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the coordination polymer was confirmed by IR, 1H NMR, elemental analysis and thermal analysis. The crystal structure of the coordination polymer was also determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/m, and crystallographic data of the coordination polymer are: a= 0.863 1(4) nm, b=0.717 7(3) nm, c=1.116 4(5) nm, α=γ=90°, β=107.542(6)°, V=0.659 4(5) nm3; Dc=2.037 g·cm-3; Z=2; F(000)=400; μ=1.969 mm-1. Zinc(Ⅱ) atom lies at the center of an octahedron formed by the coordination of zinc atom and six O atoms which come from four different trifluoroacetate ions and two different 3-hydroxypyridine molecules where each trifluoroacetate ion and 3-hydroxypyridine are coordinated to two different zinc ions to form coordination polymer. CCDC: 253909.展开更多
The geometric configurations of binuclear Zinc( complex Zn2[(n-Bu)2NCSS]4 and the ligand Na[(n-Bu)2 NCSS] have been optimized by B3LYP quantum chemical method. The electronic structures have been performed by density ...The geometric configurations of binuclear Zinc( complex Zn2[(n-Bu)2NCSS]4 and the ligand Na[(n-Bu)2 NCSS] have been optimized by B3LYP quantum chemical method. The electronic structures have been performed by density functional theory at B3LYP/6-31G* level. The electronic spectrums of the complex and ligand were calculated by ZINDO/S-CIS method. It is indicated from the calculation that: (1) The coordination effect of bridging ligand is bigger than that of chelating one, and the bridging ligands also translate more charge to Zn than the chelating one. (2) The calculated results about electronic spectrums are similarly to experimental measurement, and farther explain that absorption band at λ=267 nm of complex is assigned to two n → π* transitions :one arising from the bridging ligands and the another mainly arising from the chelating ligands;but absorption band at λ=236 nm of complex is assigned to π → π* transition which the electron mainly translates from the bridging ligands to the chelating ligands. (3) By consideration of delocalization and polar effects in coordination, the charge transfer from ligand to metal decreases the π-π and p-π conjugation effects in the chromophore group NCS2 and to increase the energy needed for the π → π* and n → π* transitions, and results in the absorption bands shifting towards the short wavelength direction.展开更多
Soil animal communities of Pinus koraiensis broad_leaved mixed forest were studied.The purpose was to discuss the dynamic characteristic of soil animals and relationship with environmental factors.The ecosystem geogra...Soil animal communities of Pinus koraiensis broad_leaved mixed forest were studied.The purpose was to discuss the dynamic characteristic of soil animals and relationship with environmental factors.The ecosystem geography distribution law of soil animals, soil animals’role and function in ecological system were revealed.In June,August,October each year,three plots were selected. In each plot, four layers were sampled(litter layer,0～10 cm,10～20 cm & 20～30 cm),adding up to 72 soil sample.The area for large_sized soil animals was 50 cm×50 cm,and the area for middle_small_sized soil animals was 10 cm × 10 cm.Separated soil animals through adopting hand_picking method and Tullgren method respectively.Sampled the soil animals in two continuing years.Shannon_Wiener index was adopted to analyze the diversity of soil animals.Monad liner regression was used to search the relationship between soil animals and environmental factors.The dominant groups were Oribatida, Isotomidae.There were relatively great changes in groups and individual numbers of dominant groups and rare groups when the reason changed.The individual numbers of dominant groups and the groups of rare groups changed.The number of individual and group was the most in August.Obviously it correlated with climatic factors in middle temperate zone.The evenness was low and dominance was high. The diversity index was not most.Among the annual fluctuating there was a increasing trend. The evenness was low and dominance was high.The diversity index was low.It conformed with the law of reason change.The correlation between soil animals and atmospheric temperature,rainfall,ground temperature and sunlight showed the correlation with rainfall and soil temperature was the most significant.展开更多
基金Project(2020YFA0710903) supported by the National Key R&D Program of ChinaProjects(2020zzts111, 2020zzts117)supported by the Graduate Student Independent Innovation Project of Central South University,ChinaProject(202037)supported by Transport Department of Hunan Province Technology Innovation Project,China。
文摘The effects of different yaw angles on the aerodynamic performance of city electric multiple units(EMUs)were investigated in a wind tunnel using a 1:16.8 scaled model.Pressure scanning valve and six-component box-type aerodynamic balance were used to test the pressure distribution and aerodynamic force of the head car respectively from the 1.5-and 3-coach grouping city EMU models.Meanwhile,the effects of the yaw angles on the pressure distribution of the streamlined head as well as the aerodynamic forces of the train were analyzed.The experimental results showed that the pressure coefficient was the smallest at the maximum slope of the main shape-line.The side force coefficient and pressure coefficient along the head car cross-section were most affected by crosswind when the yaw angle was 55°,and replacing a 3-coach grouping with a 1.5-coach grouping had obvious advantages for wind tunnel testing when the yaw angle was within 24.2°.In addition,the relative errors of lift coefficient C_(L),roll moment coefficient C_(Mx),side force coefficient C_(S),and drag coefficient C_(D)between the 1.5-and 3-coach cases were below 5.95%,which all met the requirements of the experimental accuracy.
基金supported by the National Natural Science Foundation of China(6200220861572063+1 种基金61603225)the Natural Science Foundation of Shandong Province(ZR2016FQ04)。
文摘A novel synthetic aperture radar(SAR)image de-noising method based on the local pixel grouping(LPG)principal component analysis(PCA)and guided filter is proposed.This method contains two steps.In the first step,we process the noisy image by coarse filters,which can suppress the speckle effectively.The original SAR image is transformed into the additive noise model by logarithmic transform with deviation correction.Then,we use the pixel and its nearest neighbors as a vector to select training samples from the local window by LPG based on the block similar matching.The LPG method ensures that only the similar sample patches are used in the local statistical calculation of PCA transform estimation,so that the local features of the image can be well preserved after coefficients shrinkage in the PCA domain.In the second step,we do the guided filtering which can effectively eliminate small artifacts left over from the coarse filtering.Experimental results of simulated and real SAR images show that the proposed method outstrips the state-of-the-art image de-noising methods in the peak signalto-noise ratio(PSNR),the structural similarity(SSIM)index and the equivalent number of looks(ENLs),and is of perceived image quality.
基金supported in part by National Key R&D Program of China(Grant Nos.2021ZD0111501,2021ZD0111502)the Key Laboratory of Digital Signal and Image Processing of Guangdong Province+8 种基金the Key Laboratory of Intelligent Manufacturing Technology(Shantou University)Ministry of Education,the Science and Technology Planning Project of Guangdong Province of China(Grant No.180917144960530)the Project of Educational Commission of Guangdong Province of China(Grant No.2017KZDXM032)the State Key Lab of Digital Manufacturing Equipment&Technology(grant number DMETKF2019020)National Natural Science Foundation of China(Grant Nos.62176147,62002369)STU Scientific Research Foundation for Talents(Grant No.NTF21001)Science and Technology Planning Project of Guangdong Province of China(Grant Nos.2019A050520001,2021A0505030072,2022A1515110660)Science and Technology Special Funds Project of Guangdong Province of China(Grant Nos.STKJ2021176,STKJ2021019)Guangdong Special Support Program for Outstanding Talents(Grant No.2021JC06X549)。
文摘For swarm robots moving in a harsh or uncharted outdoor environment without GPS guidance and global communication,algorithms that rely on global-based information are infeasible.Typically,traditional gene regulatory networks(GRNs)that achieve superior performance in forming trapping pattern towards targets require accurate global positional information to guide swarm robots.This article presents a gene regulatory network with Self-organized grouping and entrapping method for swarms(SUNDER-GRN)to achieve adequate trapping performance with a large-scale swarm in a confined multitarget environment with access to only local information.A hierarchical self-organized grouping method(HSG)is proposed to structure subswarms in a distributed way.In addition,a modified distributed controller,with a relative coordinate system that is established to relieve the need for global information,is leveraged to facilitate subswarms entrapment toward different targets,thus improving the global multi-target entrapping performance.The results demonstrate the superiority of SUNDERGRN in the performance of structuring subswarms and entrapping 10 targets with 200 robots in an environment confined by obstacles and with only local information accessible.
基金supported by the Innovation Capacity Construction Project of Jilin Development and Reform Commission(2020C017-2)Science and Technology Development Plan Project of Jilin Province(20210201082GX)。
文摘Mobile CrowdSensing(MCS)is a promising sensing paradigm that recruits users to cooperatively perform sensing tasks.Recently,unmanned aerial vehicles(UAVs)as the powerful sensing devices are used to replace user participation and carry out some special tasks,such as epidemic monitoring and earthquakes rescue.In this paper,we focus on scheduling UAVs to sense the task Point-of-Interests(PoIs)with different frequency coverage requirements.To accomplish the sensing task,the scheduling strategy needs to consider the coverage requirement,geographic fairness and energy charging simultaneously.We consider the complex interaction among UAVs and propose a grouping multi-agent deep reinforcement learning approach(G-MADDPG)to schedule UAVs distributively.G-MADDPG groups all UAVs into some teams by a distance-based clustering algorithm(DCA),then it regards each team as an agent.In this way,G-MADDPG solves the problem that the training time of traditional MADDPG is too long to converge when the number of UAVs is large,and the trade-off between training time and result accuracy could be controlled flexibly by adjusting the number of teams.Extensive simulation results show that our scheduling strategy has better performance compared with three baselines and is flexible in balancing training time and result accuracy.
基金supported by the National Natural Science Foundation of China(6110602261574013)
文摘The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems（LSAS）. The former researches have confirmed that the cells groupings time-shift pilots scheme is effective to reduce inter-cell interference, especially pilot contamination, which results from the pilot reuse in adjacent cells. However, they have not specified reasonable cells groupings factor, which plays a critical role in the general performance of the LSAS. Therefore, this problem is researched in details. The time for reverse-link data transmission will be compressed, when the groupings factor surpasses a certain range. Thus it is not always beneficial to increase the cells groupings factor without limitation. Furthermore,a reasonable cells groupings factor is deduced from the perspective of optimization to enhance the system performance. Simulations verify the proposed cell grouping factor.
基金Supported by National Natural Science Foundation of China(61911530398,12231012)Consultancy Project by the Chinese Academy of Engineering(2022-JB-06,2023-JB-12)+3 种基金the Natural Science Foundation of Fujian Province of China(2021J01621)Special Projects of the Central Government Guiding Local Science and Technology Development(2021L3018)Royal Society of Edinburgh(RSE1832)Engineering and Physical Sciences Research Council(EP/W522521/1).
文摘A stochastic epidemic model with two age groups is established in this study,in which the susceptible(S),the exposed(E),the infected(I),the hospitalized(H)and the recovered(R)are involved within the total population,the aging rates between two age groups are set to be constant.The existence-and-uniqueness of global positive solution is firstly showed.Then,by constructing several appropriate Lyapunov functions and using the high-dimensional Itô’s formula,the sufficient conditions for the stochastic extinction and stochastic persistence of the exposed individuals and the infected individuals are obtained.The stochastic extinction indicator and the stochastic persistence indicator are less-valued expressions compared with the basic reproduction number.Meanwhile,the main results of this study are modified into multi-age groups.Furthermore,by using the surveillance data for Fujian Provincial Center for Disease Control and Prevention,Fuzhou COVID-19 epidemic is chosen to carry out the numerical simulations,which show that the age group of the population plays the vital role when studying infectious diseases.
文摘Lithium-ion capacitors(LICs)combine the high power dens-ity of electrical double-layer capacitors with the high energy density of lithium-ion batteries.However,they face practical limitations due to the narrow operating voltage window of their activated carbon(AC)cathodes.We report a scalable thermal treatment strategy to develop high-voltage-tolerant AC cathodes.Through controlled thermal treatment of commer-cial activated carbon(Raw-AC)under a H_(2)/Ar atmosphere at 400-800℃,the targeted reduction of degradation-prone functional groups can be achieved while preserving the critical pore structure and increasing graph-itic microcrystalline ordering.The AC treated at 400℃(HAC-400)had a significant increase in specific capacity(96.0 vs.75.1 mAh/g at 0.05 A/g)and better rate capability(61.1 vs.36.1 mAh/g at 5 A/g)in half-cell LICs,along with an 83.5%capacity retention over 7400 cycles within an extended voltage range of 2.0-4.2 V in full-cell LICs.Scalability was demonstrated by a 120 g batch production,enabling fabrication of pouch-type LICs with commercial hard carbon anodes that delivered a higher energy density of 28.3 Wh/kg at 1 C,and a peak power density of 12.1 kW/kg compared to devices using raw AC.This simple,industry-compatible approach may be used for producing ad-vanced cathode materials for practical high-performance LICs.
基金National Key Research and Development Program of China(2021YFB3101402)National Natural Science Foundation of China(62202294)。
文摘This study constructs a function-private inner-product predicate encryption(FP-IPPE)and achieves standard enhanced function privacy.The enhanced function privacy guarantees that a predicate secret key skf reveals nothing about the predicate f,as long as f is drawn from an evasive distribution with sufficient entropy.The proposed scheme extends the group-based public-key function-private predicate encryption(FP-PE)for“small superset predicates”proposed by Bartusek et al.(Asiacrypt 19),to the setting of inner-product predicates.This is the first construction of public-key FP-PE with enhanced function privacy security beyond the equality predicates,which is previously proposed by Boneh et al.(CRYPTO 13).The proposed construction relies on bilinear groups,and the security is proved in the generic bilinear group model.
文摘Herein the use of rare-earth compounds in catalytic reduction systems for the end-group functionalization of carboxyl-terminated low-molecularweight fluoropolymers was explored.Leveraging the high catalytic activity and selectivity of rare-earth compounds along with no residual impact on polymer product's performance,highly efficient catalytic reduction systems containing sodium borohydride(NaBH_(4))and rare-earth chloride(RECl_(3))were specifically designed for a telechelic carboxyl-terminated liquid fluoroeslastomer,aiming to facilitate the conversion of chainend carboxyl groups into hydroxyl groups and improvement in end-group reactivity.To achieve this,lanthanum chloride(LaCl_(3)),cerium chloride(CeCl_(3)),and neodymium chloride(NdCl_(3))were used separately to form catalytic reduction systems with NaBH_(4).The effects of solvent dosage,reaction temperature,reaction time length,and reductant dosage on carboxylic conversion were investigated,and the molecular chain structure,molecular weight,and functional group content of the raw materials and the products were analyzed and characterized by means of infrared spectroscopy(FTIR),proton nuclear magnetic resonance(^(1)H-NMR),fluorine-19 nuclear magnetic resonance(^(19)F-NMR),gel permeation chromatography(GPC),and chemical titration.Moreover,the catalytic activity and selectivity of the rare-earth chlorides,as well as the corresponding underlying interactions were discussed.Results indicated that the rare-earth-containing catalytic reduction systems studied in this work could efficiently convert the chain-end carboxyl groups into highly active hydroxyl groups,with a highest conversion up to 87.0%and differing catalytic reduction activities ranked as NaBH_(4)/CeCl_(3)>NaBH_(4)/LaCl_(3)>NaBH_(4)/NdCl_(3).Compared with the conventional lithium aluminum hydride(LiAIH_(4))reduction system,the NaBH_(4)/RECl_(3)systems provide multiple advantages such as mild reaction conditions,high conversion ratio with good selectivity,and environmental innocuity,and are potentially applicable as new reduction-catalysis combinations for the synthesis and functionalization of polymer materials.
文摘Reaction of the non-substituted/substituted unsymmetric pinene-derived complex[Pt(N^C^N')Cl]with the aryl isocyanide 2,6-dimethylphenyl isocyanide(CNXyl)afforded a mixture of two isomeric species:the ionic complex[Pt(κ^(3)-N^C^N')(CNXyl)]Cl([A]Cl)and the molecular complex[Pt(κ^(2)-N^C^N')(CNXyl)Cl](B).Isomer B was almost the dominating product.The structures of the isomer B derivatives bearing-CF_(3)and-Cl substituents on the pyridine ring of the pinene moiety(5B and 7B,respectively)have been confirmed by single-crystal X-ray diffraction,revealing a slightly distorted square planar geometry with trans-N_(N^C^N'),CNR configuration(The terminal N atom of theκ^(2)-N^C^N'ligand is trans to the isocyanide ligand CNXyl.).Isomer B is thermodynamically more stable,as confirmed by theoretical calculations.CCDC:2416415,5B;2416414,7B.
基金supported by the National Natural Science Foundation of China(No.22375021,22235003,22261132516&22205021)the BIT Research and Innovation 265 Promoting Project(Grant No.2023YCXZ017)。
文摘Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.
基金supported by the National Natural Science Foundation of China(62003264).
文摘To solve the problem of providing the best initial situation for terminal guidance when multiple missiles intercept multiple targets,a group cooperative midcourse guidance law(GCMGL)considering time-to-go is proposed.Firstly,a threedimensional(3D)guidance model is established and a cooperative trajectory shaping guidance law is given.Secondly,for estimating the unknown target maneuvering acceleration,an adaptive disturbance observer(ADO)is designed,combining finitetime theory with a radial basis function(RBF)neural network,and the convergence of the estimation error is proven using Lyapunov stability theory.Then,to ensure time-to-go cooperation among missiles within the same group and across different groups,the group consensus protocols of virtual collision point mean and the inter-group cooperative consensus protocol are designed respectively.Based on the group consensus protocols,the virtual collision point cooperative guidance law is given,and the finite-time convergence is proved by Lyapunov stability theory.Simultaneously,combined with trajectory shaping guidance law,virtual collision point cooperative guidance law and the intergroup cooperative consensus protocol,the design of GCMGL considering time-to-go is given.Finally,numerical simulation results show the effectiveness and the superiority of the proposed GCMGL.
文摘The seedlings of Vernicia montana derived from seeds soaking with water (the first group)or 300 mg5L -1 mixed nitric_acid rare earth solution (the second group) were treated with various concentrations of mixed nitric_acid rare earth solution by foliage spraying. The results showed that the seedling heights sprayed with 100 和 1 000 mg·L -1 of the first group and with 50 和 100 mg·L -1 of the second group were significantly higher than the controls, and the diameter at ground level sprayed with 300 mg·L -1 of the second group was significantly greater than the control, being 26.92% more than the latter; except for spraying with 0 mg5L -1 and 700～1 500 mg5L -1 of the second group, the seedling dry weight above ground of others was 29.13%～73.91% greater than the control, whereas the seedling dry weight under ground of others was 20.78%～116.88% greater than the control; the contents of chlorophyll a and chlorophyll b for all spraying seedling were 91.67%～191.67% and 87.5%～306.25% greater than the control, respectively, and soluble proteins and soluble sugars were 16.00%～179.78% and 10.73%～105.65% greater than the control, respectively. Compared with the control, the activity of SOD tended to increase, whereas the contents of MDA decreased. These indicated that spraying leaves with optimum concentration of mixed nitric_acid rare earth solution could markedly promote the growth of seedlings and improve resistance ability of V. montana seedlings to bad environment. On the whole, the effects of spraying the leaves of seedling with 50～500 mg5L -1 mixed nitric_acid rare earth solution, which were derived from seeds soaking with 300 mg·L -1 mixed nitric_acid rare earth solution, were good.
文摘N-salicylidene-benzylamineato M(Ⅱ) complexes (ZnL2, CuL2 and CdL2) were synthesized, characterized and valued for antimicrobial activities against bacterial strands using the agar diffusion method. The crystal of ZnL2 was determined by X-ray diffraction. It crystallizes in the Monoclinic system, space group C2/c with a=2.269 1(3), b=0.918 2(1), c=1.239 5(2) nm, β=117.89(2), Z=4, R1=0.049 4, wR2=0.138 2. The complexes were found to be active against Staphylococcus aureus and Eschierichia Coli. CCDC: 249474.
文摘A novel coordination polymer of [Co( p-CPOA)(2,2′-bipy)(H2O)]n ( p-CPOA2-=4-carboxylphenoxyacetate dianion, 2,2′-bipy=2,2′-bipyridine) was synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction. The title complex crystallizes in monoclinic space group C2/c, with a=1.424 4(3) nm, b=1.316 6(3) nm, c=1.947 7(4) nm, β=104.56(3)°. V=3.535 3(14) nm3, Z=8, R=0.028 5, wR=0.089 1. The cobalt(Ⅱ) ion displays a distorted octahedral coordination geometry, defined by three carboxyl oxygen atoms from different p-CPOA2- groups, two nitrogen atoms from 2,2′-bipyridine ligand and one water molecule. The cobalt atoms are bridged by p-CPOA2- groups, forming a one-dimensional chain structure along a axis. The adjacent Co...Co atoms distance is 0.996 8 nm. A layer supramolecular network is contrsucted by the hydrogen bonds and π-π stacking interactions. CCDC: 220039.
文摘new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the coordination polymer was confirmed by IR, 1H NMR, elemental analysis and thermal analysis. The crystal structure of the coordination polymer was also determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/m, and crystallographic data of the coordination polymer are: a= 0.863 1(4) nm, b=0.717 7(3) nm, c=1.116 4(5) nm, α=γ=90°, β=107.542(6)°, V=0.659 4(5) nm3; Dc=2.037 g·cm-3; Z=2; F(000)=400; μ=1.969 mm-1. Zinc(Ⅱ) atom lies at the center of an octahedron formed by the coordination of zinc atom and six O atoms which come from four different trifluoroacetate ions and two different 3-hydroxypyridine molecules where each trifluoroacetate ion and 3-hydroxypyridine are coordinated to two different zinc ions to form coordination polymer. CCDC: 253909.
文摘The geometric configurations of binuclear Zinc( complex Zn2[(n-Bu)2NCSS]4 and the ligand Na[(n-Bu)2 NCSS] have been optimized by B3LYP quantum chemical method. The electronic structures have been performed by density functional theory at B3LYP/6-31G* level. The electronic spectrums of the complex and ligand were calculated by ZINDO/S-CIS method. It is indicated from the calculation that: (1) The coordination effect of bridging ligand is bigger than that of chelating one, and the bridging ligands also translate more charge to Zn than the chelating one. (2) The calculated results about electronic spectrums are similarly to experimental measurement, and farther explain that absorption band at λ=267 nm of complex is assigned to two n → π* transitions :one arising from the bridging ligands and the another mainly arising from the chelating ligands;but absorption band at λ=236 nm of complex is assigned to π → π* transition which the electron mainly translates from the bridging ligands to the chelating ligands. (3) By consideration of delocalization and polar effects in coordination, the charge transfer from ligand to metal decreases the π-π and p-π conjugation effects in the chromophore group NCS2 and to increase the energy needed for the π → π* and n → π* transitions, and results in the absorption bands shifting towards the short wavelength direction.
文摘Soil animal communities of Pinus koraiensis broad_leaved mixed forest were studied.The purpose was to discuss the dynamic characteristic of soil animals and relationship with environmental factors.The ecosystem geography distribution law of soil animals, soil animals’role and function in ecological system were revealed.In June,August,October each year,three plots were selected. In each plot, four layers were sampled(litter layer,0～10 cm,10～20 cm & 20～30 cm),adding up to 72 soil sample.The area for large_sized soil animals was 50 cm×50 cm,and the area for middle_small_sized soil animals was 10 cm × 10 cm.Separated soil animals through adopting hand_picking method and Tullgren method respectively.Sampled the soil animals in two continuing years.Shannon_Wiener index was adopted to analyze the diversity of soil animals.Monad liner regression was used to search the relationship between soil animals and environmental factors.The dominant groups were Oribatida, Isotomidae.There were relatively great changes in groups and individual numbers of dominant groups and rare groups when the reason changed.The individual numbers of dominant groups and the groups of rare groups changed.The number of individual and group was the most in August.Obviously it correlated with climatic factors in middle temperate zone.The evenness was low and dominance was high. The diversity index was not most.Among the annual fluctuating there was a increasing trend. The evenness was low and dominance was high.The diversity index was low.It conformed with the law of reason change.The correlation between soil animals and atmospheric temperature,rainfall,ground temperature and sunlight showed the correlation with rainfall and soil temperature was the most significant.
