The influence of grain size or grain refinement on the corrosion of Zr alloy is clarified by employing a series of electrochemical analyses and characterization techniques.The corrosion resistance,as a function of exp...The influence of grain size or grain refinement on the corrosion of Zr alloy is clarified by employing a series of electrochemical analyses and characterization techniques.The corrosion resistance,as a function of exposure time,F−concentration,and solution temperatures,of Zr alloys with different grain sizes is ascertained.The results confirm that refining the grain size can effectively enhance the short-time corrosion properties of Zr alloy in HNO_(3) with F−.The fine grained Zr alloy(~10μm in diameter)consistently exhibits a lower corrosion current density,ranging from 18%to 46%lower than that of the coarse-grained Zr alloy(~44μm).The enhanced corrosion resistance is attributed to the high density grain boundaries,which promote oxide stability,and accelerate the creation of the protective layer.The high corrosion rate and pseudo-passivation behavior of Zr alloys in fluorinated nitric acid originate from the accelerated“dissolution-passivation”of the oxide film.However,the grain refinement does not provide enduring anti-corrosion for Zr alloys.To meet the operation of spent fuel reprocessing,additional systematic efforts are required to evaluate the long term effect of grain refinement.展开更多
An increase in RE element content in Mg alloys promotes the grain boundary precipitate,which affects the mechanical properties.However,the influence of grain boundary precipitates on microstructure of Mg-RE alloys dur...An increase in RE element content in Mg alloys promotes the grain boundary precipitate,which affects the mechanical properties.However,the influence of grain boundary precipitates on microstructure of Mg-RE alloys during ageing and their role on ductility of the aged alloy is unclear.In this work,hot extrusion and ageing treatment were performed for Mg-9Gd-2Y-xNd-0.2Zr(x=1 wt.%and 3 wt.%)alloys,and grain boundary precipitates were formed in the extruded Mg-9Gd-2Y-3Nd-0.2Zr alloy due to the increase of Nd content.The extruded alloys exhibit a complete dynamic recrystallization(DRX)microstructure and a texture with the<0001>orientation parallel to the extrusion direction(ED).In addition,a large amount of fiber microstructures distributed by the second phase along the ED were formed in the Mg-9Gd-2Y-3Nd-0.2Zr alloy,while only a small amount of the second phase was observed in the Mg-9Gd-2Y-1Nd-0.2Zr alloy.After ageing treatment,a large amount ofβ'phase precipitated inside the grains.The strength of the Mg-9Gd-2Y-1Nd-0.2Zr alloy increased from 202 MPa to 275 MPa but the elongation decreased from 12.8%to 2.6%,and the strength of the Mg-9Gd-2Y-3Nd-0.2Zr alloy increased from 212 MPa to 281 MPa but the elongation decreased from 13.7%to 6.2%.Among them,the Mg-9Gd-2Y-3Nd-0.2Zr alloy showed good overall mechanical properties,especially the elongation of the aged alloy was 58%higher than that of the Mg-9Gd-2Y-1Nd-0.2Zr alloy.The increase in ductility of the aged Mg-9Gd-2Y-3Nd-0.2Zr alloy attributed to the grain boundary precipitate promotes the formation of a large number of precipitation free zones(PFZs)with widths of 130-150 nm during ageing treatment.展开更多
The macroscopic mechanical properties of rocks are significantly influenced by their microstructure.As a material bonded by mineral grains,the grain morphology of crystalline rock is the primary factor influencing the...The macroscopic mechanical properties of rocks are significantly influenced by their microstructure.As a material bonded by mineral grains,the grain morphology of crystalline rock is the primary factor influencing the strength.However,most strength criteria neglect the strength variations caused by different grain characteristics in rocks.Furthermore,the traditional linear criteria tend to overestimate tensile strength and exhibit apex singularity.To address these shortcomings,a piecewise strength criterion that considers the grain size effect has been proposed.A part of an ellipse was employed to construct the envelope of the tensive-shear region on the meridian plane,to accurately reproduce the low tensile-compressive strength ratio.Based on the analysis of experimental data,both linear and exponential modification functions that account for grain size effects were integrated into the proposed criterion.The corresponding finite element algorithm has been implemented.The accuracy and applicability of the proposed criterion were validated by comparing with the experimental data.展开更多
有机肥部分替代化肥是一种实现化肥减量的可持续农业生产措施。本研究于2020和2021连续2年以“沁黄2号”为供试材料,设不施氮(CK)、常量化肥氮(NPK)、有机肥替代25%化肥氮(25%M)、有机肥替代50%化肥氮(50%M)、有机肥替代75%化肥氮(75%M...有机肥部分替代化肥是一种实现化肥减量的可持续农业生产措施。本研究于2020和2021连续2年以“沁黄2号”为供试材料,设不施氮(CK)、常量化肥氮(NPK)、有机肥替代25%化肥氮(25%M)、有机肥替代50%化肥氮(50%M)、有机肥替代75%化肥氮(75%M)和有机肥替代100%化肥氮(100%M) 6个处理,研究不同替代率对谷子产量构成和氮素吸收的影响,并分析氮素吸收调控小米米色、糊化特性和类胡萝卜素组分的效应,明确谷子生产中有机肥最佳替代率。结果表明,2年中较低的有机肥替代化肥氮率显著提高了谷子植株氮素累积,但随着替代率的持续增加,植株氮素累积量呈降低趋势,最终影响谷子产量和小米品质。2020年, 25%M处理显著提高了谷子地上部氮素累积量,较NPK处理提高9.6%;2021年,25%M处理谷子地上部氮素累积量、生物量、穗粒数和产量达到最高,较NPK处理分别提高6.1%、12.0%、15.4%和12.0%。50%M处理显著影响了小米的米色、糊化特征和类胡萝卜素含量,与NPK相比,小米籽粒红绿值、橘色值、支链淀粉含量、总淀粉含量、小米糊化最终黏度、叶黄素含量、玉米黄质含量和黄色素含量的增幅分别可达6.0%、6.0%、7.4%、4.3%、7.8%、20.7%、17.4%和2.8%。但有机肥完全替代化肥降低了谷子地上部氮素吸收、地上部生物量、穗粒数及谷子产量,也抑制了小米叶黄素和玉米黄质含量的提升。2年均表现出谷子地上部氮吸收量与小米单粒重、直链淀粉含量和小米糊化回升值呈显著的负相关。且2021年谷子地上部氮吸收量还与小米总淀粉含量、蛋白质含量、小米粉糊化峰值黏度和小米黄色素含量呈显著的负相关,与小米糊化峰谷黏度呈显著的正相关。综上,施氮总量120 kg hm^(–2)下,有机肥替代25%~50%化肥氮能通过促进植株氮素的吸收,实现产量、米色、蒸煮特性及类胡萝卜素的协同提升,为谷子化肥减量和提质增效生产提供技术支撑。展开更多
人脸特征蕴含诸多信息,在面部属性和情感分析任务中具有重要价值,而面部特征的多样性和复杂性使人脸分析任务变得困难。针对上述难题,从面部细粒度特征角度出发,提出基于上下文通道注意力机制的人脸属性估计和表情识别(FAER)模型。首先...人脸特征蕴含诸多信息,在面部属性和情感分析任务中具有重要价值,而面部特征的多样性和复杂性使人脸分析任务变得困难。针对上述难题,从面部细粒度特征角度出发,提出基于上下文通道注意力机制的人脸属性估计和表情识别(FAER)模型。首先,构建基于ConvNext的局部特征编码骨干网络,并运用骨干网络编码局部特征的有效性来充分表征人脸局部特征之间的差异性;其次,提出上下文通道注意力(CC Attention)机制,通过动态自适应调整特征通道上的权重信息,表征深度特征的全局和局部特征,从而弥补骨干网络编码全局特征能力的不足;最后,设计不同分类策略,针对人脸属性估计(FAE)和面部表情识别(FER)任务,分别采用不同损失函数组合,以促使模型学习更多的面部细粒度特征。实验结果表明,所提FAER模型在人脸属性数据集CelebA(CelebFaces Attributes)上取得了91.87%的平均准确率,相较于次优模型SwinFace(Swin transformer for Face)高出0.55个百分点;在面部表情数据集RAF-DB和AffectNet上分别取得了91.75%和66.66%的准确率,相较于次优模型TransFER(Transformers for Facial Expression Recognition)分别高出0.84和0.43个百分点。展开更多
基金Project(U2067217)supported by the National Natural Science Foundation of ChinaProject(SASTIND)supported by the State Administration of Science,Technology and Industry for National Defense,ChinaProject(2020M683572)supported by China Postdoctoral Science Foundation。
文摘The influence of grain size or grain refinement on the corrosion of Zr alloy is clarified by employing a series of electrochemical analyses and characterization techniques.The corrosion resistance,as a function of exposure time,F−concentration,and solution temperatures,of Zr alloys with different grain sizes is ascertained.The results confirm that refining the grain size can effectively enhance the short-time corrosion properties of Zr alloy in HNO_(3) with F−.The fine grained Zr alloy(~10μm in diameter)consistently exhibits a lower corrosion current density,ranging from 18%to 46%lower than that of the coarse-grained Zr alloy(~44μm).The enhanced corrosion resistance is attributed to the high density grain boundaries,which promote oxide stability,and accelerate the creation of the protective layer.The high corrosion rate and pseudo-passivation behavior of Zr alloys in fluorinated nitric acid originate from the accelerated“dissolution-passivation”of the oxide film.However,the grain refinement does not provide enduring anti-corrosion for Zr alloys.To meet the operation of spent fuel reprocessing,additional systematic efforts are required to evaluate the long term effect of grain refinement.
基金Project(2021YFB3701103) supported by the National Key R&D Program of China。
文摘An increase in RE element content in Mg alloys promotes the grain boundary precipitate,which affects the mechanical properties.However,the influence of grain boundary precipitates on microstructure of Mg-RE alloys during ageing and their role on ductility of the aged alloy is unclear.In this work,hot extrusion and ageing treatment were performed for Mg-9Gd-2Y-xNd-0.2Zr(x=1 wt.%and 3 wt.%)alloys,and grain boundary precipitates were formed in the extruded Mg-9Gd-2Y-3Nd-0.2Zr alloy due to the increase of Nd content.The extruded alloys exhibit a complete dynamic recrystallization(DRX)microstructure and a texture with the<0001>orientation parallel to the extrusion direction(ED).In addition,a large amount of fiber microstructures distributed by the second phase along the ED were formed in the Mg-9Gd-2Y-3Nd-0.2Zr alloy,while only a small amount of the second phase was observed in the Mg-9Gd-2Y-1Nd-0.2Zr alloy.After ageing treatment,a large amount ofβ'phase precipitated inside the grains.The strength of the Mg-9Gd-2Y-1Nd-0.2Zr alloy increased from 202 MPa to 275 MPa but the elongation decreased from 12.8%to 2.6%,and the strength of the Mg-9Gd-2Y-3Nd-0.2Zr alloy increased from 212 MPa to 281 MPa but the elongation decreased from 13.7%to 6.2%.Among them,the Mg-9Gd-2Y-3Nd-0.2Zr alloy showed good overall mechanical properties,especially the elongation of the aged alloy was 58%higher than that of the Mg-9Gd-2Y-1Nd-0.2Zr alloy.The increase in ductility of the aged Mg-9Gd-2Y-3Nd-0.2Zr alloy attributed to the grain boundary precipitate promotes the formation of a large number of precipitation free zones(PFZs)with widths of 130-150 nm during ageing treatment.
基金Project(2023YFC2907403)supported by the National Key R&D Program of ChinaProject(52074021)supported by the National Natural Science Foundation of China+1 种基金Project(2242045)supported by Beijing Natural Science Foundation,ChinaProject(ZD202216)supported by the Beijing Association of Higher Education,China。
文摘The macroscopic mechanical properties of rocks are significantly influenced by their microstructure.As a material bonded by mineral grains,the grain morphology of crystalline rock is the primary factor influencing the strength.However,most strength criteria neglect the strength variations caused by different grain characteristics in rocks.Furthermore,the traditional linear criteria tend to overestimate tensile strength and exhibit apex singularity.To address these shortcomings,a piecewise strength criterion that considers the grain size effect has been proposed.A part of an ellipse was employed to construct the envelope of the tensive-shear region on the meridian plane,to accurately reproduce the low tensile-compressive strength ratio.Based on the analysis of experimental data,both linear and exponential modification functions that account for grain size effects were integrated into the proposed criterion.The corresponding finite element algorithm has been implemented.The accuracy and applicability of the proposed criterion were validated by comparing with the experimental data.
文摘有机肥部分替代化肥是一种实现化肥减量的可持续农业生产措施。本研究于2020和2021连续2年以“沁黄2号”为供试材料,设不施氮(CK)、常量化肥氮(NPK)、有机肥替代25%化肥氮(25%M)、有机肥替代50%化肥氮(50%M)、有机肥替代75%化肥氮(75%M)和有机肥替代100%化肥氮(100%M) 6个处理,研究不同替代率对谷子产量构成和氮素吸收的影响,并分析氮素吸收调控小米米色、糊化特性和类胡萝卜素组分的效应,明确谷子生产中有机肥最佳替代率。结果表明,2年中较低的有机肥替代化肥氮率显著提高了谷子植株氮素累积,但随着替代率的持续增加,植株氮素累积量呈降低趋势,最终影响谷子产量和小米品质。2020年, 25%M处理显著提高了谷子地上部氮素累积量,较NPK处理提高9.6%;2021年,25%M处理谷子地上部氮素累积量、生物量、穗粒数和产量达到最高,较NPK处理分别提高6.1%、12.0%、15.4%和12.0%。50%M处理显著影响了小米的米色、糊化特征和类胡萝卜素含量,与NPK相比,小米籽粒红绿值、橘色值、支链淀粉含量、总淀粉含量、小米糊化最终黏度、叶黄素含量、玉米黄质含量和黄色素含量的增幅分别可达6.0%、6.0%、7.4%、4.3%、7.8%、20.7%、17.4%和2.8%。但有机肥完全替代化肥降低了谷子地上部氮素吸收、地上部生物量、穗粒数及谷子产量,也抑制了小米叶黄素和玉米黄质含量的提升。2年均表现出谷子地上部氮吸收量与小米单粒重、直链淀粉含量和小米糊化回升值呈显著的负相关。且2021年谷子地上部氮吸收量还与小米总淀粉含量、蛋白质含量、小米粉糊化峰值黏度和小米黄色素含量呈显著的负相关,与小米糊化峰谷黏度呈显著的正相关。综上,施氮总量120 kg hm^(–2)下,有机肥替代25%~50%化肥氮能通过促进植株氮素的吸收,实现产量、米色、蒸煮特性及类胡萝卜素的协同提升,为谷子化肥减量和提质增效生产提供技术支撑。
文摘人脸特征蕴含诸多信息,在面部属性和情感分析任务中具有重要价值,而面部特征的多样性和复杂性使人脸分析任务变得困难。针对上述难题,从面部细粒度特征角度出发,提出基于上下文通道注意力机制的人脸属性估计和表情识别(FAER)模型。首先,构建基于ConvNext的局部特征编码骨干网络,并运用骨干网络编码局部特征的有效性来充分表征人脸局部特征之间的差异性;其次,提出上下文通道注意力(CC Attention)机制,通过动态自适应调整特征通道上的权重信息,表征深度特征的全局和局部特征,从而弥补骨干网络编码全局特征能力的不足;最后,设计不同分类策略,针对人脸属性估计(FAE)和面部表情识别(FER)任务,分别采用不同损失函数组合,以促使模型学习更多的面部细粒度特征。实验结果表明,所提FAER模型在人脸属性数据集CelebA(CelebFaces Attributes)上取得了91.87%的平均准确率,相较于次优模型SwinFace(Swin transformer for Face)高出0.55个百分点;在面部表情数据集RAF-DB和AffectNet上分别取得了91.75%和66.66%的准确率,相较于次优模型TransFER(Transformers for Facial Expression Recognition)分别高出0.84和0.43个百分点。
