A new adsorbent was successfully prepared by hydrothermal treatment and chemical activation through coal gasification fine slag(CGFS)and blue algae(BA)as raw materials and used for CO_(2)capture.The CO_(2)chemisorptio...A new adsorbent was successfully prepared by hydrothermal treatment and chemical activation through coal gasification fine slag(CGFS)and blue algae(BA)as raw materials and used for CO_(2)capture.The CO_(2)chemisorption capacity of the adsorbent was further enhanced by taking advantage of the nitrogenous bases contained in the BA.In the hydrothermal process,the addition of BA significantly increased the content of pyrrole nitrogen in the adsorbent.In the activation process,pyrrole nitrogen gradually changed into pyridine nitrogen and graphite nitrogen.Increased BA addition result in a higher specific surface area and microporosity of the adsorbent.The CO_(2)adsorption performance test proved that the CGFS-50%-CA sample has the strongest CO_(2)adsorption capacity at low temperature,up to 15.59 cm^(3)/g,which is mainly through physical adsorption,and the CGFS-10%-CA sample has the strongest CO_(2)adsorption capacity at high temperature,up to 7.31 cm^(3)/g,which is mainly through chemical adsorption.CO_(2)uptake of the CGFS-10%-CA sample was well maintained after 10 cycles,with regeneration efficiencies above 99%.The results indicate that the novel adsorbents with coexistence of physical and chemical adsorption have great potential for CO_(2)adsorption applications.展开更多
Abstract:The aim of this research is to design and operate a 10 kW hot chemical-looping gasification(CLG)unit using Fe2O3/Al2O3as an oxygen carrier and saw dust as a fuel.The effect of the operation temperature on gas...Abstract:The aim of this research is to design and operate a 10 kW hot chemical-looping gasification(CLG)unit using Fe2O3/Al2O3as an oxygen carrier and saw dust as a fuel.The effect of the operation temperature on gas composition in the air reactor and the fuel reactor,and the carbon conversion of biomass to CO2and CO in the fuel reactor have been experimentally studied.A total60 h run has been obtained with the same batch of oxygen carrier of iron oxide supported with alumina.The results show that CO and H2concentrations are increased with increasing temperature in the fuel reactor.It is also found that with increasing fuel reactor temperature,both the amount of residual char in the fuel reactor and CO2concentration of the exit gas from the air reactor are degreased.Carbon conversion rate and gasification efficiency are increased by increasing temperature and H2production at 870℃reaches the highest rate.Scanning electron microscopy(SEM),X-ray diffraction(XRD)and BET-surface area tests have been used to characterize fresh and reacted oxygen carrier particles.The results display that the oxygen carrier activity is not declined and the specific surface area of the oxygen carrier particles is not decreased significantly.展开更多
Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out us...Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out using an integrated system consisting of the boiler and a fixed-bed 60 kW (GazEla) gasification reactor.The process gas was continuously introduced above the coal burner of the boiler.The process parameters of the boiler and the gasifier were also measured and compared with the other units.Characteristic NOx emissions from automatic and manually operated boilers were also presented.展开更多
The gasification industries make use of biomass residue as feedstock to produce synthesis gas,but the gasification of this waste biomass generates tons of ash everyday.Performance properties and agglomeration behavior...The gasification industries make use of biomass residue as feedstock to produce synthesis gas,but the gasification of this waste biomass generates tons of ash everyday.Performance properties and agglomeration behavior of corncob ash(CCA) collected from the gasification of corncobs in a pilot-scale gasification station were investigated by using some experimental methods.Based on the chemical composition results,the agglomeration tendency of CCA from combustion and gasification process was also analyzed.Chemical analysis shows that the fly ash is mainly composed of inorganic matters formed by K,Mg,Ca,Na,Fe,Al,S,etc.The agglomeration characteristics indicate that the slagging degree increases with the increase of ashing temperature,and the slagging tendency of these CCA samples from gasification or combustion is different with various slagging indices.All CCA samples from combustion or gasification can cause slagging/fouling problems in thermal conversion systems.The applications of CCA are closely related to its performances,and CCA has the potential to be used in various fields,for example,as a material for ceramic products and activated carbon,as an adsorbent,as a crude fertilizer,and as a structural material.展开更多
Producer gas through gasification of biomass can be used as an alternate fuel in rural areas due to high potential of biomass resources in India.Experiments were conducted to study the performance of a diesel engine(f...Producer gas through gasification of biomass can be used as an alternate fuel in rural areas due to high potential of biomass resources in India.Experiments were conducted to study the performance of a diesel engine(four stroke,single cylinder,5.25 kW) with respect to its thermal efficiency,specific fuel consumption and diesel substitution by use of diesel alone and producer gas-cum-diesel(dual fuel mode).Three types of biomass,i.e.wood chips,pigeon pea stalks and corn cobs were used for generation of producer gas.A producer gas system consisting of a downdraft gasifier,a cooling cum cleaning unit,a filtering unit and a gas air mixing device was designed,fabricated and used to power a 5.25 kW diesel engine on dual fuel mode.Performance of the engine was reported by keeping biomass moisture contents as 8%,12%,16%,and 21%,engine speed as 1 600 r/min and with variable engine loads.The average value of thermal efficiency on dual fuel mode was found slightly lower than that of diesel mode.The specific diesel consumption was found to be 60%-64% less in dual fuel mode than that in diesel mode for the same amount of energy output.The average diesel substitution of 74% was observed with wood chips followed by corn cobs(78%) and pigeon pea stalks(82%).Based on the performance studied,the producer gas may be used as a substitute or as supplementary fuel for diesel conservation,particularly for stationary engines in agricultural operations in the farm.展开更多
All over the world,the management of End-of-life Vehicles(ELV) and Automobile Shredder Residue(ASR) is an increasing issue for the car industry.The setting up of several environmental directives,among others the notio...All over the world,the management of End-of-life Vehicles(ELV) and Automobile Shredder Residue(ASR) is an increasing issue for the car industry.The setting up of several environmental directives,among others the notion of extended producer responsibility,encourage car manufacturers to find alternatives solutions to waste disposal.For 2017,China aims for the recyclability and energy recovery of 95% of total weight of used cars,and in order to reach this rate,the development of some ASR thermal processes could be envisaged.With this research,an overview of ELV management was given and the different solutions about ASR thermal treatment were presented.It is showed that in spite of its big heterogeneity,the high heating value of ASR makes pyrolysis and gasification very interesting,compared to incineration or disposal of in landfills.展开更多
基金supported by the National Natural Science Foundation of China(22168032)the National Key Research and Development Program of China(2023YFC3904302,2023YFB4103500)the Key Projects of Ning Dong Energy and Chemical Industry Base(2023NDKJXMLX022).
文摘A new adsorbent was successfully prepared by hydrothermal treatment and chemical activation through coal gasification fine slag(CGFS)and blue algae(BA)as raw materials and used for CO_(2)capture.The CO_(2)chemisorption capacity of the adsorbent was further enhanced by taking advantage of the nitrogenous bases contained in the BA.In the hydrothermal process,the addition of BA significantly increased the content of pyrrole nitrogen in the adsorbent.In the activation process,pyrrole nitrogen gradually changed into pyridine nitrogen and graphite nitrogen.Increased BA addition result in a higher specific surface area and microporosity of the adsorbent.The CO_(2)adsorption performance test proved that the CGFS-50%-CA sample has the strongest CO_(2)adsorption capacity at low temperature,up to 15.59 cm^(3)/g,which is mainly through physical adsorption,and the CGFS-10%-CA sample has the strongest CO_(2)adsorption capacity at high temperature,up to 7.31 cm^(3)/g,which is mainly through chemical adsorption.CO_(2)uptake of the CGFS-10%-CA sample was well maintained after 10 cycles,with regeneration efficiencies above 99%.The results indicate that the novel adsorbents with coexistence of physical and chemical adsorption have great potential for CO_(2)adsorption applications.
基金Supported by the National Natural Science Foundation of China(51076154)National Key Technology Research&Development Program of 12 th Five-year of China(2011BAD15B05)
文摘Abstract:The aim of this research is to design and operate a 10 kW hot chemical-looping gasification(CLG)unit using Fe2O3/Al2O3as an oxygen carrier and saw dust as a fuel.The effect of the operation temperature on gas composition in the air reactor and the fuel reactor,and the carbon conversion of biomass to CO2and CO in the fuel reactor have been experimentally studied.A total60 h run has been obtained with the same batch of oxygen carrier of iron oxide supported with alumina.The results show that CO and H2concentrations are increased with increasing temperature in the fuel reactor.It is also found that with increasing fuel reactor temperature,both the amount of residual char in the fuel reactor and CO2concentration of the exit gas from the air reactor are degreased.Carbon conversion rate and gasification efficiency are increased by increasing temperature and H2production at 870℃reaches the highest rate.Scanning electron microscopy(SEM),X-ray diffraction(XRD)and BET-surface area tests have been used to characterize fresh and reacted oxygen carrier particles.The results display that the oxygen carrier activity is not declined and the specific surface area of the oxygen carrier particles is not decreased significantly.
基金Projects(DEC-2011/01/B/ST8/07394,DEC-2011/01/D/ST8/07399)supported by the Polish National Centre for Science(NCN)
文摘Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out using an integrated system consisting of the boiler and a fixed-bed 60 kW (GazEla) gasification reactor.The process gas was continuously introduced above the coal burner of the boiler.The process parameters of the boiler and the gasifier were also measured and compared with the other units.Characteristic NOx emissions from automatic and manually operated boilers were also presented.
基金Project(2013020137)supported by the Natural Science Foundation of Liaoning Province,ChinaProject(2015-36)supported by Rural Energy Comprehensive Construction Foundation of the Ministry of Agriculture,China
文摘The gasification industries make use of biomass residue as feedstock to produce synthesis gas,but the gasification of this waste biomass generates tons of ash everyday.Performance properties and agglomeration behavior of corncob ash(CCA) collected from the gasification of corncobs in a pilot-scale gasification station were investigated by using some experimental methods.Based on the chemical composition results,the agglomeration tendency of CCA from combustion and gasification process was also analyzed.Chemical analysis shows that the fly ash is mainly composed of inorganic matters formed by K,Mg,Ca,Na,Fe,Al,S,etc.The agglomeration characteristics indicate that the slagging degree increases with the increase of ashing temperature,and the slagging tendency of these CCA samples from gasification or combustion is different with various slagging indices.All CCA samples from combustion or gasification can cause slagging/fouling problems in thermal conversion systems.The applications of CCA are closely related to its performances,and CCA has the potential to be used in various fields,for example,as a material for ceramic products and activated carbon,as an adsorbent,as a crude fertilizer,and as a structural material.
文摘Producer gas through gasification of biomass can be used as an alternate fuel in rural areas due to high potential of biomass resources in India.Experiments were conducted to study the performance of a diesel engine(four stroke,single cylinder,5.25 kW) with respect to its thermal efficiency,specific fuel consumption and diesel substitution by use of diesel alone and producer gas-cum-diesel(dual fuel mode).Three types of biomass,i.e.wood chips,pigeon pea stalks and corn cobs were used for generation of producer gas.A producer gas system consisting of a downdraft gasifier,a cooling cum cleaning unit,a filtering unit and a gas air mixing device was designed,fabricated and used to power a 5.25 kW diesel engine on dual fuel mode.Performance of the engine was reported by keeping biomass moisture contents as 8%,12%,16%,and 21%,engine speed as 1 600 r/min and with variable engine loads.The average value of thermal efficiency on dual fuel mode was found slightly lower than that of diesel mode.The specific diesel consumption was found to be 60%-64% less in dual fuel mode than that in diesel mode for the same amount of energy output.The average diesel substitution of 74% was observed with wood chips followed by corn cobs(78%) and pigeon pea stalks(82%).Based on the performance studied,the producer gas may be used as a substitute or as supplementary fuel for diesel conservation,particularly for stationary engines in agricultural operations in the farm.
文摘All over the world,the management of End-of-life Vehicles(ELV) and Automobile Shredder Residue(ASR) is an increasing issue for the car industry.The setting up of several environmental directives,among others the notion of extended producer responsibility,encourage car manufacturers to find alternatives solutions to waste disposal.For 2017,China aims for the recyclability and energy recovery of 95% of total weight of used cars,and in order to reach this rate,the development of some ASR thermal processes could be envisaged.With this research,an overview of ELV management was given and the different solutions about ASR thermal treatment were presented.It is showed that in spite of its big heterogeneity,the high heating value of ASR makes pyrolysis and gasification very interesting,compared to incineration or disposal of in landfills.
