期刊文献+
共找到2,771篇文章
< 1 2 139 >
每页显示 20 50 100
Variable structure guidance law for attacking surface maneuver targets 被引量:16
1
作者 Han Yanhua Xu Bo 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2008年第2期337-341,共5页
The characteristics of surface maneuver targets are analyzed and a 3-D relative motion model for missiles and targets is established. A variable structure guidance law is designed considering the characteristics of ta... The characteristics of surface maneuver targets are analyzed and a 3-D relative motion model for missiles and targets is established. A variable structure guidance law is designed considering the characteristics of targets. In the guidance law, the distance between missiles and targets as well as the missile-target relative velocity are all substituted by estimation values. The estimation errors, the target's velocity, and the maneuver acceleration are all treated as bounded disturbance. The guidance law proposed can be implemented conveniently in engineering with little target information. The performance of the guidance system is analyzed theoretically and the numerical simulation result shows the effectiveness of the guidance law. 展开更多
关键词 air-to-surface missile guidance law variable structure control surface maneuver target.
在线阅读 下载PDF
Switching disturbance rejection attitude control of near space vehicles with variable structure 被引量:2
2
作者 GONG Ligang WANG Qing DONG Chaoyang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2019年第1期167-179,共13页
A switching disturbance rejection attitude control law is proposed for a near space vehicle(NSV) with variable structure.The multiple flight modes, system uncertainties and disturbances of the NSV are taken into accou... A switching disturbance rejection attitude control law is proposed for a near space vehicle(NSV) with variable structure.The multiple flight modes, system uncertainties and disturbances of the NSV are taken into account based on switched nonlinear systems. Compared with traditional backstepping design methods,the proposed method utilizes the added integrals of attitude angle and angular rate tracking errors to further decrease the tracking errors. Moreover, to reduce the computation complexity, a rapid convergent differentiator is employed to obtain the derivative of the virtual control command. Finally, for disturbance rejection, based on the idea from the extended state observer(ESO), two disturbance observers are designed by using non-smooth functions to estimate the disturbances in the switched nonlinear systems. All signals of the closed-loop system are proven to be uniformly ultimately bounded under the Lyapunov function framework. Simulation results demonstrate the effectiveness of the proposed control scheme. 展开更多
关键词 near space vehicle (NSV) variable structure SWITCHED nonlinear system EXTENDED state OBSERVER (ESO).
在线阅读 下载PDF
Optimal variable structure control with sliding modes for unstable processes 被引量:4
3
作者 KUMAR Satyendra AJMERI Moina 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第10期3147-3158,共12页
In this work,a variable structure control(VSC)technique is proposed to achieve satisfactory robustness for unstable processes.Optimal values of unknown parameters of VSC are obtained using Whale optimization algorithm... In this work,a variable structure control(VSC)technique is proposed to achieve satisfactory robustness for unstable processes.Optimal values of unknown parameters of VSC are obtained using Whale optimization algorithm which was recently reported in literature.Stability analysis has been done to verify the suitability of the proposed structure for industrial processes.The proposed control strategy is applied to three different types of unstable processes including non-minimum phase and nonlinear systems.A comparative study ensures that the proposed scheme gives superior performance over the recently reported VSC system.Furthermore,the proposed method gives satisfactory results for a cart inverted pendulum system in the presence of external disturbance and noise. 展开更多
关键词 variable structure control sliding mode control Whale optimization algorithm ROBUSTNESS non-linear system
在线阅读 下载PDF
Compensation for secondary uncertainty in electro-hydraulic servo system by gain adaptive sliding mode variable structure control 被引量:11
4
作者 张友旺 桂卫华 《Journal of Central South University of Technology》 EI 2008年第2期256-263,共8页
Based on consideration of the differential relations between the immeasurable variables and measurable variables in electro-hydraulic servo system,adaptive dynamic recurrent fuzzy neural networks(ADRFNNs) were employe... Based on consideration of the differential relations between the immeasurable variables and measurable variables in electro-hydraulic servo system,adaptive dynamic recurrent fuzzy neural networks(ADRFNNs) were employed to identify the primary uncertainty and the mathematic model of the system was turned into an equivalent linear model with terms of secondary uncertainty.At the same time,gain adaptive sliding mode variable structure control(GASMVSC) was employed to synthesize the control effort.The results show that the unrealization problem caused by some system's immeasurable state variables in traditional fuzzy neural networks(TFNN) taking all state variables as its inputs is overcome.On the other hand,the identification by the ADRFNNs online with high accuracy and the adaptive function of the correction term's gain in the GASMVSC make the system possess strong robustness and improved steady accuracy,and the chattering phenomenon of the control effort is also suppressed effectively. 展开更多
关键词 electro-hydraulic servo system adaptive dynamic recurrent fuzzy neural network(ADRFNN) gain adaptive slidingmode variable structure control(GASMVSC) secondary uncertainty
在线阅读 下载PDF
Adaptive variable structure control for large-scale time-delayed systems with unknown nonlinear dead-zone 被引量:1
5
作者 Shen Qikun Zhang Tianping 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2007年第4期865-870,共6页
The problem of adaptive fuzzy control for a class of large-scale, time-delayed systems with unknown nonlinear dead-zone is discussed here. Based on the principle of variable structure control, a design scheme of adapt... The problem of adaptive fuzzy control for a class of large-scale, time-delayed systems with unknown nonlinear dead-zone is discussed here. Based on the principle of variable structure control, a design scheme of adaptive, decentralized, variable structure control is proposed. The approach removes the conditions that the dead-zone slopes and boundaries are equal and symmetric, respectively. In addition, it does not require that the assumptions that all parameters of the nonlinear dead-zone model and the lumped uncertainty are known constants. The adaptive compensation terms of the approximation errors axe adopted to minimize the influence of modeling errors and parameter estimation errors. By theoretical analysis, the closed-loop control system is proved to be semiglobally uniformly ultimately bounded, with tracking errors converging to zero. Simulation results demonstrate the effectiveness of the approach. 展开更多
关键词 nonlinear dead-zone decentralized control adaptive control variable structure control
在线阅读 下载PDF
Decentralized Variable Structure Control of Complex Giant Singular Uncertainty Systems 被引量:1
6
作者 Wen Xiangcai&Liu Yongqing (Department of Automation, South China University of Technology Guangzhou, 510641, P. R. China.) 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 1996年第1期23-34,共12页
This paper, at the first time, considers the problem of decentralized variable structure control of complex giant singular uncertainty systems by using the property of diagonally dominant matrix and Frobenius-Person t... This paper, at the first time, considers the problem of decentralized variable structure control of complex giant singular uncertainty systems by using the property of diagonally dominant matrix and Frobenius-Person theorem. The splendid selection of switching manifold for each subsystem makes the design relatively straightforward and can be easily realized. An illustrate example is given. 展开更多
关键词 Complex giant singular uncertainty systems Multiple input interconnected Decentralized variable structure control Sliding mode Completely controllable.
在线阅读 下载PDF
Stabilization Variable Structure Control for Singular Decoupling Motor System
7
作者 Zou, Wenxun Liu, Yongqing 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 1997年第1期65-72,共8页
This paper describes the important application of variable structure control (VSC) theory on induction motor (IM) decoupling control system. A design scheme using singular system variable structure control method for ... This paper describes the important application of variable structure control (VSC) theory on induction motor (IM) decoupling control system. A design scheme using singular system variable structure control method for a decoupling IM system is presented. The scheme is shown to be robust to parametric variations and external disturbances. Simulation results show the stability and effectiveness of the proposed scheme 展开更多
关键词 Singular system Sliding mode variable structure control Decoupling control Switch- ing function.
在线阅读 下载PDF
Variable Structure Model Reference Adaptive Control with Unknown High Frequency Gain Sign 被引量:2
8
作者 DONG Wen-Han SUN Xiu-Xia LIN Yan 《自动化学报》 EI CSCD 北大核心 2007年第4期404-408,共5页
可变结构模型引用为有比一个和未知高频率获得符号大的相对的度的工厂的适应控制被建议。一个切换的计划基于为靠近的环系统的第一个辅助错误设计的监视功能被介绍。在至多切换和追踪的错误的一个有限数字收敛到能被适当地选择一些设计... 可变结构模型引用为有比一个和未知高频率获得符号大的相对的度的工厂的适应控制被建议。一个切换的计划基于为靠近的环系统的第一个辅助错误设计的监视功能被介绍。在至多切换和追踪的错误的一个有限数字收敛到能被适当地选择一些设计参数使任意地小的一个剩余集合以后,在监视函数的管理下面,切换停止,这被显示出在至多切换和追踪的错误的一个有限数字收敛到能被适当地选择一些设计参数使任意地小的一个剩余集合以后。 展开更多
关键词 混合控制 自适应系统 频率 放大信号
在线阅读 下载PDF
Design of Neural Network Variable Structure Reentry Control System for Reusable Launch Vehicle 被引量:3
9
作者 呼卫军 周军 《Defence Technology(防务技术)》 SCIE EI CAS 2008年第3期191-197,共7页
A flight control system is designed for a reusable launch vehicle with aerodynamic control surfaces and reaction control system based on a variable-structure control and neural network theory.The control problems of c... A flight control system is designed for a reusable launch vehicle with aerodynamic control surfaces and reaction control system based on a variable-structure control and neural network theory.The control problems of coupling among the channels and the uncertainty of model parameters are solved by using the method.High precise and robust tracking of required attitude angles can be achieved in complicated air space.A mathematical model of reusable launch vehicle is presented first,and then a controller of flight system is presented.Base on the mathematical model,the controller is divided into two parts:variable-structure controller and neural network module which is used to modify the parameters of controller.This control system decouples the lateraldirectional tunnels well with a neural network sliding mode controller and provides a robust and de-coupled tracking for mission angle profiles.After this a control allocation algorithm is employed to allocate the torque moments to aerodynamic control surfaces and thrusters.The final simulation shows that the control system has a good accurate,robust and de-coupled tracking performance.The stable state error is less than 1°,and the overshoot is less than 5%. 展开更多
关键词 飞行技术 自动控制 运输器 神经网络
在线阅读 下载PDF
Adaptive synchronization of a class of chaotic systems via variable structure control
10
作者 Li Huiguang Zhang Xinying Guan Xinping 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2005年第4期858-861,865,共5页
The synchronization problem under two cases is considered. One is that the bound on the uncertainty existing in the controller is known, the other is that the bound is unknown. In the latter case, the simple adaptatio... The synchronization problem under two cases is considered. One is that the bound on the uncertainty existing in the controller is known, the other is that the bound is unknown. In the latter case, the simple adaptation laws for upper bound on the norm of the uncertainty is proposed. Using this adaptive upper bound, a variable structure control is designed. The proposed method does not guarantee the convergence of the adaptive upper bound to the real one but makes the system asymptotically stable. 展开更多
关键词 chaotic synchronization UNCERTAINTY variable structure control.
在线阅读 下载PDF
A Variable Structure Model Reference Adaptive Control
11
作者 Yao Yu (School of Astronautics) 《哈尔滨工业大学学报》 EI CAS CSCD 北大核心 1990年第3期62-70,共9页
A variable structure model reference adaptive control problem for the nonlinear system is studied in this paper. First, according to the relative degree concept of th nonlinear control system an error equation between... A variable structure model reference adaptive control problem for the nonlinear system is studied in this paper. First, according to the relative degree concept of th nonlinear control system an error equation between the outputs of the reference model and the controlled plant is derived. Then, by using the variable structrue control method, an algorithm of variable structure model reference adaptive control is deduced on the basis of a new concept of reaching law. The definition of the SISO system is introduced into the MIMO nonlinear system. Finally, as an example, a pendulum nonlinear control system is simulated to demonstrated the effectiveness of the method. The results show that the method has some advantages: the design is simple, intuitive and easy to be realized in engineering. Besides, it is of practical significance for the synthesis of nonlinear control systems. 展开更多
关键词 变结构控制 自适应控制 非线性系统 相关度 变结构模型
在线阅读 下载PDF
一类线性errors-in-variables模型的参数强相合估计及其a.s.收敛速度 被引量:1
12
作者 程龙生 姚景尹 《高校应用数学学报(A辑)》 CSCD 北大核心 1996年第3期313-320,共8页
本文讨论了如下一类线性errors-in-variables模型——多元线性结构关系模型β′xk+α=0,ξk=xk+εk.{k=1,2,…,n.其中,{xk:k=1,2,…,n}为一组i.i.d.的m维随机向量,{... 本文讨论了如下一类线性errors-in-variables模型——多元线性结构关系模型β′xk+α=0,ξk=xk+εk.{k=1,2,…,n.其中,{xk:k=1,2,…,n}为一组i.i.d.的m维随机向量,{εk:k=1,2,…,n}是i.i.d.的随机误差,E(ε1)=0,Var(ε1)=σ2Im.且{xk:k=1,2,…,n}与{εk:k=1,2,…,n}相互独立.在一些条件下,我们证明了估计量β,α,σ2的强相合性、唯一性,并给出了估计量的收敛速度为o(n-1-1q),这里q∈[1,2). 展开更多
关键词 收敛速度 线性模型 强相合估计 多元分析
在线阅读 下载PDF
Reliability analysis for aeroengine turbine disc fatigue life with multiple random variables based on distributed collaborative response surface method 被引量:2
13
作者 高海峰 白广忱 +1 位作者 高阳 鲍天未 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第12期4693-4701,共9页
The fatigue life of aeroengine turbine disc presents great dispersion due to the randomness of the basic variables,such as applied load,working temperature,geometrical dimensions and material properties.In order to am... The fatigue life of aeroengine turbine disc presents great dispersion due to the randomness of the basic variables,such as applied load,working temperature,geometrical dimensions and material properties.In order to ameliorate reliability analysis efficiency without loss of reliability,the distributed collaborative response surface method(DCRSM) was proposed,and its basic theories were established in this work.Considering the failure dependency among the failure modes,the distributed response surface was constructed to establish the relationship between the failure mode and the relevant random variables.Then,the failure modes were considered as the random variables of system response to obtain the distributed collaborative response surface model based on structure failure criterion.Finally,the given turbine disc structure was employed to illustrate the feasibility and validity of the presented method.Through the comparison of DCRSM,Monte Carlo method(MCM) and the traditional response surface method(RSM),the results show that the computational precision for DCRSM is more consistent with MCM than RSM,while DCRSM needs far less computing time than MCM and RSM under the same simulation conditions.Thus,DCRSM is demonstrated to be a feasible and valid approach for improving the computational efficiency of reliability analysis for aeroengine turbine disc fatigue life with multiple random variables,and has great potential value for the complicated mechanical structure with multi-component and multi-failure mode. 展开更多
关键词 complicated mechanical structure reliability analysis multiple random variables multi-component and multi-failure mode distributed collaborative response surface method
在线阅读 下载PDF
External blast load factors for dome structures based on reliability
14
作者 Shao-bo Qi Guang-yan Huang +2 位作者 Xu-dong Zhi Feng Fan Richard GJFlay 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第2期170-182,共13页
Dome structures have been used extensively for industrial,residential,and military infrastructure.Therefore,it is necessary to understand the damage risk potential for such structures for blast-resistant design consid... Dome structures have been used extensively for industrial,residential,and military infrastructure.Therefore,it is necessary to understand the damage risk potential for such structures for blast-resistant design considerations.This paper investigates the effect of blast load variability on the design value and the structural dynamic response.Therefore,the sources of uncertainty in the external blast load on dome structures were discussed firstly.Then based on the probabilistic blast load model for the dome,the rationality of a deterministic mass-increase safety method was assessed.It was found that previous deterministic design method cannot provide a consistent and sound assurance factor or reliability index on the entire dome roof.In addition,it was also proved that the assurance-based load method fails to ensure compliance with structural safety design standards on the dome roof when compared with the reliability-based blast method.A sensitivity analysis on the probabilistic blast load was conducted,and the results indicate that stand-off distance and explosive mass both act as dominant sources to influence the mean and variability of blast load.Therefore,based on the Latin hypercube sampling method,a reliability-based external blast load factor technique was proposed.This technique was further used to estimate structural damage levels of a single-layer reticulated dome under different reliability requirements,associated with a low,medium,and high level of protection grades for a specific explosion scenario,and it indicated that this technique can be useful in the building design to achieve a higher structural anti-explosion capacity.This study herein can serve as a reference for the calculation method of designed blast load. 展开更多
关键词 Dome structure Airblast variability Deterministic design Assurance factor Reliability-based blast load factor structural damage levels
在线阅读 下载PDF
Unascertained Factor Method of Dynamic Characteristic Analysis for Antenna Structures
15
作者 朱增青 梁震涛 陈建军 《Defence Technology(防务技术)》 SCIE EI CAS 2008年第3期167-172,共6页
The dynamic characteristic analysis model of antenna structures is built,in which the structural physical parameters and geometrical dimensions are all considered as unascertained variables.And a structure dynamic cha... The dynamic characteristic analysis model of antenna structures is built,in which the structural physical parameters and geometrical dimensions are all considered as unascertained variables.And a structure dynamic characteristic analysis method based on the unascertained factor method is given.The computational expression of structural characteristic is developed by the mathematics expression of unascertained factor and the principles of unascertained rational numbers arithmetic.An example is given,in which the possible values and confidence degrees of the unascertained structure characteristics are obtained.The calculated results show that the method is feasible and effective. 展开更多
关键词 计算数学 固体力学 结构动力学 性状分析
在线阅读 下载PDF
An On-Line Modeling Based Kalman Filtering Process for Time-Interval-Variable Sequences with Application to Astronomic Surveying
16
作者 韩建国 孙才红 李彦琴 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2003年第2期52-56,共5页
The problem of variable sampling time interval which appears in application of Kalman Filtering is analyzed and the corresponding filtering process with or without present transition matrix is suggested, then an appli... The problem of variable sampling time interval which appears in application of Kalman Filtering is analyzed and the corresponding filtering process with or without present transition matrix is suggested, then an application experiment for astronomical surveying is introduced. In this process, the known stochastically variable sampling time intervals play the roles as deterministic input sequences of the state-space description, and the corresponding matrix and (if needed) state transition matrix can be established by performing real-time and structure-linear system identification. 展开更多
关键词 Kalman filtering variable sampling time interval Real-time and structure-linear system identification.
在线阅读 下载PDF
电动汽车液压ABS滑模变结构模糊PID控制设计
17
作者 张杰飞 张昊 《机械设计与制造》 北大核心 2025年第4期237-240,245,共5页
为了进一步提高汽车防抱死制动系统(ABS)控制效率和运行平稳性,设计了一种电动汽车液压ABS滑模变结构模糊PID控制方法。在分析液压ABS系统的组成的基础上,构建ABS滑模变结构控制器。在MATLAB/SIMULINK平台建立了模糊PID的控制系统,分别... 为了进一步提高汽车防抱死制动系统(ABS)控制效率和运行平稳性,设计了一种电动汽车液压ABS滑模变结构模糊PID控制方法。在分析液压ABS系统的组成的基础上,构建ABS滑模变结构控制器。在MATLAB/SIMULINK平台建立了模糊PID的控制系统,分别从不同高低附着系数路面以及不同负载工况两方面开展仿真分析。研究结果表明:当路面属于高附着系数时,模糊PID控制后滑移率达到了一个合适的范围,车辆获得了最大制动强度,极大缩短制动距离。在(60~20)km/h范围内进行制动时,轴间滑模控制能够与前后轴制动力分配高效匹配,制动效果理想。处于高-低附路面工况下时,模糊PID控制模式比常规制动与ABS滑模制动性能更优。模糊PID制动快速达到了稳定制动状态。 展开更多
关键词 ABS控制 模糊PID MATLAB平台 滑模变结构
在线阅读 下载PDF
复杂网络自适应柔性变结构外同步控制
18
作者 孙艳琴 吴怀宇 《控制理论与应用》 北大核心 2025年第5期1048-1056,共9页
本文研究具有外部时变干扰的两个复杂网络外同步问题.为加强网络的抗干扰能力和保证外部扰动的精确抑制,提出了一种基于扰动观测器的自适应柔性变结构控制(DO-ASVSC)策略.首先,利用观测器将外部干扰等效到输入控制端来实现对干扰的完全... 本文研究具有外部时变干扰的两个复杂网络外同步问题.为加强网络的抗干扰能力和保证外部扰动的精确抑制,提出了一种基于扰动观测器的自适应柔性变结构控制(DO-ASVSC)策略.首先,利用观测器将外部干扰等效到输入控制端来实现对干扰的完全控制,其适用于任意一个复杂网络含扰动,也适用于同时具有扰动的两个网络,扩大了应用范围.其次,结合自适应控制思想,改进动态柔性变结构控制策略,根据李雅普诺夫稳定性理论和线性不等式技术,推导满足外同步条件的有关定理.因所设计的鲁棒控制器不含符号函数,减少了抖振现象,避免了因高频切换控制信号可能造成执行器的损坏现象.最后,通过数值算例,验证了控制方案的有效性和优越性. 展开更多
关键词 复杂网络 同步 扰动观测器 抖振 自适应柔性变结构控制
在线阅读 下载PDF
模糊技能多映射的变精度模型与构建知识结构的矩阵方法
19
作者 杨竞菁 李进金 王鸿伟 《郑州大学学报(理学版)》 北大核心 2025年第5期78-87,共10页
基于变精度α-模型构建知识结构是当前研究的热点之一。根据阈值取值范围的不同拓展了三种基于模糊技能多映射的变精度能力模型,讨论了它们所构建的知识结构的性质,并证明了由它们构建的知识结构族是一致的。在此基础上,提出基于模糊技... 基于变精度α-模型构建知识结构是当前研究的热点之一。根据阈值取值范围的不同拓展了三种基于模糊技能多映射的变精度能力模型,讨论了它们所构建的知识结构的性质,并证明了由它们构建的知识结构族是一致的。在此基础上,提出基于模糊技能多映射构建知识结构的矩阵方法,并通过实验验证了方法的可行性和有效性,分析了模糊技能多映射中问题数、技能数对算法执行时间和空间的影响。 展开更多
关键词 知识空间 知识结构 模糊技能多映射 变精度能力模型
在线阅读 下载PDF
热分析获取锅炉内煤着火特性——Part Ⅱ:本征反应动力学
20
作者 刘洋 石泽正 +7 位作者 陈朝帅 苟皓语 陶继业 徐世明 余波 赵培涛 傅培舫 周怀春 《煤炭学报》 北大核心 2025年第4期2246-2261,共16页
煤焦的本征反应动力学模型是计算流体力学(CFD)模拟锅炉内煤着火燃烧速率所需的关键子模型,通常可由热分析获得。热分析反应动力学的研究虽然已发展了数十年,但仍然存在3个问题:(1)非等温和等温动力学参数的不统一;(2)定值动力学参数和... 煤焦的本征反应动力学模型是计算流体力学(CFD)模拟锅炉内煤着火燃烧速率所需的关键子模型,通常可由热分析获得。热分析反应动力学的研究虽然已发展了数十年,但仍然存在3个问题:(1)非等温和等温动力学参数的不统一;(2)定值动力学参数和变动力学参数均值的不统一;(3)缺乏不含不确定参数的通用动力学模型,如常用的n级动力学模型、随机孔模型和自催化模型分别含有不确定性参数,如反应级数n、结构参数ψ、反应指数a和c。为解决上述问题,提出了通用表面活化函数模型GSAFM,其反应机理函数f(X)=1-X(X为转化率),且活化能EX和指前因子AX是随转化率变化的。采用4种等转化率法(变动力学参数模型)包括等温(ISO)GSAFM、非等温(NON)GSAFM、Flynn-Wall-Ozawa(FWO)和Kissinger-Akahira-Sunose(KAS),以及一种定值动力学模型ISAFM,对将军庙(JJM)和红沙泉(HSQ)煤焦的非等温和等温燃烧的本征反应速率进行了预测。结果表明,ISO GSAFM具有最好的预测效果;FWO和KAS的预测效果很差,主要由于这2种模型涉及的温度积分近似处理给EX的求取带来了一定的误差,该误差在求取AX时呈指数级放大。ISOGSAFM获取的煤焦等温燃烧的EX均值为141k J/mol,与ISAFM获取的146 k J/mol接近,从而解决了问题(2);其获取的动力学参数可以很好地预测煤焦非等温燃烧的本征反应速率,表明非等温和等温试验可以共用ISO GSAFM获取的动力学参数,即解决了问题(1);其f(X)=1–X,具有不含不确定参数的通用性,即解决了问题(3)。ISO GSAFM得到的煤焦的EX在着火区间达到最大值,这一现象表明,煤在锅炉内的着火过程是其燃烧过程中最困难的环节;随后,EX由于煤焦燃烧进入稳定阶段而逐渐减小,但在反应后期会转变为快速增大的趋势,这符合煤焦在反应后期存在失活现象的事实。因此,ISO GSAFM在解决问题(1)~(3)的同时还能解释试验现象,有望为以基于定值动力学模型的CFD模拟提供新的本征反应动力学子模型。同种煤阶的JJM和HSQ煤焦存在理化结构上的差异,但两者的EX随转化率变化的趋势相似且大小差异小于5%,采用各自变动力学参数的算数平均可对其本征反应速率进行准确预测,表明同种煤阶的不同煤焦的本征反应速率可以用基于GSAFM的均值动力学参数进行预测,即有望实现同一种煤阶的煤焦反应速率采用同一种变动力学参数(多样本的均值)进行预测。此外,GSAFM表明煤焦的EX只与其化学结构相关,利用变活化能的特征值可精细化地研究煤焦的化学结构对其本征反应性影响的内在机理,如前述的着火困难和失活机理等;用煤焦的化学结构预测出EX后,可通过GSAFM直接预测出煤焦的本征反应速率;上述关联方法为煤焦结构与反应性的研究提供了新的思路。 展开更多
关键词 热分析 通用表面活化函数模型 等转化率法 本征反应动力学 变活化能 着火特性 化学结构
在线阅读 下载PDF
上一页 1 2 139 下一页 到第
使用帮助 返回顶部